EP0052047B2 - Cathode thermo-électronique - Google Patents
Cathode thermo-électronique Download PDFInfo
- Publication number
- EP0052047B2 EP0052047B2 EP81401713A EP81401713A EP0052047B2 EP 0052047 B2 EP0052047 B2 EP 0052047B2 EP 81401713 A EP81401713 A EP 81401713A EP 81401713 A EP81401713 A EP 81401713A EP 0052047 B2 EP0052047 B2 EP 0052047B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- porous body
- impregnated
- cathode
- barium
- thermoelectronic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052788 barium Inorganic materials 0.000 claims description 19
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 18
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 16
- 229910052721 tungsten Inorganic materials 0.000 claims description 14
- 239000010937 tungsten Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- -1 calcium aluminates Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 claims description 2
- 230000000994 depressogenic effect Effects 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 239000011819 refractory material Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 239000011733 molybdenum Substances 0.000 description 7
- 239000003870 refractory metal Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
- 229910052762 osmium Inorganic materials 0.000 description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 229910052702 rhenium Inorganic materials 0.000 description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 229910001080 W alloy Inorganic materials 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 150000001552 barium Chemical class 0.000 description 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- TWXDDNPPQUTEOV-UHFFFAOYSA-N hydron;n-methyl-1-phenylpropan-2-amine;chloride Chemical compound Cl.CNC(C)CC1=CC=CC=C1 TWXDDNPPQUTEOV-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- OUFGXIPMNQFUES-UHFFFAOYSA-N molybdenum ruthenium Chemical group [Mo].[Ru] OUFGXIPMNQFUES-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/20—Cathodes heated indirectly by an electric current; Cathodes heated by electron or ion bombardment
- H01J1/28—Dispenser-type cathodes, e.g. L-cathode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J23/00—Details of transit-time tubes of the types covered by group H01J25/00
- H01J23/02—Electrodes; Magnetic control means; Screens
- H01J23/04—Cathodes
Definitions
- the present invention relates to a new thermoelectronic cathode structure.
- Such cathodes find their field of application in electronic tubes, tubes with localized constants such as triodes and tetrodes, or tubes with distributed constants such as klystrons and magnetrons used at microwave frequencies.
- Another improvement consisted in replacing the reserve of alkaline earth with a ceramic consisting of a mixture of alumina, alkaline earth oxides and tungsten powder.
- L type cathodes have always had a density of emitted current, at equal temperature, greater than that of so-called impregnated cathodes, even in the best cases when the latter are covered with '' a film of a refractory metal with high output work such as osmium, ruthenium, iridium, rhenium, which tends to increase the current density.
- thermoelectronic cathode comprising inside a cylindrical envelope, a heating filament located in the lower part of said envelope, and two superposed porous bodies inserted at the top of the envelope.
- the porous bodies are produced by a mixture comprising by weight 90% of powdered tungsten and 10% of barium carbonate or barium peroxide and carbon, mixture covered with a layer of powdered tungsten sintered during activation. It is therefore not a porous body of the impregnated type and the technique for producing this type of cathode is very complex when it is desired to have doses of known volume and weight.
- thermo-electronic cathode comprising, inside a cylindrical envelope, a heating filament situated in the lower part of said envelope, and two superposed porous bodies, inserted in the upper part of the envelope, both porous body being constituted by a lower body containing an emissive material, covered with the upper body, the surface of the upper porous body forming the emissive surface of the cathode, characterized in that the lower porous body is a porous body of porosity between 16 and 50% impregnated with the emissive material and the upper porous body is a non-impregnated porous body with porosity between 16 and 21%.
- FIG. 1 shows an example of a cathode structure "L" of the prior art.
- a cathode is constituted by a molybdenum tube 1, divided into two cavities; the lower part contains the heating filament 2; the upper part consists of a chamber 3 containing a reserve 4 of barium and calcium carbonates for example.
- a porous tunstene disc 5 is attached to the top of the barium reservoir, so that the upper cavity communicates outward only through the porous body.
- the upper face of this disc may include a thin layer 6 of a refractory metal with high output work such as osmium, iridium, rhenium, ruthenium, or an alloy of several of these materials.
- a refractory metal with high output work such as osmium, iridium, rhenium, ruthenium, or an alloy of several of these materials.
- FIG. 2 represents an example of a cathode structure impregnated with the prior art.
