EP0198570A2 - Process for producing a thin-walled tubing from a zirconium-niobium alloy - Google Patents
Process for producing a thin-walled tubing from a zirconium-niobium alloy Download PDFInfo
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- EP0198570A2 EP0198570A2 EP86300259A EP86300259A EP0198570A2 EP 0198570 A2 EP0198570 A2 EP 0198570A2 EP 86300259 A EP86300259 A EP 86300259A EP 86300259 A EP86300259 A EP 86300259A EP 0198570 A2 EP0198570 A2 EP 0198570A2
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- niobium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/186—High-melting or refractory metals or alloys based thereon of zirconium or alloys based thereon
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- This invention relates to a process for fabricating thin-walled tubing such as nuclear fuel cladding, from a zirconium-niobium alloy such that the alloys of the. resultant products have a particular microstructure which enables the material to resist corrosion in high temperature aqueous environments.
- Zero-Nb alloys have been traditionally of interest to the nuclear industry because of their high strengths. It is this feature, in conjunction with reasonably good corrosion resistance, which ultimately led to the selection of the alloy of zirconium containing 2.5 per cent by weight niobium, as the standard pressure- tube material for present generation Canadian Deuterium Uranium (CANDU) reactors. Although it was originally believed that the zirconium-niobium alloys had inferior resistance to irradiation enhanced corrosion relative to existing alloys, such as Zircaloy-2 or Zircaloy-4, it ultimately became apparent that they actually had superior in-pile corrosion properties when properly heat treated, as described by J. E. LeSurf, ASTM STP-458, p. 286. As a result of this finding, there has been increasing interest in zirconium-niobium alloys as potential fuel cladding materials in future generation, high performance, light water reactors.
- zirconium-niobium alloys can be fabricated into thin-walled tubing, of about 0.040 inch or less in wall thickness, which exhibits excellent corrosion resistance, by a process that does not require extensively long final annealing times, by the use of relatively low temperature anneals between cold working steps and a final low temperature anneal.
- thin-walled tubing can be fabricated that has a microstructure where second phase beta-niobium particles are homogeneously dispersed in the zirconium matrix in extremely fine particle size to provide excellent corrosion resistance of the resultant article under both in-pile and out-of-pile conditions.
- the present invention resides in a process for fabricating thin-walled tubing from a zirconium-niobium alloy containing from 1 to 2.5 per cent by weight niobium as homogeneously dispersed finely divided particles characterized by beta-treating a zirconium-niobium alloy billet containing from 1 to 2.5 per cent by weight niobium; extruding said beta-treated billet at a temperature no higher than 650°C to form a tube shell; further deforming said tube shell by cold working the same in a plurality of cold working stages; annealing said tube shell, between each of said stages of cold working, at a temperature below 650°C; and final annealing the resultant tubing at a temperature below 600°C, so as to produce a microstructure of the material having niobium particles of a size below about 800 angstroms homogeneously dispersed therein.
- the fabrication of thin-walled tubing from a zirconium-niobium alloy is effected according to the present invention with the production of tubing exhibiting excellent corrosion resistance and resistance to hydride formation.
- zirconium alloys containing 1.0 per cent by weight and 2.5 per cent by weight niobium.
- the zirconium-niobium alloys may contain a minor amount, up to 0.5 per cent by weight of a third element, such as copper, iron, molybdenum, nickel, tungsten, vanadium and chromium.
- a third element such as copper, iron, molybdenum, nickel, tungsten, vanadium and chromium.
- An example of such an alloy is one containing zirconium with 2.5 per cent niobium and 0.5 per cent copper.
- the alloys are first subjected to a beta-treatment by heating the alloy to from 950-1000°C and water-quenching the same to a temperature below the alpha + beta to alpha transus temperature.
- the billet is then prepared for extrusion by drilling an axial hole along the center line of the billet, machining the outside diameter to desired dimensions, and applying a lubricant to the surfaces of the billet.
- the billet diameter is then reduced by extrusion at a lower than conventional temperature, below 700°C, through a frustoconical die and over a mandrel.
- a beta-anneal of the extruded tube shell may then be effected, depending upon the alloy, by heating to from 850-1050°C, followed by rapid cooling.
- the billet may then be cold worked by pilgering, at a source of primary fabrication, to reduce the wall thickness and outside diameter.
