Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/50—Perfumes
  • C11D3/502—Protected perfumes
  • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/001—Softening compositions

Definitions

• the invention relates to laundry compositions and more particularly to a method and composition for providing a slow-release fragrance in a softergent composition.
• compositions useful as fabric softeners and laundry detergents are those found in the U.S. Patents 4,145,184 (Brain et al, 1979); 4,259,373 (Demessemaekers et al., 1981); 4,292,035 (Battrell, 1981); 4,417,994 (Stoddart, 1983); 4,367,158 (Sprecker, 1983); 4,536,315 (Ramachandran et al, 1985); 4,536,316 (Ramachandran, 1985); and 4,539,135 (Ramachandran et al, 1985).
• the invention comprises a solid composition of a non-­ionic or a cationic surfactant having a volatile fragrance dispersed in the composition.
• volatile fragrance means a compound which slowly volatilizes at room temperatures to provide a fragrant aroma.
• the invention also comprises a softergent composition which comprises the solid composition described above in admixture with a laundry detergent composition.
• softergent as used herein means a laundering composition which comprises a laundry detergent and a fabric softener.
• compositions of the invention are useful in laundering textile fabrics.
• the cationic surfactants employed as a matrix for the fragrances in the compositions of the invention are solids (at room temperatures) selected from conventionally employed fabric softeners/antistat compounds, which are substantially water-insoluble (less than 1 percent solubility by weight at a temperature of 30°C.). Such compounds are inclusive of quaternary ammonium compounds and amines having at least one straight-chain organic groups of at least 8 carbon atoms.
• Preferred cation surfactant softener/antistat compounds are those within the structural formula:- wherein R1, R2 and R3 each independently represent hydrogen or hydrocarbyl of 1 to 22 carbon atoms, inclusive; R4 is alkyl or alkenyl of 8 to 22 carbon atoms, inclusive; and X is an anion selected from the group consisting of halogen, acetate, phosphate, nitrate, and methyl sulfate radicals.
• hydrocarbyl as used herein means the monovalent moiety obtained upon removal of a hydrogen atom from a parent hydrocarbon.
• Representative of hydrocarbyl are alkyl of 1 of 22 carbon atoms, inclusive, such a methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, undecyl, decyl, dodecyl, octadecyl, nonodecyl, eicosyl, heneicosyl, docosyl and the isomeric forms thereof; aryl of 6 to 22 carbon atoms, inclusive, such a phenyl, tolyl, xylyl, napthyl, biphenyl and the like; aralkyl of 7 to 22 carbon atoms, inclusive, such as benzyl, phenethyl, phenpropyl, phenbutyl, phenhexyl,
• R1, R2, R3 and/or R4 may be attached to the quaternary nitrogen atom through an ether, alkoxy, ester or amide linkage.
• quaternary ammonium compounds useful for the invention are di-hydrogenated tallow dimethyl ammonium methyl sulfate; di-hydrogenated tallow dimethyl ammonium chloride, and 1-methly-1-alkylamidoethyl-2-alkylimidazolinium methyl sulfate wherein the "alkyls" are oleyl or saturated hydrocarbyls derived from tallow or hydrogenated tallow.
• the quaternary ammonium salts employed herein are preferably substantially free of a conductive salt; the term "conductive salt” being used herein to refer to salts which are electrically conductive in aqueous solution.
• the conductive salts generally have a cation-anion bond of at least 50% ionic character as calculated in accordance with the method described in Pauling, "The Nature of the Chemical Bond", 3rd Edition, 1960.
• substantially free is meant a concentration of conductive salt less than that present at normal impurity levels in the quaternary ammonium compound. Generally, the concentration of conductive salt is below 1%, by weight.
• non-ionic surfactants employed as a matrix for the fragrances in the compositions of the invention are also solids at room temperatures and are selected from known compounds which are substantially water-insoluble (less than 10 percent solubility by weight at a temperature of 30°C.).
• Representative of such non-ionic surfactants are the ethoxylated aliphatic alcohols.
