EP0099281B1 - Process for the combustion in a fluidized bed of low grade fuels, especially coal or oil shales - Google Patents

Process for the combustion in a fluidized bed of low grade fuels, especially coal or oil shales Download PDF

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Publication number
EP0099281B1
EP0099281B1 EP83401189A EP83401189A EP0099281B1 EP 0099281 B1 EP0099281 B1 EP 0099281B1 EP 83401189 A EP83401189 A EP 83401189A EP 83401189 A EP83401189 A EP 83401189A EP 0099281 B1 EP0099281 B1 EP 0099281B1
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Prior art keywords
fluidized bed
grate
zone
fluidization
fuel
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EP83401189A
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German (de)
French (fr)
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EP0099281A1 (en
Inventor
Jean-Louis Bouju
Pascal Georges
Guy Lamusse
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Fives Cail Babcock SA
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Fives Cail Babcock SA
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Priority to AT83401189T priority Critical patent/ATE15535T1/en
Publication of EP0099281A1 publication Critical patent/EP0099281A1/en
Application granted granted Critical
Publication of EP0099281B1 publication Critical patent/EP0099281B1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/002Fluidised bed combustion apparatus for pulverulent solid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
    • F23C10/20Inlets for fluidisation air, e.g. grids; Bottoms
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
    • F23C10/24Devices for removal of material from the bed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23HGRATES; CLEANING OR RAKING GRATES
    • F23H11/00Travelling-grates
    • F23H11/12Travelling-grates inclined travelling grates; Stepped travelling grates

Abstract

1. Process for the combustion in a fluidized bed of low grade fuels, especially of coal or oil shales, on a travelling grate (5) inclined upwards from the front to the rear, with blowing compartments (9a, 9b, 9c, 9d, 9e) of air any other oxidant gas arranged below the grate (5) which is fed at fore with fuel, the front area of the said grate constituting a fluidisation zone (F) and the rear part of the said grate forming at a higher level than that of the fluidized bed (12) a transport section (T) of the ashes in form of a permanent layer, characterized in that : - starting from a fixed point (15), behind the fluidization zone (F), one maintains an insufficient blowing to generate the fluidization, so that between the fluidization zone (F) and the transport section (T) an intermediate settling zone (S) takes form, where ashes deposit along a bank (14), the said bank extending through the whole length of the settling zone (S), being renewed by successive parallel sections in proportion to the displacement of the grate (S), and - the flow rate of the blowing air is distributed in the blowing compartments (9a, 9b, 9c, 9d, 9e) in such a way as to create a methodical outflow of the fuel from to the rear of the fluidized bed (12), allowing the ashes to be brought in the settling zones (S) with a view to extract them.

Description

La présente invention concerne la combustion en lit fluidisé de combustibles pauvres, notamment de schistes houillers ou bitumineux.The present invention relates to the combustion in a fluidized bed of lean fuels, in particular coal or bituminous shales.

La technique de la combustion en lit fluidisé est connue depuis longtemps. On utilise avantageusement à cet effet une installation constituée par une paroi avant sensiblement verticale, munie d'un dispositif d'alimentation en combustible sous forme de particules, deux parois latérales, une grille mobile inclinée vers le haut de l'avant à l'arrière, ladite grille étant aménagée entre les deux parois latérales, à une certaine distance de celles-ci, et une pluralité de caissons de soufflage d'air ou de tout autre gaz comburant disposés sous la grille. Une installation de ce genre est décrite dans le brevet FR-A-1 092 540. Le brevet FR-A-1 440 039 décrit une installation similaire comprenant en outre, une pluralité de vannes, chacune d'elles étant affectée à un caisson de soufflage particulier.The technique of combustion in a fluidized bed has been known for a long time. An installation is advantageously used for this purpose, consisting of a substantially vertical front wall, provided with a fuel supply device in the form of particles, two side walls, a movable grid inclined upwards from front to rear. , said grid being arranged between the two side walls, at a certain distance from the latter, and a plurality of boxes for blowing air or any other oxidizing gas disposed under the grid. An installation of this kind is described in patent FR-A-1,092,540. Patent FR-A-1,440,039 describes a similar installation further comprising a plurality of valves, each of which being assigned to a box of particular blowing.