- This intermediate production is called a TREX (Tube Reduced Extrusion), which may then be sent to a tube mill for fabrication by cold working, intermediate low temperature annealing, and a final anneal under the fabricating steps of the present invention to produce the desired thin-walled tubing.
- the material is preferably cold worked by pilgering, and 3 to 5 stages of cold working effected, preferably 3 to 4 stages.
- the present invention produces thin-walled zirconium alloy tubing wherein the alloying elements are homogeneously dispersed throughout the zirconium in a finely divided state.
- the particles, homogeneously dispersed are of an average particle size below 800 angstroms, and preferably the average particle size is below about 500 angstroms.
- niobium-containing zirconium alloy (A) ingot containing 1.0 per cent by weight niobium and the balance zirconium, was conventionally broken down in billets of about six inches in diameter (Step 1).
- a six-inch diameter billet was then given a beta treatment, Step 2, which comprised holding the billet in a furnace at about 968-996°C (1775-1825°F) for about fifteen minutes and then water quenching the billet.
- the beta-treated billet was machined, bore-holed and inspected in preparation for extrusion.
- the hollow niobium-containing zirconium alloy billet was then heated to about 649°C (1200°F) and extruded (Step 3) to a hollow tube having an outside diameter of 2.5 inches and a wall thickness of 0.43 inch.
- the extruded hollow tube was beta-annealed (Step 4) at 954°C (17500F) for a period of fifteen minutes in preparation for a first cold working step (a pilgering reduction), (Step 5).
- the beta-annealed extrusion was pilgered in Step 5 to a TREX having an outside diameter of 1.75 inches and a wall thickness of 0.3 inch.
- the TREX was then annealed, (Step 6), at 500°C (932°F) for a period of 8 hours. Following the annealing of the TREX, the same was then cold pilgered to a tube shell having an outside diameter of 1.25 inches and a wall thickness of 0.16 inch, (Step 7).
- the tube shell was then further annealed and cold worked according to the following sequence.
- the tube shell was annealed, (Step 8), at about 524°C (975°F) for 7.5 hours and further cold pilgered, (Step 9), to reduce the tube shell to one having an outside diameter of 0.875 inch and a wall thickness of 0.085 inch.
- This tube shell was again annealed at about 524°C (975°F) for 7.5 hours, (Step 10).
- the annealed tube shell was again further cold pilgered, (Step 11), to give a tube shell having an outside diameter of 0.602 inch and a wall thickness of 0.045 inch.
- the tube was then subjected to a final anneal at about 427°C (800°F) for 4 hours, (Step 14).
- the cold working anneal for the tubes formed from composition B were effected at about 580°C (1076°F) for 8 hours (rather than 524°C (975°F) for 7.5 hours as with A).
- the remaining treatment steps, including the final anneal were the same as those used with composition A.
- the TREX was then annealed in Step 6 at 600°C (1112°F) for a period of 8 hours.
- the material was therefore subjected to an additional anneal for 3 hours at about 685°C (1265°F) and the material then subjected to Step 7 with successful pilgering.
- the first cold working anneal, Step 8 was carried out at about 593°C (1100 0 F) for a period of 8 hours.
- Step 13 the tube was subjected to a final anneal, Step 14, for 7.5 hours at about 480°C (896°F).
- niobium-containing zirconium alloy tubes of the present invention have in-pile corrosion resistance superior to that of Zircaloy-4. This is a property which, in the past, has been attributed only to "heat treated” 2.5% Nb-zirconium alloys (see “The Effect of Aging and Irradiation on the Corrosion of Zr-2.5 wt % Nb", V. F. Urbanic, J. E. LeSurf and A. B. Johnson, Jr.: Corrosion 31 (1975) 15).
- FIG. 2 Further evidence of the superiority of the tubing prepared according to the present invention is illustrated in Figure 2 where two groups of corrosion data are presented for a zirconium alloy containing 1 per cent by weight niobium.
- the first group of data (dash lines: 350, 400 and 450°C) were reported for sheet material which was fabricated via standard Russian processing techniques (see A. A. Kiselev, et al., AECL-1724, 1963).
- the second group of data solid lines: 360 and 427°C
- the superiority of the present tubing is demonstrated by the fact that the same exhibits lower weight gains at 360 and 427°C than the Russion material does, even though the latter was exposed at lower corrosion temperatures 350 and 400°C respectively.
