EP0121179A2 - Support pour décalcomanies du type à détachement et du type à glissement - Google Patents

Support pour décalcomanies du type à détachement et du type à glissement Download PDF

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Publication number
EP0121179A2
EP0121179A2 EP84103093A EP84103093A EP0121179A2 EP 0121179 A2 EP0121179 A2 EP 0121179A2 EP 84103093 A EP84103093 A EP 84103093A EP 84103093 A EP84103093 A EP 84103093A EP 0121179 A2 EP0121179 A2 EP 0121179A2
Authority
EP
European Patent Office
Prior art keywords
separating layer
copolymer
water
layer
decals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84103093A
Other languages
German (de)
English (en)
Other versions
EP0121179A3 (en
EP0121179B1 (fr
Inventor
Henner Drum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoffmann & Engelmann AG
Original Assignee
Hoffmann & Engelmann AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoffmann & Engelmann AG filed Critical Hoffmann & Engelmann AG
Publication of EP0121179A2 publication Critical patent/EP0121179A2/fr
Publication of EP0121179A3 publication Critical patent/EP0121179A3/de
Application granted granted Critical
Publication of EP0121179B1 publication Critical patent/EP0121179B1/fr
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175—Transfer using solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175—Transfer using solvent
    • B44C1/1754—Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
    • Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
    • Y10T428/277—Cellulosic substrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31993—Of paper

Definitions

  • the invention relates to a carrier for stripping - or Abschiebemul of absorbent paper with an applied barrier layer and a soluble separating layer by water for receiving a pressure and / or lacquer layer.
  • Carriers for decals or decals are known (DE-OS 25 51 860 corresponding to US Pat. No. 4,049,860 or also US Pat. No. 2,970,076). They contain a water- or heat-soluble separating layer, on which the decoration picture is printed by screen printing or offset printing. When transferring the decor image to the desired surface, either manually or mechanically, depending on the procedure, a residual amount of separating layer components is always transferred.
  • Components of the separating layer are usually gum arabic, polyvinyl alcohol, carboxymethyl cellulose, polyvinyl acetate, polyglycols or oligosaccharides or polysaccharides.
  • Decals or decals are also known which are used outside the ceramic area. These images are transferred to glass, metal, enamel, plastic etc. at temperatures up to max. Fixed at 250 ° C on the base, while the paint mask surrounding the decor image is retained.
  • a significant drawback of the known separating layers is that go with- transferred release layer components at attack of water on the substrate into solution again and the adhesion of the D ekorsentes reduce or cancel.
  • Such images can also be produced in reverse printing, with the advantage that a heat-activatable adhesive is applied in the last working step. Such images then adhere permanently to the base after the heat treatment.
  • the solution to this problem is based on a support for decals or decals of the type mentioned above, and it is characterized in that the separating layer contains or consists of a homo- or copolymer of acrylic acid and / or a copolymer of alkyl vinyl ether and maleic anhydride.
  • the separating layer preferably consists of a mixture of a homo- or copolymer of acrylic acid or a copolymer of methyl vinyl ether and maleic anhydride, and a polysaccharide, in particular dextrin.
  • homopolymers or copolymers of acrylic acid have proven suitable as materials for the separating layer.
  • the homopolymers have molecular weights of 2,000 to 250,000.
  • suitable copolymers are those composed of acrylic acid / acrylic acid esters or methacrylic acid esters. Their molecular weights are in the range from 30,000 to 260,000. These products are commercially available.
  • the homopolymers or copolymers are preferably used in a mixture with customary substances known and suitable for the separating layer. These include the substances described at the beginning. Mixtures with polysaccharides, in particular dextrin, are very particularly preferably used. For the optimal configuration of the invention, it has proven to be advantageous if the separating layer contains at least 50 percent by weight of homo- or copolymer.
