EP0388393B1 - Method of treating rolled strip - Google Patents

Method of treating rolled strip Download PDF

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Publication number
EP0388393B1
EP0388393B1 EP90890025A EP90890025A EP0388393B1 EP 0388393 B1 EP0388393 B1 EP 0388393B1 EP 90890025 A EP90890025 A EP 90890025A EP 90890025 A EP90890025 A EP 90890025A EP 0388393 B1 EP0388393 B1 EP 0388393B1
Authority
EP
European Patent Office
Prior art keywords
precipitation
hardened
tensile strength
band
hardenable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP90890025A
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German (de)
French (fr)
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EP0388393A1 (en
Inventor
Rupert Dipl.-Ing. Harreither
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Berndorf Band GmbH
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Berndorf Band GmbH
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Filing date
Publication date
Application filed by Berndorf Band GmbH filed Critical Berndorf Band GmbH
Publication of EP0388393A1 publication Critical patent/EP0388393A1/en
Application granted granted Critical
Publication of EP0388393B1 publication Critical patent/EP0388393B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/02Hardening by precipitation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12806Refractory [Group IVB, VB, or VIB] metal-base component
    • Y10T428/12826Group VIB metal-base component
    • Y10T428/12847Cr-base component

Definitions

  • the invention relates to a method for producing metallic strips with precipitation-hardened materials, in particular with chromium-nickel steels, and to a strip which is produced by this method.
  • Endless belts and press plates are used in single-day, multi-day and double-belt presses and other devices. On such devices laminates, laminates, laminated chipboard, fiberboard and the like. Like. Made, the determination is available for both technical and decorative use.
  • Such pressing tools u. between the press plates or endless strips, consist of alloys, in particular steel.
  • the belt circumference can be between 6 m and 30 m, the belt width between 0.6 m and 3 m.
  • the thickness of the tape is usually between 0.6 mm and 2 mm.
  • the outer surface, that is to say the working surface, of the belts not only serves to carry out the required pressing pressure, that is to say the technical function, but is also intended, if appropriate, to also produce structured embossments on the surface of the product produced.
  • the tape serves as a negative form. Due to the structuring and the pressures to be exerted, it is necessary to increase the wear resistance, while at the same time having a good non-stick effect against the adhesives and resins used, such as those used in the laminates, press materials and laminated chipboard, fiberboard and the like. Like. Are used, should be available. These non-stick properties are particularly advantageously achieved with one or more electroplated hard chrome layers.
  • Cold-rolled austenitic chrome-nickel steels 17/7 with a tensile strength of approximately 1,200 N / mm2 or martensitic chromium-nickel steels 13/4 with a tensile strength of 1,000 N / mm2 are used as materials for such strips.
  • the tensile strength of the martensitic chrome-nickel steel is low, based on the application requirements, whereas the strength of the strip made of austenistic steel, which is reduced due to the low strength of the weld seams at about 700 N / mm2, has a particularly disadvantageous effect.
  • precipitation-hardenable chrome-nickel steels have good weldability, and both the base material and the weld seam can have a tensile strength of up to 1,800 N / mm2, such materials for belts have failed because of the application of hard chrome layers to the already precipitation-hardened steel strip Hydrogen diffusion in the hardened material hydrogen embrittlement occur, which lead to the breakage of the materials.
  • Precipitation-hardenable chromium-nickel steels of this type have become known under the abbreviations 15-7 PH, 17-4 PH, 15-5 PH, 17-7 PH, PH 15-7 Mo, PH 13-8 Mo.
  • the elements responsible for precipitation hardening are copper, aluminum, silicon and titanium.
  • a method for producing galvanically coated spring steel is known.
  • a soft annealed steel is galvanically coated with copper and subjected to a tempering process after a washing and drying process.
  • the coated spring is heated in an oven to a temperature of approx. 810 ° C for two minutes and then quenched to a temperature between 370 ° C and 400 ° C.
  • the invention has for its object to provide a method for producing a metallic tape or a metallic tape which has a high tensile strength both in the base material and in the weld seam and at the same time has a good non-stick property against adhesives and resins, such as those used in the manufacture of laminates and Like. Find use, has, furthermore, no hydrogen embrittlement of the base material and thus lower strength and service life should occur.
  • the process according to the invention for the production of metallic strips with precipitation hardened materials, in particular with chromium-nickel steels, for strip or double strip presses with hot or cold rolled strips is that the strip is made of precipitation hardenable solution-annealed material with a tensile strength equal to or less than 1,250 N / mm2 galvanically with a Hard chrome layer is coated, whereupon the precipitation-hardenable material is precipitation-hardened up to at least a tensile strength of 1,400 N / mm2.
  • the upstream treatment of the strip hydrogen diffusion into the steel surface during the deposition of the chrome layer is completely unexpectedly prevented. Damage due to hydrogen embrittlement of the base material occurs when the tensile strength of the base material is greater than 1,250 N / mm2.
  • the band according to the invention with a precipitation-hardened material consists in that the precipitation-hardened metallic material has a tensile strength of at least 1,400 N / mm2 and a high hardness and at least one side of the band has at least one firmly adhering electrodeposited hard chrome layer.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Electroplating Methods And Accessories (AREA)

