EP0352316A1 - Composition repulsive d'insectes - Google Patents
Composition repulsive d'insectesInfo
- Publication number
- EP0352316A1 EP0352316A1 EP19890901552 EP89901552A EP0352316A1 EP 0352316 A1 EP0352316 A1 EP 0352316A1 EP 19890901552 EP19890901552 EP 19890901552 EP 89901552 A EP89901552 A EP 89901552A EP 0352316 A1 EP0352316 A1 EP 0352316A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- agent
- weight
- composition according
- composition
- toluamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 239000000077 insect repellent Substances 0.000 title claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000005871 repellent Substances 0.000 claims abstract description 15
- 230000002940 repellent Effects 0.000 claims abstract description 15
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 10
- 230000003381 solubilizing effect Effects 0.000 claims abstract description 8
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims abstract description 7
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims abstract description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims abstract description 5
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 5
- 239000003623 enhancer Substances 0.000 claims abstract description 4
- -1 vinyl compound Chemical class 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 239000000284 extract Substances 0.000 claims description 6
- 239000000443 aerosol Substances 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 claims description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003380 propellant Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims description 3
- 244000131522 Citrus pyriformis Species 0.000 claims description 3
- 241000208152 Geranium Species 0.000 claims description 3
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 241000208181 Pelargonium Species 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 240000004460 Tanacetum coccineum Species 0.000 claims description 3
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- 229940015367 pyrethrum Drugs 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 2
- 239000003026 cod liver oil Substances 0.000 claims description 2
- 235000012716 cod liver oil Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229920006158 high molecular weight polymer Polymers 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- WONYMNWUJVKVII-UHFFFAOYSA-N 3,5-diiodothyropropionic acid Chemical compound IC1=CC(CCC(=O)O)=CC(I)=C1OC1=CC=C(O)C=C1 WONYMNWUJVKVII-UHFFFAOYSA-N 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 210000004185 liver Anatomy 0.000 claims 1
- 229940105132 myristate Drugs 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 238000000265 homogenisation Methods 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 241000256103 Simuliidae Species 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229960001631 carbomer Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000008389 polyethoxylated castor oil Substances 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241000256186 Anopheles <genus> Species 0.000 description 1
- 241000256054 Culex <genus> Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241001354481 Mansonia <mosquito genus> Species 0.000 description 1
- 241000256091 Psorophora Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000255628 Tabanidae Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
Definitions
- the present invention relates to an insect repellant composition for application to human skin as well as hair, or clothing, as well as the fur of animals.
- the object of the invention is to provide an insect repellent composition which makes it possible to remedy the main drawbacks presented by known repellent compositions; namely: unpleasant odor and limited duration of effectiveness either by absorption or m abolishing Li on of the composition by the skin, or by perspiration due to high heat or stress or by abrasion of the composition caused in particular by washing the treated surface or by the movement of air on this surface. This is how we observe efficiency reductions of around 60%, compared to a wind-free atmosphere, when the wind reaches a speed of 190m / minute.
- the composition according to the invention comprises at least one active repellant, chosen from extracts of pelargonium, geranium, lavender, pyrethrum, lemon flower, as well as N, N-dié hy1-m-toluamide, a plasticizing agent and an agent amplifying the repellent effect of the above active compounds.
- the plasticizing agent is a vinyl compound.
- the vinyl compound is polyvinylpyrrolidone.
- the amplifying agent is cyclopentane-1-one-2-npentane-3-methyl ethyl ester known under the name of Hedione.
- the composition comprises, by weight, from 30 to 75% of 95% ethanol, from 5 to 50% of N, N-diethyl-m-toluamide, from 0, there 2% of polyvinylpyrrolidone, from 2 to 10% of isopropyl myristate, from 2 to 10% of dipropylene glycol, from 0.1 to 2.5% of amplifier, from 0.1 to 2.5% of a solubilizing homogenizing agent and natural extracts from 0.1 to 2.5%.
- the composition according to the invention which is repellent for most insects and in particular for the following mosquitoes: ⁇ edes Aegypti, Culex, Mansonia, Anopheles, Psorophora, for fleas, ticks, horseflies, black flies, black flies stable, Cerotopogonidae, has the main characteristic of allowing the creation, on covered surfaces and mainly on the skin where the repellant compositions lose their effectiveness as quickly as possible due to absorption, metabolization, perspiration and / or l 'abrasion, a film, which resists time, external conditions as well as changes in the state of the covered surface and which regulates and slows its release from the active ingredients of the composition, in which most of these ingredients remain present active repellents, ingredients whose activity is advantageously increased by the incorporation into the composition of an enhancer, said composition also having the advantage of being made up mainly of natural products which are non-toxic for humans and animals .
