EP0109022A2 - Composition détergente concentrée liquide appropriée pour la préparation de détergents liquides pour lavages délicats de lingerie et pour la vaisselle. - Google Patents
Composition détergente concentrée liquide appropriée pour la préparation de détergents liquides pour lavages délicats de lingerie et pour la vaisselle. Download PDFInfo
- Publication number
- EP0109022A2 EP0109022A2 EP83111093A EP83111093A EP0109022A2 EP 0109022 A2 EP0109022 A2 EP 0109022A2 EP 83111093 A EP83111093 A EP 83111093A EP 83111093 A EP83111093 A EP 83111093A EP 0109022 A2 EP0109022 A2 EP 0109022A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- composition according
- alcohols
- surfactants
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 239000003599 detergent Substances 0.000 title claims abstract description 28
- 239000007788 liquid Substances 0.000 title claims abstract description 13
- 238000004851 dishwashing Methods 0.000 title description 4
- 238000010412 laundry washing Methods 0.000 title 1
- 239000013543 active substance Substances 0.000 claims abstract description 17
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 11
- 150000001298 alcohols Chemical class 0.000 claims abstract description 8
- 238000010790 dilution Methods 0.000 claims abstract description 8
- 239000012895 dilution Substances 0.000 claims abstract description 8
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
- 239000000194 fatty acid Substances 0.000 claims abstract description 7
- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 125000000129 anionic group Chemical group 0.000 claims abstract description 6
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 claims abstract description 5
- -1 alkylphenols Substances 0.000 claims abstract description 4
- 239000003792 electrolyte Substances 0.000 claims abstract description 4
- 229920001519 homopolymer Polymers 0.000 claims abstract description 4
- 150000002576 ketones Chemical class 0.000 claims abstract description 4
- 125000006353 oxyethylene group Chemical group 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 150000002334 glycols Chemical class 0.000 claims abstract description 3
- 239000000047 product Substances 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 150000003841 chloride salts Chemical class 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 238000000855 fermentation Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 150000004677 hydrates Chemical class 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims 1
- QACCCIVMWADWMN-UHFFFAOYSA-N ethane-1,2-diol;methoxymethane Chemical compound COC.OCCO QACCCIVMWADWMN-UHFFFAOYSA-N 0.000 claims 1
- 238000006386 neutralization reaction Methods 0.000 claims 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 150000001253 acrylic acids Chemical class 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 13
- 238000005063 solubilization Methods 0.000 description 6
- 230000007928 solubilization Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 235000008504 concentrate Nutrition 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/655—Mixtures of sulfonated products with alkylolamides of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
Definitions
- This invention relates to liquid detergents, and more particularly to a liquid light duty detergent composition complete with all the ingredients, including the minor components, having a high concentration of active materials, in the form of a viscous liquid, quickly dilutable in water, adapted for preparing liquid detergents ready to be used.
- Detergents and more particularly liquid detergents, are substantially formed by surfactants, either of anionic, non-ionic or amphoteric type, defined as active agents, and by various materials added to obtain particular effects, such as for example bleaching agents or builders in case of laundering products, or abrasive powders in case of bathroom or kitchen-cleaning products, and/or minor agents such as electrolytes, perfumes, anti-fermentation agents, dyes, and the like.
- surfactants either of anionic, non-ionic or amphoteric type, defined as active agents, and by various materials added to obtain particular effects, such as for example bleaching agents or builders in case of laundering products, or abrasive powders in case of bathroom or kitchen-cleaning products, and/or minor agents such as electrolytes, perfumes, anti-fermentation agents, dyes, and the like.
- anionic surfactants the most widely used is the straightchain alkylaryl sulfonate, in the form of sodium potassium, ammonium and alkanol ammonium salts (LAS Na, LAS K, LAS Tea), or combination of the above.
- alkylaryl sulfonates also sodium alkane--sulfonates (SAS Na), sulfonated -olefines, and sodium alkylethoxy sulfates (AES Na) of low ethoxylation type are frequently used.
- SAS Na sodium alkane--sulfonates
- AES Na sodium alkylethoxy sulfates
- non-ionic surfactants the most widely used are the ethylene oxide condensates with alkanolamides, or fatty alcohols, or fatty acids, or alkylphenols.
- amphoteric surfactants the betaine derivatives, imidazole derivatives, and amine oxides are widely used.