Description

Die Erfindung bezieht sich auf ein Verfahren zur Herstellung von metallischen Bändern mit ausscheidungsgehärteten Werkstoffen, insbesondere mit Chrom-Nickelstählen, und auf ein Band, das nach diesem Verfahren hergestellt ist.The invention relates to a method for producing metallic strips with precipitation-hardened materials, in particular with chromium-nickel steels, and to a strip which is produced by this method.

Endlose Bänder und Preßbleche gelangen in Einetagen-, Mehretagen- und Doppelbandpressen sowie anderen Vorrichtungen zum Einsatz. Auf derartigen Vorrichtungen werden Laminate, Schichtpreßstoffe, kaschierte Spanplatten, Faserplatten u. dgl. hergestellt, wobei die Bestimmung sowohl zur technischen als auch dekorativen Verwendung vorliegt. Derartige Preßwerkzeuge, u. zw. die Preßbleche bzw. endlosen Bänder, bestehen aus Legierungen, insbesondere aus Stahl. Entsprechend den zum Einsatz kommenden Einrichtungen kann der Bandumfang zwischen 6 m und 30 m, die Bandbreite zwischen 0,6 m und 3 m betragen. Die Dicke des Bandes beträgt in der Regel zwischen 0,6 mm und 2 mm. Die Außenoberfläche, also die Arbeitsfläche, der Bänder dient nicht alleine dazu, den erforderlichen Preßdruck, also die technische Funktion, auszuführen, sondern soll gegebenenfalls auch zur Herstellung von strukturierten Prägungen auf der Oberfläche des erzeugten Produktes führen. Das Band dient hiebei als Negativform. Auf Grund der Strukturierung und der auszuübenden Drucke ist es erforderlich, den Verschleißwiderstand zu erhöhen, wobei gleichzeitig eine gute Antihaftwirkung gegenüber den zum Einsatz gelangenden Klebern und Harzen, wie sie bei den Laminaten, Preßstoffen und kaschierten Spanplatten, Faserplatten u. dgl. zum Einsatz kommen, vorliegen soll. Diese Antihafteigenschaften werden besonders vorteilhaft mit einer oder mehreren galvanisch aufgebrachten Hartchromschichten erreicht.Endless belts and press plates are used in single-day, multi-day and double-belt presses and other devices. On such devices laminates, laminates, laminated chipboard, fiberboard and the like. Like. Made, the determination is available for both technical and decorative use. Such pressing tools, u. between the press plates or endless strips, consist of alloys, in particular steel. Depending on the equipment used, the belt circumference can be between 6 m and 30 m, the belt width between 0.6 m and 3 m. The thickness of the tape is usually between 0.6 mm and 2 mm. The outer surface, that is to say the working surface, of the belts not only serves to carry out the required pressing pressure, that is to say the technical function, but is also intended, if appropriate, to also produce structured embossments on the surface of the product produced. The tape serves as a negative form. Due to the structuring and the pressures to be exerted, it is necessary to increase the wear resistance, while at the same time having a good non-stick effect against the adhesives and resins used, such as those used in the laminates, press materials and laminated chipboard, fiberboard and the like. Like. Are used, should be available. These non-stick properties are particularly advantageously achieved with one or more electroplated hard chrome layers.