Dans les applications courantes de telles installations, on fait appel à des combustibles relativement riches brûlant à une température d'au moins 1200°C. A une telle température, les cendres s'agglomèrent sous forme de mâchefers qui se déposent au fond du lit sur toute la longueur de celui-ci. Ces agglomérats sont extraits par la grille elle-même à travers la surface libre du lit, à l'arrière de la zone de fluidisation. Un soufflage modéré, insuffisant pour provoquer une fluidisation, peut être avantageusement maintenu vers l'arrière de la grille, à un niveau supérieur à celui du lit, pour éviter que les agglomérats transportés par la grille ne viennent se coller sur celle-ci.In current applications of such installations, relatively rich fuels are used which burn at a temperature of at least 1200 ° C. At such a temperature, the ash agglomerates in the form of bottom ash which is deposited at the bottom of the bed over the entire length thereof. These agglomerates are extracted by the grid itself through the free surface of the bed, behind the fluidization zone. A moderate blowing, insufficient to cause fluidization, can advantageously be maintained towards the rear of the grid, at a level higher than that of the bed, to prevent the agglomerates transported by the grid from sticking to it.

On a déjà pensé à étendre le domaine d'application de cette technique à la combustion de combustibles pauvres à forte teneur en cendres.It has already been thought of extending the field of application of this technique to the combustion of poor fuels with a high ash content.

La difficulté réside en ce que la température de combustion s'établit à une valeur souvent inférieure à 1000°C et de toute façon inférieure à la température nécessaire à la formation d'agglomérats. Il devient alors pratiquement impossible d'évacuer les cendres, ou tout au moins leur évacuation entraîne l'évacuation simultanée d'une quantité relativement importante d'imbrûlés. Le rendement thermique de la combustion est très médiocre, ce qui est d'autant plus gênant que la teneur en cendres est élévée.The difficulty is that the combustion temperature is often less than 1000 ° C and in any case less than the temperature necessary for the formation of agglomerates. It then becomes practically impossible to evacuate the ashes, or at least their evacuation results in the simultaneous evacuation of a relatively large quantity of unburnt materials. The thermal efficiency of combustion is very poor, which is all the more annoying the higher the ash content.

L'invention a essentiellement pour but de surmonter cette difficulté.The object of the invention is essentially to overcome this difficulty.

Elle consiste surtout à former entre la zone de fluidisation et la zone de transport, une zone de sédimentation intermédiaire, et à établir une circulation méthodique du combustible de manière à amener dans ladite zone de sédimentation la quasi totalité des cendres qui s'y déposent après que le combustible ait séjourné dans le lit fluidisé le temps minimal nécessaire à sa combustion complète.It consists above all in forming between the fluidization zone and the transport zone, an intermediate sedimentation zone, and in establishing a methodical circulation of the fuel so as to bring into said sedimentation zone almost all of the ash which is deposited there after the fuel has remained in the fluidized bed for the minimum time necessary for its complete combustion.

L'invention a plus précisément pour objet un procédé de combustion en lit fluidisé de combustibles pauvres, notamment de schistes houillers ou bitumineux, sur une grille inclinée vers le haut de l'avant à l'arrière, des caissons de soufflage d'air ou de tout autre gaz comburant étant aménagés au-dessous de la grille qui est alimentée par l'avant en combustible, la partie avant de ladite grille constituant une zone de fluidisation, et la partie arrière de ladite grille constituant, à un niveau supérieur à celui du lit fluidisé, une zone de transport des cendres sous forme de couche fixe, caractérisé en ce que:

  • - l'on maintient à partir d'un point fixe, à l'arrière de la zone de fluidisation, un soufflage insuffisant pour provoquer une fluidisation, de sorte qu'il se forme entre la zone de fluidisation et la zone de transport, une zone intermédiaire de sédimentation dans laquelle les cendres se déposent suivant un talus, ledit talus qui s'étend sur toute la longueur de la zone de sédimentation, se renouvelant par tranches parallèles successives au fur et à mesure du déplacement de la grille, et
  • - l'on répartit le débit d'air de soufflage dans les caissons de manière à créer un écoulement méthodique du combustible de l'avant vers l'arrière du lit fluidisé, permettant ainsi l'amenée des cendres dans la zone de sédimentation en vue de leur extraction.
A more specific subject of the invention is a method of combustion in a fluidized bed of poor fuels, in particular coal shale or bituminous, on a grid inclined upwards from front to rear, air-blowing boxes or any other oxidizing gas being arranged below the grid which is supplied with fuel from the front, the front part of said grid constituting a fluidization zone, and the rear part of said grid constituting, at a level higher than that fluidized bed, an ash transport zone in the form of a fixed layer, characterized in that:
  • - Maintaining from a fixed point, behind the fluidization zone, an insufficient blowing to cause fluidization, so that it forms between the fluidization zone and the transport zone, a intermediate sedimentation zone in which the ashes are deposited along an embankment, said embankment which extends over the entire length of the sedimentation zone, being renewed by successive parallel sections as the grate moves, and
  • - the blowing air flow is distributed in the boxes so as to create a methodical flow of fuel from the front to the rear of the fluidized bed, thus allowing the ashes to be brought into the sedimentation zone in view of their extraction.

L'on règle le niveau et l'étendue du lit fluidisé par modification de la position dudit point fixe.The level and the extent of the fluidized bed are adjusted by modifying the position of said fixed point.

On règle la vitesse de la grille, pour un débit de combustible et une teneur en cendres donnés, afin d'obtenir un temps minimal de séjour du combustible dans le lit fluidisé pour une combustion complète, et une épaisseur le couche fixe de cendres prédéterminée.The speed of the grate is adjusted, for a given fuel flow rate and a given ash content, in order to obtain a minimum residence time of the fuel in the fluidized bed for complete combustion, and a predetermined thickness of the fixed layer of ash.

On règle le niveau et l'étendue du lit fluidisé en modifiant le nombre de caissons mis en service avec un débit suiffisant pour provoquer une fluidisation, d'une part, et la répartition du débit d'air entre les dits caissons, d'autre part.The level and the extent of the fluidized bed are adjusted by modifying the number of boxes put into service with a sufficient flow rate to cause fluidization, on the one hand, and the distribution of the air flow rate between said boxes, on the other hand go.

L'invention sera mieux comprise en se référant à la description qui suit, faite en regard des dessins annexés, concernant une forme de réalisation d'une installation pour la mise en oeuvre du procédé selon l'invention, donnée à titre d'exemple non limitatif.The invention will be better understood by referring to the description which follows, given with reference to the appended drawings, concerning an embodiment of an installation for implementing the method according to the invention, given by way of example not limiting.

La figure 1 représente schématiquement en coupe longitudinale une telle installation.Figure 1 shows schematically in longitudinal section such an installation.

La figure 2 est une vue en coupe transversale de cette installation.Figure 2 is a cross-sectional view of this installation.

Sur les figures, le repère 1 désigne la paroi avant 1 de l'installation et les repères 2 et 3 ses parois latérales. La paroi 1 est munie d'une tubulure 4 d'alimentation en combustible sous forme de particules en provenance d'un dispositif de concassage non représenté.In the figures, the reference 1 designates the front wall 1 of the installation and the references 2 and 3 its side walls. The wall 1 is provided with a pipe 4 for supplying fuel in the form of particles from a not shown crushing device.

Une grille 5 inclinée vers le haut de l'avant vers l'arrière est aménagée entre les parois 2 et 3 à une certaine distance de celles-ci. Cette grille avantageusement constituée par le brin supérieur d'une chaîne sans fin, reçoit le combustible sortant de la tubulure 4.A grid 5 inclined upwards from front to rear is arranged between the walls 2 and 3 at a certain distance from them. This grid advantageously constituted by the upper strand of a endless chain, receives the fuel leaving the pipe 4.

