EP0253018A1 - Cigarette mouthpiece covering paper - Google Patents

Cigarette mouthpiece covering paper Download PDF

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Publication number
EP0253018A1
EP0253018A1 EP86113950A EP86113950A EP0253018A1 EP 0253018 A1 EP0253018 A1 EP 0253018A1 EP 86113950 A EP86113950 A EP 86113950A EP 86113950 A EP86113950 A EP 86113950A EP 0253018 A1 EP0253018 A1 EP 0253018A1
Authority
EP
European Patent Office
Prior art keywords
paper
water
printing ink
base paper
cigarette
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86113950A
Other languages
German (de)
French (fr)
Inventor
Hermann Friedrich Neuhaus
Ruth Stein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ICI Lacke Farben GmbH
Original Assignee
ICI Lacke Farben GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ICI Lacke Farben GmbH filed Critical ICI Lacke Farben GmbH
Publication of EP0253018A1 publication Critical patent/EP0253018A1/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/36Printing on other surfaces than ordinary paper on pretreated paper, e.g. parchment, oiled paper, paper for registration purposes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/56Making tipping materials, e.g. sheet cork for mouthpieces of cigars or cigarettes, by mechanical means
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/12Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
    • D21H5/14Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of cellulose fibres only
    • D21H5/16Tobacco or cigarette paper

Definitions

  • the invention relates to a cigarette mouthpiece covering paper, consisting of a base paper of lo - 4o g / m2 weight and a printed printing ink.
  • Such cigarette tip papers have been known for decades.
  • colored papers were used as the base paper, more recently white papers are used, which are printed twice with printing ink.
  • These are papers that are used as a filter wrapper, as a mouthpiece or as a filter or mouthpiece coating.
  • the printed printing ink has organic solvents, which are removed from the printed cigarette mouthpiece covering paper by evaporation after drying in drying systems and are passed into the free environment by suction systems.
  • the environmental protection authorities have also requested recovery systems for the solvent so that the smell of the solvent does not affect local residents who are close to production facilities.
  • Such systems are expensive and expensive to operate because they consume significant amounts of energy.
  • the base papers used must have a number of technical properties, such as a special tear strength, for example, in order to be able to fast forward of printing and quick drying following the printing, but also to be able to be processed quickly in the cigarette machines. For this reason, the industry uses a base paper which has a water absorption capacity of about 17 g / m2 in 60 seconds, measured in the Cobb test.
  • the invention consists in that a base paper is used as paper which in the Cobb test has a water absorption capacity of 6-12 g / m 2 in 60 seconds, that at least 60% of water is used as solvent in the printing ink and that as a binder for the Pigments shellac is used.
  • Such a cigarette tip paper has the advantage that the print gives an improved picture, which may be due to the fact that when using shellac on the surface, pigments are exposed which were completely enclosed by the binder in the previously used binders the printing ink due to moisture or water on the lips of the consumer is not possible because the shellac after it has solidified in the drying process after the printing process can no longer be solved by simple water. This is also the reason why the pigment exposed on its surface facing away from the paper cannot be detached from the paper or the binder between the pigment and the paper.
  • drying water as a solvent does not pose any environmental problems. The ink can be extinguished with water in the event of fire, if it catches fire at all. That is also a Advantage during transport and storage because no special precautionary measures against fire have to be taken.
  • a cigarette tip paper is produced with a light brown base paper, which has 3o g / m2 weight and a water absorption capacity of 9 g / m2 in 60 seconds in the Cobb test.
  • This base paper is printed with a printing ink containing 9o% water and 1o% ethyl alcohol as a solvent.
  • Shellac is used as a binding agent used in the following composition: 40% solvent 15% shellac 35% pigments, which are composed of mixtures of iron oxide and titanium oxide.
  • This ink was applied to the base paper on a conventional printing machine, as has been used for years in the manufacture of cigarette tip paper. With the same drying times, there were improved images compared to printing inks with organic solvents.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The paper consisting of a base paper with a substance of 10 - 40 g/m<2> and a print-applied ink. It is the function of the invention to so improve a cigarette mouthpiece covering paper as described at the beginning that an environmentally friendly manufacture with an improved quality of the cigarette mouthpiece covering paper becomes possible. The invention consists in that, as paper, a base paper is used which in the Cobb Test has a water absorption capacity of 6 - 12 g/m<2> in 60 seconds, in that at least 60% of the solvent used for the printing ink is water and in that shellac is used as the binding agent for the pigments.

