EP0053461A1 - Extrudierungs-Beschichtungsverfahren - Google Patents

Extrudierungs-Beschichtungsverfahren Download PDF

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Publication number
EP0053461A1
EP0053461A1 EP81305488A EP81305488A EP0053461A1 EP 0053461 A1 EP0053461 A1 EP 0053461A1 EP 81305488 A EP81305488 A EP 81305488A EP 81305488 A EP81305488 A EP 81305488A EP 0053461 A1 EP0053461 A1 EP 0053461A1
Authority
EP
European Patent Office
Prior art keywords
substrate
die
extrusion
orifice
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP81305488A
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English (en)
French (fr)
Inventor
Ralf Korpman
Felice Charles Palermo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Permacel
Original Assignee
Permacel
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Filing date
Publication date
Application filed by Permacel filed Critical Permacel
Publication of EP0053461A1 publication Critical patent/EP0053461A1/de
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • B05C11/1042—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material provided with means for heating or cooling the liquid or other fluent material in the supplying means upstream of the applying apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
    • B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
    • B05C5/0254—Coating heads with slot-shaped outlet

Definitions

  • Extrusion coating of viscous materials mainly materials having viscosities in the range of from about 100,000 to 800,000 centipoises at 350°F such as tacky industrial grade pressure-sensitive adhesive compositions, certain hot melt adhesive compositions and certain intermediate temperature melting thermoplastic film forming compositions, are usually carried out by operations in which the extrudate issues from a die positioned laterally above the bite or nip formed between a highly polished metal chill roll (sometimes called coating roll) bearing the substrate and a rubber or pressure roll, and falls into the nip to be air drawn to the desired film thickness and then laminated onto the substrate.
  • a highly polished metal chill roll sometimes called coating roll
  • the die has been positioned above the metal chill roll or the pressure roll but nevertheless at a location sufficiently above the roll so that the film curtain is drawn to reduce its thickness while unattached to the substrate.
  • the extruded film curtain is widest as it leaves the die and narrows during its free fall to the substrate.
  • This phenomenon called draw-down or neck-in is dependent on the composition type, melt temperature and distance of the die above the substrate.
  • the neck-in is accompanied by a thickening of the outside edges of the falling curtain.
  • This thickened edge called an edge bead can be from three to six times thicker than the coating thickness.
  • the edge bead must be removed from the coated or laminated substrate in order to eliminate handling problems.
  • a smooth, uniform coating can be obtained from a viscous composition by extruding a hot molten composition onto a substrate through a die positioned directly over a polished metal chill roll or coating roll of an extrusion coating line at a distance which provides a separation between the die lip or die orifice and substrate of no greater than about 50 mils and wherein the substrate is drawn to the die orifice from a direction such that the angle formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion of the composition or extrudate through the orifice is less than 90°, and wherein the substrate is drawn away from the die orifice in a direction such that the angle formed between the direction of extrusion and a line representing the initial departing direction of the coated substrate immediately on formation is no greater than 90°.
  • the coated product obtained according to the process of the present invention is of superior quality, having no beading effect at the outer edges. Moreover, it has been found that with some substrates coating may be carried out without the use of pressure rolls and still result in a product in which there is good anchorage of the ccating to the substrate. This is especially beneficial when the substrate has low tensile strength so that it may become subject to being torn by the pressure roll.
  • the process is also advantageously employed for extrusion coating onto substrates of thermoplastic materials of moderate softening temperatures which are not necessarily of the high viscosity of the adhesive compositions but have properties hereinafter described.
  • coating composition is employed without qualification it is intended to embrace both the viscous adhesive compositions and nonadhesive thermoplastic coating polymers of moderate softening temperatures.
  • viscous materials may be extruded in the absence of solvent through a die of conventional opening size, e.g., 20 to 50 mils and coated uniformly onto a substrate at a coating thickness as low as about 0.75 mil, generally 0.75 to 6 mils, without the problem of neck-in and/or other nonuniformity encountered when highly viscous material is coated employing conventional procedures of extruding and drawing.
