EP0043989B1 - Process for the production of a laminated sheet - Google Patents

Process for the production of a laminated sheet Download PDF

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Publication number
EP0043989B1
EP0043989B1 EP81105114A EP81105114A EP0043989B1 EP 0043989 B1 EP0043989 B1 EP 0043989B1 EP 81105114 A EP81105114 A EP 81105114A EP 81105114 A EP81105114 A EP 81105114A EP 0043989 B1 EP0043989 B1 EP 0043989B1
Authority
EP
European Patent Office
Prior art keywords
layer
lacquer
solvent
metal layer
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP81105114A
Other languages
German (de)
French (fr)
Other versions
EP0043989A1 (en
Inventor
Eleonore Czichy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cessione grobena AG
Original Assignee
Interletter AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Interletter AG filed Critical Interletter AG
Priority to AT81105114T priority Critical patent/ATE10073T1/en
Publication of EP0043989A1 publication Critical patent/EP0043989A1/en
Application granted granted Critical
Publication of EP0043989B1 publication Critical patent/EP0043989B1/en
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/14—Metallic leaves or foils, e.g. gold leaf
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
    • B44C1/1737—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff on a substrate unsuitable for direct deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/005—Removing selectively parts of at least the upper layer of a multi-layer article
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
    • H05K3/20—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern
    • H05K3/205—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern using a pattern electroplated or electroformed on a metallic carrier
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24736—Ornamental design or indicia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24843—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2843—Web or sheet containing structurally defined element or component and having an adhesive outermost layer including a primer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Definitions

  • the invention relates to a method for producing a composite film according to the preamble of claim 1.
  • a special method according to the so-called hot gilding process in which, by means of a die, areas corresponding to a provisional carrier layer on which there is a non-stick, transferable coating with a lacquer layer and a metal layer thereon, by hot pressing the die the metal layer and the lacquer layer can be lifted off and applied to a substrate. The viewer then looks through the lacquer layer at the exposed, transferred metal areas.
  • the object of the invention is to provide a method for producing a composite film according to the preamble of claim 1, which can be used particularly economically for short runs, but does not offer the viewer the exposed metal areas, but rather metal areas covered with transparent lacquer, so that a special one Gloss effect occurs.
  • the method according to the invention means that the composite film with its rear adhesive layer can be glued onto any surface. If the carrier layer is transparent, it does not have to be removed, even if it can be removed. In any case, the viewer looks at the remaining areas of the metal layer through the lacquer layer, which increases the gloss of the remaining areas of the metal layer.
  • a layer 4 of a lacquer is first continuously applied to a polyester film 2, from which the film 2 is to be pulled off cold.
  • a vinyl lacquer which has been dissolved in a mixture of acetone and 2-butanone has proven successful.
  • a continuous, like the layer 4 transparent, but color-tinted layer 6 was applied to the layer 4, for example a pigmented lacquer based on vinyl chloride / vinyl acetate. If no tinting is desired, layer 6 can be omitted. Layer 6 can also be omitted if layer 4 is tinted.
  • An image structure 10 was applied to the continuous layer 8 by means of printing ink or by means of a light-hardened emulsion.
  • the image structure 10 thus left areas 12 free.
  • the aluminum layer could be removed with a suitable solvent, such as sodium hydroxide solution. 5% vinegar essence can be used to stop the dissolving process and to neutralize the sodium hydroxide solution.
  • the layer regions 6 and 4 can then be removed by suitable solvents.
  • the image structure is coated with a pressure-sensitive adhesive 14. (In the figures, the thickness ratios are of course not shown to scale, but in such a way that the layer structure becomes clear.)

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Printing Methods (AREA)

Abstract

A composite foil from which metallically lustrous layer areas which have an image structure are to be transferred onto a base, with a carrier layer, with a lacquer layer on said carrier layer, with a metal layer on said lacquer layer and with an adhesive layer on said metal layer, wherein said lacquer layer (4) and said metal layer (8) are divided into areas which have the shape of the image structure, and wherein said carrier layer (2) can be detached from said lacquer layer (4) and the adhesive (14) which is located between the areas by pulling off said carrier layer at room temperature wherein the metal layer is formed from vapor deposited metal and adhesive (14) is a contact adhesive.