- Concentrated detergent compositions comprising a mixture of anionic, non-ionic and amphoteric surfactants, are known.
- composition of the above mentioned prior art patent so as to obtain: a) a concentrate containing about the 70% of active matter; b) by reducing the non-ionic surfactants content in the composition and c) by eliminating the free alkali in the composition so as to obtain a neutral pH value, as highly desiderable especially for a light duty and dishwashing detergent, a dissolving time of more than 60 minutes was obtained.
- the main obstacle in the formulation of such a product is the low water solubilization speed of almost all the most-commonly used surfactants when they are in a highly concentrated form, which is, obviously, the only possible form for the product according to this invention.
- the desired result is obtained of a quick and easy solubilization in water, lower than 3 minutes in many cases, by simple dilution with minimum stirring.
- polar solvents such as alcohols, glycols, glycol ethers, low molecular weight ketones
- the object of this invention is to provide a complete detergent, characterized at the same time by the following features:
- anionic surfactants have proved to be suitable, namely the straight-chain alkylarylsulfonates, particularly the salts of potassium and triethanolamine, the sodium alkansulfonates and sodium alkylethoxy sulfates (containing 2 to 3 moles of ethylene oxide).
- solvents light alcohols with number of carbon atoms 1 to 3, low molecular weight ketones such as acetone and methylethylketone, and some glycol ethers such as monomethyl-ether glycol ether and monoethyl-ether glycol ether may be used.
- the total active agents are formed, in addition to the anionic surfactant main constituents, also by non--ionic surfactants in smaller percentages, mainly as foam stabilizers and, due to their dispersing and fluidizing characteristics, in order to permit the admixture of minor additives, such as perfumes, into the composition without impairing the peculiar characteristics, particularly the high solubilization property of the composition.
- the invention advantageously uses the polycondensed alkylphenols with 4 to 9 moles of ethylene oxide, polycondensed straight alcohols (type C 9 - C 15 ) with 7 to 15 moles of ethylene oxide, and polycondensed alkanolamides of fatty acids (coconut type) with 1 to 5 moles of ethylene oxide.
- the concentrated composition can incorporate therein water-soluble polymeric materials, of the oxyethylene homopolymer type, having a molecular weight in the range 400,000 to 5,000,000 and marketed under the Trademark "Polyox" registered by Union Carbide, with concentrations of 1 to 5%.
- acids are neutralized, in the mixing and diluting step, by basic materials, such as alkaline hydrates, ammonium hydroxide, alkanolamines, admixtured into the concentrated composition for this purpose;
- basic materials such as alkaline hydrates, ammonium hydroxide, alkanolamines, admixtured into the concentrated composition for this purpose;
- alkanolamides of fatty acids length of chain C 10-22 ) added according to a ratio higher than 1:20 into the concentrated composition
- electrolytes particularly chlorides and sulfates of alkaline metals, alkaline-earth metals ammonium, added according to a ratio higher than 1:20 into the concentrated composition.
- the main surfactants used in these examples are usually marketed and available materials, indicated by the symbols generally used to designate them in the technical literature (for example, LAS, SAS, AES), followed by the respective concentration of active agent.
- Each formulation comprises the indication of the percentage composition, the contents of total active agent (anionic + non-ionic surfactants) and the solution time required to achieve the solubilization in water, at the ambient temperature, by simple manual shaking, to obtain diluted final solutions with 12% concentration of total active agent.
- a combination is reported here of a concentrated composition into which, in the dilution step, viscosity--enhancing materials are added.