  • Separating layers consisting of homo- or copolymers of acrylic acid mixed with dextrin can be used to decorate unglazed ceramic substrates. After baking in the rapid firing process, no residues are visible in the non-image areas.
  • Copolymers of alkyl vinyl ether and maleic anhydride, in particular of methyl vinyl ether and maleic anhydride, have also proven to be very suitable as materials for the separating layer according to the invention.
  • Mixtures of homo- or copolymers of acrylic acid and of copolymers of alkyl vinyl ether and maleic anhydride can also be used for the separating layer according to the invention.
  • different dissolving and floating times of the images are achieved, which is particularly important in the case of machine application.
  • simple and relatively inexpensive separating layers can be achieved, which can be used for a wide variety of applications.
  • the invention achieves that a carrier for decals or decals can be provided, which meets both the requirements for , To suit decorative images after the residue-free decorations, may be used as well for a water soluble coating, with subsequent fixing of the D-e korsentes, by transferring the remainder of release layer components in a water-insoluble state.
  • the invention is explained in more detail with reference to the attached figure. It shows schematically a cross section of a carrier according to the invention for decals or decals. Position 1 of the paper carrier is specified therein, on average with a mass per unit area in the range from approximately 100 to 200 g / m 2 .
  • the paper carrier contains a barrier layer 2, which makes one surface of the paper carrier less porous. It can consist of pure surface sizing or of a sealable spread, for example starch, casein, glue, alkali metal silicate or water glass with and without clay filler. The presence of the barrier layer 2 prevents excessive penetration and absorption of the material according to the invention to be applied for the separating layer 3.
  • the separating layer 3 made of the materials described is applied over the barrier layer 2 by means of a suitable application method.
  • the dry weight to be applied is 6 to 15 g / m 2 . Drying takes place at approx. 80 ° C in a drying tunnel.
  • the individual components are first dissolved in water.
  • Dextrin is sprinkled in cold water and dissolved with moderate stirring.
  • Polyacrylic acid is commercially available as a solution.
  • copolymer of acrylic acid and acrylic acid ester (PAS / PAE) is dissolved in water at 70 ° C. by neutralization, for example by adding 23 parts of triethanolamine to 100 parts of copolymer.
  • dextrin can impair residue-free combustion, according to the invention a proportion of 50 percent by weight in the formulation should not be exceeded.
  • dextrin is also useful to the extent that its presence has a positive influence on the floating and peeling properties with regard to the separating layer and the decor.
  • dextrin is suitable as a reaction partner to PVE / MA.
  • the paper supports provided with the separating layers 1 to 9 are coated with a commercially available, residue-free burning acrylic varnish (varnish 83450 from Degussa) as a varnish mask and air-dried.
  • test specimens prepared in this way are briefly placed on the back with water.
  • the peeling paint film is pushed onto unglazed ceramic pieces after 1 minute and spread using a rubber squeegee.
  • the air-dry pieces are then heated to 550 ° C., the paint mask being completely burned, and then cooled again.
  • Recipes 1 and 2 clearly show traces of unburned interface.
  • Recipes 3 to 9 show no traces of clays, i.e. Even at a relatively low firing temperature, the residues of the separating layer that are also transferred are burned without residue, without leaving soot particles.
  • a lacquer mask applied to the separating layer according to recipe 4 instead of an applied decorative image with lacquer mask is transferred in the usual way to a plastic container (bottle) as a base and exposed to a temperature of approximately 200 ° C. for 15 minutes.
  • a plastic container is treated accordingly, a material according to recipe 1 being used as the separating layer.
  • both containers are exposed to water containing surfactants as a test solution. While the paint mask, transferred with the help of recipe 4, which withstands the action of water for 20 minutes, the paint mask, which was transferred with the help of recipe 1 for the separating layer, floats after the same time.