Description

Die Erfindung betrifft ein Verfahren zur Herstellung einer Verbundfolie nach dem Oberbegriff des Anspruchs 1.The invention relates to a method for producing a composite film according to the preamble of claim 1.

Bei einem nach der FR-PS 1 591 695 bekannten Verfahren dieser Art liegen im Ergebnis die die Form der Bildstruktur aufweisenden Bereiche der lösungsmittelresistenten Schicht und der auf diesen verbleibenden Bereiche der Metallschicht zwischen einer Unterlagsfolie und einer Deckfolie. Je nachdem, ob man die Unterlagsfolie oder die Deckfolie abzieht, blickt man auf die lösungsmittelresistenten Bereiche (die dann freiliegen) oder die Metallbereiche (die dann freiliegen).In a method of this type known from FR-PS 1 591 695, the regions of the solvent-resistant layer which have the shape of the image structure and the regions of the metal layer which remain there lie between an underlay film and a cover film. Depending on whether you remove the backing film or the cover film, you look at the solvent-resistant areas (which are then exposed) or the metal areas (which are then exposed).

Nach der DE-OS 2222144 ist ein spezielles Verfahren gemäß dem sog. Heißvergoldungsprozeß bekannt, bei dem mittels einer Matrize von einer provisorischen Trägerschicht, auf der sich ein antihaftend wirkender, übertragbarer Überzug mit Lackschicht und darauf eine Metallschicht befinden, durch Heißpressen der Matrize entsprechende Bereiche der Metallschicht und der Lackschicht abgehoben und auf eine Trägerunterlage aufgebracht werden können. Der Betrachter sieht dann durch die Lackschicht auf die freiliegenden, übertragenen Metallbereiche.According to DE-OS 2222144, a special method according to the so-called hot gilding process is known, in which, by means of a die, areas corresponding to a provisional carrier layer on which there is a non-stick, transferable coating with a lacquer layer and a metal layer thereon, by hot pressing the die the metal layer and the lacquer layer can be lifted off and applied to a substrate. The viewer then looks through the lacquer layer at the exposed, transferred metal areas.

Aufgabe der Erfindung ist es, ein Verfahren zur Herstellung einer Verbundfolie nach dem Oberbegriff des Anspruchs 1 anzugeben, das besonders wirtschaftlich für kleine Auflagen benutzt werden kann, dem Betrachter aber nicht die freiliegenden Metallbereiche darbietet, sondern mit transparentem Lack überzogene Metallbereiche, so daß eine besondere Glanzwirkung auftritt.The object of the invention is to provide a method for producing a composite film according to the preamble of claim 1, which can be used particularly economically for short runs, but does not offer the viewer the exposed metal areas, but rather metal areas covered with transparent lacquer, so that a special one Gloss effect occurs.

Die Lösung dieser Aufgabe ist im Kennzeichen des Anspruchs 1 angegeben.The solution to this problem is specified in the characterizing part of claim 1.

Das erfindungsgemäße Verfahren führt dazu, daß die Verbundfolie mit ihrer rückwärtigen Klebstoffschicht auf eine beliebige Unterlage aufgeklebt werden kann. Ist die Trägerschicht durchsichtig, so braucht sie nicht entfernt zu werden, gleich wenn sie entfernt werden kann. Jedenfalls blickt der Betrachter auf die stehengebliebenen Bereiche der Metallschicht durch die Lackschicht, was den Glanz der stehengebliebenen Bereiche der Metallschicht erhöht.The method according to the invention means that the composite film with its rear adhesive layer can be glued onto any surface. If the carrier layer is transparent, it does not have to be removed, even if it can be removed. In any case, the viewer looks at the remaining areas of the metal layer through the lacquer layer, which increases the gloss of the remaining areas of the metal layer.

Vorteilhafte Ausgestaltungen der Erfindung sind in den Unteransprüchen angegeben.Advantageous embodiments of the invention are specified in the subclaims.

Die Erfindung wird im folgenden an einem Ausführungsbeispiel unter Hinweis auf die Zeichnungen erläutert.