- a filament 2 is located inside a molybdenum cylinder 1 containing a body of porous tungsten 7 which is impregnated with barium and calcium aluminates.
- the upper face of the body 7 can be covered with a thin layer 6 of a refractory metal with high output work from one of those mentioned above.
- the underside of the body 7 rests on a molybdenum bottom 8 ensuring sealing.
- FIG. 3 represents an example of a cathode structure according to the invention.
- the cathode according to the invention consists of a cylindrical molybdenum body 1 inside which is located a filament 2 in its lower part and a set of two porous bodies superimposed in its upper part: a porous body 9 free of all impregnating, with a porosity of between 16 and 21%, made of tungsten or a tungsten alloy and of a refractory metal with high output work such as iridium, rhenium, osmium, ruthenium, porous body of which the front face 10 is the only one through which the emissive material can escape, and a porous body 12 in contact with the rear face 11 of the porous body 9 impregnated with barium and calcium aluminates or a mixture comprising barium aluminates, of calcium and a scandium or barium scandate oxide, this porous body having a porosity of between 16 and 50%, for example.
- the rear face of the porous body 12 is sealed by conventional means such as the deposition of molybden
- the front face 10 of the non-impregnated porous body 9 can be covered with a layer of refractory metal with high output work.
- the porous impregnated body may consist of tungsten impregnated with barium and calcium aluminates, an alloy of tungsten and a refractory metal with high output work impregnated with barium aluminates and calcium or tungsten impregnated with a mixture of barium aluminates and calcium and a scandium oxide.
- a gap or gap 14 which is filled, in order to improve the thermal contact before placing the porous body 3, either of powder of a conductive metal at high melting temperature, or a grid of molybdenum or tungsten, with a very fine mesh, of pitch 20 Ilm for example, which serves as additional conductance for the diffusion of barium towards the porous body 9, or of a flexible clicking ensuring contact between the bodies cathodes, either using a thread.
- This gap 14 can be eliminated by making the assembly by pressing.
- the porous body 9 generally has a curved shape obtained by machining or by pressing.
- the operating mechanism of this type of cathode is as follows: the free barium is produced in the porous body 12 by heating the assembly using the filament 2, by chemical reaction between the impregnating agent and the tungsten.
- This barium then migrates through the pores of the body 3 from the face 11 to the face 10 where it covers its surface, thus lowering the work of leaving it.
- An electrode placed opposite the cathode, at a certain distance, and brought to a positive potential with respect to the cathode, collects the electrons emitted by the latter.
Landscapes
- Solid Thermionic Cathode (AREA)
- Microwave Tubes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8023884A FR2494035A1 (fr) | 1980-11-07 | 1980-11-07 | Cathode thermo-electronique pour tube hyperfrequences et tube incorporant une telle cathode |
| FR8023884 | 1980-11-07 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0052047A1 EP0052047A1 (fr) | 1982-05-19 |
| EP0052047B1 EP0052047B1 (fr) | 1986-01-08 |
| EP0052047B2 true EP0052047B2 (fr) | 1990-05-02 |
Family
ID=9247818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81401713A Expired - Lifetime EP0052047B2 (fr) | 1980-11-07 | 1981-10-27 | Cathode thermo-électronique |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4494035A (show.php) |
| EP (1) | EP0052047B2 (show.php) |
| JP (1) | JPS57107534A (show.php) |
| DE (1) | DE3173470D1 (show.php) |