  • the component or components of the coating composition are fed into an extruder in a conventional manner, the component or components then are advanced forward in the extruder barrel heated at temperatures in the 'range of 325°F to 450°F to produce a molten homogeneous composition, and the composition then passed through an elongated extrusion die directly onto a substrate as it moves on a coating roll past the orifice of said die.
  • Coating roll as herein employed is meant the highly polished metal chill or chrome roll which is normally employed together with a rubber or silicone rubber pressure roll for extrusion laminating).
  • the orifice of the die is positioned over the coating roll in such a manner that the distance between the substrate and the die orifice will not be greater than about 50 mils.
  • the substrate is caused to be drawn to the die orifice from a direction such that the angle formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion of the composition through the orifice is less than 90°.
  • the coated substrate must be drawn away from the die orifice in a direction such that the angle forced between a line representing the direction of extrusion and a line representing the initial exiting or departing direction of the coated substrate immediately on formation is no greater than 90°.
  • extrudate 12 is seen issuing from die 21 through die orifice 22 onto substrate 11 passing beneath the die orifice on a coating roll 31 at a distance no greater than about 50 mils.
  • the coating roll generally is cooled and may be of rubber coated metal as well as uncoated metal.
  • the extrudate 12 contacts and coats the moving substrate 11 at X directly beneath the die orifice to form a coated substrate 13.
  • the angular direction of approach of the substrate to the direction of the extrusion as well as the initial angular direction of departure of the newly formed coated substrate to the direction of extrusion is extremely important.
  • the angle alpha (a) formed between a line B representing the direction of the incoming substrate and line A representing the direction of extrusion through the center of the die orifice must be less than 90°.
  • the direction of approach of the incoming substrate is controlled by feed guide roll 33.
  • the angle beta (s) formed between line A along the direction of extrusion and line C in the departing direction of the substrate at the moment after contact by the extrudate, namely, the initial momentary exiting direction of the coated substrate is also critical.
  • This angle 6 should be 90° or less.
  • Figure 3 shows a modification in which the die 21 is positioned off top dead center (12 o'clock) of the coating roll in the upstream direction and directed downward and not to center of the roll.
  • Figure 4 shows a modification in which the position of die 21 with respect to the circumference of the chrome roll is substantially the same as in Figure 3 but in which the direction of the die orifice or line A is toward the center Y of the roll.
  • Figure 5 shows a modification in which die 21 is positioned off top dead center in the downstream direction of the coating roll. When the die is positioned downstream and is directed downward instead of toward the center, it is necessary to provide guide roll 38 to assure angle 6. to be 90° or less.
  • the distance of the substrate from the die orifice is also important.
  • the distance should not be greater than about 50 mils.
  • the distance of 50 mils is approximately the maximum distance permissible for the extrudate issuing from the die orifice to traverse.
  • the extrudate still is under high pressure and retains its direction of motion until it comes in contact with a substrate at which time it changes its direction to that of the substrate.
  • the initial change in direction and the angle (s) formed thereby is essential and critical to good anchorage of the extrudate to the substrate.
  • the distance may coincide with the distance between the die lip and the circumference of the coating roll.
  • the distance between the die lip and substrate may be slightly different from the distance between the die lip and circumference of the coating roll if the die is positioned off top dead center.
  • the distance between the die orifice and the coating roll surface may be somewhat greater than 50 mils and still achieve a maximum distance between the substrate and die orifice of no greater than 50 mils.
  • the thickness of the coating depends on the throughput rate of extruder width of substrate and the speed of the moving substrate.
  • the die has an orifice of 20 to 50 mils at ambient temperature. It is to be understood that under conditions of extrusion, which are generally in the temperature range of about 325°-450°F, there is expansion of the metal and the die orifice is slightly larger than the cold dimensions.
  • the extrusion assembly may be operated at a linear speed of about 50 feet to about 1000 feet per minute. The actual linear speed will vary depending on the diameter of the extruder barrel which determines throughput rate, the slot width of the die which determines substrate width, and the coating thickness desired.
  • Extruder barrels are commonly available in various diameter sizes, e.g., 3-1/2 inch with throughput rate of 600 pounds per hour, and 4-1/2 inch, 6 inch, 8 inch, etc., with higher throughput rates.
  • One typical commercial slot width is 60 inches.