• Such surfactants are well known as are methods of their preparation; see for example the extensive list of commercially available ethoxylated aliphatic alcohols given in the Kirk-Othmer Encyclopedia of Chemical Technology, Second Edition, Volume 19, Pages 538-539.
• Volatile fragrances employed in the compositions of the invention include natural, essential oils and synthetic perfumes, and blends thereof.
• perfume refers to odoriferous materials which are able to provide a pleasing fragrance to fabrics, and encompasses conventional materials commonly used in detergent compositions to counteract a malodor in such compositions and/or provide a pleasing fragrance thereto.
• the perfumes may be in the liquid state at ambient temperature, although solid perfumes are preferred. Included among the perfumes contemplated for use herein are materials such as aldehydes, ketones, esters and the like which are conventionally employed to impart a pleasing fragrance to liquid and granular detergent compositions. Naturally occurring plant and animal oils are also commonly used as components of perfumes.
• the perfumes useful for the present invention may have relatively simple compositions or may comprise complex mixtures of natural and synthetic chemical components, all of which are intended to provide a pleasant odor or fragrance when applied to fabrics.
• the perfumes used in detergent compositions are generally selected to meet normal requirements of odor, stability, price and commercial availability.
• a description of the materials conventionally used in detergent perfumery is set forth by R.T. Steltenkamp, in The Journal of The American Oil Chemists Society , Vol. 45, No. 6, pp.429-432, such disclosure being incorporated herein by reference.
• Typical perfumery materials include: natural essential oils such as lemon oil, mandarin oil, clove leaf oil, petitgrain oil, ceder wood oil, patchouli oil, lavender oil, neroli oil, yland oil, rose absolute or jasmin absolute; natural resins such as labdanum resin or olibanum resin; single perfumery chemicals which may be isolated from natural sources of manufactured synthetically, as for example alcohols such as geraniol, nerol, citronellol, linalool, tetrahydrogeraniol, betaphenylethyl alcohol, methyl phenyl carbinol, dimethyl benzyl carbinol, menthol or cedrol; acetates and other esters derived from such alcohols; aldehydes such as citral, citronellal, hydroxycitronellal, lauric aldehyde, undecylenic aldehyde, cinnamaldehyde, amyl cinnamic aldehyde
• the fragrance is preferably substantially insoluble in water.
• compositions of the invention may be prepared by heating the solid surfactant to a temperature above its melting point and dispersing into the melt a fragrance emitting proportion of the volatile fragrance.
• a fragrance emitting proportion is generally within the range of from 1 to 60 percent by weight of the total cationic surfactant matrix.
• Conventional stirring apparatus may be used to obtain a homogenous dispersion.
• the dispersions may then be allowed to re-solidify by cooling to ambient, room temperatures.
• the re-solidified composition is comminuated to obtain solid particles of a diameter which will pass through a No. 325 mesh screen (U.S. Sieve Series).
• the solid surfactant can be pre-mixed with the volatile fragrance, and the mixture melted and re-solidified.
• the molten mixture of surfactant and volatile fragrance may be chill sprayed to obtain re-solidified particles of the desired size to avoid the otherwise necessary step of comminuating a larger solid.
• compositions of the invention are advantageously employed as components of softergent laundry compositions by admixture with conventional laundry detergent compositions.
• the conventional laundry detergent compositions with which the present fabric softening compositions of the invention may be incorporated may contain one or more surface active agents selected from the group consisting of anionic, nonionic, cationic, ampholytic and zwitterionic detergents.
• the synthetic organic detergents employed in the practice of the invention may be one or more of a wide variety of such compounds which are well known and are described at length in the text "Surface Active Agents and Detergents", Vol. II, by Schwartz, Perry and Berch, published in 1958 by Interscience Publishers, the relevant disclosure of which is hereby incorporated by reference.
• the softergent compositions of the invention preferably employ one or more anionic detergent compounds as the primary detergent.
