EP0033988B1 - Procédé pour la préparation d'une nappe fibreuse présentant des motifs de creux ayant des zones de haute densité espacées et qui sont imprégnées avec un liant - Google Patents

Procédé pour la préparation d'une nappe fibreuse présentant des motifs de creux ayant des zones de haute densité espacées et qui sont imprégnées avec un liant Download PDF

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Publication number
EP0033988B1
EP0033988B1 EP81200093A EP81200093A EP0033988B1 EP 0033988 B1 EP0033988 B1 EP 0033988B1 EP 81200093 A EP81200093 A EP 81200093A EP 81200093 A EP81200093 A EP 81200093A EP 0033988 B1 EP0033988 B1 EP 0033988B1
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European Patent Office
Prior art keywords
web
zones
supports
fabric
array
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Expired
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EP81200093A
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German (de)
English (en)
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EP0033988A2 (fr
EP0033988A3 (en
Inventor
Peter Graves Ayers
John Michael Raley
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Procter and Gamble Co
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Procter and Gamble Co
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Priority to AT81200093T priority Critical patent/ATE20365T1/de
Publication of EP0033988A2 publication Critical patent/EP0033988A2/fr
Publication of EP0033988A3 publication Critical patent/EP0033988A3/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02—Patterned paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/006—Making patterned paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/005—Mechanical treatment

