EP0334604B1 - Method and apparatus for cooling molten filaments in spinning apparatus - Google Patents

Method and apparatus for cooling molten filaments in spinning apparatus Download PDF

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Publication number
EP0334604B1
EP0334604B1 EP89302795A EP89302795A EP0334604B1 EP 0334604 B1 EP0334604 B1 EP 0334604B1 EP 89302795 A EP89302795 A EP 89302795A EP 89302795 A EP89302795 A EP 89302795A EP 0334604 B1 EP0334604 B1 EP 0334604B1
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EP
European Patent Office
Prior art keywords
cooling
cooling air
filaments
filament
upstream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89302795A
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German (de)
French (fr)
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EP0334604B2 (en
EP0334604A3 (en
EP0334604A2 (en
Inventor
Eiji Katou
Akifumi Katou
Yoshihiro Yoshimura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
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Mitsui Petrochemical Industries Ltd
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Publication date
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Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Priority to AT89302795T priority Critical patent/ATE97704T1/en
Publication of EP0334604A2 publication Critical patent/EP0334604A2/en
Publication of EP0334604A3 publication Critical patent/EP0334604A3/en
Application granted granted Critical
Publication of EP0334604B1 publication Critical patent/EP0334604B1/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes
    • D01D5/092Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes

Definitions

  • the present invention relates to a method for cooling a plurality of molten filaments comprised of a thermoplastic resin extruded from dies and to an apparatus for carrying out that method.
  • Figure 3 shows a spinning apparatus for filaments comprised of polyethylene, polypropylene, or other thermoplastic resins.
  • a plurality of molten filaments 2 extruded from a die 1 are cooled by cooling air blown from a cooling apparatus 3 and then taken up with a draft.
  • the cooling apparatus 3 comprises a chimney 4 connected to a die 1 in a manner so as to surround the molten filaments 2 and a gas temperature adjustment apparatus 5 composed of coolers.
  • the apparatus 5 cools the cooling air to the desired temperature and the cooling air is fed to the chimney 4 by a fan 6 and is blown from the inner peripheral surface thereof through a filter 7.
  • Reference numeral 8 is an exhaust fan.
  • the filaments are gradually cooled, the filaments tend to adhere to each other and, further, the cooling zone must be made longer, and thus the size of the apparatus is necessarily increased.
  • US-A-3 070 839 describes apparatus which varies the cooling potential of the cooling air along the filament path by giving a greater volume to the flow of air at the upstream region than at the downstream region.
  • GB-A-0 998 664 describes apparatus which uses a similar method to cool filaments, the rate of the flow downstream being greater by about 35% than upstream.
  • an object of the present invention is to obviate the above-mentioned problems, caused by a too rapid or gradual cooling of the filaments.
  • a method of cooling molten filaments in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown out from a cooling apparatus and are taken up with a draft, characterised by comprising controlling the temperature of the cooling air blown from the cooling apparatus so that the cooling effect in the upstream region of the filament path is made weaker than the cooling effect in the downstream region of the filament path.
  • a cooling apparatus in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown from a cooling device and taken up with a draft, the cooling device being adapted to perform greater cooling in downstream regions of the filament path than in upstream regions of the filament path, characterised in that the difference in strength of cooling is achieved by providing the cooling air at different temperatures along the length of the filament path.
  • the above-mentioned problems can be solved by controlling the temperature and/or volume of the cooling air so that the cooling is performed stronger, in stages or continuously, from upstream to downstream of the filament flow.
  • the easiest way to change the cooling in stages and the easiest in terms of control is to divide the cooling zone into several sections, a cooling apparatus is provided for each section, and the cooling by the apparatus is made stronger in the downstream direction.
  • the degree of strength of the cooling can be changed.
  • the temperature and volume of air for cooling largely depend upon the materials to be extruded, the temperature of the molten filaments, and the extrusion rate, the temperature of the cooling air is preferably -20 ° C to 140°C, more preferably 0 to 100 ° C, and the volume of the cooling air to be blown is preferably 2 to 40 m 3 /kg, more preferably 5 to 25 m 3 /kg
