EP0346993A2 - Flüssige Waschmittelzusammensetzungen - Google Patents
Flüssige Waschmittelzusammensetzungen Download PDFInfo
- Publication number
- EP0346993A2 EP0346993A2 EP19890201528 EP89201528A EP0346993A2 EP 0346993 A2 EP0346993 A2 EP 0346993A2 EP 19890201528 EP19890201528 EP 19890201528 EP 89201528 A EP89201528 A EP 89201528A EP 0346993 A2 EP0346993 A2 EP 0346993A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- soap
- weight
- electrolyte
- composition
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the surfactant material in such compositions usually comprises one or more surfactants which may be soap or non-soap synthetic surfactants.
- Soap is a particularly useful material since it is capable of a multiplicity of roles. It can be used as a detergent-active agent, as a builder and as a fabric softening agent. Thus, it is a very desirable aim to formulate liquid detergents which are relatively rich in soap. In the case of isotropic liquids containing little or no inorganic builder, it is relatively easy to formulate with high soap levels. It is much more difficult to incorporate large enough quantities in the aqueous structured liquids referred to above.
- the term electrolyte means any water-soluble salt.
- the amount of electrolyte should be sufficient to cause formation of a lamellar phase by the soap/surfactant to endow solid suspending capability.
- the composition comprises at least 1.0% by weight, more preferably at least 5.0% by weight, most preferably at least 17.0% by weight of electrolyte.
- the electrolyte may also be a detergency builder, such as the inorganic builder sodium tripolyphosphate, or it may be a non-functional electrolyte, such as sodium sulphate or chloride.
- the inorganic builder comprises all or part of the electrolyte.
- compositions must also be capable of suspending particulate solids although particularly preferred are those systems where such solids are actually in suspension.
- the solids may be undissolved electrolyte, the same or different from the electrolyte in solution, the latter being saturated in electrolyte. Additionally or alternatively, they may be materials which are substantially insoluble in water alone. Examples of such substantially insoluble materials are aluminosilicate builders and particles of calcite abrasive.
- Suitable nonionic surfactants which may be used include in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
- Specific nonionic detergent compounds are alkyl (C6-C22) phenols-ethylene oxide condensates, the condensation products of aliphatic (C8-C18) primary or secondary linear or branched alcohols with ethylene oxide, and products made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylene diamine.
- Other so-called nonionic detergent compounds include long-chain tertiary amine oxides, long-chain tertiary phosphine oxides and dialkyl sulphoxides.
- compositions of the present invention preferably also contain a builder in addition to the soap.
- the non- soap builder is preferably present at a level of at least 5% by weight; the maximum level is preferably 30%.
- a detergency builder is any material which is capable of reducing the level of free calcium ions in the wash liquor and will preferably provide the composition with other beneficial properties such as the generation of an alkaline pH, and the suspension of soil removed from the fabric. They may be classed as inorganic, organic non-polymeric and organic polymeric. Generally, we prefer that any inorganic builder comprises all or part of the electrolyte (provided water-soluble).
- phosphorus-containing inorganic detergency builders include the water-soluble salts, especially alkaline metal pyrophosphates, orthophosphates, polyphosphates and phosphonates.
