EP0175598A1 - Verfahren zur Vorbehandlung von Oberflächen aus Uran oder Uranlegierungen - Google Patents
Verfahren zur Vorbehandlung von Oberflächen aus Uran oder Uranlegierungen Download PDFInfo
- Publication number
- EP0175598A1 EP0175598A1 EP85401419A EP85401419A EP0175598A1 EP 0175598 A1 EP0175598 A1 EP 0175598A1 EP 85401419 A EP85401419 A EP 85401419A EP 85401419 A EP85401419 A EP 85401419A EP 0175598 A1 EP0175598 A1 EP 0175598A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solution
- uranium
- pickling
- rinsing
- followed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 229910052770 Uranium Inorganic materials 0.000 title claims abstract description 18
- 229910000711 U alloy Inorganic materials 0.000 title claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 28
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000126 substance Substances 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims abstract description 14
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims abstract description 14
- 238000007747 plating Methods 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 238000005554 pickling Methods 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 25
- 229910017604 nitric acid Inorganic materials 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000011282 treatment Methods 0.000 claims description 9
- 238000005530 etching Methods 0.000 claims description 8
- 238000005238 degreasing Methods 0.000 claims description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229910000756 V alloy Inorganic materials 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- UKFXCUGNITXGKG-UHFFFAOYSA-N uranium vanadium Chemical compound [V].[V].[U] UKFXCUGNITXGKG-UHFFFAOYSA-N 0.000 claims description 3
- 238000003486 chemical etching Methods 0.000 claims description 2
- 238000005488 sandblasting Methods 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 3
- 239000000956 alloy Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 57
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 238000005219 brazing Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/46—Pretreatment of metallic surfaces to be electroplated of actinides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1837—Multistep pretreatment
- C23C18/1844—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/30—Acidic compositions for etching other metallic material
Definitions
- the method according to the invention is characterized in that it comprises a step of chemical attack on the surface of the uranium or uranium alloy part using a solution of nickel chloride and acid hydrochloric.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- ing And Chemical Polishing (AREA)
- Chemically Coating (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8411387 | 1984-07-18 | ||
FR8411387A FR2567913B1 (fr) | 1984-07-18 | 1984-07-18 | Procede de preparation de la surface de pieces en uranium ou en alliage a base d'uranium |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0175598A1 true EP0175598A1 (de) | 1986-03-26 |
EP0175598B1 EP0175598B1 (de) | 1988-09-21 |
Family
ID=9306243
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85401419A Expired EP0175598B1 (de) | 1984-07-18 | 1985-07-11 | Verfahren zur Vorbehandlung von Oberflächen aus Uran oder Uranlegierungen |
Country Status (4)
Country | Link |
---|---|
US (1) | US4673585A (de) |
EP (1) | EP0175598B1 (de) |
DE (1) | DE3565126D1 (de) |
FR (1) | FR2567913B1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0225244A1 (de) * | 1985-11-19 | 1987-06-10 | Commissariat A L'energie Atomique | Vorbehandlungsverfahren für Werkstücke aus Uran-Titan-Legierungen, vorzugsweise zur stromlosen Nickelplattierung |
AU632591B2 (en) * | 1989-06-30 | 1993-01-07 | Eltech Systems Corporation | Metal substrate of improved surface morphology |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2984884A (en) * | 1958-06-09 | 1961-05-23 | Aerpat Ag | Stressed panel fastener |
CH363871A (fr) * | 1956-08-08 | 1962-08-15 | Pechiney Prod Chimiques Sa | Procédé de revêtement métallique des surfaces métalliques |
FR1564575A (de) * | 1968-01-24 | 1969-04-25 | ||
FR2017505A1 (de) * | 1968-09-06 | 1970-05-22 | Atomic Energy Commission |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB853522A (en) * | 1945-01-09 | 1960-11-09 | Atomic Energy Authority Uk | Nickel coatings and method of applying |
US2928168A (en) * | 1945-01-24 | 1960-03-15 | Allen G Gray | Iron coated uranium and its production |
US3700482A (en) * | 1970-12-01 | 1972-10-24 | Atomic Energy Commission | Uranium surface preparation for electroless nickel plating |
-
1984
- 1984-07-18 FR FR8411387A patent/FR2567913B1/fr not_active Expired
-
1985
- 1985-07-08 US US06/752,595 patent/US4673585A/en not_active Expired - Fee Related
- 1985-07-11 EP EP85401419A patent/EP0175598B1/de not_active Expired
- 1985-07-11 DE DE8585401419T patent/DE3565126D1/de not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH363871A (fr) * | 1956-08-08 | 1962-08-15 | Pechiney Prod Chimiques Sa | Procédé de revêtement métallique des surfaces métalliques |
US2984884A (en) * | 1958-06-09 | 1961-05-23 | Aerpat Ag | Stressed panel fastener |
FR1564575A (de) * | 1968-01-24 | 1969-04-25 | ||
FR2017505A1 (de) * | 1968-09-06 | 1970-05-22 | Atomic Energy Commission |
Non-Patent Citations (1)
Title |
---|
METAL FINISHING, vol. 74, no. 3, mars 1976, pages 37-42; H.R. JOHNSON et al.: "Etching and plating of uranium alloys" * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0225244A1 (de) * | 1985-11-19 | 1987-06-10 | Commissariat A L'energie Atomique | Vorbehandlungsverfahren für Werkstücke aus Uran-Titan-Legierungen, vorzugsweise zur stromlosen Nickelplattierung |
AU632591B2 (en) * | 1989-06-30 | 1993-01-07 | Eltech Systems Corporation | Metal substrate of improved surface morphology |
Also Published As
Publication number | Publication date |
---|---|
US4673585A (en) | 1987-06-16 |
FR2567913B1 (fr) | 1989-11-10 |
EP0175598B1 (de) | 1988-09-21 |
FR2567913A1 (fr) | 1986-01-24 |
DE3565126D1 (en) | 1988-10-27 |
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