Description

Die Erfindung betrifft ein Zigarettenmundstücksbelag­papier, bestehend aus einem Basispapier von lo - 4o g/m² Gewicht und einer aufgedruckten Druckfarbe.The invention relates to a cigarette mouthpiece covering paper, consisting of a base paper of lo - 4o g / m² weight and a printed printing ink.

Derartige Zigarettenmundstücksbelagpapiere sind seit Jahrzehnten bekannt. Als Basispapier wurden früher ein­gefärbte Papiere verwandt, in neuerer Zeit werden weiße Papiere verwandt, die zweimal mit Druckfarbe bedruckt sind. Es handelt sich hier um solche Papiere, die als Filterumhüllung, als Mundstück oder als Filter bzw. Mundstücksbelag verwendet werden. Die aufgedruckte Druck­farbe weist organische Lösungsmittel auf, die nach dem Druckvorgang in Trockenanlagen von dem bedruckten Zigaret­tenmundstücksbelagpapier durch Verdunsten entfernt werden und durch Absauganlagen in die freie Umgebung geleitet werden. In neuerer Zeit werden von den auf Umweltschutz bedachten Behörden auch Rückgewinnungsanlagen für das Lösungsmittel gefordert, damit der Lösungsmittelgeruch nicht in der Nähe von Fabrikationsstätten wohende An­wohner beeinträchtigt. Derartige Anlagen sind kostspie­lig und im Betrieb teuer, weil sie erhebliche Energie ver­brauchen. Die verwendeten Basispapiere müssen eine Reihe von technischen Eigenschaften, wie eine besondere Reiß­festigkeit z.B., haben, um einerseits einen schnellen Vor­ gang des Bedruckens und eines schnellen Trocknens im Anschluß an das Bedrucken zu haben, aber auch um schnell in den Zigarettenmaschinen verarbeitet werden zu können. Aus diesem Grunde benutzt die Industrie ein Basispapier, welches eine Wasseraufnahmefähigkeit von etwa 17 g/m² in 60 Sekunden aufweist, gemessen im Cobb-Test.Such cigarette tip papers have been known for decades. In the past, colored papers were used as the base paper, more recently white papers are used, which are printed twice with printing ink. These are papers that are used as a filter wrapper, as a mouthpiece or as a filter or mouthpiece coating. The printed printing ink has organic solvents, which are removed from the printed cigarette mouthpiece covering paper by evaporation after drying in drying systems and are passed into the free environment by suction systems. In recent times, the environmental protection authorities have also requested recovery systems for the solvent so that the smell of the solvent does not affect local residents who are close to production facilities. Such systems are expensive and expensive to operate because they consume significant amounts of energy. The base papers used must have a number of technical properties, such as a special tear strength, for example, in order to be able to fast forward of printing and quick drying following the printing, but also to be able to be processed quickly in the cigarette machines. For this reason, the industry uses a base paper which has a water absorption capacity of about 17 g / m² in 60 seconds, measured in the Cobb test.

Versuche, als Lösungsmittel in der Druckfarbe Wasser zu verwenden, was die Druckfarbe schwerer entflammbar und bei Brand leichter löschbar machen würde, sind bisher gescheitert, weil die als Basispapier verwendbaren Papie­re sich aus mehrerenGründen nicht für eine Bedruckung mit Farben eignen, die Wasser alsLösungsmittel enthalten: In Versuchen kräuselten sich die Basispapier nach dem Bedruckungsvorgang und beim Aufwickeln auf die Bobine, das Druckbild war nicht einwandfrei, sondern infolge einer zu hohen Wasseraufnahmefähigkeit des Basispapieres verwaschen, das gekräuselte Papier ließ sich auf den Zigarettenmaschinen nicht verarbeiten, weil seine Reiß­festigkeit abgenommen hatte, auch der glatte Einlauf des Papieres in die Maschine war nicht mehr gewährleistet und es gab daher ständig Produktionsunterbrechungen durch ein Abreißen des von der Bobine abgewickelten Papieres. Bei den Versuchen stellte sich auch heraus, daß die ver­wendeten wasserlöslichen Bindemittel erhebliche Probleme mit sich bringen, nicht nur bei der Bedruckung und der nachfolgenden Trocknung, sondern auch bis zum Zigaretten­verbraucher hin, bei dem sich die Druckfarbe an der Lippe löste, weil das verwendete Bindemittel nicht spei­chelfest war: Aus diesem Grunde werden bis heute ledig­lich Bindemittel verwendet, die zu ihrer Verarbeitung organischer Lösungsmittel bedürfen.Attempts to use water as a solvent in the printing ink, which would make the printing ink more flame retardant and more easily extinguished in the event of fire, have so far failed because the papers which can be used as base paper are unsuitable for printing with colors containing water as a solvent for a number of reasons: In experiments, the base paper curled after the printing process and when it was wound onto the reel, the printed image was not perfect, but was washed out due to the base paper being too water absorbent, and the crimped paper could not be processed on the cigarette machines because its tear strength had decreased, too The smooth entry of the paper into the machine was no longer guaranteed and there were therefore continuous production interruptions due to the paper being unwound from the reel. The experiments also found that the water-soluble binders used pose significant problems, not only in terms of printing and subsequent drying, but also to the cigarette consumer, where the ink on the lip loosened because the binder used was not resistant to saliva: For this reason, only binders are used that require organic solvents to be processed.