- composition A In order to obtain a 12% diluted product of total active agent in the dilution step, .the composition A will be added with a viscosity-enhancing material in the form of a polyacrylic acid in water emulsion and sodium chloride in the following ratios:
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT83111093T ATE28893T1 (de) | 1982-11-09 | 1983-11-07 | Konzentrierte fluessige detergenszusammensetzung,geeignet fuer die herstellung von fluessigen waeschefeinwaschmitteln oder geschirrwaschmitteln. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT12659/82A IT1164469B (it) | 1982-11-09 | 1982-11-09 | Composizione detergente concentrata sotto forma di liquido viscoso rapidamente solubile in acqua adatta alla preparazione mediante diluizione di detersivi liquidi pronti per l'uso |
| IT1265982 | 1982-11-09 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0109022A2 true EP0109022A2 (fr) | 1984-05-23 |
| EP0109022A3 EP0109022A3 (en) | 1985-04-24 |
| EP0109022B1 EP0109022B1 (fr) | 1987-08-12 |
Family
ID=11142541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP83111093A Expired EP0109022B1 (fr) | 1982-11-09 | 1983-11-07 | Composition détergente concentrée liquide appropriée pour la préparation de détergents liquides pour lavages délicats de lingerie et pour la vaisselle. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0109022B1 (fr) |
| AT (1) | ATE28893T1 (fr) |
| DE (1) | DE3372986D1 (fr) |
| EG (1) | EG16154A (fr) |
| ES (1) | ES527093A0 (fr) |
| IT (1) | IT1164469B (fr) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0243685A2 (fr) * | 1986-04-09 | 1987-11-04 | MIRA LANZA S.p.a. | Composition détergente concentrée diluable |
| EP0264825A2 (fr) * | 1986-10-23 | 1988-04-27 | Henkel Kommanditgesellschaft auf Aktien | Préparation pâteuse contenant peu d'eau |
| EP0301882A1 (fr) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Compositions détergentes liquides |
| FR2622205A1 (fr) * | 1987-10-21 | 1989-04-28 | Univ Toulouse | Utilisation de sels de metaux alcalins et alcalino-terreux pour rendre visqueuses des solutions aqueuses de surfactifs anioniques, et compositions visqueuses ainsi obtenues |
| EP0333014A2 (fr) * | 1988-03-16 | 1989-09-20 | Henkel Kommanditgesellschaft auf Aktien | Détergent liquide |
| EP0340001A2 (fr) * | 1988-04-29 | 1989-11-02 | Unilever Plc | Produits détergents liquides |
| EP0347110A1 (fr) * | 1988-06-13 | 1989-12-20 | Colgate-Palmolive Company | Agent de nettoyage pour tout usage stable, concentré et homogène |
| WO1993003129A1 (fr) * | 1991-08-02 | 1993-02-18 | Unilever Plc | Composition liquide concentree pour laver la vaisselle a la main comprenant une base d'alcane diol |
| EP0598143A1 (fr) * | 1992-10-30 | 1994-05-25 | DELTA OMEGA TECHNOLOGIES, Ltd. | Agent nettoyant, mouillant et solvant |
| US5415798A (en) * | 1994-01-14 | 1995-05-16 | Betz Paperchem Inc. | Concentrated high flash point surfactant compositions |
| WO1996026156A2 (fr) * | 1995-02-23 | 1996-08-29 | Ecolab Inc. | Appareil et procede pour distribuer une solution visqueuse prete a l'emploi |
| GB2319256A (en) * | 1996-11-16 | 1998-05-20 | Reckitt & Colmann Prod Ltd | Hard surface cleaner |
| US5837065A (en) * | 1994-03-23 | 1998-11-17 | Amway Corporation | Concentrated all-purpose light duty liquid cleaning composition and method of use |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4105592A (en) * | 1974-06-21 | 1978-08-08 | The Procter & Gamble Company | Liquid detergent compositions |
| GB1527141A (en) * | 1976-01-06 | 1978-10-04 | Procter & Gamble | Liquid detergent composition |
| DE2913049A1 (de) * | 1979-03-31 | 1980-10-16 | Henkel Kgaa | Fluessiges reinigungsmittel |
-
1982
- 1982-11-09 IT IT12659/82A patent/IT1164469B/it active
-
1983
- 1983-11-07 DE DE8383111093T patent/DE3372986D1/de not_active Expired