  • the materials to be extruded include, for example, polyethylene, polypropylene and other thermoplastic resins.
  • the molten filaments extruded from the die are cooled weakly at the upstream portion of the cooling zone and strongly at the downstream portion thereof.
  • the cooling is weak, the temperature difference of the filament surface and interior is made small and the draft is applied in that state to ensure that, a uniform draft is applied, whereby the elasticity, tensile strength, and other physical properties of the filaments are improved, and melting and breaking occur with difficulty.
  • a strong cooling is performed for solidification, so adhesion between filaments occurs with difficulty.
  • FIG. 1 shows a first embodiment of two-stage cooling apparatus according to the present invention, having the same construction as that of the cooling apparatus 3 provided in the spinning apparatus as shown in Fig. 3, except for the filter at the bottom of the cooling apparatus 3, i.e., is comprised of a chimney 12 and a gas temperature adjustment apparatus 13 comprised of coolers.
  • the said apparatus sends the cooling air, cooled to a desired low temperature by the top stage gas temperature adjustment apparatus 13, to the chimney 12 by the fan 14 and connects this to a cooling apparatus 11 so that it is blown out from the inside peripheral surface. It blows out relatively high temperature cooling air from the top stage and relatively low temperature cooling air from the bottom stage thus slowly cooling the molten filaments 2 at the top stage and rapidly cooling them at the bottom stage.
  • the preferable cooling conditions are as follows:
  • the temperature of the cooling air blown out from the bottom stage is made lower than that at the top stage, but it is also possible to change the air amounts of the fans 6 and 14 so as to increase the amount of air of the bottom stage over the top stage and further possible to change both the temperature and air amount of the top and bottom stages.
  • a typical example of the cooling condition when polyethlene is used is as follows:
  • the embodiment shown in Fig. 2 is comprised in the same way as the apparatus shown in Fig. 1 outside of the fact that the fan 6 in the apparatus shown in Fig. 1 is made an exhaust fan and the cooling air of the bottom stage is exhausted from the fan 16, heated by the heater 17, then blown out from the top stage. As a result, cooling air of a relatively higher temperature is blown out from the top stage and cooling air of a relatively lower temperature is blown out from the bottom stage.
  • the above-mentioned embodiment shows an example where two cooling apparatuses are connected for two-stage cooling, but in another embodiment three or more cooling apparatuses may be connected for multi-stage cooling and in still another embodiment heating wires may be wound around the internal peripheral surface of the chimney and the pitch made gradually closer upstream so as to heat the cooling air and give it a temperature gradient so that the temperature gradually falls downstream, whereby the cooling can be made continuously stronger downstream.
  • the flow path of the cooling air can be formed to be gradually narrower upstream or formed so that the pressure loss gradually increases, thereby gradually decreasing the amount of the cooling air upstream.
  • the cooling is made performed weaker at the upstream side and stronger at the downstream side, thereby improving the elasticity, tensile strength, and other physical properties of the filaments without enlarging the apparatus and further making molten breakage difficult and preventing mutual adhesion of filaments.
  • the ratio of the weaker portion of the cooling at the cooling zone can be increased so as to avoid rapid cooling or elongation of the cooling zone.
  • a plurality of cooling apparatuses are connected so as to strengthen the cooling in stages downstream.
  • the temperature of the cooling air can be given a temperature gradient descending in the downstream direction and the cooling can be made continuously stronger downstream.
  • the volume of the cooling air can be gradually increased downstream and thus the cooling can be made continuously stronger downstream.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

A method for cooling molten filaments in a spinning apparatus where, a plurality of molten filaments (2) extruded from a die (1) are cooled by cooling air blown out from a cooling apparatus (3) and are taken up with a draft, wherein the temperature and/or volume of the cooling air blown from the cooling apparatus is controlled so that the cooling is performed stronger, in stages or continuously, from upstream to downstream.