Die zum Einsatz gelangenden Bänder sollen eine gute Formstabilität bei den thermischen und mechanischen Beanspruchungen während des Preßvorganges aufweisen und insbesondere plastische Verformungen vermeiden, wobei gleichzeitig aus Gründen einer vorteilhaften Energiebilanz bei dem Arbeitsverfahren die Preßbänder besonders dünn ausgebildet werden sollen. Zur Vermeidung von plastischen, also dauerhaften, Verformungen ist eine hohe Streckgrenze des Bandwerkstoffes bevorzugt.The belts used should have good dimensional stability in the thermal and mechanical stresses during the pressing process and in particular avoid plastic deformations, while at the same time the pressing belts should be made particularly thin for reasons of an advantageous energy balance in the working process. To avoid plastic, i.e. permanent, deformation, a high yield strength of the strip material is preferred.

Als Werkstoffe für derartige Bänder kommen kaltgewalzte austenitische Chrom-Nickelstähle 17/7 mit einer Zugfestigkeit mit etwa 1.200 N/mm² bzw. martensitische Chrom-Nickelstähle 13/4 mit einer Zugfestigkeit um 1.000 N/mm² zum Einsatz. Die Zugfestigkeit des martensitischen Chrom-Nickelstahles ist, bezogen auf die Anwendungserfordernisse, gering, wohingegen die, durch die geringe Festigkeit der Schweißnähte mit etwa 700 N/mm², reduzierte Festigkeit des Bandes aus austenistischem Stahl sich besonders nachteilig auswirkt.Cold-rolled austenitic chrome-nickel steels 17/7 with a tensile strength of approximately 1,200 N / mm² or martensitic chromium-nickel steels 13/4 with a tensile strength of 1,000 N / mm² are used as materials for such strips. The tensile strength of the martensitic chrome-nickel steel is low, based on the application requirements, whereas the strength of the strip made of austenistic steel, which is reduced due to the low strength of the weld seams at about 700 N / mm², has a particularly disadvantageous effect.

Obwohl die ausscheidungshärtbaren Chrom-Nickelstähle eine gute Schweißbarkeit aufweisen, und sowohl das Grundmatrial als auch die Schweißnaht eine Zugfestigkeit bis zu 1.800 N/mm² aufweisen können, sind derartige Werkstoffe für Bänder daran gescheitert, daß bei der Aufbringung von Hartchromschichten auf das bereits ausscheidungsgehärtete Stahlband durch Wasserstoffdiffusion in den gehärteten Werkstoff Wasserstoffversprödungen auftreten, die bis zum Bruch der Werkstoffe führen. Derartige ausscheidungshärtbare Chrom-Nickelstähle sind unter den Kurzbezeichnungen 15-7 PH, 17-4 PH, 15-5 PH, 17-7 PH, PH 15-7 Mo, PH 13-8 Mo bekannt geworden. Als für die Ausscheidungshärtung verantwortlichen Elemente sind Kupfer, Aluminium, Silizium, Titan zu nennen.Although the precipitation-hardenable chrome-nickel steels have good weldability, and both the base material and the weld seam can have a tensile strength of up to 1,800 N / mm², such materials for belts have failed because of the application of hard chrome layers to the already precipitation-hardened steel strip Hydrogen diffusion in the hardened material hydrogen embrittlement occur, which lead to the breakage of the materials. Precipitation-hardenable chromium-nickel steels of this type have become known under the abbreviations 15-7 PH, 17-4 PH, 15-5 PH, 17-7 PH, PH 15-7 Mo, PH 13-8 Mo. The elements responsible for precipitation hardening are copper, aluminum, silicon and titanium.

Aus der CH-A-226.028 wird ein Verfahren zur Verbesserung der Haftung von Chromschichten auf Eisen- und Stahlsubstraten bekannt. Die bessere Haftung zwischen der Chromschichte und dem Untergrund aus Eisen und Stahl soll hiebei durch ein thermisches Diffusionsverfahren verbessert werden. Zwischen der Chromschichte und dem Substrat aus Eisen oder Stahl kann eine weitere Zwischenschichte, beispielsweise aus Nickel oder Kobalt vorgesehen sein.From CH-A-226.028 a method for improving the adhesion of chrome layers on iron and steel substrates is known. The better adhesion between the chrome layer and the iron and steel substrate is to be improved by a thermal diffusion process. A further intermediate layer, for example made of nickel or cobalt, can be provided between the chrome layer and the substrate made of iron or steel.