- specific examples of inorganic phosphate builders include sodium and potassium tripolyphosphates, phosphates and hexametaphosphates.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB888813978A GB8813978D0 (en) | 1988-06-13 | 1988-06-13 | Liquid detergents |
GB8813978 | 1988-06-13 | ||
GB8826235 | 1988-11-09 | ||
GB888826235A GB8826235D0 (en) | 1988-11-09 | 1988-11-09 | Liquid detergent compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0346993A2 true EP0346993A2 (de) | 1989-12-20 |
EP0346993A3 EP0346993A3 (de) | 1990-08-16 |
Family
ID=26294012
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89201528A Withdrawn EP0346993A3 (de) | 1988-06-13 | 1989-06-12 | Flüssige Waschmittelzusammensetzungen |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0346993A3 (de) |
JP (1) | JPH0234700A (de) |
AU (1) | AU627461B2 (de) |
BR (1) | BR8902772A (de) |
CA (1) | CA1334919C (de) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0359308A2 (de) * | 1988-09-16 | 1990-03-21 | Unilever N.V. | Flüssige Waschmittel |
EP0452106A2 (de) * | 1990-04-10 | 1991-10-16 | ALBRIGHT & WILSON UK LIMITED | Konzentrierte wässrige Tensidlösung |
WO1991016409A1 (en) * | 1990-04-25 | 1991-10-31 | Unilever N.V. | Liquid detergent compositions |
WO1994016680A1 (en) * | 1993-01-22 | 1994-08-04 | Unilever Plc | Dilution-thickening, personal washing composition |
EP0623670A2 (de) | 1993-05-07 | 1994-11-09 | ALBRIGHT & WILSON UK LIMITED | Oberflächenaktive Zusammensetzungen auf wässriger Basis |
US5672580A (en) * | 1990-04-25 | 1997-09-30 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid detergent compositions |
EP0798372A2 (de) * | 1996-03-29 | 1997-10-01 | Unilever N.V. | Waschmittelzusammensetzung |
WO2002057401A1 (en) * | 2001-01-19 | 2002-07-25 | Reckitt Benckiser N.V. | Improvements in or relating to liquid detergent compositions |
US7417014B2 (en) | 2006-06-13 | 2008-08-26 | Conopco, Inc. | Dilution thickened personal cleansing composition |
WO2009060312A3 (en) * | 2007-08-17 | 2009-11-05 | Rhodia Asia Pacific Pte, Limited | Structured soap compositions |
US8029772B2 (en) | 2001-12-21 | 2011-10-04 | Rhodia Inc. | Stable surfactant compositions for suspending components |
US8828364B2 (en) | 2007-03-23 | 2014-09-09 | Rhodia Operations | Structured surfactant compositions |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2693827B2 (ja) * | 1988-06-13 | 1997-12-24 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 液体洗剤組成物 |
JPH0547692U (ja) * | 1991-07-26 | 1993-06-25 | 三豊工業株式会社 | パイプとプレートとの取付構造 |
JP5118315B2 (ja) * | 2006-06-26 | 2013-01-16 | ライオン株式会社 | 洗剤組成物 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB938783A (en) * | 1960-03-02 | 1963-10-09 | Unilever Ltd | Liquid detergent compositions |
FR1548948A (de) * | 1966-12-20 | 1968-12-06 | ||
US3522186A (en) * | 1966-12-12 | 1970-07-28 | Procter & Gamble | Abrasive liquid detergent compositions |
EP0038101A1 (de) * | 1980-04-09 | 1981-10-21 | Unilever N.V. | Flüssige Reinigungsmittelzusammensetzungen auf der Basis von Komplexbildnern und Verfahren zur Herstellung |
EP0151884A2 (de) * | 1983-12-22 | 1985-08-21 | Albright & Wilson Limited | Flüssige Reinigungsmittelzusammensetzungen |
EP0301883A1 (de) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Flüssige Reinigungsmittelzusammensetzungen |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1468181A (en) * | 1973-10-11 | 1977-03-23 | Unilever Ltd | Liquid detergent composition |
JPS616895A (ja) * | 1984-06-20 | 1986-01-13 | 日立化成工業株式会社 | 内層抵抗体付き多層印刷配線板 |
JPS6114300A (ja) * | 1984-06-29 | 1986-01-22 | ライオン株式会社 | 液体洗浄剤組成物の製造方法 |
JPS62199697A (ja) * | 1986-02-26 | 1987-09-03 | ライオン株式会社 | 液体洗浄剤組成物 |
US8522186B2 (en) * | 2011-12-16 | 2013-08-27 | Industrial Technology Research Institute | Method and apparatus of an integrated circuit |
-
1989
- 1989-06-07 CA CA 602027 patent/CA1334919C/en not_active Expired - Fee Related
- 1989-06-07 JP JP14501089A patent/JPH0234700A/ja active Pending