• the anionic detergent may be supplemented, if desired, with another type of detergent, preferably an ampholytic detergent.
• a nonionic detergent is generally less preferred for the present invention, however, when used in combination with a detergent builder salt, nonionic detergents can be advantageously utilized.
• anionic detergents useful in the present invention are those surface active compounds which contain an organic hydrophobic group containing from about 8 to 26 carbon atoms and preferably from about 10 to 18 carbon atoms in their molecular structure and at least one water-solubilizing group selected from the group consisting of sulfonate, sulfate, carboxylate, phosphonate and phosphate so as to form a water-soluble detergent.
• Suitable anionic detergents include soaps, such as, the water-soluble salts (e.g., the sodium, potassium, ammonium and alkanol-ammonium salts) of higher fatty acids or resin salts containing from about 8 to 20 carbon atoms. Particularly useful are the sodium and potassium salts of the fatty acid mixtures derived from coconut oil and tallow, for example, sodium coconut soap and potassium tallow soap.
• the water-soluble salts e.g., the sodium, potassium, ammonium and alkanol-ammonium salts
• the sodium and potassium salts of the fatty acid mixtures derived from coconut oil and tallow for example, sodium coconut soap and potassium tallow soap.
• anionic detergents are the olefin sulfonates including long chain alkene sulfonates, long chain hydroxyalkane sulfonates or mixtures of alkene sulfonates and hydroxyalkane sulfonates.
• sulfated ethoxylated higher fatty alcohols of the formula RO(C2H4O) m SO3M, wherein R is a fatty alkyl of from 10 to 18 carbon atoms, m is from 2 to 6 (preferably having a value from about 1/5 to 1/2 the number of carbon atoms in R) and M is a solubilizing salt-forming cation, such as an alkali metal, ammonium, lower alkylamino or lower alkanolamino, or a higher alkyl benzene sulfonate wherein the higher alkyls of 10 to 15 carbon atoms are present.
• R is a fatty alkyl of from 10 to 18 carbon atoms
• m is from 2 to 6 (preferably having a value from about 1/5 to 1/2 the number of carbon atoms in R)
• M is a solubilizing salt-forming cation, such as an alkali metal, ammonium, lower alkylamino or lower alkanola
• the proportion of ethylene oxide in the polyethoxylated higher alkanol sulfate is preferably 2 to 5 moles of ethylene oxide groups per mole of anionic detergent, with three moles being most preferred, especially when the higher alkanol is of 11 to 15 carbon atoms.
• the preferred water-soluble anionic detergent compounds are the ammonium and substituted ammonium (such as mono, di and tri-ethanolamine), alkali metal (such as, sodium and potassium) and alkaline earth metal (such as, calcium and magnesium) salts of the higher alkyl benzene sulfonates, olefin sulfonates and higher alkyl sulfates.
• ammonium and substituted ammonium such as mono, di and tri-ethanolamine
• alkali metal such as, sodium and potassium
• alkaline earth metal such as, calcium and magnesium
• the nonionic organic detergents are characterized by the presence of an organic hydrophobic group and an organic hydrophillic group and are typically produced by the condensation of an organic aliphatic or alkyl aromatic hydrophobic compound with ethylene oxide (hydrophilic in nature). Practically any hydrophobic compound having a carboxy, hydroxy, amido or amino group with a free hydrogen attached to the nitrogen can be condensed with ethylene oxide or with the polyhydration product thereof, polyethylene glycol, to form a nonionic detergent. The length of the hydrophilic or polyoxyethylene chain can be readily adjusted to achieve the desired balance between the hydrophobic and hydrophilic groups.
• the nonionic detergent is preferably a poly-lower alkoxylated higher alkanol wherein the alkanol is of 10 to 18 carbon atoms and wherein the number of moles of lower alkylene oxide (to 2 or 3 carbon atoms) is from 3 to 12.
• the higher alkanol is a higher fatty alcohol of 11 to 15 carbon atoms and which contain from 5 to 9 lower alkoxy groups per mole.
