CA1160517A - Extrusion coating process - Google Patents

Abstract

ABSTRACT

The invention is concerned with a direct extrusion process for preparing a coating substrate from a viscous coating composition. The process of the invention comprises feeding the component material or materials of a coating composition into an extruder having a barrel and an elon-gated extrusion die orifice leading away from the barrel and advancing the material or materials forward in the extruder barrel to obtain a molten homogeneous composition, and then through the extrusion die orifice. A substrate is directed into positive engagement with the outlet opening defined by the extrusion die and the homogeneous composition is extruded through the extrusion die orifice onto the substrate to force the substrate away from the die and to form a uniform coating on the substrate. The coated substrate is then moved into immediate contact with a closely disposed coating roll. The substrate is drawn to the die orifice from a direction such that the angle ? formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion is less than 90°, whereas the coated substrate is drawn away from the die orifice in a direction such that the angle ? formed between the direction of extrusion and a line representing the initial departing direction of the coated substrate immediately on formation when combined with the angle ? is less than 180°.
The invention is particularly useful in the manufacture of viscous pressure-sensitive adhesive sheets and tapes.

Description

EXTRUSION COATING PROCESS

This invention is directed to a process for extrusion coating.

BACKGROUND OF THE INVENTION

Extrusion coating of viscous materials, mainly materials having viscosities in the range of from about 100,000 to 800,000 centipoises at 350F such as tacky industrial grade pressure-sensitive adhesive compositions, certain hot melt adhesive compositions and certain intermediate temperature melting thermoplastic film forming composi-tions, are usually carried out by operations in which the extrudate issues from a die positioned laterally above the bite or nip formed between a highly polished metal chill roll (sometimes called coating roll) bearing the substrate and a rubber or pressure roll, and falls into the nip to be air drawn to the desired film thickness and then laminated onto the substrate. Sometimes, the die has been positioned above the metal chill roll or the pressure roll but nevertheless at a location sufficiently above the roll so that the film curtain is drawn to reduce its thickness while unattached to the substrate. The extruded film curtain is widest as it leaves the die and narrows during its free fall to the substrate. This phenomenon called draw-down or neck-in is dependent on the composition type, melt temperature and distance of the die above the substrate. The neck-in is accompanied by a thickening of the outside edges of the falling curtain. This thickened edge called an edge bead can be from three to six times thicker than the coating thickness. The edge bead must be removed from the coated or laminated substrate in order to eliminate handling problems. The removal which is carried out by trimming off the edge beads represents a major economic loss since no economical way has been found to recover and reuse this material. Not on~y the bead material but the substrate also must be eliminated and considered a loss. Although ways have been devised to minimi~e the loss of materials, additional manipulations are necessary and t:otal loss is not avoided.

Additionally, coatings of manufacturing widths (approxi-mately 5 feet) are difficult to obtain and maintain in uniform thickness. Further, with some substrates, good anchorage of the adhesive is difficult to achieve. It is highly desirable to devise a procedure capable of pro-ducing a coated product from a highly viscous coating composition of high quality and uniformity, and with minimum economic waste.

STATEMENT OF THE INVENTION

In accordance with the present invention, there is provided a direct extrusion process for preparing a coating substrate from a viscous coating composition, which com-prises feeding the component material or materials of a coating composition into an extruder having a barrel and an elongated extrusion die orifice leading away from the barrel; and advancing the material or materials forward in the extruder barrel to obtain a molten homogeneous compo-sition, and then through the extrusion die orifice. A
substrate is directed into positive engagement with the outlet opening defined by the extrusion die and the homo-geneous composition is extruded through the extrusion dieorifice onto the substrate to force the substrate away from the die and to form a uniform coating on the substrate. The coated substrate is then moved into immediate contact with a closely disposed coating roll. The substrate is drawn to the die orifice from a direction such that the angle 1 16~517 -2a-formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion is less than 90, whereas the coated substrate is drawn away from the die orifice in a direction such that the angle ~ formed between the direction of extrusion and a line representing -the initial departing direction of the coated substrate immediately on formation when combined with the angle o<
is less than 180.
According to a preferred embodiment, the maximum distance between the die orifice and the coating roll is about 150 mils.