Es ist die Aufgabe der Erfindung, ein Zigarettenmund­stücksbelagpapier der eingangs genannten Art dahin­gehend zu verbessern, daß eine umweltfreundliche Her­stellung bei einer verbesserten Qualität des Zigaretten­mundstücksbelagpapieres möglich wird.It is the object of the invention to improve a cigarette mouthpiece covering paper of the type mentioned at the outset in such a way that environmentally friendly production is possible with an improved quality of the cigarette mouthpiece covering paper.

Die Erfindung besteht darin, daß als Papier ein Basis­papier verwendet wird, welches im Cobb-Test eine Wasser­aufnahmefähigkeit von 6 - 12 g/m² in60 sec aufweist, daß als Lösungsmittel in der Druckfarbe Wasser zumindest zu 60 % verwendet wird und daß als Bindemittel für die Pigmente Schellack verwendet wird.The invention consists in that a base paper is used as paper which in the Cobb test has a water absorption capacity of 6-12 g / m 2 in 60 seconds, that at least 60% of water is used as solvent in the printing ink and that as a binder for the Pigments shellac is used.

Ein derartiges Zigarettenmundstücksbelagpapier hat den Vorteil, daß der Druck ein verbessertes Bild gibt, was darauf zurückzuführen sein dürfte, daß bei der Verwen­dung von Schellack an der Oberfläche Pigmente freiliegen, die bei den bisher verwendeten Bindemitteln voll vom Bindemittel umschlossen waren.Darüber hinaus ist ein Lösen der Druckfarbe durch Feuchtigkeits- oder Wasser­einwirkung an den Lippen des Verbrauchers nicht möglich, weil der Schellack nach seinem Festwerden im Trocknungs­vorgang nach dem Druckvorgang nicht mehr durch einfache Wassereinwirkung lösbar ist. Dieses ist auch der Grund dafür, daß das an seiner dem Papier abgekehrten Ober­fläche freiliegende Pigment nicht von dem Papier bzw. dem Bindemittel zwischen dem Pigment und dem Papier ab­gelöst werden kann. Darüber hinaus sind auch erhebliche Vorteile bei der Verarbeitung erzielt: Die Trocknung des Lösungsmittels Wasser bringt keinerlei Umweltprobleme mit sich. Die Druckfarbe ist bei Brand mit Wasser lösch­bar, so sie überhaupt in Brand gerät. Das ist auch ein Vorteil beim Transport und bei der Lagerung, weil hier keine besonderen Vorsichtsmaßnahmen gegenüber Feuer zu ergreifen sind.Such a cigarette tip paper has the advantage that the print gives an improved picture, which may be due to the fact that when using shellac on the surface, pigments are exposed which were completely enclosed by the binder in the previously used binders the printing ink due to moisture or water on the lips of the consumer is not possible because the shellac after it has solidified in the drying process after the printing process can no longer be solved by simple water. This is also the reason why the pigment exposed on its surface facing away from the paper cannot be detached from the paper or the binder between the pigment and the paper. In addition, there are also considerable advantages in processing: Drying water as a solvent does not pose any environmental problems. The ink can be extinguished with water in the event of fire, if it catches fire at all. That is also a Advantage during transport and storage because no special precautionary measures against fire have to be taken.