• the lower alkoxy is ethoxy but in some instances it may be desirably mixed with propoxy the latter, if present, usually being a minor (less than 50%) constituent.
• Exemplary of such compounds are those wherein the alkanol is of 12 to 15 carbon atoms and which contain about 7 ethylene oxide groups per mole, e.g., Neodol 25-7, and Neodol 23-6.5, which products are made by Shell Chemical Company, Inc.
• the former is a condensation product of a mixture of higher fatty alcohols averaging about 12 to 15 carbon atoms, with about 7 moles of ethylene oxide and the latter is a corresponding mixture wherein the carbon atom content of the higher fatty alcohol is 12 to 13 and the number of ethylene oxide groups per mole averages about 6.5.
• the higher alcohols are primary alkanols.
• Zwitterionic detergents such as the betaines and sulfobetaines having the following formula are also useful: wherein R is an alkyl group containing from about 8 to 18 carbon atoms, R2 and R3 are each an alkyl or hydroxyalkyl group containing about 1 to 4 carbon atoms, R4 is an alkylene or hydroxyakylene group containing 1 to 4 carbon atoms, and X is C or S:O.
• the alkyl group can contain one or more intermediate linkages such as amido, ether, or polyether linkages or nonfunctional substituents such as hydroxyl or halogen which do not substantially affect the hydrophobic character of the group.
• X is C
• the detergent is called a betaine
• X is S:O
• the detergent is called a sulfobetaine or sultaine.
• Cationic surface active agents may also be employed as detergents. They comprise compounds which contain an organic hydrophobic group which forms part of a cation when the compound is dissolved in water, and an anionic group. Typical cationic detergents are amine and quaternary ammonium compounds.
• cationic detergents include: normal primary amines of the formula RNH2 wherein R is an alkyl group containing from about 12 to 15 carbon atoms; diamines having the formula RNHC2H4NH2 wherein R is an alkyl group containing from about 12 to 22 carbon atoms, such as N-2 -aminoethly-stearyl amine and N-2-aminoethyl myristyl amine; amide-linked amines such as those having the formula R1CONHC2H4NH2 wherein R1 is an alkyl group containing about 8 to 20 carbon atoms, such as N-2-amino ethylstearyl amide and N-amino ethylmyristyl amide; quaternary ammonium compounds wherein typically one of the groups linked to the nitrogen atom is an aklyl group containing about 8 to 22 carbon atoms and three of the groups linked to the nitrogen atom are alkyl groups which contain 1 to 3 carbon atom
• the alkyl group may contain intermediate linkages such as amide which do not substantially affect the hydrophobic character of the group, for example, stearyl amido propyl quaternary ammonium chloride.
• Typical quaternary ammonium detergents are ethyldimethylstearylammonium chloride, benzyldimethylstearyl­ammonium chloride, trimethylstearylammonium chloride, trimethylcetylammonium bromide, dimethylethyllaurylammonium chloride, dimethylpropylmyristyl ammonium choloride, the corresponding methosulfates and acetates.
• Amopholytic detergents are well known in the art and many detergents of this class are disclosed by Schwartz, Perry and Berch in the aforementioned "Surface Active Agents and Detergents.”
• Examples of amphoteric detergents include: alkyl betaiminodiepropionates and long chain imidazole derivatives having the general formula: wherein R is an acyclic hydrophobic group containing from about 8 to 18 carbon atoms and M is a cation to neutralize the charge of the anion.
• Specific amphoteric detergents include the disodium salt of undecyclomidiniumethoxyethionic acid-2-ethionic acid, dodecyl beta alanine, and the inner salt of 2-trimethylamino lauric acid.
• the softergent compositions of the invention optionally contain a detergent builder of the type commonly used in detergent formulations.
• Useful builders include any of the conventional inorganic water-soluble builder salts, such as, for example, water-soluble salts of phosphates, pyrophosphates, orthophosphates, polyphosphates, silicates, carbonates, and the like.