| FR (1) | FR2494035A1 (show.php) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0719530B2 (ja) * | 1984-06-29 | 1995-03-06 | 株式会社日立製作所 | 陰極線管 |
| JPH0416344Y2 (show.php) * | 1985-07-02 | 1992-04-13 | ||
| FR2596198A1 (fr) * | 1986-03-19 | 1987-09-25 | Thomson Csf | Cathodes pour klystron a faisceaux multiples, klystron comportant de telles cathodes et procede de fabrication de telles cathodes |
| JPS63236239A (ja) * | 1987-03-10 | 1988-10-03 | シーメンス、アクチエンゲゼルシヤフト | 放電管用デイスペンサー陰極とその製法 |
| US4810926A (en) * | 1987-07-13 | 1989-03-07 | Syracuse University | Impregnated thermionic cathode |
| US5266414A (en) * | 1988-03-18 | 1993-11-30 | Varian Associates, Inc. | Solid solution matrix cathode |
| FR2647952A1 (fr) * | 1989-05-30 | 1990-12-07 | Thomson Tubes Electroniques | Cathode thermoelectronique impregnee pour tube electronique |
| CH678671A5 (show.php) * | 1989-08-22 | 1991-10-15 | Asea Brown Boveri | |
| DE19527723A1 (de) * | 1995-07-31 | 1997-02-06 | Philips Patentverwaltung | Elektrische Entladungsröhre oder Entladungslampe und Scandat-Vorratskathode |
| JP3696720B2 (ja) * | 1997-07-09 | 2005-09-21 | 松下電器産業株式会社 | 含浸型陰極とその製造方法 |
| JPH11102636A (ja) | 1997-09-26 | 1999-04-13 | Matsushita Electron Corp | 陰極、陰極の製造方法、受像管 |
| US6495949B1 (en) * | 1999-11-03 | 2002-12-17 | Orion Electric Co., Ltd. | Electron tube cathode |
| FR2833406A1 (fr) * | 2001-12-10 | 2003-06-13 | Thomson Licensing Sa | Cathode pour tube a vide a duree de vie amelioree |
| CN103311066B (zh) * | 2013-06-03 | 2015-08-19 | 哈尔滨工业大学 | 具有内芯的用于航天器自持空心阴极的发射体 |
| CN116387116B (zh) * | 2023-03-29 | 2025-05-30 | 中国科学院空天信息创新研究院 | 浸渍型阴极及其制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE526506A (show.php) * | 1953-02-16 | |||
| NL198428A (show.php) * | 1954-06-29 | |||
| BE543391A (show.php) * | 1954-12-06 | |||
| US3076915A (en) * | 1954-12-24 | 1963-02-05 | Egyesuelt Izzolampa | Cathode assembly and method of making same |
| NL272981A (show.php) * | 1961-01-02 | |||
| US3373307A (en) * | 1963-11-21 | 1968-03-12 | Philips Corp | Dispenser cathode |
| US3558966A (en) * | 1967-03-01 | 1971-01-26 | Semicon Associates Inc | Directly heated dispenser cathode |
| BE759174A (fr) * | 1969-11-21 | 1971-05-19 | Philips Nv | Cathode a reserve et son procede de realisation |
| US3842309A (en) * | 1970-11-12 | 1974-10-15 | Philips Corp | Method of manufacturing a storage cathode and cathode manufactured by said method |
| US3719856A (en) * | 1971-05-19 | 1973-03-06 | O Koppius | Impregnants for dispenser cathodes |
| DE2245717A1 (de) * | 1972-09-18 | 1974-03-28 | Patra Patent Treuhand | Elektrode mit einem poroesen sinterkoerper |
| US4165473A (en) * | 1976-06-21 | 1979-08-21 | Varian Associates, Inc. | Electron tube with dispenser cathode |
| FR2390825A1 (fr) * | 1977-05-13 | 1978-12-08 | Thomson Csf | Cathode thermo-ionique a grille incorporee, son procede de fabrication et tube electronique comportant une telle cathode |
| DE2808134A1 (de) * | 1978-02-25 | 1979-08-30 | Licentia Gmbh | Vorratskathode |
| US4310603A (en) * | 1978-11-30 | 1982-01-12 | Varian Associates, Inc. | Dispenser cathode |
| JPS5652835A (en) * | 1979-10-01 | 1981-05-12 | Hitachi Ltd | Impregnated cathode |
-
1980
- 1980-11-07 FR FR8023884A patent/FR2494035A1/fr active Granted
-
1981
- 1981-10-27 DE DE8181401713T patent/DE3173470D1/de not_active Expired
- 1981-10-27 EP EP81401713A patent/EP0052047B2/fr not_active Expired - Lifetime
- 1981-11-04 US US06/318,316 patent/US4494035A/en not_active Expired - Lifetime
- 1981-11-06 JP JP17731181A patent/JPS57107534A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE3173470D1 (en) | 1986-02-20 |
| US4494035A (en) | 1985-01-15 |
| JPS57107534A (en) | 1982-07-05 |
| FR2494035B1 (show.php) | 1983-05-13 |
| EP0052047A1 (fr) | 1982-05-19 |
| FR2494035A1 (fr) | 1982-05-14 |
| EP0052047B1 (fr) | 1986-01-08 |
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