EP0201368A1 - Markierungs- und Denaturierungszusammensetzung besonders geeignet um Dieselöl und gleichartige Ölprodukte zu markieren und zu denaturieren - Google Patents

Markierungs- und Denaturierungszusammensetzung besonders geeignet um Dieselöl und gleichartige Ölprodukte zu markieren und zu denaturieren Download PDF

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Publication number
EP0201368A1
EP0201368A1 EP86400642A EP86400642A EP0201368A1 EP 0201368 A1 EP0201368 A1 EP 0201368A1 EP 86400642 A EP86400642 A EP 86400642A EP 86400642 A EP86400642 A EP 86400642A EP 0201368 A1 EP0201368 A1 EP 0201368A1
Authority
EP
European Patent Office
Prior art keywords
marking
denaturing
anthraquinone
oil
diesel oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86400642A
Other languages
English (en)
French (fr)
Other versions
EP0201368B1 (de
Inventor
Carlo Prandi
Alberto Osti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Italia SpA
Original Assignee
PIGMENTI ITALIA SpA
PIGMENTI ITALIA SpA
BASF Italia SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PIGMENTI ITALIA SpA, PIGMENTI ITALIA SpA, BASF Italia SpA filed Critical PIGMENTI ITALIA SpA
Publication of EP0201368A1 publication Critical patent/EP0201368A1/de
Application granted granted Critical
Publication of EP0201368B1 publication Critical patent/EP0201368B1/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/003—Marking, e.g. coloration by addition of pigments
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones

Definitions

  • the Invention relates to a marking and denaturing composition, particularly suitable for marking and denaturing diesel oil and similar oil products.
  • U.S. patent 4 209 302 discloses the use of naphtylamine derivatives. However, these compounds do not completely satisfy the requirements herein-above, especially because they can easily be extracted from the marked product.
  • the invention concerns a marking and denaturing composition, particularly suitable for diesel oil and for similar oil products, containing an anthraquinone derivative having the formula: where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 identical or different, represent a hydrogen atom, a halogen atom or an alkyl, cycloalkyl or arylalkyl radical having from 1 to 12 carbon atoms.
  • Oils products similar to diesel oil are, for example, gasoline, kerosene oil and lamp oil.
  • anthraquinone derivative to be used as a marker can vary within wide limits and the minimum value merely depends upon the identification test. By using the simple and rapid test described herein-after, concentrations as low as 1 to 3 ppm can be used.
  • a greater amount is added, in order to obtain in any case a positive result and also to foresee the case where the marked product is diluted at the time the fraud occurs. From a practical point of view, from 1 to 300 ppm (and preferably 3-50 ppm) can be used.
  • the markers according to the present invention should be prescribed, in particular, when an anthraquinone dye and/or an azoic dye is present; best results are obtained when using said markers or marking compositions in admixture with furfural and/or with other suitable organic solvents, for example xylenes, these xylenes generally acting as a diluent.
  • Example 1 was repeated, by carrying out the test on the same diesel oil, without any admixture of the marking solution, the final bottom layer was light brown.
  • Example 6 was repeated while replacing gasoline by lamp oil to be used for the lighting of fishing boats.
  • the final bottom aqueous layer obtained also presented a deep red color.
  • Example 1 was repeated while modifying the chemical nature of the marker and its concentration; data and results are on table 1.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
EP86400642A 1985-04-12 1986-03-26 Markierungs- und Denaturierungszusammensetzung besonders geeignet um Dieselöl und gleichartige Ölprodukte zu markieren und zu denaturieren Expired EP0201368B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2031685 1985-04-12
IT20316/85A IT1200452B (it) 1985-04-12 1985-04-12 Composizione denaturante e marcante,particolarmente adatta per gasolio

Publications (2)

Publication Number Publication Date
EP0201368A1 true EP0201368A1 (de) 1986-11-12
EP0201368B1 EP0201368B1 (de) 1989-07-19

Family

ID=11165673

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86400642A Expired EP0201368B1 (de) 1985-04-12 1986-03-26 Markierungs- und Denaturierungszusammensetzung besonders geeignet um Dieselöl und gleichartige Ölprodukte zu markieren und zu denaturieren

Country Status (3)