1 16~517 - The coated product obtained according to the process of the present invention is of superior quality, having no beading effect at the outer edges. Moreover, it has been found that with some substrates coating may be carried out without the use of pressure rolls and still result in a product in which there is good anchorage of the coating to the substrate. This is especially beneficial when the substrate has low tensile strength so that it may become subject to being torn by the pressure roll.
In addition, the process is also advantageously employed for extrusion coating onto substrates of thermoplastic materials of moderate softening temperatures which are not necessarily of the high viscosity of the adhesive compo-sitions but have properties hereinafter described. Whenthe expression "coating composition" is employed without qualification it is intended to embrace both the viscous adhesive compositions and nonadhesive thermoplastic coating polymers of moderate softening temperatures.
BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 is a schematic end view of a portion of an extru-sion apparatus for the process of the present invention showing the die, substrate and rolls.

Figure la is a schematic end view similar to Figure 1 but including a pressure roll.

Figure 2 is an enlarged view at the point of encounter of the extrudate with the substrate.

Figure 3 is a view representing a die positioned off top dead center of the metal chill or coating roll in the upstream direction.

l 3 6~517 Figure 4 is a view showing the die at the same position as in Figure 3 but with the die orifice directed to the center of the coating roll.

Figure 5 is a view representing a die positioned off top dead center in the downstream direction.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

In the process of the present invention, viscous materials, materials with viscosity in the order of 100,000 to 800,000 centipoises, may be extruded in the absence of solvent through a die of conventional opening size, e. g., 20 to 50 mils and coated uniformly onto a substrate at a coating thickness as low as about 0.75 mil, generally 0.75 to 6 mils, without the problem of neck-in and/or other nonuniformity encountered when highly viscous material is coated employing conventional procedures of extruding and drawing.
In carrying out the process of the present invention, the component or components of the coating composition, gen-erally in dry particulate form are fed into an extruder in a conventional marmer, the component or components then are advanced forward in the extruder barrel heated at temperatures in the range of 325 F to 450 F to produce a molten homogeneous composition, and the composition then passed through an elongated extrusion die directly onto a substrate as it moves past the orifice of the die.
("Coating roll" as herein employed is meant the highly polished metal chill or chrome roll which is normally employed together with a rubber or silicone rubber pressure roll for extrusion laminating). The orifice of the die is positioned over the coating roll in such a manner that the distance between the die orifice and associated ,~ ., 116~517 substrate and the spaced chill roll will not be greater than about 150 mils. Further, the substrate is caused to be drawn to the die orifice from a direction such that the angle formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion of the composition through the orifice is less than 90. Still further, the coated substrate must be drawn away from the die orifice in a direction such that the angle formed between a line representing the direction of extrusion and a line representing the initial exiting or departiny direction of the coated substrate immediately on formation when combined with the angle formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion of the extrudate through the orifice is less than 180. This results in the substrate being wrapped about and in contact with the die lips in the area of the die orifice opening tsee Fig. 2). The extruded material forces the substrate away from the orifice and results in a uniform coating on the substrate.

The invention may be understood more clearly by reference to the drawings. In both Figures 1 and la, extrudate 12 is seen issuing from die 21 through die orifice 22 onto substrate 11 passing in contact with the die beneath the die orifice. The incoming substrate touches the lip of the die on the incoming side, and the sheet on the out-going side is separated from the lip only by the thickness of the coating. The coated substrate then moves to coating roll 31 spaced at a distance no greater than about 150 mils from the surface of the die. (The coating roll gen-erally is cooled and may be of rubber coated metal as wellas uncoated metal.) The extrudate 12 forces the ~ubstrate away from the die and uniformly coats the moving substrate l 160517 11 at X directly beneath the die orifice to form a coated substrate 13. After leaving the die the coated substrate almost immediately contacts the coating roll. This is important in order to minimize sheet fluttering and sheet sagging which results in the most uniform coat being provided. Possible drooling of the adhesive is minimized with the almost instant contact of the coated substrate with the cold roll which acts to rapidly solidify the extrudate.