Description

    1. Field of the Invention
  • The present invention relates to a method for cooling a plurality of molten filaments comprised of a thermoplastic resin extruded from dies and to an apparatus for carrying out that method.
  • 2. Description of the Related Art
  • Figure 3 shows a spinning apparatus for filaments comprised of polyethylene, polypropylene, or other thermoplastic resins. In this apparatus, a plurality of molten filaments 2 extruded from a die 1 are cooled by cooling air blown from a cooling apparatus 3 and then taken up with a draft. The cooling apparatus 3 comprises a chimney 4 connected to a die 1 in a manner so as to surround the molten filaments 2 and a gas temperature adjustment apparatus 5 composed of coolers. The apparatus 5 cools the cooling air to the desired temperature and the cooling air is fed to the chimney 4 by a fan 6 and is blown from the inner peripheral surface thereof through a filter 7. Reference numeral 8 is an exhaust fan.
  • In the cooling of molten filaments, if the temperature of the cooling air is lowered or the air flow rate is increased so as to rapidly cool the filaments, only the surface of the filaments will be cooled and solidified. If a draft is applied to the filaments in that state, the filaments will melt and break or the elasticity, tensile strength, and other physical properties of the yarn will be lowered.
  • Conversely, if the filaments are gradually cooled, the filaments tend to adhere to each other and, further, the cooling zone must be made longer, and thus the size of the apparatus is necessarily increased.
  • Even if the spinning speed is increased or changed, if the cooling is carried out without changing the length of the cooling zone, a rapid cooling becomes necessary, and thus the problems discussed above will arise.
  • US-A-3 070 839 describes apparatus which varies the cooling potential of the cooling air along the filament path by giving a greater volume to the flow of air at the upstream region than at the downstream region. GB-A-0 998 664 describes apparatus which uses a similar method to cool filaments, the rate of the flow downstream being greater by about 35% than upstream.
  • Accordingly, an object of the present invention is to obviate the above-mentioned problems, caused by a too rapid or gradual cooling of the filaments.
  • Other objects and advantages of the present invention will be apparent from the following description.
  • In accordance with the present invention, there is provided a method of cooling molten filaments in a spinning apparatus, where a plurality of molten filaments extruded from a die are cooled by cooling air blown out from a cooling apparatus and are taken up with a draft, characterised by comprising controlling the temperature of the cooling air blown from the cooling apparatus so that the cooling effect in the upstream region of the filament path is made weaker than the cooling effect in the downstream region of the filament path.
  • In accordance with the present invention, there is also provided a cooling apparatus in a spinning apparatus where a plurality of molten filaments extruded from a die are cooled by cooling air blown from a cooling device and taken up with a draft, the cooling device being adapted to perform greater cooling in downstream regions of the filament path than in upstream regions of the filament path, characterised in that the difference in strength of cooling is achieved by providing the cooling air at different temperatures along the length of the filament path.
  • The present invention will be better understood from the description set forth below with reference to the accompanying drawings, in which:
    • Figure 1 is a schematic view of a spinning apparatus provided with a cooling apparatus according to a first embodiment of the present invention;
    • Fig. 2 is a schematic view of a spinning apparatus provided with another cooling apparatus; and
    • Fig. 3 is a schematic view of a conventional spinning apparatus.
    DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • According to the present invention, the above-mentioned problems can be solved by controlling the temperature and/or volume of the cooling air so that the cooling is performed stronger, in stages or continuously, from upstream to downstream of the filament flow.
  • The easiest way to change the cooling in stages and the easiest in terms of control is to divide the cooling zone into several sections, a cooling apparatus is provided for each section, and the cooling by the apparatus is made stronger in the downstream direction.
  • To change the cooling continuously, it is possible to adopt, for example, a method of arranging a heater in the flow path of the cooling air, and the pitch of the heating wires is made closer in the upstream direction so as to gradually increase the amount of heat generated, whereby the cooling air is warmed by contact with the heater and then blown or a method of forming the flow path of the cooling air is gradually narrowed in the upstream direction or the pressure loss is gradually increased to gradually reduce the amount of air upstream of the filament flow.
  • Further, when changing the spinning speed is changed, the degree of strength of the cooling can be changed.