- the present processing provides uniform distribution of very fine precipitate particles in the microstructure of niobium-containing zirconium alloys.
- the microstructure of the fully annealed tubing is illustrated in Figures 3A, B, C and D for composition "A”; 4A, B, C and D for composition "B”; and 5A, B, C and D for composition "C”.
- TEM transmission electron micrographs
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Abstract
Description
- This invention relates to a process for fabricating thin-walled tubing such as nuclear fuel cladding, from a zirconium-niobium alloy such that the alloys of the. resultant products have a particular microstructure which enables the material to resist corrosion in high temperature aqueous environments.
- Binary zirconium-niobium (Zr-Nb) alloys have been traditionally of interest to the nuclear industry because of their high strengths. It is this feature, in conjunction with reasonably good corrosion resistance, which ultimately led to the selection of the alloy of zirconium containing 2.5 per cent by weight niobium, as the standard pressure- tube material for present generation Canadian Deuterium Uranium (CANDU) reactors. Although it was originally believed that the zirconium-niobium alloys had inferior resistance to irradiation enhanced corrosion relative to existing alloys, such as Zircaloy-2 or Zircaloy-4, it ultimately became apparent that they actually had superior in-pile corrosion properties when properly heat treated, as described by J. E. LeSurf, ASTM STP-458, p. 286. As a result of this finding, there has been increasing interest in zirconium-niobium alloys as potential fuel cladding materials in future generation, high performance, light water reactors.
- At present, there is one major drawback which could prevent successful employment of zirconium-niobium alloys as fuel cladding materials. This problem stems from the fact that superior corrosion resistance has been obtained only after application of the following multi-step processing sequence: 1) anneal at 850-950°C and water quench; 2) cold work to 10 to 30 per cent reduction (optional); and 3) anneal for approximately 24 hours at approximately 500°C. This processing is easily applied to the thick-walled pressure tubes for which it was developed, but cannot be applied to commercially produced thin-walled tubing with its inherently tight dimensional specifications and long lengths (-4 m), which causes problems relative to maintaining the shape of the tubing. It is thus necessary that an alternate processing system be adopted for the production of thin-walled tubing from zirconium-niobium alloys, for use as fuel cladding. Also, any such processing system must yield superior corrosion resistance and at the same time, be consistent with practices employed in the commercial production of fuel cladding.
- We have found that zirconium-niobium alloys can be fabricated into thin-walled tubing, of about 0.040 inch or less in wall thickness, which exhibits excellent corrosion resistance, by a process that does not require extensively long final annealing times, by the use of relatively low temperature anneals between cold working steps and a final low temperature anneal. By using the processing techniques of the present invention, thin-walled tubing can be fabricated that has a microstructure where second phase beta-niobium particles are homogeneously dispersed in the zirconium matrix in extremely fine particle size to provide excellent corrosion resistance of the resultant article under both in-pile and out-of-pile conditions.
- Accordingly, the present invention resides in a process for fabricating thin-walled tubing from a zirconium-niobium alloy containing from 1 to 2.5 per cent by weight niobium as homogeneously dispersed finely divided particles characterized by beta-treating a zirconium-niobium alloy billet containing from 1 to 2.5 per cent by weight niobium; extruding said beta-treated billet at a temperature no higher than 650°C to form a tube shell; further deforming said tube shell by cold working the same in a plurality of cold working stages; annealing said tube shell, between each of said stages of cold working, at a temperature below 650°C; and final annealing the resultant tubing at a temperature below 600°C, so as to produce a microstructure of the material having niobium particles of a size below about 800 angstroms homogeneously dispersed therein.
- The fabrication of thin-walled tubing from a zirconium-niobium alloy is effected according to the present invention with the production of tubing exhibiting excellent corrosion resistance and resistance to hydride formation.
- Especially useful are zirconium alloys containing 1.0 per cent by weight and 2.5 per cent by weight niobium. The zirconium-niobium alloys may contain a minor amount, up to 0.5 per cent by weight of a third element, such as copper, iron, molybdenum, nickel, tungsten, vanadium and chromium. An example of such an alloy is one containing zirconium with 2.5 per cent niobium and 0.5 per cent copper.