Le repère 6 désigne le talus de combustible formé contre la paroi 1, tandis que les repères 7 et 8 désignent les talus formés contre les parois latérales 2 et 3.The reference 6 designates the fuel slope formed against the wall 1, while the references 7 and 8 designate the slope formed against the side walls 2 and 3.

Au-dessous de la grille 5 sont déposés des caissons de soufflage d'air ou de tout autre gaz comburant. Ces caissons, au nombre de cinq dans l'exemple représenté, sont respectivement repérés 9a, 9b, 9c, 9d et 9e de l'avant vers l'arrière de la grille entre les tambours 10 et 11 de celle-ci.Below the grid 5 are deposited boxes for blowing air or any other oxidizing gas. These boxes, five in number in the example shown, are respectively marked 9a, 9b, 9c, 9d and 9e from the front to the rear of the grid between the drums 10 and 11 thereof.

Seuls les caissons 9a, 9b et 9c délivrent un débit d'air suffisant pour provoquer une fluidisation du combustible dans le lit 12 qui se forme au-dessus desdits caissons. Les caissons 9d et 9e délivrent une quantité d'air insuffisante pour provoquer une fluidisation. La zone située au-dessus du caisson 9d constitue une zone de sédimentation des cendres dont il sera parlé plus explicitement ci-après, tandis que la zone située au-dessus du caisson 9e constitue, de façon connue en soi, une zone de transport des cendres et de décolmatage de la grille 5.Only the boxes 9a, 9b and 9c deliver an air flow sufficient to cause fluidization of the fuel in the bed 12 which forms above said boxes. The boxes 9d and 9e deliver an amount of air insufficient to cause fluidization. The area above the casing 9d constitutes an ash sedimentation area which will be discussed more explicitly below, while the area above the casing 9e constitutes, in a manner known per se, an area for transporting ash and unclog grid 5.

Chaque caisson est associé à une vanne de réglage du débit d'air en provenance d'un ventilateur, non représenté, ces vannes sont respectivement repérées 13a, 13b, 13c, 13d, 13e. Ces vannes permettent de répartir le débit d'air total de telle sorte que ce débit diminue progressivement de l'avant vers l'arrière, ce qui provoque à l'intérieur du lit 12, un écoulement méthodique du combustible. On entend par écoulement méthodique, un écoulement de l'avant vers l'arrière à une vitesse telle que le temps de séjour du combustible dans le lit 12 soit égal au minimum nécessaire pour assurer sa combustion complète, tandis que les seules cendres sont amenées à l'extrémité arrière du lit 12 où elles passent de la zone de fluidisation F à la zone de sédimentation S. Dans cette dernière zone les cendres se déposent suivant un talus 14 dont la hauteur est égale à celle de la couche fixe extraite du lit par le déplacement de la grille 5 vers la zone de transport T. Le talus 14 s'étend sur toute la longueur de la zone de sédimentation S et il se renouvelle par tranches successives au fur et à mesure de l'avence- ment de la grille.Each box is associated with a valve for adjusting the air flow rate coming from a fan, not shown, these valves are respectively marked 13a, 13b, 13c, 13d, 13e. These valves make it possible to distribute the total air flow so that this flow decreases progressively from front to rear, which causes inside the bed 12, a methodical flow of fuel. The term “methodical flow” is understood to mean a flow from the front to the rear at a speed such that the residence time of the fuel in the bed 12 is equal to the minimum necessary to ensure its complete combustion, while the only ashes are brought to the rear end of the bed 12 where they pass from the fluidization zone F to the sedimentation zone S. In this latter zone the ashes are deposited along a slope 14 whose height is equal to that of the fixed layer extracted from the bed by the displacement of the grid 5 towards the transport zone T. The embankment 14 extends over the entire length of the sedimentation zone S and it is renewed in successive sections as the grid advances .