  • Although the temperature and volume of air for cooling largely depend upon the materials to be extruded, the temperature of the molten filaments, and the extrusion rate, the temperature of the cooling air is preferably -20 ° C to 140°C, more preferably 0 to 100°C, and the volume of the cooling air to be blown is preferably 2 to 40 m3/kg, more preferably 5 to 25 m3/kg The materials to be extruded include, for example, polyethylene, polypropylene and other thermoplastic resins.
  • The molten filaments extruded from the die are cooled weakly at the upstream portion of the cooling zone and strongly at the downstream portion thereof. When the cooling is weak, the temperature difference of the filament surface and interior is made small and the draft is applied in that state to ensure that, a uniform draft is applied, whereby the elasticity, tensile strength, and other physical properties of the filaments are improved, and melting and breaking occur with difficulty. Further, at the downstream side where the filaments are taken up, a strong cooling is performed for solidification, so adhesion between filaments occurs with difficulty. Thus, it is possible to make the cooling zone shorter than with gradual cooling of the whole.
  • If the spinning speed is increased, it is possible to avoid rapid cooling by increasing the ratio of the weak cooling in the cooling zone. Note that when the spinning speed is reduced, there is no problem if the ratios of the strength of the cooling are varied.
  • Embodiments
  • Figure 1 shows a first embodiment of two-stage cooling apparatus according to the present invention, having the same construction as that of the cooling apparatus 3 provided in the spinning apparatus as shown in Fig. 3, except for the filter at the bottom of the cooling apparatus 3, i.e., is comprised of a chimney 12 and a gas temperature adjustment apparatus 13 comprised of coolers. The said apparatus sends the cooling air, cooled to a desired low temperature by the top stage gas temperature adjustment apparatus 13, to the chimney 12 by the fan 14 and connects this to a cooling apparatus 11 so that it is blown out from the inside peripheral surface. It blows out relatively high temperature cooling air from the top stage and relatively low temperature cooling air from the bottom stage thus slowly cooling the molten filaments 2 at the top stage and rapidly cooling them at the bottom stage.
  • For example, when polyethylene is used, the preferable cooling conditions are as follows:
    • Top stage: 30 ° C x 8 m3/kg
    • Bottom stage: 10 ° C x 8 m3/kg
  • In the above-mentioned embodiment, the temperature of the cooling air blown out from the bottom stage is made lower than that at the top stage, but it is also possible to change the air amounts of the fans 6 and 14 so as to increase the amount of air of the bottom stage over the top stage and further possible to change both the temperature and air amount of the top and bottom stages.
  • A typical example of the cooling condition when polyethlene is used is as follows:
    • Top stage: 20 ° C x 4 m3/kg
    • Bottom stage: 10 ° C x 8 m3/kg
  • The embodiment shown in Fig. 2 is comprised in the same way as the apparatus shown in Fig. 1 outside of the fact that the fan 6 in the apparatus shown in Fig. 1 is made an exhaust fan and the cooling air of the bottom stage is exhausted from the fan 16, heated by the heater 17, then blown out from the top stage. As a result, cooling air of a relatively higher temperature is blown out from the top stage and cooling air of a relatively lower temperature is blown out from the bottom stage.
  • The above-mentioned embodiment shows an example where two cooling apparatuses are connected for two-stage cooling, but in another embodiment three or more cooling apparatuses may be connected for multi-stage cooling and in still another embodiment heating wires may be wound around the internal peripheral surface of the chimney and the pitch made gradually closer upstream so as to heat the cooling air and give it a temperature gradient so that the temperature gradually falls downstream, whereby the cooling can be made continuously stronger downstream. Further, in another embodiment, the flow path of the cooling air can be formed to be gradually narrower upstream or formed so that the pressure loss gradually increases, thereby gradually decreasing the amount of the cooling air upstream.
  • As mentioned above, according to the method of claim 1, the cooling is made performed weaker at the upstream side and stronger at the downstream side, thereby improving the elasticity, tensile strength, and other physical properties of the filaments without enlarging the apparatus and further making molten breakage difficult and preventing mutual adhesion of filaments.
  • According to the method of claim 2, even if the spinning speed is changed to make it faster, the ratio of the weaker portion of the cooling at the cooling zone can be increased so as to avoid rapid cooling or elongation of the cooling zone.
  • In the cooling apparatus of claim 6, a plurality of cooling apparatuses are connected so as to strengthen the cooling in stages downstream.
  • In the cooling apparatus of claim 7, the temperature of the cooling air can be given a temperature gradient descending in the downstream direction and the cooling can be made continuously stronger downstream.
  • In the cooling apparatus according to claim 8, the volume of the cooling air can be gradually increased downstream and thus the cooling can be made continuously stronger downstream.