  • Fig. 1 zeigt eine Verbundfolie in den ersten Phasen ihrer Herstellung im Querschnitt;
  • Fig. 2 zeigt die fertige Verbundfolie im Querschnitt.
The invention is explained below using an exemplary embodiment with reference to the drawings.
  • Fig. 1 shows a composite film in the first phases of its manufacture in cross section;
  • Fig. 2 shows the finished composite film in cross section.

Auf eine Polyesterfolie 2 ist zunächst durchgehend eine Schicht 4 aus einem Lack aufgebracht, von dem die Folie 2 kalt abzuziehen ist. Bei einer Folie 2 aus Polyester hat sich ein Vinyllack bewährt, der in einem Gemisch aus Azeton und Butanon-2 gelöst war. Auf die Schicht 4 wurde eine durchgehende, ebenso wie die Schicht 4 transparente, aber farblich getönte Schicht 6 aufgebracht, etwa ein pigmentierter Lack auf Vinylchlorid/Vinylacetat-Basis. Ist keine Tönung erwünscht, kann die Schicht 6 entfallen. Die Schicht 6 kann auch entfallen, wenn die Schicht 4 getönt wird. Auf die durchgehende Schicht 6 wurde eine durchgehende Metallschicht 8, etwa aus Aluminium aufgebracht, etwa durch Aufdampfen. Auch eine solche Metallschicht kann mit farbgebenden Zusätzen versehen sein.A layer 4 of a lacquer is first continuously applied to a polyester film 2, from which the film 2 is to be pulled off cold. In the case of a film 2 made of polyester, a vinyl lacquer which has been dissolved in a mixture of acetone and 2-butanone has proven successful. A continuous, like the layer 4 transparent, but color-tinted layer 6 was applied to the layer 4, for example a pigmented lacquer based on vinyl chloride / vinyl acetate. If no tinting is desired, layer 6 can be omitted. Layer 6 can also be omitted if layer 4 is tinted. A continuous metal layer 8, for example made of aluminum, was applied to the continuous layer 6, for example by vapor deposition. Such a metal layer can also be provided with coloring additives.

Auf die durchgehende Schicht 8 wurde mittels Druckfarbe oder mittels licht-gehärteter Emulsion eine Bildstruktur 10 aufgebracht. Die Bildstruktur 10 ließ somit Bereiche 12 frei. In diesen Bereichen 12 konnte die Aluminiumschicht mit einem geeigneten Lösungsmittel, etwa Natronlauge, entfernt werden. Zum Stoppen des Lösungsvorgangs und zum Neutralisieren der Natronlauge kann 5°/oige Essigessenz verwendet werden. Anschließend können die Schichtbereiche 6 und 4 durch geeignete Lösungsmittel entfernt werden. Ist dies geschehen, so wird die Bildstruktur mit einem Haftkleber 14 beschichtet. (In den Figuren sind die Dickenverhältnisse selbstverständlich nicht maßstabgerecht dargestellt, sondern so, daß der Schichtaufbau klar wird.)An image structure 10 was applied to the continuous layer 8 by means of printing ink or by means of a light-hardened emulsion. The image structure 10 thus left areas 12 free. In these areas 12, the aluminum layer could be removed with a suitable solvent, such as sodium hydroxide solution. 5% vinegar essence can be used to stop the dissolving process and to neutralize the sodium hydroxide solution. The layer regions 6 and 4 can then be removed by suitable solvents. Once this has been done, the image structure is coated with a pressure-sensitive adhesive 14. (In the figures, the thickness ratios are of course not shown to scale, but in such a way that the layer structure becomes clear.)

Claims (12)