In order to achieve the aims of the present invention, namely to provide a highly uniform coating with a substantially total absence of neck-in or edge-bead forma-tion, the angular direction of approach of the substrate to the direction of the extrusion as well as the initial angular direction of departure of the newly formed coated substrate to the direction of extrusion is extremely important. Thus, the angle alpha (~ ) formed between a line B representing the direction of the incoming substrate and line A representing the direction of extrusion through the center of the die orifice must be less than 90. The direction of approach of the incoming substrate is con-trolled by feed guide roll 33. Similarly, the angle beta (~) formed between line A along the direction of extrusion and line C in the departing direction of the substrate at the moment after contact by the extrudate, namely, the initial momentary exiting direction of the coated substrate is also critical. The sum of angle ~ and angle ~
should be less than 180, which insures that the substrate is in positive engagement with the die lips. This positive contacting relationship insures that the required coating thickness is obtained by the preset setting of the tension and speed of the moving substrate combined with the extrusion pressure and the viscosity of the extrudate leaving the die orifice. When the die is positioned so that the die l 16~517 orifice 22 is directed to the center Y of the coating roll 31, the angle formed at X between line A and line C is approximately 90.

This is more clearly seen in Figure 2 wherein substrate 11 fed from feed guide roll 33 moves toward the die 21 along hypothetical line B. Extrudate 12 issues from orifice 22 of die 21 along hypothetical line A contacting substrate 11 at point X no greater than about 150 mils above the circumference of the coater roll 31. Angle ~
is formed between lines A and B at X. The moving direction of the coated substrate 13 at point X is along line C and the angle formed between A and C is ~. In this embodiment, depending on the diameter of the coating roll 31, the angle ~ will be slightly in excess of 90 but the sum of angles and ~ will be less than 180.

Figure 3 shows a modification in which the die 21 is positioned off top dead center (12 o'clock) of the coating roll in the upstream direction and directed downward and not to the center of the roll. Figure 4 shows a modifica-tion in which the position of die 21 with respect to the circumference of the chrome roll is substantially the same as in Figure 3 but in which the direction of the die orifice or line A is toward the center Y of the roll.
Figure S shows a modification in which die 21 is positioned off top dead center in the downstream direction of the coating roll. When the die is positioned downstream and is directed downward instead of toward the center, it is necessary to provide guide roll 38 to assure that the sum of angles ~ and ~ is less than 180. These latter illustra-tions represent some of the modifications which can be made, mainly modifications in the position of the die along the circumference of the coating roll and the direction of the die orifice. These latter modifications may be varied -7a to any position on the circumference provided that angle ~ is always less than 90 and the sum of angles ~ and is less than 180 .

As previously indicated, it is desired that the spacing between the die orifice and the coating roller be no greater than about 150 mils. Thus, after leaving the die the coated substrate almost immediately contacts the chill roll which acts to rapidly solidify the substrate and minimize drooling. This very small spacing between die and coating roll further insures uniform coating by minimizing sheet fluttering and sheet sagging.

In the coated substrate, the thickness of the coating depends on the speed of the moving substrate and the extruder throughput rate. Typically the die has an orifice of 20 to 50 mils at l ~ 6~1 7 - ambient temperature. It is to be understood that under conditions of extrusion, which are generally in the tem-perature range of about 325-450E, there is expansion of the metal and the die orifice is slightly larger than the cold dimensions. The extrusion assembly may be operated at a linear speed of about 50 feet to about 1000 feet per minute. The actual linear speed will vary depending on the diameter of the extruder barrel which determines throughput rate, the slot width of the die which deter-mines substrate width, and the coating thickness desired.Extruder barrels are commonly available in various di-ameter sizes, e.g., 3-1/2 inch with throughput rate of 600 pounds per hour, and 4-1/2 inch, 6 inch, 8 inch, etc., with higher throughput rates. One typical commercial slot width is 60 inches. Typically, coating thicknesses are 0.5 to 1.5 mils for film substrate, 1 to 2 mils for paper substrate, 2 to 3 mils for reinforced film substrate, and 3 to 4 mils for cloth substrate. Thus, for example, to obtain a coating of one ounce per square yard (approxi-mately 1 mil in thickness) at a 58 inch width, the linearspeed on a 3-1/2 inch extruder may be 298 feet per minute and on a 4-1/2 inch extruder, 596 feet per minute.

The viscous materials to which the process of the present invention is primarily directed are adhesive compositions and certain thermoplastic materials and compositions having moderate softening temperatures, i.e. in the range of about 325F to about 450F. Industrial grade high performance pressure-sensitive adhesive coated sheets and tapes are particularly suited to be advantageously manufactured by the process of the present invention.