- In one embodiment of the invention, the alloys are first subjected to a beta-treatment by heating the alloy to from 950-1000°C and water-quenching the same to a temperature below the alpha + beta to alpha transus temperature. The billet is then prepared for extrusion by drilling an axial hole along the center line of the billet, machining the outside diameter to desired dimensions, and applying a lubricant to the surfaces of the billet. The billet diameter is then reduced by extrusion at a lower than conventional temperature, below 700°C, through a frustoconical die and over a mandrel. A beta-anneal of the extruded tube shell may then be effected, depending upon the alloy, by heating to from 850-1050°C, followed by rapid cooling. The billet may then be cold worked by pilgering, at a source of primary fabrication, to reduce the wall thickness and outside diameter. This intermediate production is called a TREX (Tube Reduced Extrusion), which may then be sent to a tube mill for fabrication by cold working, intermediate low temperature annealing, and a final anneal under the fabricating steps of the present invention to produce the desired thin-walled tubing. In the formation of the thin-walled tubing, the material is preferably cold worked by pilgering, and 3 to 5 stages of cold working effected, preferably 3 to 4 stages.
- The present invention produces thin-walled zirconium alloy tubing wherein the alloying elements are homogeneously dispersed throughout the zirconium in a finely divided state. The particles, homogeneously dispersed, are of an average particle size below 800 angstroms, and preferably the average particle size is below about 500 angstroms.
- In order that the invention can be more clearly understood, convenient embodiments thereof will now be described, by way of example, with reference to the accompanying drawings in which:
- Figure 1 is a flow diagram of a process for fabricating thin-walled tubing;
- Figure 2 is a graph illustrating the superior corrosion resistance of the zirconium-niobium alloy containing 1 per cent niobium processed according to the flow diagram of Figure 1, as compared with reported corrosion resistance of such an alloy;
- Figures 3A, B, C and D show transmission electron microscopy photomicrographs illustrating the typical precipitate distribution and size observed in a fully annealed tubing formed from a zirconium alloy containing 1.0 per cent by weight niobium and produced according to the flow diagram of Figure 1;
- Figures 4A, B, C and D show transmission electron microscopy photomicrographs illustrating the typical precipitate distribution and size observed in a fully annealed tubing formed from a zirconium alloy containing 2.5 per cent by weight niobium and produced according to the flow diagram of Figure 1; and
- Figures 5A, B, C and D show transmission electron microscopy photomicrographs illustrating the typical precipitate distribution and size observed in a fully annealed tubing formed from a zirconium alloy containing 2.5 per cent by weight niobium and 0.5 per cent by weight copper and produced according to the flow diagram of Figure 1.
- Referring to Figure 1, a niobium-containing zirconium alloy (A) ingot, containing 1.0 per cent by weight niobium and the balance zirconium, was conventionally broken down in billets of about six inches in diameter (Step 1). A six-inch diameter billet was then given a beta treatment,
Step 2, which comprised holding the billet in a furnace at about 968-996°C (1775-1825°F) for about fifteen minutes and then water quenching the billet. At this point, the beta-treated billet was machined, bore-holed and inspected in preparation for extrusion. The hollow niobium-containing zirconium alloy billet was then heated to about 649°C (1200°F) and extruded (Step 3) to a hollow tube having an outside diameter of 2.5 inches and a wall thickness of 0.43 inch. - The extruded hollow tube was beta-annealed (Step 4) at 954°C (17500F) for a period of fifteen minutes in preparation for a first cold working step (a pilgering reduction), (Step 5). The beta-annealed extrusion was pilgered in Step 5 to a TREX having an outside diameter of 1.75 inches and a wall thickness of 0.3 inch. The TREX was then annealed, (Step 6), at 500°C (932°F) for a period of 8 hours. Following the annealing of the TREX, the same was then cold pilgered to a tube shell having an outside diameter of 1.25 inches and a wall thickness of 0.16 inch, (Step 7). The tube shell was then further annealed and cold worked according to the following sequence. The tube shell was annealed, (Step 8), at about 524°C (975°F) for 7.5 hours and further cold pilgered, (Step 9), to reduce the tube shell to one having an outside diameter of 0.875 inch and a wall thickness of 0.085 inch. This tube shell was again annealed at about 524°C (975°F) for 7.5 hours, (Step 10). The annealed tube shell was again further cold pilgered, (Step 11), to give a tube shell having an outside diameter of 0.602 inch and a wall thickness of 0.045 inch. A further cold working anneal, (Step 12), was effected at about 524°C (975°F) for 7.5 hours and the tube shell finally cold pilgered, (Step 13), to give a tube having an outside diameter of 0.423 inch and a wall thickness of 0.025 inch. The tube was then subjected to a final anneal at about 427°C (800°F) for 4 hours, (Step 14).