- 1989-06-09 AU AU36269/89A patent/AU627461B2/en not_active Ceased
- 1989-06-12 BR BR898902772A patent/BR8902772A/pt unknown
- 1989-06-12 EP EP89201528A patent/EP0346993A3/de not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB938783A (en) * | 1960-03-02 | 1963-10-09 | Unilever Ltd | Liquid detergent compositions |
US3522186A (en) * | 1966-12-12 | 1970-07-28 | Procter & Gamble | Abrasive liquid detergent compositions |
FR1548948A (de) * | 1966-12-20 | 1968-12-06 | ||
EP0038101A1 (de) * | 1980-04-09 | 1981-10-21 | Unilever N.V. | Flüssige Reinigungsmittelzusammensetzungen auf der Basis von Komplexbildnern und Verfahren zur Herstellung |
EP0151884A2 (de) * | 1983-12-22 | 1985-08-21 | Albright & Wilson Limited | Flüssige Reinigungsmittelzusammensetzungen |
EP0301883A1 (de) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Flüssige Reinigungsmittelzusammensetzungen |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0359308A2 (de) * | 1988-09-16 | 1990-03-21 | Unilever N.V. | Flüssige Waschmittel |
EP0359308A3 (de) * | 1988-09-16 | 1991-01-16 | Unilever N.V. | Flüssige Waschmittel |
EP0452106A2 (de) * | 1990-04-10 | 1991-10-16 | ALBRIGHT & WILSON UK LIMITED | Konzentrierte wässrige Tensidlösung |
EP0452106A3 (en) * | 1990-04-10 | 1992-08-05 | Albright & Wilson Limited | Concentrated aqueous surfactants |
TR27723A (tr) * | 1990-04-10 | 1995-06-22 | Albright & Wilson | Katilari asili hale getirme maddeleri veya camasir deterjanlari olarak kullanilmaya mahsus konsantre, sulu yüzey aktif maddeler. |
WO1991016409A1 (en) * | 1990-04-25 | 1991-10-31 | Unilever N.V. | Liquid detergent compositions |
US5672580A (en) * | 1990-04-25 | 1997-09-30 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid detergent compositions |
WO1994016680A1 (en) * | 1993-01-22 | 1994-08-04 | Unilever Plc | Dilution-thickening, personal washing composition |
EP0623670A2 (de) | 1993-05-07 | 1994-11-09 | ALBRIGHT & WILSON UK LIMITED | Oberflächenaktive Zusammensetzungen auf wässriger Basis |
EP0798372A3 (de) * | 1996-03-29 | 1999-12-08 | Unilever N.V. | Waschmittelzusammensetzung |
EP0798372A2 (de) * | 1996-03-29 | 1997-10-01 | Unilever N.V. | Waschmittelzusammensetzung |
WO2002057401A1 (en) * | 2001-01-19 | 2002-07-25 | Reckitt Benckiser N.V. | Improvements in or relating to liquid detergent compositions |
US6936578B2 (en) | 2001-01-19 | 2005-08-30 | Reckitt Benckiser N.V. | Nonaqueous liquid detergent compositions |
US8029772B2 (en) | 2001-12-21 | 2011-10-04 | Rhodia Inc. | Stable surfactant compositions for suspending components |
US7417014B2 (en) | 2006-06-13 | 2008-08-26 | Conopco, Inc. | Dilution thickened personal cleansing composition |
US8828364B2 (en) | 2007-03-23 | 2014-09-09 | Rhodia Operations | Structured surfactant compositions |
WO2009060312A3 (en) * | 2007-08-17 | 2009-11-05 | Rhodia Asia Pacific Pte, Limited | Structured soap compositions |
CN101784651B (zh) * | 2007-08-17 | 2012-08-08 | 罗迪亚亚太有限公司 | 结构化的肥皂组合物 |
RU2475525C2 (ru) * | 2007-08-17 | 2013-02-20 | Родиа Эйша Пасифик Пте, Лимитед | Структурированные мыльные композиции |
US9090861B2 (en) | 2007-08-17 | 2015-07-28 | Rhodia Asia Pacific Ltd. | Structured soap compositions |
Also Published As
Publication number | Publication date |
---|---|
BR8902772A (pt) | 1990-02-01 |
AU627461B2 (en) | 1992-08-27 |
JPH0234700A (ja) | 1990-02-05 |
EP0346993A3 (de) | 1990-08-16 |
CA1334919C (en) | 1995-03-28 |
AU3626989A (en) | 1989-12-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): CH DE ES FR GB IT LI NL SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): CH DE ES FR GB IT LI NL SE |
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17P | Request for examination filed |
Effective date: 19900905 |
|
RAP3 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: UNILEVER PLC Owner name: UNILEVER N.V. |
|
17Q | First examination report despatched |
Effective date: 19930430 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19950321 |