Landscapes

  • Decoration By Transfer Pictures (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Laminated Bodies (AREA)
EP84103093A 1983-03-30 1984-03-21 Support pour décalcomanies du type à détachement et du type à glissement Expired EP0121179B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19833311728 DE3311728A1 (de) 1983-03-30 1983-03-30 Traeger fuer abzieh- oder abschiebebilder
DE3311728 1983-03-30

Publications (3)

Publication Number Publication Date
EP0121179A2 true EP0121179A2 (fr) 1984-10-10
EP0121179A3 EP0121179A3 (en) 1984-11-14
EP0121179B1 EP0121179B1 (fr) 1987-05-20

Family

ID=6195177

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84103093A Expired EP0121179B1 (fr) 1983-03-30 1984-03-21 Support pour décalcomanies du type à détachement et du type à glissement

Country Status (6)

Country Link
US (1) US4529654A (fr)
EP (1) EP0121179B1 (fr)
JP (1) JPS59185689A (fr)
DE (2) DE3311728A1 (fr)
ES (1) ES530804A0 (fr)
FI (1) FI841235A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0665263A1 (fr) * 1994-01-26 1995-08-02 Kureha Kagaku Kogyo Kabushiki Kaisha Matériau multicouche barrière au gaz et procédé de sa production

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3337023A1 (de) * 1983-10-12 1985-04-25 Hoffmann & Engelmann Ag, 6730 Neustadt Papiertraeger
EP0681913A1 (fr) * 1985-02-05 1995-11-15 Avery International Corporation Matériaux composés de surface pour des enseignes
US4946532A (en) * 1985-02-05 1990-08-07 Avery International Corporation Composite facestocks and liners
US4888075A (en) * 1985-02-05 1989-12-19 Avery International Corporation Composite facestocks and liners
US5143570A (en) * 1985-02-05 1992-09-01 Avery Dennison Corporation Composite facestocks and liners
US5372669A (en) * 1985-02-05 1994-12-13 Avery Dennison Corporation Composite facestocks and liners
US5186782A (en) * 1990-10-17 1993-02-16 Avery Dennison Corporation Method for high speed labelling of deformable substrates
JP2593754B2 (ja) * 1991-08-05 1997-03-26 名古屋パルプ株式会社 絵付け転写用紙
DE4210976C2 (de) * 1991-10-17 1997-05-22 Buelent Oez Verfahren zum Übertragen von auf Druckvorlagen befindlichen Abbildungen auf Stoffe und Papier zur Durchführung des Verfahrens
US5516393A (en) * 1993-04-29 1996-05-14 Avery Dennison Corporation Labelling of substrates
AU5176396A (en) * 1995-03-20 1996-10-08 Richard S. Zemel Graphic transfer and method
CN1088426C (zh) * 1995-06-05 2002-07-31 艾弗里·丹尼森公司 耐热压敏胶结构体
US6264786B1 (en) 1998-05-28 2001-07-24 Mattel, Inc. User-created temporary tattoos
US6524675B1 (en) 1999-05-13 2003-02-25 3M Innovative Properties Company Adhesive-back articles
DE19927758B4 (de) * 1999-06-17 2005-09-22 Ugt Limited, Tuen Mun Verfahren zum Übertragen eines Bildes auf eine Fläche
GB2351038B (en) * 1999-06-18 2003-03-12 Tam Chit Ho Process for transferring an image onto a surface
US20030039826A1 (en) 2000-03-20 2003-02-27 Sun Edward I. Conformable and die-cuttable biaxially oriented films and labelstocks
US6645642B2 (en) * 2001-04-11 2003-11-11 International Papar Company Paper articles exhibiting long term storageability and method for making same
DE10125681C1 (de) 2001-05-25 2003-02-20 Buelent Oez Verfahren zum Übertragen von auf Druckvorlagen befindlichen Abbildungen auf farbige Unterlagen sowie hierzu geeignetes Vorlagematerial
FI111922B (fi) * 2002-05-31 2003-10-15 Perlos Oyj Menetelmä kolmiulotteisten pintojen kuviointiin
EP2159322B1 (fr) * 2004-07-06 2015-01-21 International Paper Company Substrats de papier contenant un composant antimicrobien ainsi que ses procédés de fabrication et son utilisation
CN1318695C (zh) * 2005-10-13 2007-05-30 中国制浆造纸研究院 水转移陶瓷贴花底纸用涂布水转原纸的制造方法
WO2010148156A1 (fr) * 2009-06-16 2010-12-23 International Paper Company Substrats de papier antimicrobien utiles dans des applications de joint de panneaux muraux
US9996789B2 (en) * 2015-09-21 2018-06-12 Cutaneous Information Technologies Llc Method and apparatus for manufacturing cutaneous information devices
US10406830B2 (en) 2017-03-29 2019-09-10 Xerox Corporation Decal print process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US3128197A (en) * 1961-07-11 1964-04-07 Buntpapierfabrik A G Ceramic underglaze decalcomania and method of making same
US3669704A (en) * 1969-11-28 1972-06-13 Thomas L Reiling Non-curling decalcomania paper comprising a discontinuous polymer-starch particlebarrier layer
DE2551860A1 (de) * 1975-11-19 1977-06-02 Hoffmann & Engelmann Ag Papiertraeger

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2729288C2 (de) * 1977-06-29 1979-06-13 Fa. F. Xaver Leipold, 8502 Zirndorf Abziehbild und Verfahren zu seiner Herstellung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US3128197A (en) * 1961-07-11 1964-04-07 Buntpapierfabrik A G Ceramic underglaze decalcomania and method of making same
US3669704A (en) * 1969-11-28 1972-06-13 Thomas L Reiling Non-curling decalcomania paper comprising a discontinuous polymer-starch particlebarrier layer
DE2551860A1 (de) * 1975-11-19 1977-06-02 Hoffmann & Engelmann Ag Papiertraeger

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0665263A1 (fr) * 1994-01-26 1995-08-02 Kureha Kagaku Kogyo Kabushiki Kaisha Matériau multicouche barrière au gaz et procédé de sa production
US5897960A (en) * 1994-01-26 1999-04-27 Kureha Kagaku Kogyo K.K. Laminate and production process thereof

Also Published As

Publication number Publication date
JPS59185689A (ja) 1984-10-22
ES8505752A1 (es) 1985-06-01
EP0121179A3 (en) 1984-11-14
FI841235A (fi) 1984-10-01
ES530804A0 (es) 1985-06-01
DE3463748D1 (en) 1987-06-25
DE3311728A1 (de) 1984-10-04
EP0121179B1 (fr) 1987-05-20
FI841235A0 (fi) 1984-03-28
US4529654A (en) 1985-07-16

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