The extrudable high performance industrial pressure-sensitive adhcsives contemplated to be employed are generally a mixture comprising an elastomer component and a tackifier resin component, such compositions having 1 ~ 6~517 - g viscosities in the range of from about 100,000 to about 800,000 centipoises at 350F.

The elastomer in such adhesive compositions is character-ized by having thermoplastic properties. Thus, the elas-tomer component which may be a mixture of elastomers necessarily contain materials known in the art as thermo-plastic elastomers or thermoplastic rubbers. These rubbers generally begin to soften at about 200F (93C) and have a softening temperature maximum of about 450F
(232C). The most useful and best known of these thermo-plastic elastomers are block copolymers which may be those referred to as A-B-A block copolymer or as A-B block copolymer in which A designates a thermoplastic block and B designates an elastomeric block. In the A-B-A block copolymers, the terminal or end polymer blocks are the thermoplastic blocks and the middle or internal blocks are the rubbery blocks. In the A-B block copolymers the B block forms one of the end blocks rather than a mid-block. The thermoplastic A block is a polymer of alkenyl-arene, preferably styrene or styrene homolog or analog.
lhe B block is a polymer of an unsaturated aliphatic hydrocarbon of 4 to 6 carbon atoms, preferably of a conjugated aliphatic diene and most frequently a polymer of butadiene or isoprene. B also may be a polymer of a lower alkene such as ethylene or butylene. The A-B-~block copolymers may be any variation of linear, branched, or radial copolymers with rubbery mid-blocks and thermo-plastic end-blocks, including those sometimes designated as A-B-C block copolymers in which C is a thermoplastic end-block but of a different polymer than A. The radial or teleblock copolymers are sometimes designated (A-BtnX
wherein X is an organic or inorganic whole functional atom or molecule, n is an integer corresponding to the value of the functional group originally present in X, and in which (A-Bt radiates from X in a way that A is an end block.

l 16~517 The A-s-A block copolymers employed as the elastomer component generally are those in which the individual A
block has a number average molecular weight of at least 6000, usually from about 8000 to 30,000 and constitute from about 5 to 50 percent, usually about 10 to 30 percent by weight of the A-B-A block copolymer. The B block portion has a number average molecular weight in the range of from about 45,000 to about 180,000. The number average molecular weight of the entire block copolymer may be in the range of about 75,000 to 200,000 when linear or branched, and about 125,000 to 400,000 when radial.
Usually, the linear and branched copolymers are in the range of 100,000 to 150,000 and the radial in the range of 150,000 to 250,000. In A-B block copolymers, the number average molecular weight of the A block is generally from about 7000 to about 20,000 and the total molecular weight usually does not exceed about 150,000.

Suitable thermoplastic elastomeric block copolymers are prepared by stepwise solution polymerization of the components. They are also available commercially. The preparations and properties of block copolymers are amply described in the literature such as, for example, "Thermo-plastic Rubber (A-B-A Block Copolymers) in Adhesives" by J.T. Harlan, et al., in "Handbook of Adhesives" edited by Irving Skeist, Van Nostrand Reinhold Co., New York, Second Edition (1977), pages 30~-330; "Rubber-Related Polymers, I. Thermoplastic Elastomers" by W.R. Hendricks, et al., in "Rubber Technology" edited by Maurice Morton, Van Nostrand Reinhold Co., New York (1973), pages 515-533; and U.S.
Patents 3,519,585; 3,787,531; and 3,281,383; and for A-B
block copolymers, U.S. Patents 3,519,585 and 3,787,531.

When the thermoplastic elastomer is a block copolymer, it may be an A-B-A or an A-B block copolymer or a mixture of 1 16~517 the two types. When the A block is polystyrene and B
block is polyisoprene, the elastomers are referred to as an S-I-S block copolymer or S-I block copolymer. When the A block is polystyrene and the B block is polybutadiene, 5 the elastomers are known as S-B-S or S-B block copolymer.

When the A-B-A block copolymer or A-B block copolymer is used as the primary elastomer of the elastomer component, the component may be modified by the addition of from 0 to 10 25 percent by weight based on the weight of the thermo-plastic elastomer, of a more conventional diene elastomer such as natural rubber, polymers based on butadiene or isoprene, butadiene-styrene (SBR) rubber, butadiene-acrylonitrile (NBR) rubber, butyl rubber and the like, 15 provided they are in a low plasticity state, e.g., less than about 40 Mooney units.

