EP0334604B1 - Method and apparatus for cooling molten filaments in spinning apparatus - Google Patents
Method and apparatus for cooling molten filaments in spinning apparatus Download PDFInfo
- Publication number
- EP0334604B1 EP0334604B1 EP89302795A EP89302795A EP0334604B1 EP 0334604 B1 EP0334604 B1 EP 0334604B1 EP 89302795 A EP89302795 A EP 89302795A EP 89302795 A EP89302795 A EP 89302795A EP 0334604 B1 EP0334604 B1 EP 0334604B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- cooling air
- filaments
- filament
- upstream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
- D01D5/092—Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
Definitions
- the present invention relates to a method for cooling a plurality of molten filaments comprised of a thermoplastic resin extruded from dies and to an apparatus for carrying out that method.
- Figure 3 shows a spinning apparatus for filaments comprised of polyethylene, polypropylene, or other thermoplastic resins.
- a plurality of molten filaments 2 extruded from a die 1 are cooled by cooling air blown from a cooling apparatus 3 and then taken up with a draft.
- the cooling apparatus 3 comprises a chimney 4 connected to a die 1 in a manner so as to surround the molten filaments 2 and a gas temperature adjustment apparatus 5 composed of coolers.
- the apparatus 5 cools the cooling air to the desired temperature and the cooling air is fed to the chimney 4 by a fan 6 and is blown from the inner peripheral surface thereof through a filter 7.
- Reference numeral 8 is an exhaust fan.
- the filaments are gradually cooled, the filaments tend to adhere to each other and, further, the cooling zone must be made longer, and thus the size of the apparatus is necessarily increased.
- US-A-3 070 839 describes apparatus which varies the cooling potential of the cooling air along the filament path by giving a greater volume to the flow of air at the upstream region than at the downstream region.
- GB-A-0 998 664 describes apparatus which uses a similar method to cool filaments, the rate of the flow downstream being greater by about 35% than upstream.
- an object of the present invention is to obviate the above-mentioned problems, caused by a too rapid or gradual cooling of the filaments.
- a method of cooling molten filaments in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown out from a cooling apparatus and are taken up with a draft, characterised by comprising controlling the temperature of the cooling air blown from the cooling apparatus so that the cooling effect in the upstream region of the filament path is made weaker than the cooling effect in the downstream region of the filament path.
- a cooling apparatus in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown from a cooling device and taken up with a draft, the cooling device being adapted to perform greater cooling in downstream regions of the filament path than in upstream regions of the filament path, characterised in that the difference in strength of cooling is achieved by providing the cooling air at different temperatures along the length of the filament path.
- the above-mentioned problems can be solved by controlling the temperature and/or volume of the cooling air so that the cooling is performed stronger, in stages or continuously, from upstream to downstream of the filament flow.
- the easiest way to change the cooling in stages and the easiest in terms of control is to divide the cooling zone into several sections, a cooling apparatus is provided for each section, and the cooling by the apparatus is made stronger in the downstream direction.
- the degree of strength of the cooling can be changed.
- the temperature and volume of air for cooling largely depend upon the materials to be extruded, the temperature of the molten filaments, and the extrusion rate, the temperature of the cooling air is preferably -20 ° C to 140°C, more preferably 0 to 100 ° C, and the volume of the cooling air to be blown is preferably 2 to 40 m 3 /kg, more preferably 5 to 25 m 3 /kg
- the materials to be extruded include, for example, polyethylene, polypropylene and other thermoplastic resins.
- the molten filaments extruded from the die are cooled weakly at the upstream portion of the cooling zone and strongly at the downstream portion thereof.
- the cooling is weak, the temperature difference of the filament surface and interior is made small and the draft is applied in that state to ensure that, a uniform draft is applied, whereby the elasticity, tensile strength, and other physical properties of the filaments are improved, and melting and breaking occur with difficulty.
- a strong cooling is performed for solidification, so adhesion between filaments occurs with difficulty.