- A second niobium-containing alloy (B) ingot, containing 2.5 per cent by weight niobium and the balance zirconium, was treated according to the present process, the B composition ingot treated as was A, except for the following variations. An examination of the TREX indicated that the B composition had not received the correct beta-anneal and was, prior to Step 7, given a further, extra annealing at 580°C (1076°F) for a period of 8 hours. Also, the cold working anneal for the tubes formed from composition B were effected at about 580°C (1076°F) for 8 hours (rather than 524°C (975°F) for 7.5 hours as with A). The remaining treatment steps, including the final anneal were the same as those used with composition A.
- A third niobium-containing alloy (C) ingot, containing 2.5 per cent by weight niobium, 0.5 per cent by weight copper, and the balance zirconium, was treated according to the present invention, the C composition ingot treated as was composition A through Step 5. The TREX was then annealed in
Step 6 at 600°C (1112°F) for a period of 8 hours. When the cold working of Step 7 was attempted, transverse cracks appeared. The material was therefore subjected to an additional anneal for 3 hours at about 685°C (1265°F) and the material then subjected to Step 7 with successful pilgering. Also, the first cold working anneal, Step 8, was carried out at about 593°C (11000F) for a period of 8 hours. Subsequent cold working anneals were effected at about 580°C (1076°F), as with composition B. After the final cold work step,Step 13, the tube was subjected to a final anneal,Step 14, for 7.5 hours at about 480°C (896°F). - Stress-relieved sections of tubing of compositions A, B and C, processed as described above, were corrosion tested in a static autoclave in 427°C, 10.3MPa steam; and 360°C, 18.7MPa water; and compared with results of such corrosion testing of Zircaloy-4. The results of the corrosion tests are listed in Table I and demonstrate that zirconium-niobium alloys processed according to the present invention have corrosion resistance superior to that of Zircaloy-4.
- Further evidence of the corrosion resistance of the alloys treated according to the present invention is obtained by comparing the corrosion rates of the tubing of niobium-containing alloy containing 2.5 per cent by weight niobium (alloy B) with published data which characterizes the corrosion rates of 2.5 per cent niobium-zirconium in the "heat treated" condition as described by J. E. LeSurf in "The Corrosion Behavior of 2.5 Nb Zirconium Alloy", Applications-Related Phenomenon for Zirconium and Its Alloys, ASTM STP 458, American Society for Testing and Materials, 1969, pp. 286-300. This comparison is presented in Table II.
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- Additional evidence of the superior corrosion resistance of the alloys treated according to the present invention is provided by the post-irradiation examinations performed on cladding of fuel rods. Two experimental Zr-Nb alloys were exposed in the BR-3 pressurized water reactor located in Mol, Belgium, for about seven and one-half months (at power). Five high-power fuel rods were removed and sectioned at five elevations; one section at the peak power location; two sections at 90% power, above and below the peak power location; and two sections at 50% power near the ends. The minimum, maximum, and mean oxide thicknesses from those five sections are listed in Table III, in comparison with Zircaloy-4:
- These examinations indicate that niobium-containing zirconium alloy tubes of the present invention have in-pile corrosion resistance superior to that of Zircaloy-4. This is a property which, in the past, has been attributed only to "heat treated" 2.5% Nb-zirconium alloys (see "The Effect of Aging and Irradiation on the Corrosion of Zr-2.5 wt % Nb", V. F. Urbanic, J. E. LeSurf and A. B. Johnson, Jr.: Corrosion 31 (1975) 15).
- Further evidence of the superiority of the tubing prepared according to the present invention is illustrated in Figure 2 where two groups of corrosion data are presented for a zirconium alloy containing 1 per cent by weight niobium. The first group of data (dash lines: 350, 400 and 450°C) were reported for sheet material which was fabricated via standard Russian processing techniques (see A. A. Kiselev, et al., AECL-1724, 1963). The second group of data (solid lines: 360 and 427°C) were obtained from tubing processed according to the present invention. The superiority of the present tubing is demonstrated by the fact that the same exhibits lower weight gains at 360 and 427°C than the Russion material does, even though the latter was exposed at lower corrosion temperatures 350 and 400°C respectively.