• Organic builders include water-soluble phosphonates, polyphosphonates, polyhydroxysulfonates, polyacetates, carboxylates, polycarboxylates, succinates and the like.
• inorganic phosphate builders include sodium and potassium tripolyphosphates, pyrophosphates and hexametaphosphates.
• the organic polyphosphonates specifically include, for example, the sodium and potassium salts of ethane, 1-hydroxy-1, 1-diphosphonic acid and sodium and potassium salts of ethane-1,1,2-triphosphonic acid. Examples of these are other phosphorous builder compounds are disclosed in the U.S. Pat. Nos. 3,213,030; 3,422,021; 3,422,137 and 3,400,176.
• inert, water-soluble filler salt may be desirable in the laundering compositions of the invention.
• a preferred filler salt is an alkali metal sulfate, such as, potassium or sodium sulfate.
• Various adjuvants may be included in the laundry softergent compositions of the invention.
• these include; colorants, e.g., pigments and dyes; bleaches, such as, sodium perborate, anti-redeposition agents such as alkali metal salts of carboxymethylcellulose; optical brighteners such as anionic, cationic or nonionic brighteners; foam stabilizers, such as alkanolamides and the like, all of which are well-known in the fabric washing art for use in softergent compositions.
• Flow promoting agents commonly referred to as flow aids, many also be employed to maintain the particulate compositions as free-flowing beads or powder.
• Starch derivatives and special dyes and special clays are commercially available as additives which enhance the flowability of an otherwise tacky or pasty particulate composition.
• compositions were used individually employing the conventional laundering procedures involving water washing, rinsing, and machine drying.
• a load of 6 lbs. of fabric consisting of terry cloth towels was arranged in General Electric heavy duty washing machines.
• 100 gms of the detergent composition was sprinkled around clothes. Dials were set at normal wash, hot/cold temperature, and full wash cycle. The total wash time being 45-50 minutes.
• An unfragranced spray dried granular detergent composition was prepared from the following ingredients: Parts sodium dodecyl benzene sulfonate 15.0 Neodol 25-7* 5.0 sodium tripolyphosphate 30.0 sodium silicate 10.0 sodium sulfate 39.8 carboxymethyl cellulose 0. 2 100.0 * The condensation product of a mixture of C12-C15 Average alcohols ethoxylated with 7 moles of ethylene oxide/mole of alcohol, Shell Chemical Co., Inc.
• the detergent composition of Preparation, 1 supra ., (99.5 gms) was blended with 0.5 gms of the fragrance 3350D* in a blender for 30 minutes.
• This preparation is a typical marketed detergent product. * Bush, Boake, Allen, Inc.
• composition was put together according to the method of the Example 1 described in U.S. Patent No. 4,536,315 but using the fragrance 3350D, supra.
• the composition is a softergent on particles of a smectite-type of clay with an adhesive agent.
• An encapsulated fragrance 3350D, Supra. was prepared as follows:- Solid benzalkonium chloride (90.0 gms) was mixed with the fragrance and the mixture was then heated to 110°C until completely molten. The molten solution of the fragrance is stirred and chill sprayed through a nozzle using a Bowman spray dryer. The product collected as a free flowing solid which had a fragrance content of 10% by weight.
• the detergent formulation of preparation 1, supra. (5.0 gms.) was then blended with the encapsulated fragrance (5.0 gms).
• compositions prepared according to the Examples 1-4 were then tested for fragrance strength and character as described above.
• a detergent powder formulation was then prepared according to the following recipe: Ingredient Parts by Weight Sodium Dodecyl Benzene Sulfonate 15.0 Neodol 25-7, supra.

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• 1989
  • 1989-03-23 EP EP19890302947 patent/EP0334666A3/de not_active Withdrawn
  • 1989-03-23 ZA ZA892227A patent/ZA892227B/xx unknown
  • 1989-03-23 JP JP1071639A patent/JPH0270797A/ja active Pending
  • 1989-03-23 AU AU31649/89A patent/AU3164989A/en not_active Abandoned

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