- FIG. 1 shows a first embodiment of two-stage cooling apparatus according to the present invention, having the same construction as that of the cooling apparatus 3 provided in the spinning apparatus as shown in Fig. 3, except for the filter at the bottom of the cooling apparatus 3, i.e., is comprised of a chimney 12 and a gas temperature adjustment apparatus 13 comprised of coolers.
- the said apparatus sends the cooling air, cooled to a desired low temperature by the top stage gas temperature adjustment apparatus 13, to the chimney 12 by the fan 14 and connects this to a cooling apparatus 11 so that it is blown out from the inside peripheral surface. It blows out relatively high temperature cooling air from the top stage and relatively low temperature cooling air from the bottom stage thus slowly cooling the molten filaments 2 at the top stage and rapidly cooling them at the bottom stage.
- the preferable cooling conditions are as follows:
- the temperature of the cooling air blown out from the bottom stage is made lower than that at the top stage, but it is also possible to change the air amounts of the fans 6 and 14 so as to increase the amount of air of the bottom stage over the top stage and further possible to change both the temperature and air amount of the top and bottom stages.
- a typical example of the cooling condition when polyethlene is used is as follows:
- the embodiment shown in Fig. 2 is comprised in the same way as the apparatus shown in Fig. 1 outside of the fact that the fan 6 in the apparatus shown in Fig. 1 is made an exhaust fan and the cooling air of the bottom stage is exhausted from the fan 16, heated by the heater 17, then blown out from the top stage. As a result, cooling air of a relatively higher temperature is blown out from the top stage and cooling air of a relatively lower temperature is blown out from the bottom stage.
- the above-mentioned embodiment shows an example where two cooling apparatuses are connected for two-stage cooling, but in another embodiment three or more cooling apparatuses may be connected for multi-stage cooling and in still another embodiment heating wires may be wound around the internal peripheral surface of the chimney and the pitch made gradually closer upstream so as to heat the cooling air and give it a temperature gradient so that the temperature gradually falls downstream, whereby the cooling can be made continuously stronger downstream.
- the flow path of the cooling air can be formed to be gradually narrower upstream or formed so that the pressure loss gradually increases, thereby gradually decreasing the amount of the cooling air upstream.
- the cooling is made performed weaker at the upstream side and stronger at the downstream side, thereby improving the elasticity, tensile strength, and other physical properties of the filaments without enlarging the apparatus and further making molten breakage difficult and preventing mutual adhesion of filaments.
- the ratio of the weaker portion of the cooling at the cooling zone can be increased so as to avoid rapid cooling or elongation of the cooling zone.
- a plurality of cooling apparatuses are connected so as to strengthen the cooling in stages downstream.
- the temperature of the cooling air can be given a temperature gradient descending in the downstream direction and the cooling can be made continuously stronger downstream.
- the volume of the cooling air can be gradually increased downstream and thus the cooling can be made continuously stronger downstream.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
- The present invention relates to a method for cooling a plurality of molten filaments comprised of a thermoplastic resin extruded from dies and to an apparatus for carrying out that method.
- Figure 3 shows a spinning apparatus for filaments comprised of polyethylene, polypropylene, or other thermoplastic resins. In this apparatus, a plurality of
molten filaments 2 extruded from a die 1 are cooled by cooling air blown from acooling apparatus 3 and then taken up with a draft. Thecooling apparatus 3 comprises achimney 4 connected to a die 1 in a manner so as to surround themolten filaments 2 and a gastemperature adjustment apparatus 5 composed of coolers. Theapparatus 5 cools the cooling air to the desired temperature and the cooling air is fed to thechimney 4 by afan 6 and is blown from the inner peripheral surface thereof through afilter 7.Reference numeral 8 is an exhaust fan. - In the cooling of molten filaments, if the temperature of the cooling air is lowered or the air flow rate is increased so as to rapidly cool the filaments, only the surface of the filaments will be cooled and solidified. If a draft is applied to the filaments in that state, the filaments will melt and break or the elasticity, tensile strength, and other physical properties of the yarn will be lowered.
- Conversely, if the filaments are gradually cooled, the filaments tend to adhere to each other and, further, the cooling zone must be made longer, and thus the size of the apparatus is necessarily increased.