- 1983-11-07 AT AT83111093T patent/ATE28893T1/de not_active IP Right Cessation
- 1983-11-07 EP EP83111093A patent/EP0109022B1/fr not_active Expired
- 1983-11-08 ES ES527093A patent/ES527093A0/es active Granted
- 1983-11-09 EG EG692/83A patent/EG16154A/xx active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4105592A (en) * | 1974-06-21 | 1978-08-08 | The Procter & Gamble Company | Liquid detergent compositions |
| GB1527141A (en) * | 1976-01-06 | 1978-10-04 | Procter & Gamble | Liquid detergent composition |
| DE2913049A1 (de) * | 1979-03-31 | 1980-10-16 | Henkel Kgaa | Fluessiges reinigungsmittel |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0243685A3 (fr) * | 1986-04-09 | 1989-03-22 | MIRA LANZA S.p.a. | Composition détergente concentrée diluable |
| EP0243685A2 (fr) * | 1986-04-09 | 1987-11-04 | MIRA LANZA S.p.a. | Composition détergente concentrée diluable |
| EP0264825A3 (fr) * | 1986-10-23 | 1990-08-08 | Henkel Kommanditgesellschaft auf Aktien | Préparation pâteuse contenant peu d'eau |
| EP0264825A2 (fr) * | 1986-10-23 | 1988-04-27 | Henkel Kommanditgesellschaft auf Aktien | Préparation pâteuse contenant peu d'eau |
| EP0301882A1 (fr) * | 1987-07-31 | 1989-02-01 | Unilever Plc | Compositions détergentes liquides |
| AU600587B2 (en) * | 1987-07-31 | 1990-08-16 | Unilever Plc | Liquid detergent compositions |
| FR2622205A1 (fr) * | 1987-10-21 | 1989-04-28 | Univ Toulouse | Utilisation de sels de metaux alcalins et alcalino-terreux pour rendre visqueuses des solutions aqueuses de surfactifs anioniques, et compositions visqueuses ainsi obtenues |
| EP0333014A3 (fr) * | 1988-03-16 | 1991-05-15 | Henkel Kommanditgesellschaft auf Aktien | Détergent liquide |
| EP0333014A2 (fr) * | 1988-03-16 | 1989-09-20 | Henkel Kommanditgesellschaft auf Aktien | Détergent liquide |
| EP0340001A2 (fr) * | 1988-04-29 | 1989-11-02 | Unilever Plc | Produits détergents liquides |
| EP0340001A3 (fr) * | 1988-04-29 | 1991-07-10 | Unilever Plc | Produits détergents liquides |
| EP0347110A1 (fr) * | 1988-06-13 | 1989-12-20 | Colgate-Palmolive Company | Agent de nettoyage pour tout usage stable, concentré et homogène |
| WO1993003129A1 (fr) * | 1991-08-02 | 1993-02-18 | Unilever Plc | Composition liquide concentree pour laver la vaisselle a la main comprenant une base d'alcane diol |
| EP0598143A1 (fr) * | 1992-10-30 | 1994-05-25 | DELTA OMEGA TECHNOLOGIES, Ltd. | Agent nettoyant, mouillant et solvant |
| US5415798A (en) * | 1994-01-14 | 1995-05-16 | Betz Paperchem Inc. | Concentrated high flash point surfactant compositions |
| US5837065A (en) * | 1994-03-23 | 1998-11-17 | Amway Corporation | Concentrated all-purpose light duty liquid cleaning composition and method of use |
| WO1996026156A2 (fr) * | 1995-02-23 | 1996-08-29 | Ecolab Inc. | Appareil et procede pour distribuer une solution visqueuse prete a l'emploi |
| WO1996026156A3 (fr) * | 1995-02-23 | 1996-10-17 | Ecolab Inc | Appareil et procede pour distribuer une solution visqueuse prete a l'emploi |
| US5816446A (en) * | 1995-02-23 | 1998-10-06 | Ecolab Inc. | Dispensing a viscous use solution by diluting a less viscous concentrate |
| GB2319256A (en) * | 1996-11-16 | 1998-05-20 | Reckitt & Colmann Prod Ltd | Hard surface cleaner |
| GB2319256B (en) * | 1996-11-16 | 2000-09-27 | Reckitt & Colmann Prod Ltd | Light duty cleaner |
| US6130197A (en) * | 1996-11-16 | 2000-10-10 | Reckitt & Colman Products Limited | Hard surface cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| ES8504241A1 (es) | 1985-04-16 |
| ATE28893T1 (de) | 1987-08-15 |
| DE3372986D1 (en) | 1987-09-17 |
| IT8212659A0 (it) | 1982-11-09 |
| ES527093A0 (es) | 1985-04-16 |
| EP0109022B1 (fr) | 1987-08-12 |
| EG16154A (en) | 1987-07-30 |
| EP0109022A3 (en) | 1985-04-24 |
| IT1164469B (it) | 1987-04-08 |
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