EP0346993A2 - Flüssige Waschmittelzusammensetzungen - Google Patents

Flüssige Waschmittelzusammensetzungen Download PDF

Info

Publication number
EP0346993A2
EP0346993A2 EP19890201528 EP89201528A EP0346993A2 EP 0346993 A2 EP0346993 A2 EP 0346993A2 EP 19890201528 EP19890201528 EP 19890201528 EP 89201528 A EP89201528 A EP 89201528A EP 0346993 A2 EP0346993 A2 EP 0346993A2
Authority
EP
European Patent Office
Prior art keywords
soap
weight
electrolyte
composition
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19890201528
Other languages
English (en)
French (fr)
Other versions
EP0346993A3 (de
Inventor
Guido Clemens Van Den Brom
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB888813978A external-priority patent/GB8813978D0/en
Priority claimed from GB888826235A external-priority patent/GB8826235D0/en
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP0346993A2 publication Critical patent/EP0346993A2/de
Publication of EP0346993A3 publication Critical patent/EP0346993A3/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0026Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Definitions

  • the surfactant material in such compositions usually comprises one or more surfactants which may be soap or non-soap synthetic surfactants.
  • Soap is a particularly useful material since it is capable of a multiplicity of roles. It can be used as a detergent-active agent, as a builder and as a fabric softening agent. Thus, it is a very desirable aim to formulate liquid detergents which are relatively rich in soap. In the case of isotropic liquids containing little or no inorganic builder, it is relatively easy to formulate with high soap levels. It is much more difficult to incorporate large enough quantities in the aqueous structured liquids referred to above.
  • the term electrolyte means any water-­soluble salt.
  • the amount of electrolyte should be sufficient to cause formation of a lamellar phase by the soap/surfactant to endow solid suspending capability.
  • the composition comprises at least 1.0% by weight, more preferably at least 5.0% by weight, most preferably at least 17.0% by weight of electrolyte.
  • the electrolyte may also be a detergency builder, such as the inorganic builder sodium tripolyphosphate, or it may be a non-functional electrolyte, such as sodium sulphate or chloride.
  • the inorganic builder comprises all or part of the electrolyte.
  • compositions must also be capable of suspending particulate solids although particularly preferred are those systems where such solids are actually in suspension.
  • the solids may be undissolved electrolyte, the same or different from the electrolyte in solution, the latter being saturated in electrolyte. Additionally or alternatively, they may be materials which are substantially insoluble in water alone. Examples of such substantially insoluble materials are aluminosilicate builders and particles of calcite abrasive.
  • Suitable nonionic surfactants which may be used include in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
  • Specific nonionic detergent compounds are alkyl (C6-C22) phenols-ethylene oxide condensates, the condensation products of aliphatic (C8-C18) primary or secondary linear or branched alcohols with ethylene oxide, and products made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylene diamine.
  • Other so-called nonionic detergent compounds include long-­chain tertiary amine oxides, long-chain tertiary phosphine oxides and dialkyl sulphoxides.
  • compositions of the present invention preferably also contain a builder in addition to the soap.
  • the non-­ soap builder is preferably present at a level of at least 5% by weight; the maximum level is preferably 30%.
  • a detergency builder is any material which is capable of reducing the level of free calcium ions in the wash liquor and will preferably provide the composition with other beneficial properties such as the generation of an alkaline pH, and the suspension of soil removed from the fabric. They may be classed as inorganic, organic non-­polymeric and organic polymeric. Generally, we prefer that any inorganic builder comprises all or part of the electrolyte (provided water-soluble).
  • phosphorus-containing inorganic detergency builders include the water-soluble salts, especially alkaline metal pyrophosphates, orthophosphates, polyphosphates and phosphonates.
  • specific examples of inorganic phosphate builders include sodium and potassium tripolyphosphates, phosphates and hexametaphosphates.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)
EP89201528A 1988-06-13 1989-06-12 Flüssige Waschmittelzusammensetzungen Withdrawn EP0346993A3 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB888813978A GB8813978D0 (en) 1988-06-13 1988-06-13 Liquid detergents
GB8813978 1988-06-13
GB8826235 1988-11-09
GB888826235A GB8826235D0 (en) 1988-11-09 1988-11-09 Liquid detergent compositions

