EP0357042A2 - Zusammensetzung und Verfahren für die Entwicklung latenter elektrostatischer Bilder - Google Patents
Zusammensetzung und Verfahren für die Entwicklung latenter elektrostatischer Bilder Download PDFInfo
- Publication number
- EP0357042A2 EP0357042A2 EP89116016A EP89116016A EP0357042A2 EP 0357042 A2 EP0357042 A2 EP 0357042A2 EP 89116016 A EP89116016 A EP 89116016A EP 89116016 A EP89116016 A EP 89116016A EP 0357042 A2 EP0357042 A2 EP 0357042A2
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- EP
- European Patent Office
- Prior art keywords
- toner
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- magnetic
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- Prior art date
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- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229940102838 methylmethacrylate Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- DNPFOADIPJWGQH-UHFFFAOYSA-N octan-3-yl prop-2-enoate Chemical compound CCCCCC(CC)OC(=O)C=C DNPFOADIPJWGQH-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229940068921 polyethylenes Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/083—Magnetic toner particles
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/10—Developers with toner particles characterised by carrier particles
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0819—Developers with toner particles characterised by the dimensions of the particles
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/083—Magnetic toner particles
- G03G9/0831—Chemical composition of the magnetic components
Definitions
- the carrier may have a maximum magnetization ⁇ m of 25 to 220 emu/g, preferably 30 to 210 emu/g upon magnetization at 5000 Oe.
- ferrite carriers preferably have a maximum magnetization ⁇ m of 30 to 100 emu/g. With a maximum magnetization ⁇ m of less than 25 emu/g, carrier drag-out will often occur. If the maximum magnetization ⁇ m of the carrier is more than 220 emu/g, the resulting magnetic brush would form a hard head causing scratches on the photoconductor. It is to be noted that these magnetic properties may be measured by means of a vibration magnetometer.
- the magnetic powder preferably has a mean particle diameter of from 0.01 to 10 ⁇ m, more preferably from 0.05 to 3 ⁇ m.
- FIG. 1 schematically illustrates a developing unit of the magnetic brush development type.
- the developing unit includes a developing tank 2 for receiving a developing composition 1 therein, a sleeve roll 3, and a magnetic roll 4 coaxially received in the sleeve 3 for free rotation. Relative rotation is induced between the sleeve roll 3 and the magnet roll 4 by rotating either one or both of them.
- a blade 5 is spaced from the sleeve roll 3 to define a gap between the blade and the sleeve, serving to form a layer of the developing composition on the sleeve roll 3.
- a photoconductor 6, an arcuate section of which is shown in the figure, is disposed in close facing relationship to the sleeve roll 3.
- the carrier should preferably have a mean particle diameter of 15 to 30 ⁇ m.
- Carriers 1 and 3 and Toners A and B are the same as in Example 1.
- Toners C and D are the same as Toners A and B except that Compositions A and B were replaced by the following Compositions C and D, respectively.
