WO1989006904A1 - Composition repulsive d'insectes - Google Patents

Composition repulsive d'insectes Download PDF

Info

Publication number
WO1989006904A1
WO1989006904A1 PCT/EP1989/000062 EP8900062W WO8906904A1 WO 1989006904 A1 WO1989006904 A1 WO 1989006904A1 EP 8900062 W EP8900062 W EP 8900062W WO 8906904 A1 WO8906904 A1 WO 8906904A1
Authority
WO
WIPO (PCT)
Prior art keywords
agent
weight
composition according
composition
toluamide
Prior art date
Application number
PCT/EP1989/000062
Other languages
English (en)
French (fr)
Inventor
Serge André LEUTHOLD
Original Assignee
Leuthold Serge Andre
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leuthold Serge Andre filed Critical Leuthold Serge Andre
Publication of WO1989006904A1 publication Critical patent/WO1989006904A1/fr

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/36Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/22Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/02Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants

Definitions

  • the present invention relates to an insect repellant composition for application to human skin as well as hair, or clothing, as well as the fur of animals.
  • the object of the invention is to provide an insect repellent composition which makes it possible to remedy the main drawbacks presented by known repellent compositions; namely: unpleasant odor and limited duration of effectiveness either by absorption or m abolishing Li on of the composition by the skin, or by perspiration due to high heat or stress or by abrasion of the composition caused in particular by washing the treated surface or by the movement of air on this surface. This is how we observe efficiency reductions of around 60%, compared to a wind-free atmosphere, when the wind reaches a speed of 190m / minute.
  • the composition according to the invention comprises at least one active repellant, chosen from extracts of pelargonium, geranium, lavender, pyrethrum, lemon flower, as well as N, N-dié hy1-m-toluamide, a plasticizing agent and an agent amplifying the repellent effect of the above active compounds.
  • the plasticizing agent is a vinyl compound.
  • the vinyl compound is polyvinylpyrrolidone.
  • the amplifying agent is cyclopentane-1-one-2-npentane-3-methyl ethyl ester known under the name of Hedione.
  • the composition comprises, by weight, from 30 to 75% of 95% ethanol, from 5 to 50% of N, N-diethyl-m-toluamide, from 0, there 2% of polyvinylpyrrolidone, from 2 to 10% of isopropyl myristate, from 2 to 10% of dipropylene glycol, from 0.1 to 2.5% of amplifier, from 0.1 to 2.5% of a solubilizing homogenizing agent and natural extracts from 0.1 to 2.5%.
  • the composition according to the invention which is repellent for most insects and in particular for the following mosquitoes: ⁇ edes Aegypti, Culex, Mansonia, Anopheles, Psorophora, for fleas, ticks, horseflies, black flies, black flies stable, Cerotopogonidae, has the main characteristic of allowing the creation, on covered surfaces and mainly on the skin where the repellant compositions lose their effectiveness as quickly as possible due to absorption, metabolization, perspiration and / or l 'abrasion, a film, which resists time, external conditions as well as changes in the state of the covered surface and which regulates and slows its release from the active ingredients of the composition, in which most of these ingredients remain present active repellents, ingredients whose activity is advantageously increased by the incorporation into the composition of an enhancer, said composition also having the advantage of being made up mainly of natural products which are non-toxic for humans and animals .
  • This composition whose odor is pleasant and which contains, according to the invention and as described below, a plasticizing and fixing agent as well as an amplifying agent, has real repulsive activity for a minimum period of 4 to 8 hours which could reach 14 hours depending on external conditions when it is applied in the following quantities, which vary in particular according to outdoor atmospheric conditions, such as the temperature whose rise causes dispersion or abrasion from 0.05 to 0, 2 mg per cm on the skin and
  • Said composition which contains polyvinylpyrrolidone, which constitutes the plasticizing and fixing agent for the formation of the abovementioned film, natural active repellent extracts, such as pelargonium, geranium, lavender, pyrethrum, lemon flowers, as well as NN-die hy1-m-toluamide, an amplifier consisting of cyclopentane -l-one-2- npentane-3-methyl ethyl ester whose property is to ensure a synergistic effect with the active repellent extracts, advantageously comprises, by weight, from 30 to 75% of 95% ethanol, from 5 to 50% of N, N-5 diethyl-m-toluamide, from 0.4 to 2% of polyvinylpyrrolidone, from 2 to 10% of isopropyl myristate, from 2 to 10% of dipropylene glycol, from 0.1 to 2.5% of the aforementioned enhancer and from 0.1 to 2.5% of a solubilizing homogenizing
  • composition 10 polyoxyethylene nonyl phenyl ether known as "Lamacite" and from 0.1 to 2.5% of natural repellents.
  • the aforementioned composition may also comprise a dye improving its appearance, this dye, introduced into the composition at a rate of
  • composition comprising, by weight, 65.5% 95% ethanol, 20% N, N-diethyl-m-toluamide, 1% polyvinylpyrrolidone, 8% isopropyl myristate, 4% dipropylene glycol, 0.1% amplifying agent, 0.5% solubilizing homogenizing agent and 0.9%
  • the repellant composition can be either in the form of an aerosol, or in the form of a gel which can in particular be used in a dispenser with a dispensing head.
  • either propellant is used as durosol, at a rate of 20 to 25% by weight, ie a mixture of propane and butane at a rate of 40% by weight.
  • the composition When the composition is in the form of a gel, it comprises by weight, 45 to 55% of the composition defined above, 25 to 35% of demineralized water, 12.7 to 17.5% of alcohol 95% ethyl, from 0.1 to 1.3% of a viscosity-increasing agent, such as a very high molecular weight polymer known as a "carbomer”, from 1.5% to 4.5% of hydrogenated cod liver oil, known in particular under the name of "Cremophor 2H40" and from 0.5 to 2% of polyoxyethylene (15) cocoamine known under the name of "Ethomeen C / 25".
  • a viscosity-increasing agent such as a very high molecular weight polymer known as a "carbomer”
  • hydrogenated cod liver oil known in particular under the name of "Cremophor 2H40”
  • polyoxyethylene (15) cocoamine known under the name of "Ethomeen C / 25”.
  • the composition is advantageously that which is defined above, and more particularly that which comprises 65.5% of 95% ethanol, 20% of N, N-diethyl-1-m-toluamide, 1% polyvinylpyrrolidone, 8% isopropyl myristate, 4% dipropylene glycol, 0.1% amplifier, 0.5% solubilizing homogenizing agent and 0.9% natural repellents.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Pest Control & Pesticides (AREA)
  • Botany (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)
PCT/EP1989/000062 1988-01-27 1989-01-20 Composition repulsive d'insectes WO1989006904A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH269/88-6 1988-01-27
CH26988A CH676412A5 (enrdf_load_stackoverflow) 1988-01-27 1988-01-27