Hier wirken das besondere Basispapier, das besondere Lösungsmittel und das ausgewählte Bindemittel zu einem einheitlichen technischen Erfolg zusammen: Es entsteht durch dieses Zusammenwirken einerseits eine erleichter­te Verarbeitung und andererseits ein besonders gutes Bild bei sehr festhaftendem, nicht durch Speichel lös­barem Pigment- oder Bindemittelteil.This is where the special base paper, the special solvent and the selected binder work together to form a uniform technical success: this interaction creates easier processing on the one hand and a particularly good image with a very firmly adhering pigment or binder part that cannot be removed by saliva.

Man kann als Lösungsmittel in der Druckfarbe Wasser zu 100 % verwenden. Es kann aber auch Anwendungsfälle geben, in denen neben dem Wasser alsLösungsmittel auch Alko­hole verwendet werden, um die Vorteile eines Azeotropen­gemisches zu nutzen. Da die Verwendung desLösungsmittels Alkohol jedoch nur in begrenztem Umfange stattfinden wird, ergeben sich hierdurch keine Schwierigkeiten hinsichtlich der Umweltbelastung, es ergeben sich auch keine Nachteile am Produkt.100% water can be used as a solvent in the printing ink. However, there may also be applications in which alcohols are used in addition to water as a solvent in order to take advantage of an azeotrope mixture. However, since the use of the solvent alcohol will only take place to a limited extent, there are no difficulties with regard to environmental pollution and there are no disadvantages to the product.

Ausführungsbeispiel:Design example:

Es wird ein Zigarettenmundstücksbelagpapier mit einem hellbraunen Basispapier hergestellt, welches 3o g/m² Gewicht und eine Wasseraufnahmefähigkeit von 9 g/m² in 60 sec. im Cobb-Test aufweist. Dieses Basispapier wird mit einer Druckfarbe bedruckt, die als Lösungsmit­tel 9o % Wasser und 1o % Äthylalkohol enthält. Als Binde­mittel dient Schellack.Es werden die üblichen Pigmente in folgender Zusammensetzung verwendet:
40 % Lösungsmittel
15 % Schellack
35 % Pigmente,
die sich aus Mischungen von Eisenoxyd und Titanoxyd zusammensetzen. Diese Druckfarbe wurde auf einer üb­lichen Druckmaschine auf das Basispaier aufgebracht, wie sie jahrelang bereits in derHerstellung von Ziga­rettenmundstücksbelagpapier verwendet wurde. Es ergaben sich bei gleichen Trocknungszeiten gegenüber Druckfarben mit organischen Lösungsmitteln verbesserte Bilder.
A cigarette tip paper is produced with a light brown base paper, which has 3o g / m² weight and a water absorption capacity of 9 g / m² in 60 seconds in the Cobb test. This base paper is printed with a printing ink containing 9o% water and 1o% ethyl alcohol as a solvent. Shellac is used as a binding agent used in the following composition:
40% solvent
15% shellac
35% pigments,
which are composed of mixtures of iron oxide and titanium oxide. This ink was applied to the base paper on a conventional printing machine, as has been used for years in the manufacture of cigarette tip paper. With the same drying times, there were improved images compared to printing inks with organic solvents.

Claims (3)

