EP0100690A1 - Formannehmende Beschichtung mit hohem Reibungswiderstand - Google Patents

Formannehmende Beschichtung mit hohem Reibungswiderstand Download PDF

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Publication number
EP0100690A1
EP0100690A1 EP83401121A EP83401121A EP0100690A1 EP 0100690 A1 EP0100690 A1 EP 0100690A1 EP 83401121 A EP83401121 A EP 83401121A EP 83401121 A EP83401121 A EP 83401121A EP 0100690 A1 EP0100690 A1 EP 0100690A1
Authority
EP
European Patent Office
Prior art keywords
layer
coating
support layer
thickness
thin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83401121A
Other languages
English (en)
French (fr)
Other versions
EP0100690B1 (de
Inventor
Gérard Biotteau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Manufacture Francaise des Chaussures ERAM SA
Original Assignee
Manufacture Francaise des Chaussures ERAM SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Manufacture Francaise des Chaussures ERAM SA filed Critical Manufacture Francaise des Chaussures ERAM SA
Priority to AT83401121T priority Critical patent/ATE22581T1/de
Publication of EP0100690A1 publication Critical patent/EP0100690A1/de
Application granted granted Critical
Publication of EP0100690B1 publication Critical patent/EP0100690B1/de
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0065Organic pigments, e.g. dyes, brighteners
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0052Compounding ingredients, e.g. rigid elements
    • D06N7/0055Particulate material such as cork, rubber particles, reclaimed resin particles, magnetic particles, metal particles, glass beads
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1471Protective layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372Particulate matter
    • Y10T428/24405Polymer or resin [e.g., natural or synthetic rubber, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/266Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension of base or substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848Three or more layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2344Coating or impregnation is anti-slip or friction-increasing other than specified as an abrasive