On voit que la zone de sédimentation S s'étend sur toute la longueur du caisson 9d, à partir d'un point fixe 15 matérialisé par la trace sur le plan de la figure de l'extrémité supérieure de la face avant du caisson 9d. On peut modifier la position de ce point vers l'avant en réglant la vanne 13c de telle sorte que le caisson 9c ne délivre plus un débit suffisant pour assurer une fluidisation. La zone de sédimentation S se déplace et ne recouvre plus que le caisson 9c, la zone de transport T recouvrant les caissons 9d et 9e. On peut, bien entendu, déplacer ce point vers l'arrière en admettant au contraire dans le caisson 9d un débit suffisant pour provoquer une fluidisation. La zone de sédimentation S se déplace et recouvre le seul caisson 9e, tandis que la zone de transport T, très courte est démunie de caissons. Le niveau N et l'étendue de la zone de fluidisation F sont donc réglés par modification de la position du point 15 au moyen des vannes 13a, 13b, 13c, 3d et 13e.It can be seen that the sedimentation zone S extends over the entire length of the box 9d, from a fixed point 15 materialized by the trace on the plane of the figure of the upper end of the front face of the box 9d. We can change the position of this point forward by adjusting the valve 13c so that the box 9c no longer delivers sufficient flow to ensure fluidization. The sedimentation zone S moves and no longer covers only the caisson 9c, the transport zone T covering the caissons 9d and 9e. One can, of course, move this point backwards by admitting on the contrary in the box 9d a flow sufficient to cause fluidization. The sedimentation zone S moves and covers the only box 9e, while the very short transport zone T is devoid of boxes. The level N and the extent of the fluidization zone F are therefore adjusted by modifying the position of point 15 by means of the valves 13a, 13b, 13c, 3d and 13e.

On peut régler, d'autre part, la vitesse de la grille pour un débit de combustible et une teneur en cendres de celui-ci donnés, afin d'agir corrélativement sur le temps minimal de séjour du combustible dans le lit 12 pour une combustion complète, ainsi que pour obtenir une couche fixe d'épaisseur optimale dans la zone de transport T.On the other hand, the speed of the grate can be adjusted for a given fuel flow rate and an ash content thereof, in order to act correlatively on the minimum stay time of the fuel in the bed 12 for combustion. complete, as well as to obtain a fixed layer of optimum thickness in the transport zone T.

On donnera, ci-après, à titre d'exemple, les caractéristiques d'une installation pilote réalisée par la demanderesse et les résultats d'essais obtenus:

Figure imgb0001
The following will give, by way of example, the characteristics of a pilot installation carried out by the applicant and the test results obtained:
Figure imgb0001

Le nombre de caissons pourra différer de cinq. Il est même avantageux, pour assurer un réglage plus fin de la position du point 15 de prévoir, pour une longueur de grille donnée, un nombre plus important de caissons de plus faible longueur. On peut également envisager, au lieu d'agir sur le nombre des caissons, de prévoir à l'intérieur de chacun d'eux un dispositif de cloisonnement réglable.The number of boxes may differ from five. It is even advantageous, to ensure a finer adjustment of the position of point 15, to provide, for a given grid length, a greater number of boxes of shorter length. One can also consider, instead of acting on the number of boxes, to provide inside each of them an adjustable partitioning device.

On peut également pour réalisier un programme donné, prévoir une télécommande des vannes 13a, 13b, 13c, 13d, 13e réglables en fonction des différents paramètres (teneur en cendres, vitesse de la grille, hauteur de la couche, répartition du débit d'air et de combustible). Ces différents paramètres peuvent être enregistrés sur le tableau d'un pupitre de commande.It is also possible to carry out a given program, by providing a remote control of the valves 13a, 13b, 13c, 13d, 13e adjustable according to the various parameters (ash content, speed of the grate, height of the layer, distribution of the air flow and fuel). These different parameters can be recorded on the panel of a control panel.