1. Zigarettenmundstücksbelagpapier, bestehend aus einem Basispapier von 1o - 4o g/m² Gewicht und einer aufgedruckten Druckfarbe,
dadurch gekennzeichnet,
daß ein Papier als Basispapier verwendet wird, welches im Cobb-Test eine Wasseraufnahmefähig­keit von 6 - 12 g/m² in 60 sec aufweist,
daß als Lösungsmittel in der Druckfarbe Wasser zumindest zu 60 % verwendet wird
und daß als Bindemittel für die Pigmente Schellack verwendet wird.
1. cigarette tip paper, consisting of a base paper of 1o - 4o g / m² weight and a printed printing ink,
characterized,
that a paper is used as the base paper which has a water absorption capacity of 6-12 g / m 2 in 60 seconds in the Cobb test,
that at least 60% of water is used as a solvent in the printing ink
and that shellac is used as a binder for the pigments.
2. Zigarettenmundstücksbelagpapier nach Anspruch 1,
dadurch gekennzeichnet,
daß als Lösungsmittel Alkohole, insbesondere Äthylalkohol, verwendet wird.
2. cigarette tip paper according to claim 1,
characterized,
that alcohols, especially ethyl alcohol, are used as solvents.
3. Zigarettenmundstücksbelagpapier nach Anspruch 1 und 2,
dadurch gekennzeichnet,
daß als Basispapier ein hellbraunes Papier mit 3o g/m² Gewicht und einer Wasseraufnahmefähig­keit von 9 g/m² in 60 sec. im Cobb-Test ver­wendet wird
und daß als Druckfarbe eine Farbe folgender Zu­sammensetzung verwendet wird:
90 % Wasser
10 % Äthylalkohol.
3. cigarette tip paper according to claim 1 and 2,
characterized,
that a light brown paper with 3o g / m² weight and a water absorption capacity of 9 g / m² is used as the base paper in 60 seconds in the Cobb test
and that a printing ink of the following composition is used:
90% water
10% ethyl alcohol.
EP86113950A 1986-07-10 1986-10-08 Cigarette mouthpiece covering paper Withdrawn EP0253018A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP86109428 1986-07-10
EP86109428 1986-07-10

Publications (1)

Publication Number Publication Date
EP0253018A1 true EP0253018A1 (en) 1988-01-20

Family

ID=8195260

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86113950A Withdrawn EP0253018A1 (en) 1986-07-10 1986-10-08 Cigarette mouthpiece covering paper

Country Status (1)

Country Link
EP (1) EP0253018A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0414015A2 (en) * 1989-08-03 1991-02-27 Kimberly-Clark Corporation Tissue web, method for preparing and use of same
WO1999051439A1 (en) * 1998-04-03 1999-10-14 British American Tobacco (Investments) Limited Flexographic printing on smoking article web material
CN106149474A (en) * 2016-07-28 2016-11-23 滁州卷烟材料厂 A kind of cigarette aluminum-free internal lining paper of high forming degree

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB376413A (en) * 1931-05-05 1932-07-14 Nicholas Drey Improvements in printing inks
DE649474C (en) * 1932-04-07 1937-08-25 Kast & Ehinger G M B H Lightfast printing inks for printing with rubber printing forms
US3884707A (en) * 1973-11-09 1975-05-20 Beatrice Foods Co Printing ink and process
DE2743986A1 (en) * 1977-09-30 1979-04-12 Glatz Julius Gmbh MOUTHPAPER FOR CIGARETTES
DE3016766A1 (en) * 1979-05-02 1980-11-13 Fuji Photo Film Co Ltd RECORDING MATERIALS FOR INK JET RECORDING

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB376413A (en) * 1931-05-05 1932-07-14 Nicholas Drey Improvements in printing inks
DE649474C (en) * 1932-04-07 1937-08-25 Kast & Ehinger G M B H Lightfast printing inks for printing with rubber printing forms
US3884707A (en) * 1973-11-09 1975-05-20 Beatrice Foods Co Printing ink and process
DE2743986A1 (en) * 1977-09-30 1979-04-12 Glatz Julius Gmbh MOUTHPAPER FOR CIGARETTES
DE3016766A1 (en) * 1979-05-02 1980-11-13 Fuji Photo Film Co Ltd RECORDING MATERIALS FOR INK JET RECORDING

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WORLD SURFACE COATINGS ABSTRACTS, Band 59, Nr. 524, Februar 1986, Seite 212, Zusammenfassung Nr. 8600997, Oxford, GB; & JP-A-85 031 871 (HITACHI LTD) *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0414015A2 (en) * 1989-08-03 1991-02-27 Kimberly-Clark Corporation Tissue web, method for preparing and use of same
EP0414015A3 (en) * 1989-08-03 1991-04-03 Kimberly-Clark Corporation Tissue web, method for preparing and use of same
WO1999051439A1 (en) * 1998-04-03 1999-10-14 British American Tobacco (Investments) Limited Flexographic printing on smoking article web material
GB2351040A (en) * 1998-04-03 2000-12-20 British American Tobacco Co Flexographic printing on smoking article web material
GB2351040B (en) * 1998-04-03 2002-06-19 British American Tobacco Co Flexographic printing on smoking article web material
CN106149474A (en) * 2016-07-28 2016-11-23 滁州卷烟材料厂 A kind of cigarette aluminum-free internal lining paper of high forming degree

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