Definitions

  • this shape stability constitutes a drawback because the coating, due to the shape stability of the support layer, does not adapt to non-planar surfaces or to applications such as the coating of the parts of the bridges of boats on the left surface, the coating of the various handles and handles on which a helical winding is carried out with covering of a relatively narrow band, etc.
  • a sheet material on calendar nonwoven of 0.3 mm such as that described in French patent No. 2,439,084 has a deformation at the breaking limit of 3 to 15% for a force of 50 to 60 N exerted on a strip of a centimeter wide. In fact, the elongation that it is possible to obtain at the time of application is extremely low and even practically zero.
  • the object of the present invention is to solve this problem and to create a sheet coating of the type comprising a surface layer consisting of a crumb at least partially embedded in a layer of polymerizable resin which is thin and which is conformable on a left surface. .
  • a thin sheet material having a coefficient of elongation between 20 and 60% is used as the support layer for a tensile force per linear centimeter less than 20N.
  • the thin layer material constituting the support layer may be a plastic film obtained by extrusion or calendering having a thickness of between 0.01 and L mm, preferably between 0.05 and 0.10 mm, a stretch fabric of the stretch knit type having a thickness of less than 3 mm or a needled or chemically bonded nonwoven having a thickness of less than 1 millimeter and a elongation before rupture between 20 and 60%.
  • the plastic film can be based on plasticized polyvinyl chloride, polyester or cellulose acetate. Stretch knitting can be made with natural or synthetic fibers.
  • the deformable nonwoven consists for example of a mixture of cotton fibers and of superpolyamide chemically bonded by an acrylic binder.
  • the limit values of the elongation and the tensile force have been fixed taking into account the fact that the tensile force which it is possible to exert on the strip during the laying operation is limited to a manual force, that an elongation of less than 20% is insufficient to obtain the necessary conformability and that an elongation of more than 60% is capable of causing a tearing of the surface layer of resin and of crumb which exhibits an elongation before rupture of the order of 50 to 60%.
  • the dorsal face of the support layer is coated with a contact adhesive.
  • a contact adhesive preferably an adhesive adhering by simple pressure. This makes it possible to adhere the covering layer to the left surface along the rump line and then apply it on either side thereof, exerting on the lateral edges the tensile force necessary to ensure elongation corresponding to the curvatures of the surface.
  • the adhesive layer is protected by a peelable film such as a sheet of paper having a low adhesion power for the adhesive.
  • the product according to the invention comprises an upper layer of polymerized resin, in particular polyurethane in which is at least partially coated a crumb of a compatible material, in particular in polyurethane, having a particle size comprised between 0.2 and 1 mm, the overall thickness of the layer being between 0.5 and 3 mm, a support layer constituted by a thin sheet material having an elongation coefficient between 20 and 60% for a tensile force per linear centimeter less than 20N and bonded with the above layer by chemical welding during the polymerization of compatible materials and / or partial coating of the constituent fibers of this thin sheet material and a layer of contact adhesive protected by a peelable film on the dorsal face of the support layer, and the thickness overall coating is between 0.5 and 3 mm.
  • a layer of polymerized resin is applied to the upper layer to coat the crumb.
  • the coating obtained has a high coefficient of friction which gives it a non-slip property and it is thermally insulating under a small thickness, which makes it particularly suitable for being applied to handles and handles such as fishing rod handles, racket handles tennis, ski pole grips, bicycle handlebars and steering wheels, tool handles and butts, its elongation capacity allowing the application by helical winding of a strip with overlapping of the turns.
  • handles and handles such as fishing rod handles, racket handles tennis, ski pole grips, bicycle handlebars and steering wheels, tool handles and butts, its elongation capacity allowing the application by helical winding of a strip with overlapping of the turns.
  • It is also a covering material which is particularly well suited for left or flat surfaces such as upper windsurfing surfaces, boat decks, stair treads, display units for dashboards and rear areas of cars, various wall coverings. , etc.
  • a plasticized polyvinyl chloride film having a thickness of 0.05 mm, a tensile strength of ION per linear cm and an elongation before rupture of 60% was used as the support layer.
  • This film was coated on one side with an adhesive based on acrylic resin adhering by simple pressure and protected by a sheet of paper.
  • an adhesion primer was applied and then deposited by casting using a die and at the rate of 600 gr / m 2 a polymerizable mixture having the following composition by weight:
  • a layer of solid powder material consisting of a polyurethane powder having a graded particle size between 0.2 and 1 mm is spread over said layer at the rate of 200 gr / m 2 .
  • the assembly is passed through a hot air drying oven at a temperature of 80 ° C for 5 minutes.
  • the sheet material obtained has a thickness of approximately 1 mm and a weight of 850 to 900 gr per m 2 . Its elongation is 60% under a tensile force of 1 6 N per linear cm.
  • a nonwoven consisting of a mixture of polyamide and cotton fibers linked together by an acrylic resin was used as support layer, the support layer having a surface weight of 200 gr / m 2 , a thickness of 0.7 mm and a elongation at the breaking limit of 60%.
  • One side of the nonwoven was coated with a heat-reactivable synthetic rubber-based adhesive layer protected by a protective paper.
  • the resin was crosslinked with evaporation of the solvents by passage through an oven at 80 ° C for 7 minutes.
  • a second layer of polyurethane resin was then deposited on the upper side by spraying at a rate of 50 gr / m 2 , this resin having the following formula:
  • the sheet material was passed through an oven at 80 ° C for 7 minutes to complete crosslinking and evaporation of the solvents.
  • the second layer of polyurethane resin constitutes a protective film against dirt; it increases resistance to abrasion and protects the crumb which is on the surface.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
EP83401121A 1982-06-15 1983-06-02 Formannehmende Beschichtung mit hohem Reibungswiderstand Expired EP0100690B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83401121T ATE22581T1 (de) 1982-06-15 1983-06-02 Formannehmende beschichtung mit hohem reibungswiderstand.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8210464A FR2528356A1 (fr) 1982-06-15 1982-06-15 Revetement conformable a haut coefficient de frottement
FR8210464 1982-06-15

Publications (2)

Publication Number Publication Date
EP0100690A1 true EP0100690A1 (de) 1984-02-15
EP0100690B1 EP0100690B1 (de) 1986-10-01