Additionally, the elastomer component may be an ethylene vinyl acetate copolymer (EVA) copolymer. These are 20 generally random copolymers containing from about 28 to 60 percent vinyl acetate by weight. These may be used singly, as mixtures of ethylene vinyl acetate polymers or as mixture with a A-B-A or A-B block copolymers.

25 The tackifying resin for the tackifier component may be a natural or synthetic polymer, preferably solid having a softening point in the range of about 85C to about 150C
and includes rosin, hydrogenated rosin, dehydrogenated rosin, rosin esters such as erythritol and glycerol 30 esters, polymerized alpha or beta pinene, polymerized mixture of piperylene and isoprene, and the like. Other materials are described in the chapter entitled "Pressure-Sensitive Tapes and Labels" by C.W. Bemmel in "Handbook of Adhesives" edited by Irving Skeist, Van Nostrand Reinhold Co., (1977) pages 724-735.

l 1 60517 In addition to the foregoing, the adhesive compositions may include other conventional additives such as antioxi-dants, heat stabilizers, ultraviolet absorbers, pigments, inorganic fillers, parting agents and the like.

Representative of some of the adhesive compositions which may be advantageously employed in the process of the present invention include compositions which are described in U.S. Patents 3,783,072 and 3,98~,509.
The process is also adaptable to being employed for use with coating materials which are not adhesive compositions. Coating materials which may beneficially employ the process of the present in~ention include certain copolyesters, certain modified ethylene polymers and other thermoplastic materials which have a torque value not to exceed 600 meter grams when measured by working at 220C at 75 r.p.m. in a recording torque dynamometer (Plasti-CorderO EPL-V750 manufactured by C.W. Brabender Co., Hackensack, N.J.).

Copolyesters are copolymers of.

O O
Il ~I
~C-X-C-O-Y-O~
and O O
Il ll ~C--X '--C--O--Y '--0~

wherein X and X' are nuclei of aromatic or aliphatic dicarboxylic acids and Y and Y' are nuclei of alkylene diols. Those copolyesters which are of high viscosity and moderate softening temperature in the range hereinbefore indicated are adaptable to being employed in the present process.

1 16~517 Other coating materials which may be usefully employed include low melting modified polyethylene and ethylene vinyl acetate having a vinyl acetate content of 20 percent or higher.

The invention is a useful coating process employing materials whether adhesive or not which are highly viscous, e.g., having a viscosity higher than 100,000 centipoises and not previously considered suitable for extrusion coating provided they have moderate softening temperatures, e.g., not above about 450F (232C).
Coating and/or adhesive materials of low viscosity also may be employed in the process of the present invention although for these materials, oth~er methods not adaptable to highly viscous compositions are available for achieving uniform coating.

..
The following examples illustrate the invention but are not to be construed as limiting:
EXAMPLES I-VIII

Pressure-sensitive adhesive coated substrates are prepared by feeding the component materials indicated in Table A
(in parts by weight) into an extruder, mixing and melting at temperatures in the range of from about 350 to 425F, and extruding through a die orifice of 20 mils onto various substrates. Suitable substrates are paper, polyvinyl chloride, cloth, polyester and aluminum foil.
The coated substrates have adhesive film thickness of less than 5 mils and are uniform throughout with substantially no beading effect. The coated substrates are slitted to form pressure-sensitive adhesives tapes of good adhesion and hold.

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l 1 6~517 EXAMPLES IX-X

In separate operations, poly(ethylene terephthlate-co-ethylene azelate) of apparent molecular weight of about 20,000 (VPE 5571, Goodyear Tire and Rubber Company) and modified polyethylene of apparent molecular weight of 8000, viscosity of 8500 centipo ses at 150C, and softening point of about 106C (EPOLENE wax C-16, Eastman Kodak Company) are fed into the hopper of an extruder and heated at about 350F and extruded through the die onto a paper substrate to obtain copolyester and modified polyethylene coated paper respectively with substantially no beading effect. The coated films may be used as substrates for adhesive tapes as wel-l as for waterproof coverings.