- This composition whose odor is pleasant and which contains, according to the invention and as described below, a plasticizing and fixing agent as well as an amplifying agent, has real repulsive activity for a minimum period of 4 to 8 hours which could reach 14 hours depending on external conditions when it is applied in the following quantities, which vary in particular according to outdoor atmospheric conditions, such as the temperature whose rise causes dispersion or abrasion from 0.05 to 0, 2 mg per cm on the skin and
- Said composition which contains polyvinylpyrrolidone, which constitutes the plasticizing and fixing agent for the formation of the abovementioned film, natural active repellent extracts, such as pelargonium, geranium, lavender, pyrethrum, lemon flowers, as well as NN-die hy1-m-toluamide, an amplifier consisting of cyclopentane -l-one-2- npentane-3-methyl ethyl ester whose property is to ensure a synergistic effect with the active repellent extracts, advantageously comprises, by weight, from 30 to 75% of 95% ethanol, from 5 to 50% of N, N-5 diethyl-m-toluamide, from 0.4 to 2% of polyvinylpyrrolidone, from 2 to 10% of isopropyl myristate, from 2 to 10% of dipropylene glycol, from 0.1 to 2.5% of the aforementioned enhancer and from 0.1 to 2.5% of a solubilizing homogenizing
- composition 10 polyoxyethylene nonyl phenyl ether known as "Lamacite" and from 0.1 to 2.5% of natural repellents.
- the aforementioned composition may also comprise a dye improving its appearance, this dye, introduced into the composition at a rate of
- composition comprising, by weight, 65.5% 95% ethanol, 20% N, N-diethyl-m-toluamide, 1% polyvinylpyrrolidone, 8% isopropyl myristate, 4% dipropylene glycol, 0.1% amplifying agent, 0.5% solubilizing homogenizing agent and 0.9%
- the repellant composition can be either in the form of an aerosol, or in the form of a gel which can in particular be used in a dispenser with a dispensing head.
- either propellant is used as durosol, at a rate of 20 to 25% by weight, ie a mixture of propane and butane at a rate of 40% by weight.
- the composition When the composition is in the form of a gel, it comprises by weight, 45 to 55% of the composition defined above, 25 to 35% of demineralized water, 12.7 to 17.5% of alcohol 95% ethyl, from 0.1 to 1.3% of a viscosity-increasing agent, such as a very high molecular weight polymer known as a "carbomer”, from 1.5% to 4.5% of hydrogenated cod liver oil, known in particular under the name of "Cremophor 2H40" and from 0.5 to 2% of polyoxyethylene (15) cocoamine known under the name of "Ethomeen C / 25".
- a viscosity-increasing agent such as a very high molecular weight polymer known as a "carbomer”
- hydrogenated cod liver oil known in particular under the name of "Cremophor 2H40”
- polyoxyethylene (15) cocoamine known under the name of "Ethomeen C / 25”.