- Even if the spinning speed is increased or changed, if the cooling is carried out without changing the length of the cooling zone, a rapid cooling becomes necessary, and thus the problems discussed above will arise.
- US-A-3 070 839 describes apparatus which varies the cooling potential of the cooling air along the filament path by giving a greater volume to the flow of air at the upstream region than at the downstream region. GB-A-0 998 664 describes apparatus which uses a similar method to cool filaments, the rate of the flow downstream being greater by about 35% than upstream.
- Accordingly, an object of the present invention is to obviate the above-mentioned problems, caused by a too rapid or gradual cooling of the filaments.
- Other objects and advantages of the present invention will be apparent from the following description.
- In accordance with the present invention, there is provided a method of cooling molten filaments in a spinning apparatus, where a plurality of molten filaments extruded from a die are cooled by cooling air blown out from a cooling apparatus and are taken up with a draft, characterised by comprising controlling the temperature of the cooling air blown from the cooling apparatus so that the cooling effect in the upstream region of the filament path is made weaker than the cooling effect in the downstream region of the filament path.
- In accordance with the present invention, there is also provided a cooling apparatus in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown from a cooling device and taken up with a draft, the cooling device being adapted to perform greater cooling in downstream regions of the filament path than in upstream regions of the filament path, characterised in that the difference in strength of cooling is achieved by providing the cooling air at different temperatures along the length of the filament path.
- The present invention will be better understood from the description set forth below with reference to the accompanying drawings, in which:
- Figure 1 is a schematic view of a spinning apparatus provided with a cooling apparatus according to a first embodiment of the present invention;
- Fig. 2 is a schematic view of a spinning apparatus provided with another cooling apparatus; and
- Fig. 3 is a schematic view of a conventional spinning apparatus.
- According to the present invention, the above-mentioned problems can be solved by controlling the temperature and/or volume of the cooling air so that the cooling is performed stronger, in stages or continuously, from upstream to downstream of the filament flow.
- The easiest way to change the cooling in stages and the easiest in terms of control is to divide the cooling zone into several sections, a cooling apparatus is provided for each section, and the cooling by the apparatus is made stronger in the downstream direction.
- To change the cooling continuously, it is possible to adopt, for example, a method of arranging a heater in the flow path of the cooling air, and the pitch of the heating wires is made closer in the upstream direction so as to gradually increase the amount of heat generated, whereby the cooling air is warmed by contact with the heater and then blown or a method of forming the flow path of the cooling air is gradually narrowed in the upstream direction or the pressure loss is gradually increased to gradually reduce the amount of air upstream of the filament flow.
- Further, when changing the spinning speed is changed, the degree of strength of the cooling can be changed.
- Although the temperature and volume of air for cooling largely depend upon the materials to be extruded, the temperature of the molten filaments, and the extrusion rate, the temperature of the cooling air is preferably -20 ° C to 140°C, more preferably 0 to 100°C, and the volume of the cooling air to be blown is preferably 2 to 40 m3/kg, more preferably 5 to 25 m3/kg The materials to be extruded include, for example, polyethylene, polypropylene and other thermoplastic resins.
- The molten filaments extruded from the die are cooled weakly at the upstream portion of the cooling zone and strongly at the downstream portion thereof. When the cooling is weak, the temperature difference of the filament surface and interior is made small and the draft is applied in that state to ensure that, a uniform draft is applied, whereby the elasticity, tensile strength, and other physical properties of the filaments are improved, and melting and breaking occur with difficulty. Further, at the downstream side where the filaments are taken up, a strong cooling is performed for solidification, so adhesion between filaments occurs with difficulty. Thus, it is possible to make the cooling zone shorter than with gradual cooling of the whole.
- If the spinning speed is increased, it is possible to avoid rapid cooling by increasing the ratio of the weak cooling in the cooling zone. Note that when the spinning speed is reduced, there is no problem if the ratios of the strength of the cooling are varied.