Publications (1)

Publication Number Publication Date
WO1989006904A1 true WO1989006904A1 (fr) 1989-08-10

Family

ID=4183156

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1989/000062 WO1989006904A1 (fr) 1988-01-27 1989-01-20 Composition repulsive d'insectes

Country Status (4)

Country Link
EP (1) EP0352316A1 (enrdf_load_stackoverflow)
CA (1) CA1312006C (enrdf_load_stackoverflow)
CH (1) CH676412A5 (enrdf_load_stackoverflow)
WO (1) WO1989006904A1 (enrdf_load_stackoverflow)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5118711A (en) * 1990-09-27 1992-06-02 International Flavors & Fragrances Inc. Ketone, ketoesters and alcohol in repelling insects; use of aliphatic ester in attracting insects and process and apparatus for determination of insect repellency and attractancy
EP0495684A1 (en) * 1991-01-18 1992-07-22 Clilco, Ltd. Lice-repellant compositions
US5298250A (en) * 1990-08-06 1994-03-29 R & C Products Pty Ltd. Insect repellent
WO1995007024A1 (en) * 1993-09-11 1995-03-16 Anthony Pisacane Repellant material
US5411992A (en) * 1991-01-18 1995-05-02 Clilco Ltd. Lice repellant composition
EP0713647A1 (en) * 1994-11-24 1996-05-29 Jaico N.V. Insect-repellent composition based on pyrethrum extract
US5635174A (en) * 1992-09-18 1997-06-03 International Flavors & Fragrances Inc. Insect repellent and attractant compositions and methods for using same
US5683687A (en) * 1992-09-18 1997-11-04 International Flavors & Fragrances Inc. Insect attractant compositions and methods for using same
FR2755825A1 (fr) * 1996-11-15 1998-05-22 Firmenich & Cie Composition pour repousser les cafards
WO1998023150A1 (en) * 1996-11-26 1998-06-04 Schering-Plough Healthcare Products Inc. Insect repellent emulsions
US6605643B1 (en) 1997-11-24 2003-08-12 Schering-Plough Healthcare Products, Inc. Insect repellent emulsions
WO2007093298A1 (de) * 2006-02-16 2007-08-23 Saltigo Gmbh Gel-formulierung zur arthropoden- und plathelminthen-abwehr
WO2007093297A3 (de) * 2006-02-16 2007-12-13 Saltigo Gmbh Wasser-in-öl-formulierung zur arthropoden- und plathelminthen-abwehr
WO2008090476A3 (en) * 2007-01-25 2008-10-30 Centre Nat Rech Scient Phytosanitary formulations