Claims (4)

1. Process for the combustion in a fluidized bed of low grade fuels, especially of coal or oil shales, on a travelling grate (5) inclined upwards from the front to the rear, with blowing compartments (9a, 9b, 9c, 9d, 9e) of air or any other oxidant gas arranged below the grate (5) which is fed at fore with fuel, the front area of the said grate constituting a fluidisation zone (F) and the rear part of the said grate forming at a higher level than that of the fluidized bed (12) a transport section (T) of the ashes in form of a permanet layer, characterized in that:
- starting from a fixed point (15), behind the fluidization zone F), one maintains an insufficient blowing to generate the fluidization, so that between the fluidization zone (F) and the transport section (T) an intermediate settling zone (S) takes form, where ashes deposit along a bank (14), the said bank extending through the whole length of the settling zone (S), being renewed by successive parallel sections in proportion to the displacement of the grate (S), and
- the flow rate of the blowing air is distributed in the blowing compartments (9a, 9b, 9c, 9d, 9e) in such a way as to create a methodical outflow of the fuel from the front to the rear of the fluidized bed (12), allowing the ashes to be brought in the settling zone (S) with a view to extract them.
2. Process according to claim 1, characterized in that the level (N) and the extent of the fluidized bed (12) are adjusted by changing the position of the said fixed point.
3. Process according to claims 1 or 2, characterized in that the speed of the grate (5) is adjusted for a given output of the fuel and its given ash content, in order to obtain the minimal residing time of the fuel in the fluidized bed (12) for complete combustion and a predetermined thickness of the permanent layer of ashes.
4. Process according to claim 2, characterized in that the level (N) and the extent of the fluidized bed (12) are adjusted by changing the number of compartments (9a, 9b, 9c, 9d, 9e) set into operation with a sufficient flow rate as to generate the fluidization, on one hand, and the distribution of the air flor rate between the said compartments on the other hand.
EP83401189A 1982-06-15 1983-06-10 Process for the combustion in a fluidized bed of low grade fuels, especially coal or oil shales Expired EP0099281B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83401189T ATE15535T1 (en) 1982-06-15 1983-06-10 METHOD OF COMBUSTIONING LOW-QUALITY FUELS IN THE FLUIDIZED BED, ESPECIALLY BURNING SLATE OR BITUMINOUS SLATE.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8210385A FR2528543A1 (en) 1982-06-15 1982-06-15 METHOD OF COMBUSTION OF FLUIDIZED BED OF POOR FUELS, ESPECIALLY HOT OR BITUMINOUS SCHISTES, AND INSTALLATION FOR CARRYING OUT SAID METHOD
FR8210385 1982-06-15

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EP0099281A1 EP0099281A1 (en) 1984-01-25
EP0099281B1 true EP0099281B1 (en) 1985-09-11

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AT (1) ATE15535T1 (en)
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FR (1) FR2528543A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2553496B1 (en) * 1983-10-13 1988-02-26 Fives Cail Babcock FLUIDIZED BED COMBUSTION DEVICE FOR POOR FUELS, ESPECIALLY COAL OR BITUMINOUS SHELLS
FR2578629B1 (en) * 1985-03-11 1987-04-30 Fives Cail Babcock FLUIDIZED BED COMBUSTION OR GASIFYING DEVICE COMPRISING AN ENDLESS CHAIN FOR ASH REMOVAL
CN104848212B (en) * 2015-05-27 2017-04-05 山西大学 The method that a kind of solid sulphur controlled temperature combustion of gangue is utilized with lime-ash efficient coupling

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Publication number Priority date Publication date Assignee Title
FR1092540A (en) * 1953-10-29 1955-04-22 Cie Ind De Procedes Et D Appli Improvements in processes for carrying out chemical reactions in the fluidized phase and device for their implementation
FR1440039A (en) * 1965-04-13 1966-05-27 Cie Ind De Procedes Et D Appli Mechanical hanging chain grate for fluidized bed combustion
US3625164A (en) * 1971-04-21 1971-12-07 Air Prod & Chem Combustion of high-sulfur coal in a fluidized bed reactor
US3776150A (en) * 1972-03-06 1973-12-04 Awt Systems Inc Fluidized bed system for solid wastes
FR2261051B1 (en) * 1974-02-14 1980-08-08 Activit Sa

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DE3360786D1 (en) 1985-10-17
EP0099281A1 (en) 1984-01-25
FR2528543A1 (en) 1983-12-16
ATE15535T1 (en) 1985-09-15
FR2528543B1 (en) 1985-03-15

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