Aus der GB-A-797.423 wird ein Verfahren zur Herstellung von galvanisch beschichtetem Federstahl bekannt. Es wird hiebei ein weichgeglühter Stahl galvanisch mit Kupfer beschichtet und nach einem Wasch- und Trockenvorgang einem Anlaßvorgang unterzogen. Hiebei wird zuerst die beschichtete Feder auf zwei Minuten in einem Ofen auf eine Temperatur von ca. 810° C erhitzt und anschließend auf eine Temperatur zwischen 370° C und 400° C abgeschreckt.From GB-A-797.423 a method for producing galvanically coated spring steel is known. A soft annealed steel is galvanically coated with copper and subjected to a tempering process after a washing and drying process. First, the coated spring is heated in an oven to a temperature of approx. 810 ° C for two minutes and then quenched to a temperature between 370 ° C and 400 ° C.

Der Erfindung ist zur Aufgabe gesetzt, ein Verfahren zur Herstellug eines metallischen Bandes bzw. ein metallisches Band zu schaffen, das eine hohe Zugfestigkeit sowohl im Grundmaterial als auch in der Schweißnaht aufweist und gleichzeitig eine gute Antihafteigenschaft gegenüber Klebern und Harzen, wie sie bei der Herstellung von Laminaten u. dgl. Verwendung finden, besitzt, wobei weiters keine Wasserstoffversprödung des Grundwerkstoffes und damit geringere Festigkeit und Lebensdauer auftreten soll.The invention has for its object to provide a method for producing a metallic tape or a metallic tape which has a high tensile strength both in the base material and in the weld seam and at the same time has a good non-stick property against adhesives and resins, such as those used in the manufacture of laminates and Like. Find use, has, furthermore, no hydrogen embrittlement of the base material and thus lower strength and service life should occur.

Das erfindungsgemäße Verfahren zur Herstellung von metallischen Bändern mit ausscheidungsgehärteten Werkstoffen, insbesondere mit Chrom-Nickelstählen, für Band- oder Doppelbandpressen mit warm- oder kaltgewalzten Bändern besteht darin, daß das Band aus ausscheidungshärtbarem lösungsgeglühtem Werkstoff mit einer Zugfestigkeit gleich oder kleiner 1.250 N/mm² galvanisch mit einer Hartchromschichte beschichtet wird, worauf der ausscheidungshärtbare Werkstoff bis zumindest einer Zugfestigkeit von 1.400 N/mm² ausscheidungsgehärtet wird. Mit der vorgeschalteten Behandlung des Bandes wird völlig unerwartet die Wasserstoffdiffusion in die Stahloberfläche bei der Abscheidung der Chromschichte verhindert. Eine Schädigung durch Wasserstoffversprödung des Grundwerkstoffes tritt dann auf, wenn die Zugfestigkeit desselben größer als 1.250 N/mm² ist.The process according to the invention for the production of metallic strips with precipitation hardened materials, in particular with chromium-nickel steels, for strip or double strip presses with hot or cold rolled strips is that the strip is made of precipitation hardenable solution-annealed material with a tensile strength equal to or less than 1,250 N / mm² galvanically with a Hard chrome layer is coated, whereupon the precipitation-hardenable material is precipitation-hardened up to at least a tensile strength of 1,400 N / mm². With the upstream treatment of the strip, hydrogen diffusion into the steel surface during the deposition of the chrome layer is completely unexpectedly prevented. Damage due to hydrogen embrittlement of the base material occurs when the tensile strength of the base material is greater than 1,250 N / mm².

Das erfindungsgemäße Band mit einem ausscheidungsgehärteten Werkstoff besteht darin, daß der ausscheidungsgehärtete metallische Werkstoff eine Zugfestigkeit von zumindest 1.400 N/mm² und eine hohe Härte aufweist und zumindest eine Seite des Bandes zumindest eine festhaftende galvanisch abgeschiedene Hartchromschichte aufweist.The band according to the invention with a precipitation-hardened material consists in that the precipitation-hardened metallic material has a tensile strength of at least 1,400 N / mm² and a high hardness and at least one side of the band has at least one firmly adhering electrodeposited hard chrome layer.