Publications (2)

Publication Number Publication Date
EP0346993A2 true EP0346993A2 (de) 1989-12-20
EP0346993A3 EP0346993A3 (de) 1990-08-16

Family

ID=26294012

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89201528A Withdrawn EP0346993A3 (de) 1988-06-13 1989-06-12 Flüssige Waschmittelzusammensetzungen

Country Status (5)

Country Link
EP (1) EP0346993A3 (de)
JP (1) JPH0234700A (de)
AU (1) AU627461B2 (de)
BR (1) BR8902772A (de)
CA (1) CA1334919C (de)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0359308A2 (de) * 1988-09-16 1990-03-21 Unilever N.V. Flüssige Waschmittel
EP0452106A2 (de) * 1990-04-10 1991-10-16 ALBRIGHT & WILSON UK LIMITED Konzentrierte wässrige Tensidlösung
WO1991016409A1 (en) * 1990-04-25 1991-10-31 Unilever N.V. Liquid detergent compositions
WO1994016680A1 (en) * 1993-01-22 1994-08-04 Unilever Plc Dilution-thickening, personal washing composition
EP0623670A2 (de) 1993-05-07 1994-11-09 ALBRIGHT & WILSON UK LIMITED Oberflächenaktive Zusammensetzungen auf wässriger Basis
US5672580A (en) * 1990-04-25 1997-09-30 Lever Brothers Company, Division Of Conopco, Inc. Liquid detergent compositions
EP0798372A2 (de) * 1996-03-29 1997-10-01 Unilever N.V. Waschmittelzusammensetzung
WO2002057401A1 (en) * 2001-01-19 2002-07-25 Reckitt Benckiser N.V. Improvements in or relating to liquid detergent compositions
US7417014B2 (en) 2006-06-13 2008-08-26 Conopco, Inc. Dilution thickened personal cleansing composition
WO2009060312A3 (en) * 2007-08-17 2009-11-05 Rhodia Asia Pacific Pte, Limited Structured soap compositions
US8029772B2 (en) 2001-12-21 2011-10-04 Rhodia Inc. Stable surfactant compositions for suspending components
US8828364B2 (en) 2007-03-23 2014-09-09 Rhodia Operations Structured surfactant compositions

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2693827B2 (ja) * 1988-06-13 1997-12-24 ユニリーバー・ナームローゼ・ベンノートシヤープ 液体洗剤組成物
JPH0547692U (ja) * 1991-07-26 1993-06-25 三豊工業株式会社 パイプとプレートとの取付構造
JP5118315B2 (ja) * 2006-06-26 2013-01-16 ライオン株式会社 洗剤組成物

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB938783A (en) * 1960-03-02 1963-10-09 Unilever Ltd Liquid detergent compositions
FR1548948A (de) * 1966-12-20 1968-12-06
US3522186A (en) * 1966-12-12 1970-07-28 Procter & Gamble Abrasive liquid detergent compositions
EP0038101A1 (de) * 1980-04-09 1981-10-21 Unilever N.V. Flüssige Reinigungsmittelzusammensetzungen auf der Basis von Komplexbildnern und Verfahren zur Herstellung
EP0151884A2 (de) * 1983-12-22 1985-08-21 Albright & Wilson Limited Flüssige Reinigungsmittelzusammensetzungen
EP0301883A1 (de) * 1987-07-31 1989-02-01 Unilever Plc Flüssige Reinigungsmittelzusammensetzungen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1468181A (en) * 1973-10-11 1977-03-23 Unilever Ltd Liquid detergent composition
JPS616895A (ja) * 1984-06-20 1986-01-13 日立化成工業株式会社 内層抵抗体付き多層印刷配線板
JPS6114300A (ja) * 1984-06-29 1986-01-22 ライオン株式会社 液体洗浄剤組成物の製造方法
JPS62199697A (ja) * 1986-02-26 1987-09-03 ライオン株式会社 液体洗浄剤組成物
US8522186B2 (en) * 2011-12-16 2013-08-27 Industrial Technology Research Institute Method and apparatus of an integrated circuit