- The present processing provides uniform distribution of very fine precipitate particles in the microstructure of niobium-containing zirconium alloys. The microstructure of the fully annealed tubing is illustrated in Figures 3A, B, C and D for composition "A"; 4A, B, C and D for composition "B"; and 5A, B, C and D for composition "C". Because of the fine particle sizes obtained, transmission electron micrographs (TEM) were taken. In deformed materials, diffraction effects from gain boundaries and dislocations interfere with particle resolution. Therefore, the study of particle dispersions was carried out on fully annealed, final tubing. The final annealing cycle for A was 8 hours at 500°C (932°F), and for B and C was 8 hours at 600°C (1112°F). Results of the chracterization of the particle distribution in the annealed material are given in Table IV as follows:
- The observed precipitate sizes and number densities represent relatively fine dispersions. This is evident when comparing the same to the average diameter in the range of 3000 Angstroms of particle sizes in a conventionally processed Zircaloy-4 alloy.
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US69354685A | 1985-01-22 | 1985-01-22 | |
US693546 | 1985-01-22 |
Publications (3)
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EP0198570A2 true EP0198570A2 (en) | 1986-10-22 |
EP0198570A3 EP0198570A3 (en) | 1987-10-14 |
EP0198570B1 EP0198570B1 (en) | 1990-08-29 |
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EP86300259A Expired - Lifetime EP0198570B1 (en) | 1985-01-22 | 1986-01-16 | Process for producing a thin-walled tubing from a zirconium-niobium alloy |
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EP (1) | EP0198570B1 (en) |
JP (1) | JPS61210166A (en) |
KR (1) | KR930009986B1 (en) |
ES (1) | ES8708021A1 (en) |
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EP0495978A1 (en) * | 1990-08-03 | 1992-07-29 | Teledyne Industries Inc | Fabrication of zircaloy mill products for improved microstructure and properties |
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US20120145287A1 (en) * | 2008-02-29 | 2012-06-14 | Korea Atomic Energy Research Institute | Zirconium alloy compositions having excellent corrosion resistance by the control of various metal-oxide and precipitate and preparation method thereof |
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JPS62180047A (en) * | 1986-02-03 | 1987-08-07 | Hitachi Ltd | Manufacture of zirconium base alloy member |
FR2688232B1 (en) * | 1992-03-04 | 1994-04-22 | Cezus Co Europ Zirconium | PROCESS FOR PRODUCING ZIRCONIUM TUBES FORMED FROM LAYERS OF DIFFERENT COMPOSITION. |
KR100382997B1 (en) † | 2001-01-19 | 2003-05-09 | 한국전력공사 | Method of Manufacturing A Tube and A Sheet of Niobium-containing Zirconium Alloys for High Burn-up Nuclear Fuel |
ITMI20061223A1 (en) * | 2006-06-26 | 2007-12-27 | Snam Progetti | BIMETALLIC PIPE RESISTANT TO CORROSION AND ITS USE IN TUBIWERO BAND EQUIPMENT |
KR101552514B1 (en) | 2014-04-25 | 2015-09-14 | 한전원자력연료 주식회사 | Gap controlling device for a pilger die assembly of cold pilger rolling mills |
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- 1986-01-20 ES ES551049A patent/ES8708021A1/en not_active Expired
- 1986-01-22 JP JP61011802A patent/JPS61210166A/en active Pending
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US2894866A (en) * | 1958-01-21 | 1959-07-14 | Marion L Picklesimer | Method for annealing and rolling zirconium-base alloys |
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Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2576322A1 (en) * | 1985-01-22 | 1986-07-25 | Westinghouse Electric Corp | PROCESS FOR FORMING ARTICLES FROM ZIRCONIUM ALLOYS |