- Figure 1 shows a first embodiment of two-stage cooling apparatus according to the present invention, having the same construction as that of the
cooling apparatus 3 provided in the spinning apparatus as shown in Fig. 3, except for the filter at the bottom of thecooling apparatus 3, i.e., is comprised of achimney 12 and a gastemperature adjustment apparatus 13 comprised of coolers. The said apparatus sends the cooling air, cooled to a desired low temperature by the top stage gastemperature adjustment apparatus 13, to thechimney 12 by thefan 14 and connects this to acooling apparatus 11 so that it is blown out from the inside peripheral surface. It blows out relatively high temperature cooling air from the top stage and relatively low temperature cooling air from the bottom stage thus slowly cooling themolten filaments 2 at the top stage and rapidly cooling them at the bottom stage. - For example, when polyethylene is used, the preferable cooling conditions are as follows:
- Top stage: 30 ° C x 8 m3/kg
- Bottom stage: 10 ° C x 8 m3/kg
- In the above-mentioned embodiment, the temperature of the cooling air blown out from the bottom stage is made lower than that at the top stage, but it is also possible to change the air amounts of the
fans - A typical example of the cooling condition when polyethlene is used is as follows:
- Top stage: 20 ° C x 4 m3/kg
- Bottom stage: 10 ° C x 8 m3/kg
- The embodiment shown in Fig. 2 is comprised in the same way as the apparatus shown in Fig. 1 outside of the fact that the
fan 6 in the apparatus shown in Fig. 1 is made an exhaust fan and the cooling air of the bottom stage is exhausted from thefan 16, heated by theheater 17, then blown out from the top stage. As a result, cooling air of a relatively higher temperature is blown out from the top stage and cooling air of a relatively lower temperature is blown out from the bottom stage. - The above-mentioned embodiment shows an example where two cooling apparatuses are connected for two-stage cooling, but in another embodiment three or more cooling apparatuses may be connected for multi-stage cooling and in still another embodiment heating wires may be wound around the internal peripheral surface of the chimney and the pitch made gradually closer upstream so as to heat the cooling air and give it a temperature gradient so that the temperature gradually falls downstream, whereby the cooling can be made continuously stronger downstream. Further, in another embodiment, the flow path of the cooling air can be formed to be gradually narrower upstream or formed so that the pressure loss gradually increases, thereby gradually decreasing the amount of the cooling air upstream.
- As mentioned above, according to the method of claim 1, the cooling is made performed weaker at the upstream side and stronger at the downstream side, thereby improving the elasticity, tensile strength, and other physical properties of the filaments without enlarging the apparatus and further making molten breakage difficult and preventing mutual adhesion of filaments.
- According to the method of
claim 2, even if the spinning speed is changed to make it faster, the ratio of the weaker portion of the cooling at the cooling zone can be increased so as to avoid rapid cooling or elongation of the cooling zone. - In the cooling apparatus of
claim 6, a plurality of cooling apparatuses are connected so as to strengthen the cooling in stages downstream. - In the cooling apparatus of
claim 7, the temperature of the cooling air can be given a temperature gradient descending in the downstream direction and the cooling can be made continuously stronger downstream. - In the cooling apparatus according to