  • coating thicknesses are 0.5 to 1.5 mils for film substrate, 1 to 2 mils for paper substrate, 2 to 3 mils for reinforced film substrate, and 3 to 4 mils for cloth substrate.
  • the linear speed on a 3-1/2 inch extruder may be 298 feet per minute and on a 4-1/2 inch extruder, 596 feet per minute.
  • the viscous materials to which the process of the present invention is primarily directed are adhesive compositions and certain thermoplastic materials and compositions having moderate softening temperatures, i.e. in the range of about 325°F to about 450°F.
  • Industrial grade high performance pressure-sensitive adhesive coated sheets and tapes are particularly suited to be advantageously manufactured by the process of the present invention.
  • extrudable high performance industrial pressure-sensitive adhesives contemplated to be employed are generally a mixture comprising an elastomer component and a tackifier resin component, such compositions having viscosities in the range of from about 100,000 to about 800,000 centipoises at 350°F.
  • the elastomer in such adhesive compositions is characterized by having thermoplastic properties.
  • the elastomer component which may be a mixture of elastomers necessarily contain materials known in the art as thermoplastic elastomers or thermoplastic rubbers. These rubbers generally begin to soften at about 200°F (93°C) and have a softening temperature maximum of about 450°F (232°C).
  • the most useful and best known of these thermoplastic elastomers are block copolymers which may be those referred to as A-B-A block copolymer or as A-B block copolymer in which A designates a thermoplastic block and B designates an elastomeric block.
  • the terminal or end polymer blocks are the thermoplastic blocks and the middle or internal blocks are the rubbery blocks.
  • the B block forms one of the end blocks rather than a mid- block.
  • the thermoplastic A block is a polymer of alkenyl- arene, preferably styrene or styrene homolog or analog.
  • the B block is a polymer of an unsaturated aliphatic hydrocarbon of 4 to 6 carbon atoms, preferably of a conjugated aliphatic diene and most frequently a polymer of butadiene or isoprene.
  • B also may be a polymer of a lower alkene such as ethylene or butylene.
  • the A-B-A block copolymers may be any variation of linear, branched, or radial copolymers with rubbery mid-blocks and thermoplastic end-blocks, including those sometimes designated as A-B-C block copolymers in which C is a thermoplastic end-block but of a different polymer than A.
  • the radial or teleblock copolymers are sometimes designated (A-B+ n X wherein X is an organic or inorganic whole functional atom or molecule, n is an integer corresponding to the value of the functional group originally present in X , and in which (A-B+ radiates from X in a way that A is an end block.
  • the A-B-A block copolymers employed as the elastomer component generally are those in which the individual A block has a number average molecular weight of at least 6000, usually from about 8000 to 30,000 and constitute from about 5 to 50 percent, usually about 10 to 30 percent by weight of the A-B-A block copolymer.
  • the B block portion has a number average molecular weight in the range of from about 45,000 to about 180,000.
  • the number average molecular weight of the entire block copolymer may be in the range of about 75,000 to 200,000 when linear or branched, and about 125,000 to 400,000 when radial.
  • the linear and branched copolymers are in the range of 100,000 to 150,000 and the radial in the range of 150,000 to 250,000.
  • the number average molecular weight of the A block is generally from about 7000 to about 20,000 and the total molecular weight usually does not exceed about 150,000.
  • thermoplastic elastomeric block copolymers are prepared by stepwise solution polymerization of the components. They are also available commercially. The preparations and properties of block copolymers are amply described in the literature such as, for example, "Thermoplastic Rubber (A-B-A Block Copolymers) in Adhesives” by J.T. Harlan, et al.,. in "Handbook of Adhesives” edited by Irving Skeist, Van Nostrand Reinhold Co., New York, Second Edition (1977), pages 304-330; "Rubber-Related Polymers, I. Thermoplastic Elastomers” by W.R.
  • thermoplastic elastomer when it is a block copolymer, it may be an A-B-A or an A-B block copolymer or a mixture of the two types.
  • the elastomers When the A block is polystyrene and B block is polyisoprene, the elastomers are referred to as an S-I-S block copolymer or S-I block copolymer.
  • the elastomers are known as S-B-S or S-B block copolymer.
  • the component may be modified by the addition of from 0 to 25 percent by weight based on the weight of the thermoplastic elastomer, of a more conventional diene elastomer such as natural rubber, polymers based on butadiene or isoprene, butadiene-styrene (SBR) rubber, butadiene- acrylonitrile ( NBR ) rubber, butyl rubber and the like, provided they are in a low plasticity state, e.g., less than about 40 Mooney units.
  • a more conventional diene elastomer such as natural rubber, polymers based on butadiene or isoprene, butadiene-styrene (SBR) rubber, butadiene- acrylonitrile ( NBR ) rubber, butyl rubber and the like, provided they are in a low plasticity state, e.g., less than about 40 Mooney units.