EP0425465A1 (en) * | 1989-10-27 | 1991-05-02 | Sandvik Aktiebolag | A method of manufacturing cladding tubes for fuel rods for nuclear reactors |
EP0495978A1 (en) * | 1990-08-03 | 1992-07-29 | Teledyne Industries Inc | Fabrication of zircaloy mill products for improved microstructure and properties |
EP0495978A4 (en) * | 1990-08-03 | 1993-01-27 | Teledyne Industries Inc | Fabrication of zircaloy mill products for improved microstructure and properties |
EP0559096A1 (en) * | 1992-03-06 | 1993-09-08 | Westinghouse Electric Corporation | Zirlo alloy and method for fabrication |
EP1223587A1 (en) * | 2001-01-09 | 2002-07-17 | Mitsubishi Materials Corporation | Fuel cladding pipe made of Zr-Nb alloy for nuclear reactor |
WO2004040587A1 (en) | 2002-10-30 | 2004-05-13 | Westinghouse Electric Sweden Ab | Method, use and device concerning cladding tubes for nuclear fuel and a fuel assembly for a nuclear pressure water reactor |
US7473329B2 (en) * | 2002-10-30 | 2009-01-06 | Westinghouse Electric Sweden Ab | Method, use and device concerning cladding tubes for nuclear fuel and a fuel assembly for a nuclear pressure water reactor |
WO2006004499A1 (en) * | 2004-07-06 | 2006-01-12 | Westinghouse Electric Sweden Ab | Fuel box in a boiling water nuclear reactor |
US8105448B2 (en) | 2004-07-06 | 2012-01-31 | Westinghouse Electric Sweden Ab | Fuel box in a boiling water nuclear reactor |
CN103650659B (en) * | 2005-12-27 | 2010-03-10 | 西北有色金属研究院 | A kind of preparation method of used by nuclear reactor zirconium-base alloy sheet material |
US8320515B2 (en) | 2006-08-24 | 2012-11-27 | Westinghouse Electric Sweden Ab | Water reactor fuel cladding tube |
US8070892B2 (en) | 2007-02-09 | 2011-12-06 | Korea Atomic Energy Research Institute | High Fe contained zirconium alloy compositions having excellent corrosion resistance and preparation method thereof |
US20120145287A1 (en) * | 2008-02-29 | 2012-06-14 | Korea Atomic Energy Research Institute | Zirconium alloy compositions having excellent corrosion resistance by the control of various metal-oxide and precipitate and preparation method thereof |
CN104550311A (en) * | 2014-12-05 | 2015-04-29 | 宁夏东方钽业股份有限公司 | Method for producing superconducting niobium pipe |
WO2017131260A1 (en) | 2016-01-27 | 2017-08-03 | 한전원자력연료 주식회사 | Method for manufacturing nuclear fuel zirconium part by using multi-stage hot-rolling |
WO2021125439A1 (en) * | 2019-12-18 | 2021-06-24 | 한전원자력연료 주식회사 | Ferritic alloy and method for manufacturing nuclear fuel cladding using same |
US11603584B2 (en) | 2019-12-18 | 2023-03-14 | Kepco Nuclear Fuel Co., Ltd. | Ferritic alloy and method of manufacturing nuclear fuel cladding tube using the same |
CN112775203A (en) * | 2020-12-23 | 2021-05-11 | 西部新锆核材料科技有限公司 | Preparation method of zirconium or zirconium alloy extruded section |
CN112775203B (en) * | 2020-12-23 | 2024-01-19 | 西部新锆核材料科技有限公司 | Preparation method of zirconium or zirconium alloy extrusion profile |
CN113201666A (en) * | 2021-04-08 | 2021-08-03 | 中广核研究院有限公司 | Zirconium alloy for fuel assembly, manufacturing method thereof and cladding tube of fuel assembly |
CN113976657A (en) * | 2021-10-21 | 2022-01-28 | 西安赛特思迈钛业有限公司 | Preparation method of titanium alloy thin-wall seamless pipe with ultra-large diameter |
CN113976657B (en) * | 2021-10-21 | 2024-04-23 | 西安赛特思迈钛业有限公司 | Preparation method of ultra-large caliber titanium alloy thin-wall seamless pipe |
Also Published As
Publication number | Publication date |
---|---|
JPS61210166A (en) | 1986-09-18 |
EP0198570A3 (en) | 1987-10-14 |
ES551049A0 (en) | 1987-09-01 |
KR860005894A (en) | 1986-08-16 |
ES8708021A1 (en) | 1987-09-01 |
KR930009986B1 (en) | 1993-10-13 |
EP0198570B1 (en) | 1990-08-29 |
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