claim 8, the volume of the cooling air can be gradually increased downstream and thus the cooling can be made continuously stronger downstream.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89302795T ATE97704T1 (en) | 1988-03-24 | 1989-03-21 | METHOD AND DEVICE FOR COOLING MELT-SPUN FILAMENTS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63070915A JP2674656B2 (en) | 1988-03-24 | 1988-03-24 | Method and apparatus for cooling molten filament in spinning device |
JP70915/88 | 1988-03-24 |
Publications (4)
Publication Number | Publication Date |
---|---|
EP0334604A2 EP0334604A2 (en) | 1989-09-27 |
EP0334604A3 EP0334604A3 (en) | 1990-03-14 |
EP0334604B1 true EP0334604B1 (en) | 1993-11-24 |
EP0334604B2 EP0334604B2 (en) | 1996-11-27 |
Family
ID=13445282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89302795A Expired - Lifetime EP0334604B2 (en) | 1988-03-24 | 1989-03-21 | Method and apparatus for cooling molten filaments in spinning apparatus |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0334604B2 (en) |
JP (1) | JP2674656B2 (en) |
KR (1) | KR960006931B1 (en) |
CN (1) | CN1022581C (en) |
AT (1) | ATE97704T1 (en) |
AU (1) | AU625777B2 (en) |
CA (1) | CA1325088C (en) |
DE (1) | DE68910857T3 (en) |
HK (1) | HK84794A (en) |
NZ (1) | NZ228457A (en) |
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DE3941824A1 (en) * | 1989-12-19 | 1991-06-27 | Corovin Gmbh | METHOD AND SPINNING DEVICE FOR PRODUCING MICROFILAMENTS |
DE29512001U1 (en) * | 1995-07-25 | 1995-10-05 | Ems-Inventa AG, Zürich | Blow wall for cooling melt-spinnable synthetic threads |
DE59705511D1 (en) * | 1996-08-28 | 2002-01-10 | Barmag Barmer Maschf | Method and device for spinning a multifilament thread |
DE19821778B4 (en) * | 1998-05-14 | 2004-05-06 | Ems-Inventa Ag | Device and method for producing microfilaments of high titer uniformity from thermoplastic polymers |
KR100574180B1 (en) * | 1998-07-23 | 2006-04-27 | 바마크 악티엔게젤샤프트 | Spinning device and method for spinning a synthetic thread |
US6444151B1 (en) * | 1999-04-15 | 2002-09-03 | E. I. Du Pont De Nemours And Company | Apparatus and process for spinning polymeric filaments |
JP2002309431A (en) * | 2000-06-21 | 2002-10-23 | Toray Eng Co Ltd | Spinning apparatus |
JP2002302862A (en) * | 2001-04-06 | 2002-10-18 | Mitsui Chemicals Inc | Method of producing nonwoven fabric and apparatus therefor |
ATE381630T1 (en) * | 2002-02-28 | 2008-01-15 | Reifenhaeuser Gmbh & Co Kg | SYSTEM FOR THE CONTINUOUS PRODUCTION OF A SPUNNOVED WEB |
PT1521869E (en) | 2002-07-05 | 2012-01-03 | Api Inst | Spinning method |
US7198843B2 (en) * | 2002-07-26 | 2007-04-03 | Kolon Industries, Inc. | High strength low shrinkage polyester drawn yarn, and a process of preparing for the same |
CN1333119C (en) * | 2003-04-11 | 2007-08-22 | 南亚塑胶工业股份有限公司 | Fine-denier polyester hollow filament spinning method and its produced pilament |
WO2006024435A1 (en) * | 2004-08-27 | 2006-03-09 | Diolen Industrial Fibers B.V. | Spinning method and device for carrying out said method |
JP2007284857A (en) * | 2006-03-22 | 2007-11-01 | Toray Ind Inc | Method for melt spinning polyester and its melt spinning apparatus |
JP5256970B2 (en) * | 2008-09-30 | 2013-08-07 | 東レ株式会社 | Melt spinning winding method and melt spinning winding device for cellulose fatty acid mixed ester fiber yarn |
CN101922056B (en) * | 2009-06-12 | 2012-05-23 | 珠海醋酸纤维有限公司 | Method for adjusting spinning channel wind |
GB2479552B (en) * | 2010-04-14 | 2015-07-08 | Aker Subsea Ltd | Subsea wellhead providing controlled access to a casing annulus |