Claims (9)

1. A method of cooling molten filaments (2) in a spinning apparatus, where a plurality of molten filaments (2) extruded from a die (1) are cooled by cooling air blown out from a cooling apparatus (3,11) and are taken up with a draft, characterised by comprising controlling the temperature of the cooling air blown from the cooling apparatus (3,11) so that the cooling effect in the upstream region of the filament path is made weaker than the cooling effect in the downstream region of the filament path.
2. A method of cooling molten filaments as claimed in claim 1, further comprising the step of changing the speed at which the filaments are spun by the spinning apparatus, whereby the degree of strength of the cooling is changed, the amount of time the filaments are exposed to the air being proportional to said speed.
3. A method according to claim 1 or 2, further comprising controlling the volume of the cooling air to adjust the cooling effect in the upstream region and in the downstream region.
4. A method according to claim 1, 2 or 3, wherein the temperature of the cooling air is controlled by heater means.
5. A method according to claim 1, 2, 3 or 4, wherein the change in cooling rate along the filament stream is continuous.
6. A method according to claim 1, 2, 3 or 4, wherein the change in cooling rate along the filament stream is stepwise.
7. A cooling apparatus in a spinning apparatus where a plurality of molten filaments (2) extruded from a die (1) are cooled by cooling air blown from a cooling device (3,11) and taken up with a draft, the cooling device (3,11) being adapted to perform greater cooling in downstream regions of the filament path than in upstream regions of the filament path, characterised in that the difference in strength of cooling is achieved by providing the cooling air at different temperatures along the length of the filament path.
8. A cooling apparatus according to claim 7, wherein there is provided a heater in the flow path of the cooling air, said heater including heating wires arranged such that the pitch of the heating wire is closer in the upstream region of the filament path than in the downstream region, whereby the temperature of the cooling air is higher near the extruding die than near the take up means.
9. A cooling apparatus according to claim 7 or 8, wherein the flow path of the cooling air is formed so as to be more restricted in the upstream parts of the filament path or is formed so as to have increased pressure loss in those parts.
EP89302795A 1988-03-24 1989-03-21 Method and apparatus for cooling molten filaments in spinning apparatus Expired - Lifetime EP0334604B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89302795T ATE97704T1 (en) 1988-03-24 1989-03-21 METHOD AND DEVICE FOR COOLING MELT-SPUN FILAMENTS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP63070915A JP2674656B2 (en) 1988-03-24 1988-03-24 Method and apparatus for cooling molten filament in spinning device
JP70915/88 1988-03-24

Publications (4)

Publication Number Publication Date
EP0334604A2 EP0334604A2 (en) 1989-09-27
EP0334604A3 EP0334604A3 (en) 1990-03-14
EP0334604B1 true EP0334604B1 (en) 1993-11-24
EP0334604B2 EP0334604B2 (en) 1996-11-27