1. Method for the production of a composite foil in which a metal layer (8) is applied upon a carrier layer (2) and a solvent-resistant layer (10) divided into zones having the form of the image structure is applied thereupon and in which the metal of the metal layer (8) is removed between the zones by means of at least one solvent, characterised in that a continuous lacquer layer (4) is applied to the carrier layer (2) before the application of the metal layer (8), in that the lacquer of this lacquer layer (4) is also removed between the zones by means of the at least one solvent and in that an adhesive coating (14) is applied upon the zones of the solvent- resistant layer (10) and the exposed zones of the carrier layer (2).
2. Method according to claim 1, characterised in that an uninterrupted, colour-toned layer (6) is applied upon the continuous lacquer layer (4) before the application of the metal layer (8) and is treated just like the continuous lacquer layer (4).
3. Method according to one of the above claims, characterised in that the solvent-resistant layer (10) is formed from an exposed photographic emulsion or a printing ink on a polyamide basis.
4. Method according to one of the above claims, characterised in that the surface to be treated with the solvent is powdered before the treatment - preferably with talcum.
5. Method according to one of the above claims, characterised in that caustic soda is used as solvent for a metal layer consisting of aluminium.
6. Method according to one of the above claims, characterised in that a polyester foil is used as carrier layer (2).
7. Method according to one of the above claims, characterised in that the continuous lacquer layer (4) is formed from vinyl lacquer.
8. Method according to one of claims 2 to 7, characterised in that as toning medium for the colourtoned layer (6) there is used a fat dyestuff, a spirit-soluble dyestuff or an inorganic pigment.
9. Method according to one of claims 2 to 8, characterised in that a vinyl chloride - vinyl acetate copolymer is used as basic material for the colour-toned layer (6).
10. Method according to one of the above claims, characterised in that the metal layer (8) is formed from aluminium, copper, silver or chromium.
11. Method according to one of the above claims, characterised in that the metal layer (8) is applied by vaporisation upon the lacquer layer (4) or the colour-toned layer (6) as the case may be.
12. Method according to one of the above claims, characterised in that the adhesive coating (14) is formed from a contact adhesive.
EP81105114A 1980-07-10 1981-07-01 Process for the production of a laminated sheet Expired EP0043989B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81105114T ATE10073T1 (en) 1980-07-10 1981-07-01 PROCESS FOR MANUFACTURING A COMPOSITE FILM.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803026236 DE3026236A1 (en) 1980-07-10 1980-07-10 COMPOSITE FILM TO BE TRANSFERRED FROM THE METALLIC GLOSSY LAYER AREAS TO A BASE
DE3026236 1980-07-10

Publications (2)

Publication Number Publication Date
EP0043989A1 EP0043989A1 (en) 1982-01-20
EP0043989B1 true EP0043989B1 (en) 1984-10-31

Family

ID=6106907

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81105114A Expired EP0043989B1 (en) 1980-07-10 1981-07-01 Process for the production of a laminated sheet

Country Status (4)

Country Link
US (2) US4477312A (en)
EP (1) EP0043989B1 (en)
AT (1) ATE10073T1 (en)
DE (2) DE3026236A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4564571A (en) * 1983-03-31 1986-01-14 Jun Masaki Transfer sheet with color pattern having metallic luster, and method of manufacturing said sheet
US4687680A (en) * 1983-12-28 1987-08-18 Oike Industrial Co., Ltd. Stamping foil
DE3401677A1 (en) * 1984-01-19 1985-07-25 Oike Industrial Co., Ltd., Kyoto Transfer film
DE3430111C1 (en) * 1984-08-16 1985-10-24 Leonhard Kurz GmbH & Co, 8510 Fürth Foil, in particular hot stamping foil, with a decorative metal layer and process for its production
DE3433012A1 (en) * 1984-09-07 1986-03-20 Interletter AG, Zürich METHOD FOR PRODUCING A TRANSFER PRINT
JPS61155000A (en) * 1984-12-28 1986-07-14 日本精機株式会社 Transfer sheet
EP0193636A1 (en) * 1985-03-08 1986-09-10 Konrad Hornschuch Aktiengesellschaft Reflecting textile band, process for its preparation and its use
US4810320A (en) * 1986-03-18 1989-03-07 Hiromichi Inagaki Method of selectively forming an aluminum evaporation face
EP0242457A1 (en) * 1986-04-17 1987-10-28 Nihon Tokkyo Kanri Company Limited A method for forming a design or representation by removing a predetermined portion or portions of a metallic film
US5186787A (en) * 1988-05-03 1993-02-16 Phillips Roger W Pre-imaged high resolution hot stamp transfer foil, article and method
US4902364A (en) * 1988-08-02 1990-02-20 Dennison Manufacturing Company Heat transfer decorations with patterned metallization
JPH0295893A (en) * 1988-09-30 1990-04-06 Nissha Printing Co Ltd Metallic luster pattern transfer material
US5017255A (en) * 1989-01-23 1991-05-21 Clyde D. Calhoun Method of transferring an inorganic image
US5219655A (en) * 1989-01-23 1993-06-15 Minnesota Mining And Manufacturing Company Composite including an inorganic image and method of transferring such an image
GB2270649A (en) * 1992-09-16 1994-03-23 Vernon Bradshaw Decalcomania having metallic components.
US5422229A (en) * 1993-08-16 1995-06-06 Fabco Products, Inc. Liquid foil employing aluminum platelets
US5751256A (en) * 1994-03-04 1998-05-12 Flexcon Company Inc. Resonant tag labels and method of making same
US5464690A (en) * 1994-04-04 1995-11-07 Novavision, Inc. Holographic document and method for forming
DE4433858C1 (en) * 1994-09-22 1996-05-09 Kurz Leonhard Fa transfer sheet
GB9709263D0 (en) 1997-05-07 1997-06-25 Astor Universal Limited Laminate structure
DE19813314A1 (en) * 1998-03-26 1999-09-30 Kurz Leonhard Fa Stamping foil, especially hot stamping foil
US6149753A (en) * 1998-08-21 2000-11-21 Chao-Yi Hung Filmless sticker and the preparation thereof
US6638386B2 (en) 2000-04-19 2003-10-28 Novavision, Inc. Method for making holographic foil
US6497778B1 (en) 2000-04-19 2002-12-24 Novavision, Inc. Method for making holographic foil
EP1631857B1 (en) * 2003-06-06 2007-03-07 Sipix Imaging, Inc. In mold manufacture of an object with embedded display panel
WO2017197061A1 (en) 2016-05-11 2017-11-16 Neenah Paper, Inc. Security document having enhanced foil durability