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9930104D0 (en) * 1999-12-20 2000-02-09 Unilever Plc Aqueous hair styling compositions
DE102005015446A1 (de) * 2005-04-05 2006-10-12 Merck Patent Gmbh Synergisten zur Verstärkung der Wirkung von Repellentien

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0051786A1 (de) * 1980-11-06 1982-05-19 Bayer Ag Formulierung zur Bekämpfung von tierischen Ektoparasiten, insbesondere Insekten und Acarinen
BE906136A (nl) * 1986-12-31 1987-04-16 Vandoninck Alfons Vloeibaar insektwegjagend middel voor menselijk gebruik in glasflesje of polyethyleenbusje afgewerkt verbruikersprodukt.
FR2599220A1 (fr) * 1986-05-29 1987-12-04 Aerosols Ste Mediterraneenne Nouvelle composition parasiticide a effet prolonge pour la prevention ou le traitement externe de l'homme et des animaux a sang chaud.
EP0251464A2 (en) * 1986-05-27 1988-01-07 The Boots Company PLC Composition for the control of insects
JPH0648902A (ja) * 1992-07-22 1994-02-22 Mikasa Kagaku Kogyo Kk 省力散布型水田用農薬

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0051786A1 (de) * 1980-11-06 1982-05-19 Bayer Ag Formulierung zur Bekämpfung von tierischen Ektoparasiten, insbesondere Insekten und Acarinen
EP0251464A2 (en) * 1986-05-27 1988-01-07 The Boots Company PLC Composition for the control of insects
FR2599220A1 (fr) * 1986-05-29 1987-12-04 Aerosols Ste Mediterraneenne Nouvelle composition parasiticide a effet prolonge pour la prevention ou le traitement externe de l'homme et des animaux a sang chaud.
BE906136A (nl) * 1986-12-31 1987-04-16 Vandoninck Alfons Vloeibaar insektwegjagend middel voor menselijk gebruik in glasflesje of polyethyleenbusje afgewerkt verbruikersprodukt.
JPH0648902A (ja) * 1992-07-22 1994-02-22 Mikasa Kagaku Kogyo Kk 省力散布型水田用農薬

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Patent Abstracts of Japan, volume 9, no. 180 (C-293)(1903), 25 juillet 1985; & JP-A-6048902 (KADOTA REESU K.K.) 16 mars 1985 *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5298250A (en) * 1990-08-06 1994-03-29 R & C Products Pty Ltd. Insect repellent
US5118711A (en) * 1990-09-27 1992-06-02 International Flavors & Fragrances Inc. Ketone, ketoesters and alcohol in repelling insects; use of aliphatic ester in attracting insects and process and apparatus for determination of insect repellency and attractancy
EP0495684A1 (en) * 1991-01-18 1992-07-22 Clilco, Ltd. Lice-repellant compositions
US5411992A (en) * 1991-01-18 1995-05-02 Clilco Ltd. Lice repellant composition
US5635174A (en) * 1992-09-18 1997-06-03 International Flavors & Fragrances Inc. Insect repellent and attractant compositions and methods for using same
US5683687A (en) * 1992-09-18 1997-11-04 International Flavors & Fragrances Inc. Insect attractant compositions and methods for using same
WO1995007024A1 (en) * 1993-09-11 1995-03-16 Anthony Pisacane Repellant material
EP0713647A1 (en) * 1994-11-24 1996-05-29 Jaico N.V. Insect-repellent composition based on pyrethrum extract
FR2755825A1 (fr) * 1996-11-15 1998-05-22 Firmenich & Cie Composition pour repousser les cafards
WO1998023150A1 (en) * 1996-11-26 1998-06-04 Schering-Plough Healthcare Products Inc. Insect repellent emulsions
US6605643B1 (en) 1997-11-24 2003-08-12 Schering-Plough Healthcare Products, Inc. Insect repellent emulsions
WO2007093298A1 (de) * 2006-02-16 2007-08-23 Saltigo Gmbh Gel-formulierung zur arthropoden- und plathelminthen-abwehr
WO2007093297A3 (de) * 2006-02-16 2007-12-13 Saltigo Gmbh Wasser-in-öl-formulierung zur arthropoden- und plathelminthen-abwehr
WO2008090476A3 (en) * 2007-01-25 2008-10-30 Centre Nat Rech Scient Phytosanitary formulations
US8980793B2 (en) 2007-01-25 2015-03-17 Centre National De La Recherche Scientifique (Cnrs) Phytosanitary formulations

Also Published As

Publication number Publication date
EP0352316A1 (fr) 1990-01-31
CA1312006C (fr) 1992-12-29
CH676412A5 (enrdf_load_stackoverflow) 1991-01-31

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