- the composition is advantageously that which is defined above, and more particularly that which comprises 65.5% of 95% ethanol, 20% of N, N-diethyl-1-m-toluamide, 1% polyvinylpyrrolidone, 8% isopropyl myristate, 4% dipropylene glycol, 0.1% amplifier, 0.5% solubilizing homogenizing agent and 0.9% natural repellents.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Pest Control & Pesticides (AREA)
- Botany (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH26988A CH676412A5 (enrdf_load_stackoverflow) | 1988-01-27 | 1988-01-27 | |
| CH269/88 | 1988-01-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0352316A1 true EP0352316A1 (fr) | 1990-01-31 |
Family
ID=4183156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19890901552 Withdrawn EP0352316A1 (fr) | 1988-01-27 | 1989-01-20 | Composition repulsive d'insectes |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0352316A1 (enrdf_load_stackoverflow) |
| CA (1) | CA1312006C (enrdf_load_stackoverflow) |
| CH (1) | CH676412A5 (enrdf_load_stackoverflow) |
| WO (1) | WO1989006904A1 (enrdf_load_stackoverflow) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZM3391A1 (en) * | 1990-08-06 | 1992-04-30 | R & C Products Pty Ltd | Insect repellent |
| US5118711A (en) * | 1990-09-27 | 1992-06-02 | International Flavors & Fragrances Inc. | Ketone, ketoesters and alcohol in repelling insects; use of aliphatic ester in attracting insects and process and apparatus for determination of insect repellency and attractancy |
| US5227163A (en) * | 1991-01-18 | 1993-07-13 | Clilco, Ltd. | Lice-repellant compositions |
| AU659625B2 (en) * | 1991-01-18 | 1995-05-25 | Clilco, Ltd. | Lice-repellant compositions |
| US5683687A (en) * | 1992-09-18 | 1997-11-04 | International Flavors & Fragrances Inc. | Insect attractant compositions and methods for using same |
| US5635173A (en) * | 1992-09-18 | 1997-06-03 | International Flavors & Fragrances | Insect repellent and attractant compositions and methods for using same |
| GB9318869D0 (en) * | 1993-09-11 | 1993-10-27 | Pisacane Anthony | Repellant material |
| EP0713647A1 (en) * | 1994-11-24 | 1996-05-29 | Jaico N.V. | Insect-repellent composition based on pyrethrum extract |
| FR2755825A1 (fr) * | 1996-11-15 | 1998-05-22 | Firmenich & Cie | Composition pour repousser les cafards |
| WO1998023150A1 (en) * | 1996-11-26 | 1998-06-04 | Schering-Plough Healthcare Products Inc. | Insect repellent emulsions |
| US6605643B1 (en) | 1997-11-24 | 2003-08-12 | Schering-Plough Healthcare Products, Inc. | Insect repellent emulsions |
| GB9930104D0 (en) * | 1999-12-20 | 2000-02-09 | Unilever Plc | Aqueous hair styling compositions |
| DE102005015446A1 (de) * | 2005-04-05 | 2006-10-12 | Merck Patent Gmbh | Synergisten zur Verstärkung der Wirkung von Repellentien |
| DE102006007547A1 (de) * | 2006-02-16 | 2007-08-30 | Lanxess Deutschland Gmbh | Gel-Formulierung zur Arthropoden- und Plathelminthen-Abwehr |
| DE102006007546A1 (de) * | 2006-02-16 | 2007-08-30 | Saltigo Gmbh | Wasser-in-Öl-Formulierung zur Arthropoden-und Plathelminthen-Abwehr |
| CA2675941C (en) * | 2007-01-25 | 2015-07-14 | Centre National De La Recherche Scientifique | Phytosanitary formulations |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3041814A1 (de) * | 1980-11-06 | 1982-06-03 | Bayer Ag, 5090 Leverkusen | Formulierung zur bekaempfung von tierischen ektoparasiten, insbesondere insekten und acarinen |
| GB8612826D0 (en) * | 1986-05-27 | 1986-07-02 | Boots Co Plc | Insecticidal compositions |
| FR2599220A1 (fr) * | 1986-05-29 | 1987-12-04 | Aerosols Ste Mediterraneenne | Nouvelle composition parasiticide a effet prolonge pour la prevention ou le traitement externe de l'homme et des animaux a sang chaud. |
| BE906136A (nl) * | 1986-12-31 | 1987-04-16 | Vandoninck Alfons | Vloeibaar insektwegjagend middel voor menselijk gebruik in glasflesje of polyethyleenbusje afgewerkt verbruikersprodukt. |
| JPH0648902A (ja) * | 1992-07-22 | 1994-02-22 | Mikasa Kagaku Kogyo Kk | 省力散布型水田用農薬 |
-
1988
- 1988-01-27 CH CH26988A patent/CH676412A5/fr not_active IP Right Cessation
-
1989
- 1989-01-20 EP EP19890901552 patent/EP0352316A1/fr not_active Withdrawn
- 1989-01-20 WO PCT/EP1989/000062 patent/WO1989006904A1/fr not_active Application Discontinuation
- 1989-01-23 CA CA000588925A patent/CA1312006C/fr not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8906904A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1989006904A1 (fr) | 1989-08-10 |
| CA1312006C (fr) | 1992-12-29 |
| CH676412A5 (enrdf_load_stackoverflow) | 1991-01-31 |
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