- Composition C Magnetic powder BL-500 (Titan Industry K.K.) 55 pbw Styrene-acrylic resin (Nihon Carbide Industry K.K.) 42.5 pbw Polypropylene 550P (Sanyo Chemicals K.K.) 2.5 pbw Aizen Spilon Black TRH (Hodogaya Chemical K.K.) 1 pbw
- Composition D Magnetic powder BL-500 (Titan Industry K.K.) 55 pbw Styrene-acrylic resin (Mitsubishi Rayon K.K.) 41 pbw Polypropylene 550P (Sanyo Chemicals K.K.) 5 pbw Bontron S-34 (Orient Chemical K.K.) 1 pbw Table 5 At
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Developing Agents For Electrophotography (AREA)
- Photoreceptors In Electrophotography (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubrication Of Internal Combustion Engines (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63213812A JP2787687B2 (ja) | 1988-08-30 | 1988-08-30 | 静電潜像現像剤および現像方法 |
JP213812/88 | 1988-08-30 | ||
JP1152978A JP2807743B2 (ja) | 1989-06-15 | 1989-06-15 | 静電潜像現像剤および現像方法 |
JP152978/89 | 1989-06-15 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0357042A2 true EP0357042A2 (de) | 1990-03-07 |
EP0357042A3 EP0357042A3 (de) | 1991-11-06 |
EP0357042B1 EP0357042B1 (de) | 1998-03-25 |
Family
ID=26481732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89116016A Expired - Lifetime EP0357042B1 (de) | 1988-08-30 | 1989-08-30 | Zusammensetzung und Verfahren für die Entwicklung latenter elektrostatischer Bilder |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0357042B1 (de) |
AT (1) | ATE164459T1 (de) |
AU (1) | AU628074B2 (de) |
CA (1) | CA1338398C (de) |
DE (1) | DE68928614T2 (de) |
DK (1) | DK174456B1 (de) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0452209A1 (de) * | 1990-04-11 | 1991-10-16 | Tomoegawa Paper Co. Ltd. | Magnetischer Toner |
EP0658821A2 (de) * | 1993-11-30 | 1995-06-21 | Konica Corporation | Entwickler vom Zwei-Komponententyp und Bildherstellungsverfahren |
EP0701178A1 (de) * | 1994-09-02 | 1996-03-13 | Mita Industrial Co. Ltd. | Bildherstellungsverfahren |
EP0703503A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0703506A1 (de) * | 1994-09-02 | 1996-03-27 | Mita Industrial Co. Ltd. | Verfahren zur Entwicklung eines elektrostatischen, latenten Bildes |
EP0703504A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0703505A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0703507A1 (de) * | 1994-09-02 | 1996-03-27 | Mita Industrial Co. Ltd. | Bildherstellungsverfahren |
EP0704768A1 (de) * | 1994-08-31 | 1996-04-03 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0704767A1 (de) * | 1994-08-31 | 1996-04-03 | Mita Industrial Co., Ltd. | Entwickler des Zweikomponententyps |
EP0813118A2 (de) * | 1996-06-10 | 1997-12-17 | Mita Industrial Co. Ltd. | Toner für Zweikomponentenentwickler |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2074745A (en) * | 1980-04-09 | 1981-11-04 | Ricoh Kk | Developer for developing latent electostatic images |
DE3140639A1 (de) * | 1980-10-13 | 1982-06-16 | Ricoh Co., Ltd., Tokyo | Elektrophotographisches verfahren |
EP0125606A1 (de) * | 1983-05-11 | 1984-11-21 | Mita Industrial Co. Ltd. | Vorrichtung zur Feststellung des günstigen Zustandes eines Entwicklers in einer Kopiermaschine |
US4675268A (en) * | 1981-11-26 | 1987-06-23 | Konishiroku Photo Industry Co., Ltd. | Process for transfer of a toner image utilizing a magnetic toner containing a binder resin and having gradual softening characteristics |
JPS63276065A (ja) * | 1987-05-07 | 1988-11-14 | Casio Electronics Mfg Co Ltd | 現像剤 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5785060A (en) * | 1980-11-17 | 1982-05-27 | Mita Ind Co Ltd | Composite developer |
US4414321A (en) * | 1980-11-27 | 1983-11-08 | Mita Industrial Co. Ltd. | Dry composite blended magnetic developer of resin encapsulated fine magnetite and resin encapsulated coarse magnetite |