EXAMPLE XI

In separate operations, adhesive coated sheets of SBR
latex saturated paper coated on the back side with a release agent (stearyl methacrylate--acrylonitrile blended with resin film former, U.S. Patent 3,502,497, Example VIII), and 0.88 gauge Mylar polyester film coated on the back side with a release agent (stearyl methacrylate--acrylonitrile, U.S. Patent 3,502,497, Example I) to be slitted in the manufacture of pressure-sensitive tapes are .
prepared first by feeding into the hopper of an extruder, the following components (in parts by weight):

S-I-S linear block copolymer 100 ~(Kraton 1107) Piperylene-isoprene tackifier 80 ~(Wingtack 95) zinc dibutyl dithiocarbamate 2

2,5-Ditertiary amylhydro~uinone '~ T! ~

~ l 6~517 The components then are mixed and melted at barrel temperatures ranging from 160 to 230C and extruded through a die ori~ice of about 20 mils onto the paper substrate and the film substrate to obtain adhesive film coated sheets of adhesive film thickness of 1.5 mils for paper substrate, and 0.75 mil for polyester film substrate. All coated sheets obtained are of good uniformity with no beading effect, i.e., substantially no thickening along the edges.
EXAMPLE XII

In a similar operation, an adhesive coated sheet of polyethylene coated cotton cloth is prepared by extruding an adhesive mixture of the following composition (parts by weight).

S-I-S block copolymer 50 (Kraton 1107) S-I linear block copolymer 50 (Solprene 311) Piperylene-isoprene tackifier 80 (Wingtack 95) Zinc dibutyl dithiocarbamate 2 2,5-Ditertiary amylhydroquinone The components are mixed and melted in the temperature range 160 to 230C and extruded through a 20 mil die orifice to obtain a 3.5 mil adhesive film on a cloth substrate of uniform thickness and substantially free of any beading effect.

1 1 6~5~ 7 EXAMPLE XIII

In still another similar operation, a saturated paper -substrate described in Example XI is coated with an adhesive mixture of the following composition:

S-I-S plus S-I block copolymer blend* 100 Piperylene-isoprene tackifier 80 zinc dibutyl dithocarbamate 2 2,5-Ditertiary amylhydroquinone *Kraton 1112, thought to be about 70 parts S-I-S and 30 parts S-I copolymers The components are mixed, melted and extruded as previously described to obtain a 1.5 mil adhesive coated paper substantially free of any beading effect.

Claims (9)

The embodiments of the invention, in which an exclusive property or privilege is claimed, are defined as follows:-

1.- A direct extrusion process for preparing a coating substrate from a viscous coating composition, which com-prises:
(a) feeding the component material or materials of a coating composition into an extruder having a barrel and an elongated extrusion die orifice leading away from said barrel;
(b) advancing the material or materials forward in the extruder barrel to obtain a molten homogeneous composition, and then through said extrusion die orifice;
(c) directing a substrate into positive engage-ment with the outlet opening defined by said extrusion die, and (d) extruding the homogeneous composition through the extrusion die orifice onto the substrate to force the substrate away from said die and forming a uniform coating on said substrate, moving the coated substrate into immediate contact with a closely disposed coating roll, said substrate being drawn to the die orifice from a direction such that the angle ? formed between a line representing the direction of approach of the substrate and a line representing the direction of extrusion is less than 90°, and said coated sub-strate being drawn away from the die orifice in a direction such that the angle .beta. formed between the direction of extrusion and a line representing the initial departing direction of the coated substrate immediately on formation when combined with the angle ? is less than 180°.

2.- A process according to claim 1, wherein the maximum distance between the die orifice and the coating roll is about 150 mils.

3.- A process according to claim 1, wherein the angle .beta. is approximately 90°.

4.- A process according to claim 1, wherein the angle .beta. is less than 90°.

5.- A process according to claim 1, wherein the angle .beta. is slightly greater than 90°.

6.- A process according to claim 1, wherein the composition is of a viscosity in the range of from about 100,000 centipoises to about 800,000 centipoises at 350°F.

7.- A process according to claim 1, wherein the coating is of a thickness in the range of from about 0.75 to 5 mils.

8.- A process according to claim 1, wherein the extrusion is carried out in the temperature range of from about 325°F. to about 450°F.

9.- A process according to claim 1, wherein the coating is an adhesive composition.