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EP89302795A Expired - Lifetime EP0334604B2 (en) 1988-03-24 1989-03-21 Method and apparatus for cooling molten filaments in spinning apparatus

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EP (1) EP0334604B2 (en)
JP (1) JP2674656B2 (en)
KR (1) KR960006931B1 (en)
CN (1) CN1022581C (en)
AT (1) ATE97704T1 (en)
AU (1) AU625777B2 (en)
CA (1) CA1325088C (en)
DE (1) DE68910857T3 (en)
HK (1) HK84794A (en)
NZ (1) NZ228457A (en)

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DE19821778B4 (en) * 1998-05-14 2004-05-06 Ems-Inventa Ag Device and method for producing microfilaments of high titer uniformity from thermoplastic polymers
KR100574180B1 (en) * 1998-07-23 2006-04-27 바마크 악티엔게젤샤프트 Spinning device and method for spinning a synthetic thread
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CN101922056B (en) * 2009-06-12 2012-05-23 珠海醋酸纤维有限公司 Method for adjusting spinning channel wind
GB2479552B (en) * 2010-04-14 2015-07-08 Aker Subsea Ltd Subsea wellhead providing controlled access to a casing annulus
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CN101831718B (en) * 2010-05-24 2012-07-04 桐乡市中辰化纤有限公司 Method for preparing super-thick denier polyester monofilament
NO334816B1 (en) * 2011-04-28 2014-06-02 Aker Subsea As The subsea well assembly
CN103582740A (en) * 2011-06-17 2014-02-12 Bp北美公司 Air-freightable containment cap for containing a subsea well
CN102797060B (en) * 2012-09-03 2015-05-13 江苏恒力化纤股份有限公司 Method and device for producing high-grade highway protective guard framework material polyester industrial yarn
CN102787378B (en) * 2012-09-03 2014-12-17 江苏恒力化纤股份有限公司 Manufacturing method for high-strength low-elongation type dacron industrial yarn
WO2015044953A1 (en) * 2013-09-26 2015-04-02 Reliance Industries Limited System, method and device for quenching synthetic multifilament fibers
KR20160001324A (en) 2014-06-27 2016-01-06 이상수 Composition for eye wash and production method thereof
CN104153741A (en) * 2014-08-26 2014-11-19 中国石油集团川庆钻探工程有限公司工程技术研究院 Control valve system for external casing packer
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IT201900023235A1 (en) * 2019-12-06 2021-06-06 Ramina S R L PLANT FOR THE PRODUCTION OF NON-WOVEN FABRIC
CN111058104A (en) * 2019-12-31 2020-04-24 浙江金海环境技术股份有限公司 Environmental temperature control method, control device, melt-blown nonwoven material production line and preparation system
CN111088534A (en) * 2020-01-17 2020-05-01 晋江市兴泰无纺制品有限公司 Refrigerating system for fiber drafting
CN114592244A (en) * 2022-02-27 2022-06-07 浙江坤兴化纤科技有限公司 Environment-friendly processing technology of high-strength polyester POY
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Also Published As

Publication number Publication date
CA1325088C (en) 1993-12-14
JP2674656B2 (en) 1997-11-12
AU625777B2 (en) 1992-07-16
EP0334604B2 (en) 1996-11-27
EP0334604A3 (en) 1990-03-14
KR960006931B1 (en) 1996-05-25
DE68910857T3 (en) 1997-04-10
ATE97704T1 (en) 1993-12-15
KR890014793A (en) 1989-10-25
DE68910857D1 (en) 1994-01-05
DE68910857T2 (en) 1994-03-17
HK84794A (en) 1994-08-26
CN1038135A (en) 1989-12-20
AU3160889A (en) 1989-09-28
CN1022581C (en) 1993-10-27
EP0334604A2 (en) 1989-09-27
NZ228457A (en) 1991-11-26
JPH01246408A (en) 1989-10-02

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