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB938783A (en) * 1960-03-02 1963-10-09 Unilever Ltd Liquid detergent compositions
US3522186A (en) * 1966-12-12 1970-07-28 Procter & Gamble Abrasive liquid detergent compositions
FR1548948A (de) * 1966-12-20 1968-12-06
EP0038101A1 (de) * 1980-04-09 1981-10-21 Unilever N.V. Flüssige Reinigungsmittelzusammensetzungen auf der Basis von Komplexbildnern und Verfahren zur Herstellung
EP0151884A2 (de) * 1983-12-22 1985-08-21 Albright & Wilson Limited Flüssige Reinigungsmittelzusammensetzungen
EP0301883A1 (de) * 1987-07-31 1989-02-01 Unilever Plc Flüssige Reinigungsmittelzusammensetzungen

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0359308A2 (de) * 1988-09-16 1990-03-21 Unilever N.V. Flüssige Waschmittel
EP0359308A3 (de) * 1988-09-16 1991-01-16 Unilever N.V. Flüssige Waschmittel
EP0452106A2 (de) * 1990-04-10 1991-10-16 ALBRIGHT & WILSON UK LIMITED Konzentrierte wässrige Tensidlösung
EP0452106A3 (en) * 1990-04-10 1992-08-05 Albright & Wilson Limited Concentrated aqueous surfactants
TR27723A (tr) * 1990-04-10 1995-06-22 Albright & Wilson Katilari asili hale getirme maddeleri veya camasir deterjanlari olarak kullanilmaya mahsus konsantre, sulu yüzey aktif maddeler.
WO1991016409A1 (en) * 1990-04-25 1991-10-31 Unilever N.V. Liquid detergent compositions
US5672580A (en) * 1990-04-25 1997-09-30 Lever Brothers Company, Division Of Conopco, Inc. Liquid detergent compositions
WO1994016680A1 (en) * 1993-01-22 1994-08-04 Unilever Plc Dilution-thickening, personal washing composition
EP0623670A2 (de) 1993-05-07 1994-11-09 ALBRIGHT & WILSON UK LIMITED Oberflächenaktive Zusammensetzungen auf wässriger Basis
EP0798372A3 (de) * 1996-03-29 1999-12-08 Unilever N.V. Waschmittelzusammensetzung
EP0798372A2 (de) * 1996-03-29 1997-10-01 Unilever N.V. Waschmittelzusammensetzung
WO2002057401A1 (en) * 2001-01-19 2002-07-25 Reckitt Benckiser N.V. Improvements in or relating to liquid detergent compositions
US6936578B2 (en) 2001-01-19 2005-08-30 Reckitt Benckiser N.V. Nonaqueous liquid detergent compositions
US8029772B2 (en) 2001-12-21 2011-10-04 Rhodia Inc. Stable surfactant compositions for suspending components
US7417014B2 (en) 2006-06-13 2008-08-26 Conopco, Inc. Dilution thickened personal cleansing composition
US8828364B2 (en) 2007-03-23 2014-09-09 Rhodia Operations Structured surfactant compositions
WO2009060312A3 (en) * 2007-08-17 2009-11-05 Rhodia Asia Pacific Pte, Limited Structured soap compositions
CN101784651B (zh) * 2007-08-17 2012-08-08 罗迪亚亚太有限公司 结构化的肥皂组合物
RU2475525C2 (ru) * 2007-08-17 2013-02-20 Родиа Эйша Пасифик Пте, Лимитед Структурированные мыльные композиции
US9090861B2 (en) 2007-08-17 2015-07-28 Rhodia Asia Pacific Ltd. Structured soap compositions

Also Published As

Publication number Publication date
BR8902772A (pt) 1990-02-01
AU627461B2 (en) 1992-08-27
JPH0234700A (ja) 1990-02-05
EP0346993A3 (de) 1990-08-16
CA1334919C (en) 1995-03-28
AU3626989A (en) 1989-12-14

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