  • the elastomer component may be an ethylene vinyl acetate copolymer (EVA) copolymer.
  • EVA ethylene vinyl acetate copolymer
  • These are generally random copolymers containing from about 28 to 60 percent vinyl acetate by weight. These may be used singly, as mixtures of ethylene vinyl acetate polymers or as mixture with a A-B-A or A-B block copolymers.
  • the tackifying resin for the tackifier component may be a natural or synthetic polymer, preferably solid having a softening point in the range of about 85°C to about 150°C and includes rosin, hydrogenated rosin, dehydrogenated rosin, rosin esters such as erythritol and glycerol esters, polymerized alpha or beta pinene, polymerized mixture of piperylene and isoprene, and the like.
  • Other materials are described in the chapter entitled "Pressure-Sensitive Tapes and Labels" by C.W. Bemmel in "Handbook of Adhesives” edited by Irving Skeist, Van Nostrand Reinhold Co., (1977) pages 724-735.
  • the adhesive compositions may include other conventional additives such as antioxidants, heat stabilizers, ultraviolet absorbers, pigments, inorganic fillers, parting agents and the like.
  • compositions which may be advantageously employed in the process of the present invention include compositions which are described in U.S. Patents 3,783,072 and 3,984,509.
  • Coating materials which may beneficially employ the process of the present invention include certain copolyesters, certain modified ethylene polymers and other thermoplastic materials which have a torque value not to exceed 600 meter grams when measured by working at 220°C at 75 r.p.m. in a recording torque dynamometer (Plasti-Corder@ EPL-V750 manufactured by C.W. Brabender Co., Hackensack, N.J.).
  • Copolyesters are copolymers of: and wherein X and X' are nuclei of aromatic or aliphatic dicarboxylic acids and Y and Y' are nuclei of alkylene . diols. Those copolyesters which are of high viscosity and moderate softening temperature in the range hereinbefore indicated are adaptable to being employed in the present process.
  • coating materials which may be usefully employed include low melting modified polyethylene and ethylene vinyl acetate having a vinyl acetate content of 20 percent or higher.
  • the invention is a useful coating process employing materials whether adhesive or not which are highly viscous, e.g., having a viscosity higher than 100,000 centipoises and not previously considered suitable for extrusion coating provided they have moderate softening temperatures, e.g., not above about 450°F (232°C). Coating and/or adhesive materials of low viscosity also may be employed in the process of the present invention although for these materials, other methods not adaptable to highly viscous compositions are available for achieving uniform coating.
  • Pressure-sensitive adhesive coated substrates are prepared by feeding the component materials indicated in Table A (in parts by weight) into an extruder, mixing and melting at temperatures in the range of from about 350° to 425°F, and extruding through a die orifice of 20 mils onto various suostrates.
  • Suitable substrates are paper, polyvinyl chloride, cloth, polyester and aluminum foil.
  • the coated substrates have adhesive film thickness of less than 5 mils and are uniform throughout with substantially no beading effect.
  • the coated substrates are slitted to form pressure-sensitive adhesives tapes of good adhesion and h:ld.
  • poly(ethylene terephthlate-co- ethylene azelate) of apparent molecular weight of about 20,000 V PE 5571, Goodyear Tire and Rubber Company
  • modified polyethylene of apparent molecular weight of 8000, viscosity of 8500 centipoises at 150°C, and softening point of about 106°C EPOL E NE wax C-16, Eastman Kodak Company
  • the coated films may be used as substrates for adhesive tapes as well as for waterproof coverings.
  • Patent 3,502,497, Example I) to be slitted in the manufacture of pressure-sensitive tapes are prepared first by feeding into the hopper of an extruder, the following components (in parts by weight): The components then are mixed and melted at barrel temperatures ranging from 160° to 230°C and extruded through a die orifice of about 20 mils onto the paper substrate and the film substrate to obtain adhesive film coated sheets of adhesive film thickness of 1.5 mils for paper substrate, and 0.75 mil for polyester film substrate. All coated sheets obtained are of good uniformity with no beading effect, i.e., substantially no thickening along the edges.
  • an adhesive coated sheet of polyethylene coated cotton cloth is prepared by extruding an adhesive mixture of the following composition (parts by weight).
  • the components are mixed and melted in the temperature range 160° to 230°C and extruded through a 20 mil die orifice to obtain a 3.5 mil adhesive film on a cloth substrate of uniform thickness and substantially free of any beading effect.
  • Example XI a saturated paper substrate described in Example XI is coated with an adhesive mixture of the following composition:
  • the components are mixed, melted and extruded as previously described to obtain a 1.5 mil adhesive coated paper substantially free of any beading effect.
EP81305488A 1980-11-21 1981-11-20 Extrudierungs-Beschichtungsverfahren Ceased EP0053461A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US20916180A 1980-11-21 1980-11-21
US209161 2002-07-31