Country Link
EP (1) EP0201368B1 (de)
DE (1) DE3664476D1 (de)
IT (1) IT1200452B (de)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1001003A1 (de) * 1998-11-09 2000-05-17 Morton International, Inc. Verfahren zur unsichtbaren Markierung von Erdölprodukten mittels sichtbarer Farbstoffe
EP1323811A2 (de) * 2001-12-20 2003-07-02 Rohm And Haas Company Verfahren zum Markieren von Kohlenwasserstoffen mit Anthrachinonen
WO2005063942A1 (de) * 2003-12-23 2005-07-14 Basf Aktiengesellschaft Kraft- und schmierstoffadditiv-konzentrate, enthaltend mindestens ein anthrachinon-derivat als markierungsstoff
US6977177B1 (en) 2004-05-26 2005-12-20 Rohm And Haas Company Method for marking hydrocarbons with substituted anthraquinones
US7157611B2 (en) 2002-07-11 2007-01-02 Rohm And Haas Company Pyrazinoporphyrazines as markers for liquid hydrocarbons
CN1321965C (zh) * 2005-07-22 2007-06-20 清华大学 蒽醌衍生物的合成方法
US7635596B2 (en) 2004-12-15 2009-12-22 Rohm And Haas Company Method for monitoring degradation of lubricating oils
US7915048B2 (en) 2003-06-13 2011-03-29 Rohm And Haas Company Method for marking hydrocarbons with substituted anthraquinones
WO2021110526A1 (en) 2019-12-03 2021-06-10 Sicpa Holding Sa Method of marking a petroleum hydrocarbon

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE524604A (de) *
GB361310A (en) * 1930-06-18 1931-11-18 Howard Ferguson Improvements in and relating to motor fuels or like combustible liquids
GB851639A (en) * 1958-09-26 1960-10-19 Exxon Research Engineering Co Improved hydrocarbon oils
US3164449A (en) * 1961-03-01 1965-01-05 Du Pont Anthraquinone dyes for gasoline
DE2702985C2 (de) * 1977-01-26 1979-02-15 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von deckenden Pyranthronpigmenten

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE524604A (de) *
GB361310A (en) * 1930-06-18 1931-11-18 Howard Ferguson Improvements in and relating to motor fuels or like combustible liquids
GB851639A (en) * 1958-09-26 1960-10-19 Exxon Research Engineering Co Improved hydrocarbon oils
US3164449A (en) * 1961-03-01 1965-01-05 Du Pont Anthraquinone dyes for gasoline
DE2702985C2 (de) * 1977-01-26 1979-02-15 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von deckenden Pyranthronpigmenten

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6274381B1 (en) 1998-11-09 2001-08-14 Rohm And Haas Company Method for invisibly tagging petroleum products using visible dyes
EP1001003A1 (de) * 1998-11-09 2000-05-17 Morton International, Inc. Verfahren zur unsichtbaren Markierung von Erdölprodukten mittels sichtbarer Farbstoffe
EP1323811A2 (de) * 2001-12-20 2003-07-02 Rohm And Haas Company Verfahren zum Markieren von Kohlenwasserstoffen mit Anthrachinonen
EP1323811A3 (de) * 2001-12-20 2003-12-03 Rohm And Haas Company Verfahren zum Markieren von Kohlenwasserstoffen mit Anthrachinonen
US6811575B2 (en) 2001-12-20 2004-11-02 Rohm And Haas Company Method for marking hydrocarbons with anthraquinones
US7157611B2 (en) 2002-07-11 2007-01-02 Rohm And Haas Company Pyrazinoporphyrazines as markers for liquid hydrocarbons
US7915048B2 (en) 2003-06-13 2011-03-29 Rohm And Haas Company Method for marking hydrocarbons with substituted anthraquinones
AU2004309053B2 (en) * 2003-12-23 2010-06-10 Basf Aktiengesellschaft Power and lubricant additive concentrates containing at least one anthrachinone derivative as a marking substance
WO2005063942A1 (de) * 2003-12-23 2005-07-14 Basf Aktiengesellschaft Kraft- und schmierstoffadditiv-konzentrate, enthaltend mindestens ein anthrachinon-derivat als markierungsstoff
US6977177B1 (en) 2004-05-26 2005-12-20 Rohm And Haas Company Method for marking hydrocarbons with substituted anthraquinones
US7635596B2 (en) 2004-12-15 2009-12-22 Rohm And Haas Company Method for monitoring degradation of lubricating oils
CN1321965C (zh) * 2005-07-22 2007-06-20 清华大学 蒽醌衍生物的合成方法
WO2021110526A1 (en) 2019-12-03 2021-06-10 Sicpa Holding Sa Method of marking a petroleum hydrocarbon

Also Published As

Publication number Publication date
IT8520316A0 (it) 1985-04-12
DE3664476D1 (en) 1989-08-24
IT1200452B (it) 1989-01-18
EP0201368B1 (de) 1989-07-19

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