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3358337A (en) * 1967-12-19 Hose clamp
US1888154A (en) * 1928-03-16 1932-11-15 Allen Leonard Manufacture and production of transfers
DE900910C (en) * 1941-12-23 1954-01-04 Eisen & Stahlind Ag Process for the production of legible single or multi-colored characters by etching
CH356051A (en) * 1954-06-03 1961-07-31 Minnesota Mining & Mfg Weather-resistant, stick-on protective film with a metallic appearance
US3089800A (en) * 1958-10-07 1963-05-14 C & H Supply Company Foil applique structure
FR1351287A (en) * 1962-03-21 1964-01-31 Letraset International Ltd Dry decals
US3463651A (en) * 1967-09-19 1969-08-26 Rubin Warsager Multicolor surface decoration and process for producing same
DE1298022B (en) * 1967-11-13 1969-06-19 Pohlenz Armin Process for the production of self-adhesive lettering, signs, figures, single letters by etching a metal foil
FR1591695A (en) * 1967-11-13 1970-05-04
FR2135471B1 (en) * 1971-05-04 1973-05-11 Cellophane Sa
GB1441982A (en) * 1973-01-18 1976-07-07 Autotype Co Ltd Dry transfer sheets
GB1445172A (en) * 1973-10-06 1976-08-04 Nicholls E R Transfer for use in making printed circuits
US3961121A (en) * 1973-12-14 1976-06-01 Rubin Warsager Transfer tape for surface decorating an article
US4012552A (en) * 1975-03-10 1977-03-15 Dennison Manufacturing Company Decorative metal film heat transfer decalcomania
ES465638A1 (en) * 1977-12-30 1978-10-01 Complisa Sa Procedure for the specular metalization of any support in bands and sheets. (Machine-translation by Google Translate, not legally binding)
US4242378A (en) * 1979-03-29 1980-12-30 Reiko Co., Ltd. Method of making a decorated film with a metal layer in the form of a given pattern
US4313994A (en) * 1979-10-24 1982-02-02 Dennison Manufacturing Company Heat transfer labeling

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US4477312A (en) 1984-10-16
DE3026236C2 (en) 1987-02-19
DE3026236A1 (en) 1982-01-28
EP0043989A1 (en) 1982-01-20
US4591527A (en) 1986-05-27
DE3166942D1 (en) 1984-12-06
ATE10073T1 (en) 1984-11-15

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