JPS57124356A (en) * | 1981-01-26 | 1982-08-03 | Mita Ind Co Ltd | Binary magnetic developer |
-
1989
- 1989-08-29 CA CA000609726A patent/CA1338398C/en not_active Expired - Fee Related
- 1989-08-29 AU AU40872/89A patent/AU628074B2/en not_active Ceased
- 1989-08-30 DE DE68928614T patent/DE68928614T2/de not_active Expired - Fee Related
- 1989-08-30 AT AT89116016T patent/ATE164459T1/de not_active IP Right Cessation
- 1989-08-30 DK DK198904286A patent/DK174456B1/da not_active IP Right Cessation
- 1989-08-30 EP EP89116016A patent/EP0357042B1/de not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2074745A (en) * | 1980-04-09 | 1981-11-04 | Ricoh Kk | Developer for developing latent electostatic images |
DE3140639A1 (de) * | 1980-10-13 | 1982-06-16 | Ricoh Co., Ltd., Tokyo | Elektrophotographisches verfahren |
US4675268A (en) * | 1981-11-26 | 1987-06-23 | Konishiroku Photo Industry Co., Ltd. | Process for transfer of a toner image utilizing a magnetic toner containing a binder resin and having gradual softening characteristics |
EP0125606A1 (de) * | 1983-05-11 | 1984-11-21 | Mita Industrial Co. Ltd. | Vorrichtung zur Feststellung des günstigen Zustandes eines Entwicklers in einer Kopiermaschine |
JPS63276065A (ja) * | 1987-05-07 | 1988-11-14 | Casio Electronics Mfg Co Ltd | 現像剤 |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN, vol. 13, no. 93 (P-838)[3441], 6th March 1989; & JP-A-63 276 065 (CASIO ELECTRONICS MFG CO., LTD) 14-11-1988 * |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5561018A (en) * | 1990-04-11 | 1996-10-01 | Tomoegawa Paper Co., Ltd. | Magnetic toner |
EP0452209A1 (de) * | 1990-04-11 | 1991-10-16 | Tomoegawa Paper Co. Ltd. | Magnetischer Toner |
EP0658821A2 (de) * | 1993-11-30 | 1995-06-21 | Konica Corporation | Entwickler vom Zwei-Komponententyp und Bildherstellungsverfahren |
EP0658821A3 (de) * | 1993-11-30 | 1995-12-06 | Konishiroku Photo Ind | Entwickler vom Zwei-Komponententyp und Bildherstellungsverfahren. |
US5576134A (en) * | 1993-11-30 | 1996-11-19 | Konica Corporation | Two-component type developer and image forming process |
EP0703503A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0703504A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0703505A1 (de) * | 1994-08-31 | 1996-03-27 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0704768A1 (de) * | 1994-08-31 | 1996-04-03 | Mita Industrial Co., Ltd. | Toner für Zweikomponentenentwickler |
EP0704767A1 (de) * | 1994-08-31 | 1996-04-03 | Mita Industrial Co., Ltd. | Entwickler des Zweikomponententyps |
US5580691A (en) * | 1994-08-31 | 1996-12-03 | Mita Industrial Co., Ltd. | Toner for a two-component type developer |
US5750301A (en) * | 1994-08-31 | 1998-05-12 | Mita Industrial Co., Ltd. | Toner for a two-component type developer |
EP0703507A1 (de) * | 1994-09-02 | 1996-03-27 | Mita Industrial Co. Ltd. | Bildherstellungsverfahren |
EP0703506A1 (de) * | 1994-09-02 | 1996-03-27 | Mita Industrial Co. Ltd. | Verfahren zur Entwicklung eines elektrostatischen, latenten Bildes |
EP0701178A1 (de) * | 1994-09-02 | 1996-03-13 | Mita Industrial Co. Ltd. | Bildherstellungsverfahren |
EP0813118A2 (de) * | 1996-06-10 | 1997-12-17 | Mita Industrial Co. Ltd. | Toner für Zweikomponentenentwickler |
EP0813118A3 (de) * | 1996-06-10 | 1998-01-07 | Mita Industrial Co. Ltd. | Toner für Zweikomponentenentwickler |
Also Published As
Publication number | Publication date |
---|---|
DK428689A (da) | 1990-03-01 |
AU628074B2 (en) | 1992-09-10 |
EP0357042A3 (de) | 1991-11-06 |
DK174456B1 (da) | 2003-03-24 |
DE68928614T2 (de) | 1998-10-22 |
DE68928614D1 (de) | 1998-04-30 |
AU4087289A (en) | 1990-03-08 |
DK428689D0 (da) | 1989-08-30 |
ATE164459T1 (de) | 1998-04-15 |
CA1338398C (en) | 1996-06-18 |
EP0357042B1 (de) | 1998-03-25 |
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