DE102010020187A1 (en) * | 2010-05-11 | 2011-11-17 | Oerlikon Textile Gmbh & Co. Kg | Method and apparatus for melt spinning and cooling a variety of synthetic filaments |
CN101831718B (en) * | 2010-05-24 | 2012-07-04 | 桐乡市中辰化纤有限公司 | Method for preparing super-thick denier polyester monofilament |
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CN102797060B (en) * | 2012-09-03 | 2015-05-13 | 江苏恒力化纤股份有限公司 | Method and device for producing high-grade highway protective guard framework material polyester industrial yarn |
CN102787378B (en) * | 2012-09-03 | 2014-12-17 | 江苏恒力化纤股份有限公司 | Manufacturing method for high-strength low-elongation type dacron industrial yarn |
WO2015044953A1 (en) * | 2013-09-26 | 2015-04-02 | Reliance Industries Limited | System, method and device for quenching synthetic multifilament fibers |
KR20160001324A (en) | 2014-06-27 | 2016-01-06 | 이상수 | Composition for eye wash and production method thereof |
CN104153741A (en) * | 2014-08-26 | 2014-11-19 | 中国石油集团川庆钻探工程有限公司工程技术研究院 | Control valve system for external casing packer |
NO342043B1 (en) * | 2015-12-08 | 2018-03-19 | Aker Solutions As | Workover Safety System |
IT201900023235A1 (en) * | 2019-12-06 | 2021-06-06 | Ramina S R L | PLANT FOR THE PRODUCTION OF NON-WOVEN FABRIC |
CN111058104A (en) * | 2019-12-31 | 2020-04-24 | 浙江金海环境技术股份有限公司 | Environmental temperature control method, control device, melt-blown nonwoven material production line and preparation system |
CN111088534A (en) * | 2020-01-17 | 2020-05-01 | 晋江市兴泰无纺制品有限公司 | Refrigerating system for fiber drafting |
CN114592244A (en) * | 2022-02-27 | 2022-06-07 | 浙江坤兴化纤科技有限公司 | Environment-friendly processing technology of high-strength polyester POY |
CN115182059B (en) * | 2022-06-13 | 2023-11-14 | 桐昆集团浙江恒超化纤有限公司 | Polyester fiber spinning equipment special for high-elastic spring spinning and spinning process |
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US3070839A (en) * | 1958-12-24 | 1963-01-01 | Du Pont | Controlled quenching apparatus |
LU44675A1 (en) * | 1962-11-15 | 1963-12-23 | ||
JPS539293A (en) * | 1976-07-14 | 1978-01-27 | Ebara Corp | Method and apparatus for regenerating activated carbon |
-
1988
- 1988-03-24 JP JP63070915A patent/JP2674656B2/en not_active Expired - Lifetime
-
1989
- 1989-03-21 AT AT89302795T patent/ATE97704T1/en not_active IP Right Cessation
- 1989-03-21 DE DE68910857T patent/DE68910857T3/en not_active Expired - Fee Related
- 1989-03-21 EP EP89302795A patent/EP0334604B2/en not_active Expired - Lifetime
- 1989-03-22 NZ NZ228457A patent/NZ228457A/en unknown
- 1989-03-22 AU AU31608/89A patent/AU625777B2/en not_active Ceased
- 1989-03-23 CA CA000594757A patent/CA1325088C/en not_active Expired - Fee Related
- 1989-03-23 CN CN89101766A patent/CN1022581C/en not_active Expired - Fee Related
- 1989-03-24 KR KR1019890003689A patent/KR960006931B1/en not_active IP Right Cessation
-
1994
- 1994-08-18 HK HK84794A patent/HK84794A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA1325088C (en) | 1993-12-14 |
JP2674656B2 (en) | 1997-11-12 |
AU625777B2 (en) | 1992-07-16 |
EP0334604B2 (en) | 1996-11-27 |
EP0334604A3 (en) | 1990-03-14 |
KR960006931B1 (en) | 1996-05-25 |
DE68910857T3 (en) | 1997-04-10 |
ATE97704T1 (en) | 1993-12-15 |
KR890014793A (en) | 1989-10-25 |
DE68910857D1 (en) | 1994-01-05 |
DE68910857T2 (en) | 1994-03-17 |
HK84794A (en) | 1994-08-26 |
CN1038135A (en) | 1989-12-20 |
AU3160889A (en) | 1989-09-28 |
CN1022581C (en) | 1993-10-27 |
EP0334604A2 (en) | 1989-09-27 |
NZ228457A (en) | 1991-11-26 |
JPH01246408A (en) | 1989-10-02 |
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