Publications (1)

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EP0053461A1 true EP0053461A1 (de) 1982-06-09

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EP81305488A Ceased EP0053461A1 (de) 1980-11-21 1981-11-20 Extrudierungs-Beschichtungsverfahren

Country Status (6)

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EP (1) EP0053461A1 (de)
JP (1) JPS57115316A (de)
AU (1) AU7696881A (de)
BR (1) BR8107578A (de)
CA (1) CA1160517A (de)
DK (1) DK517081A (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2575207A1 (fr) * 1984-12-21 1986-06-27 Renault Procede et dispositif pour l'extrusion automatique de mastic ou de colle
FR2697176A1 (fr) * 1992-10-26 1994-04-29 Valmet Paper Machinery Inc Dispositif et procédé d'enduction à jet.
DE19806609A1 (de) * 1998-02-18 1999-08-19 Beiersdorf Ag Verfahren zur kontinuierlichen, lösungsmittel- und mastikationsfreien Herstellung von druckempfindlichen Selbstklebemassen auf Basis von nicht-thermoplastischen Elastomeren sowie deren Beschichtung zur Herstellung von selbstklebenden Artikeln
US7563479B2 (en) * 1996-08-29 2009-07-21 H.B. Fuller Licensing & Financing, Inc Method for producing a continuous thermoplastic coating and articles constructed therefrom

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6884060B2 (en) * 2001-11-02 2005-04-26 R.P. Scherer Technologies, Inc. Apparatus for manufacturing encapsulated products

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1266745A (de) * 1969-06-11 1972-03-15
US3783072A (en) * 1971-11-02 1974-01-01 Johnson & Johnson Extrusion process for pressure-sensitive adhesive sheets and tapes
US4090469A (en) * 1977-03-08 1978-05-23 Inta-Roto, Inc. Breast roller pivoting
FR2377235A1 (fr) * 1977-01-17 1978-08-11 Ibm Dispositif pour application d'un fluide visqueux a un substrat

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2321912C3 (de) * 1972-06-02 1980-10-16 Bolton-Emerson, Inc., Lawrence, Mass. (V.St.A.) Vorrichtung zum Aufbringen einer heißen, schmelzflüssigen, viskosen Beschichtung
JPS5522364A (en) * 1978-08-07 1980-02-18 Wakita Seisakusho:Kk Portable sealant heating extruder

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1266745A (de) * 1969-06-11 1972-03-15
US3783072A (en) * 1971-11-02 1974-01-01 Johnson & Johnson Extrusion process for pressure-sensitive adhesive sheets and tapes
FR2377235A1 (fr) * 1977-01-17 1978-08-11 Ibm Dispositif pour application d'un fluide visqueux a un substrat
US4090469A (en) * 1977-03-08 1978-05-23 Inta-Roto, Inc. Breast roller pivoting

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2575207A1 (fr) * 1984-12-21 1986-06-27 Renault Procede et dispositif pour l'extrusion automatique de mastic ou de colle
EP0188159A2 (de) * 1984-12-21 1986-07-23 Regie Nationale Des Usines Renault Verfahren und Vorrichtung zur automatischen Extrusion von Kitt oder Klebstoff
EP0188159A3 (en) * 1984-12-21 1987-08-19 Renault Process and device for the automatic extrusion of mastic or glue
FR2697176A1 (fr) * 1992-10-26 1994-04-29 Valmet Paper Machinery Inc Dispositif et procédé d'enduction à jet.
US7563479B2 (en) * 1996-08-29 2009-07-21 H.B. Fuller Licensing & Financing, Inc Method for producing a continuous thermoplastic coating and articles constructed therefrom
DE19806609A1 (de) * 1998-02-18 1999-08-19 Beiersdorf Ag Verfahren zur kontinuierlichen, lösungsmittel- und mastikationsfreien Herstellung von druckempfindlichen Selbstklebemassen auf Basis von nicht-thermoplastischen Elastomeren sowie deren Beschichtung zur Herstellung von selbstklebenden Artikeln

Also Published As

Publication number Publication date
BR8107578A (pt) 1982-08-17
JPS57115316A (en) 1982-07-17
CA1160517A (en) 1984-01-17
DK517081A (da) 1982-05-22
AU7696881A (en) 1982-05-27

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