Family

ID=9275039

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83401121A Expired EP0100690B1 (de) 1982-06-15 1983-06-02 Formannehmende Beschichtung mit hohem Reibungswiderstand

Country Status (5)

Country Link
US (1) US4608287A (de)
EP (1) EP0100690B1 (de)
AT (1) ATE22581T1 (de)
DE (1) DE3366560D1 (de)
FR (1) FR2528356A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3622559A1 (de) * 1986-07-04 1987-05-21 Schlegel Lining Tech Gmbh Verfahren zum ausruesten der oberflaeche einer folie aus schweissbarem polymerwerkstoff mit vorspruengen sowie nach diesem verfahren hergestellte folie
US4879148A (en) * 1987-03-02 1989-11-07 Raychem Limited Marker assembly
US4980229A (en) * 1987-03-03 1990-12-25 Raychem Corporation Article surface coated with curable particulate or filamentary material
CA2058700C (en) * 1991-01-08 2000-04-04 David E. Williams Polymer backed material with non-slip surface
US5433979A (en) * 1993-05-17 1995-07-18 Norton Company Method of producing a non-slip sheet
DE4412636A1 (de) * 1994-04-13 1995-10-19 Braun Pebra Gmbh Verfahren und Anlage zur Herstellung von verformbaren Halbzeugmatten
WO1996008404A1 (en) * 1994-09-16 1996-03-21 Viatech, Inc. Lightweight ergonomic bar end
AU4869796A (en) * 1995-02-21 1996-09-11 Serrot Corporation Fabric mesh reinforced monolithic thermoplastic membrane
US5573816A (en) * 1995-06-06 1996-11-12 Norton Company Friction coating for film backings
JP2001295454A (ja) * 2000-04-07 2001-10-26 Three M Innovative Properties Co 接着シートおよび床面被覆構造体
US20120013112A1 (en) * 2010-07-13 2012-01-19 Douglas Kapp Traction Device To Walk On Ice While Wearing Ice Skate Scabbard

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2706936A (en) * 1948-06-21 1955-04-26 Minnesota Mining & Mfg Anti-skid surface covering
GB1231005A (de) * 1968-01-12 1971-05-05
DE2735669A1 (de) * 1977-07-13 1979-02-22 Ruediger Lothar Von Di Reppert Verfahren zur herstellung beschichteter tennissaiten
FR2439084A1 (fr) * 1978-10-18 1980-05-16 Eram Ind Materiau en feuille pour la realisation de sols pour la pratique des sports et procede de fabrication d'un tel materiau
US4239797A (en) * 1978-09-29 1980-12-16 Gaf Corporation Non-skid floor tile

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2112087B1 (de) * 1970-10-09 1973-11-23 Bourdin & Chausse
US3801421A (en) * 1970-11-09 1974-04-02 Minnesota Mining & Mfg Resilient composite useful as surfacing for athletics
US4196243A (en) * 1978-09-29 1980-04-01 Gaf Corporation Non-skid floor covering

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2706936A (en) * 1948-06-21 1955-04-26 Minnesota Mining & Mfg Anti-skid surface covering
GB1231005A (de) * 1968-01-12 1971-05-05
DE2735669A1 (de) * 1977-07-13 1979-02-22 Ruediger Lothar Von Di Reppert Verfahren zur herstellung beschichteter tennissaiten
US4239797A (en) * 1978-09-29 1980-12-16 Gaf Corporation Non-skid floor tile
FR2439084A1 (fr) * 1978-10-18 1980-05-16 Eram Ind Materiau en feuille pour la realisation de sols pour la pratique des sports et procede de fabrication d'un tel materiau

Also Published As

Publication number Publication date
FR2528356B1 (de) 1985-03-22
DE3366560D1 (en) 1986-11-06
US4608287A (en) 1986-08-26
EP0100690B1 (de) 1986-10-01
FR2528356A1 (fr) 1983-12-16
ATE22581T1 (de) 1986-10-15

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