Claims (2)

  1. Method for manufacturing metal bands with precipitation-hardened materials, in particular with chrome-nickel steels, for band presses or double-band presses with hot-rolled or cold-rolled bands, characterized in that the band of precipitation-hardenable, solution-treated material with a tensile strength equal to or less than 1250 N/mm² is coated galvanically with a hard chrome coating, whereupon the precipitation-hardenable material is precipitation-hardened to at least a tensile strength of 1400 N/mm².
  2. Band manufactured by the method according to claim 1, with a precipitation-hardened material, characterised in that the precipitation-hardened metal material exhibits a tensile strength of at least 1400 N/mm² and a high level of hardness, and at least one side of the band exhibits at least one firmly adhering, galvanically precipitated hard chrome coating.
EP90890025A 1989-02-07 1990-02-05 Method of treating rolled strip Expired - Lifetime EP0388393B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT249/89A AT392488B (en) 1989-02-07 1989-02-07 METHOD FOR TREATING TAPES IN THE HOT AND COLD ROLLED CONDITION
AT249/89 1989-02-07

Publications (2)

Publication Number Publication Date
EP0388393A1 EP0388393A1 (en) 1990-09-19
EP0388393B1 true EP0388393B1 (en) 1994-10-26

Family

ID=3485521

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90890025A Expired - Lifetime EP0388393B1 (en) 1989-02-07 1990-02-05 Method of treating rolled strip

Country Status (5)

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US (1) US5021102A (en)
EP (1) EP0388393B1 (en)
AT (1) AT392488B (en)
DE (1) DE59007538D1 (en)
ES (1) ES2064710T3 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT408088B (en) * 1997-10-14 2001-08-27 Berndorf Band Ges M B H & Co K ENDLESS STEEL TAPE AND METHOD FOR PRODUCING THE SAME
DE19754950A1 (en) * 1997-12-11 1999-06-24 Horst E Kleimann Area elements of iron, steel or special steel covered with a protective layer
AT412198B (en) * 2002-11-04 2004-11-25 Berndorf Band Ges M B H Endless steel band for production of plates, e.g. wood-based and plastic plates with elevations, and chipboard, and for belt presses comprises depressions
SE527180C2 (en) * 2003-08-12 2006-01-17 Sandvik Intellectual Property Rack or scraper blades with abrasion resistant layer and method of manufacture thereof
AT513128B1 (en) * 2012-07-24 2014-02-15 Berndorf Band Gmbh Method for structuring a press belt

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH211118A (en) * 1939-01-30 1940-08-31 Stin Process for producing durable metal coatings.
CH226028A (en) * 1939-12-18 1943-03-15 Kohle Und Eisenforschung Gmbh Process for the production of objects with a corrosion- and heat-resistant chrome coating.
GB797423A (en) * 1954-01-04 1958-07-02 Sidney Geoffrey Young Improvements in the manufacture of electro-plated spring steel
DE1044553B (en) * 1956-02-24 1958-11-20 Dansk Ind Syndikat Cie Use of thermal post-treatment of hard chrome-plated parts
GB934559A (en) * 1961-09-12 1963-08-21 Dreher Manfrid Method of preparing an age-hardened coated metal alloy article
US3615902A (en) * 1969-04-23 1971-10-26 United States Steel Corp Corrosion-resistant steel
JPS5537570B2 (en) * 1974-04-19 1980-09-29
US4007351A (en) * 1974-09-24 1977-02-08 Sandco Ltd. System for installing high strength steel belts
JPS5573888A (en) * 1978-11-22 1980-06-03 Nippon Kokan Kk <Nkk> High corrosion resistant zinc-electroplated steel sheet with coating and non-coating
JPS56163219A (en) * 1980-05-16 1981-12-15 Nisshin Steel Co Ltd Production of cold rolled high-tensile galvanized steel strip having low yield ratio
US4361448A (en) * 1981-05-27 1982-11-30 Ra-Shipping Ltd. Oy Method for producing dual-phase and zinc-aluminum coated steels from plain low carbon steels
CA1270408A (en) * 1987-04-07 1990-06-19 James Alexander Evert Bell Coated article having a base of age-hardened metal
JPH0347357A (en) * 1989-03-24 1991-02-28 Ikuo Hata Folded-plate roof structure
JPH0347358A (en) * 1989-07-12 1991-02-28 Ig Tech Res Inc Structure of joint for panel

Also Published As

Publication number Publication date
ATA24989A (en) 1990-09-15
ES2064710T3 (en) 1995-02-01
US5021102A (en) 1991-06-04
AT392488B (en) 1991-04-10
EP0388393A1 (en) 1990-09-19
DE59007538D1 (en) 1994-12-01

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