Definitions

  • This invention relates to a method of making a soft fibrous web such as paper for paper towels and tissue paper which is reinforced at least in part by binder material.
  • the exemplary patents described below disclose soft, relatively high bulk webs such as paper, and concomitant processes, some of which include pattern applied binder materials such as elastomers for the purpose of strengthening the fibrous webs without making them inordinately inflexible or hard or harsh to feel.
  • US Patent No. 2,958,608 to Kenneth H. Bernard discloses the treatment of a pattern bonded nonwoven fabric by means of a series of pleating and compaction steps to produce a structure in which the unbonded portions are distended to give a durable embossed appearance and soft handle to the treated fabric.
  • US Patent No. 3,301,746 which issued January 31, 1967 to Lawrence H. Sanford and James B. Sisson covers a Process for Forming Absorbent Paper by Imprinting A Fabric Knuckle Pattern Thereon Prior To Drying And Process Thereof. Briefly, a high bulk fibrous web is wet formed and predried to a fibre consistency of from about 30 to about 80 percent by avoiding substantial mechanical compression until the web is predried; then a knuckle pattern of an imprinting fabric is imprinted in the predried web while the remainder remains substantially uncompacted. The web may also be somewhat molded to the surface of the imprinting fabric by differential fluid forces prior to the predrying.
  • US Patent No. 3,812,000 which issued May 21,1974 to J. L. Salvucci et al discloses a Soft, Absorbent, Fibrous, Sheet Material Formed By Avoiding Mechanical Compression Of The Elastomer Containing Fiber Furnish Until The Sheet Is At Least 80% Dry.
  • an elastomeric bonding material is included in the fibre furnish so that it is distributed throughout the finished sheet. Additionally, more such bonding material may be applied to the sheet in a predetermined pattern by a patterned gravure roll while the sheet is being forwarded through a papermachine on a foraminous drying fabric.
  • the pattern is stated to preferably be a reticular hexagonal pattern.
  • Salvucci et al include elastomeric material in a low-bond furnish; predry to a greater extent; and may gravure print a pattern of additional binder material on the web with a patterned gravure roll.
  • Salvucci et al expressly teach away from pattern knuckle compaction as taught by Sanford-Sisson because "the pressures generated by the knuckle pattern of the woven wire are so high as to create hard portions of the web which give a feeling of harshness to the resulting product".
  • US Patent No. 3776807 which issued December 4th 1973 to C. E. Dunning et al discloses an air-laid adhesive bonded web in which the adhesive is printed in a preselected pattern to provide areas of densified fibres extending over 10-40% of the surface area of the web.
  • the unbonded areas of the web have a pillow shaped profile in cross section and are substantially free of binder material, the fibres being of an average length greater than the separation of the densified areas from each other.
  • the problem addressed by the present invention is the provision of a bonded wet-laid densified web to which binder has been applied only in the discrete high fibre density zones wherein the high bulk low density portions of the web are substantially uncompacted.
  • a method of making a pattern densified partially impregnated fibrous web comprises wet forming, without substantial mechanical compression, an embryonic web (20e) having insufficient structural integrity to be self supporting, dewatering said embryonic web, supporting the said embryonic web on an array of spaced supports on an imprinting fabric so that each of a predetermined sub-array of discrete zones of the web and each of a predetermined sub-array of said supports are juxtaposed and imprinting the fabric pattern on the web, to give a pattern densified web formed with an array of discrete zones of high fibre density, and completing the drying of said web, wherein the method comprises deflecting the spans of said embryonic web.
  • the array of spaced supports may be the knuckles of an endless imprinting carrier fabric and the sub-array of such supports may be only the top-surface-plane knuckles of the fabric in fabrics having both top-surface-plane knuckles and sub-top-surface knuckles. In fabrics having no sub-top-surface knuckles the sub-array of supports would in fact be the array of supports.
  • all of the high density zones are impregnated with binder material whereas only some may only be partially impregnated in sheets wherein partial impregnation provides sufficient sheet strength for the intended use of the sheets.
  • Impregnating means such as a full field gravure applicator may be used to impregnate the dense zones of the web biased against it whereas less-than-full-field gravure applicators may be used to only partially impregnate all or some of the dense zones of the web, or wholly impregnate only some of the dense zones.
  • the method may further comprise the step of subjecting the impregnated zones to further mechanical pressure/compaction after they are impregnated to increase the binder penetration and interfibre bonding therein.
  • a fragmentary portion of a microtomed section of a paper sheet made in accordance with the present invention is shown in the photographic Figure 1 to comprise a fibrous web 20 comprising a multiplicity of fibres 21 which are disposed in relatively high density zones 22 and 23, and arcuate-shape relatively low density span portions 24, and in which web the high density zones 22 and 23 are impregnated with a latex fibre binder material 25.
  • the method of the present invention provides a soft, pattern densified fibrous web such as a paper sheet which comprises a relatively low density fibrous field and a multiplicity of relatively high density fibrous zones disposed in a predetermined array, and in which web each of at least a substantial proportion of such dense zones are at least partially impregnated with a binder material of a type which provides interfibre bonds which are preferably substantially more flexible than ordinary inter f ibre hydrogen bonds which occur between cellulosic fibres in ordinary papermaking.
  • the web comprises a principal web-strength fibre constituent comprising fibres of sufficient average length with respect to the spacing of the impregnated high density zones that a substantial fraction of the fibres will have spaced portions thereof disposed in adjacent impregnated dense zones and in overlapping bonded relation with portions of other fibres so that the bonded principal web-strength fibres constitute a strength-skeletal-network of the web.
  • the low density field comprises arcuate-shape spans which are so disposed with respect to the dense zones that the web has a vaulted character.
  • the principal web-strength fibres have average lengths of about 2.0 mm or greater (e.g.
  • the web is characterised by a relatively low degree of interfibre bonding which may be achieved by including debonders in the furnish, or through the use of low bond fibres; and the dense zones preferably are equal in number to the number of imprinting knuckles of an imprinting fabric having a mesh count of from 10-MD/10-CD to 60-MD/60-CD filaments per inch (from 4 by 4 to 24 by 24 machine direction filaments and cross machine direction filaments per centimetre, respectively) and more preferably from 20-MD/20-CD to 50-MD/50-CD filaments per inch (from 8 by 8 to 30 by 20 machine direction filaments and cross machine direction filaments per centimetre, respectively).
  • a web made in accordance with the present invention as described above is preferably made by forming a pattern densified web of fibres of appropriate length, flexibility, and bonding propensity; supporting high density zones of the web on an array of spaced supports which are preferably generally coplanar; deflecting the webs low density span portions out of the plane of the supports; and impregnating at least a substantial proportion of the dense zones.
  • the degree of impregnation and/or bonding may be increased by subjecting the high density zones to mechanical compression after the basic impregnation has been effected.
  • a wet formed embryonic web may be so pattern densified and deflected by a differential fluid pressure while the embryonic web is disposed on an appropriate imprinting carrier fabric as described hereinafter in conjunction with discussing Figure 6; and the impregnating may be effected, for instance, by a pressure biased gravure apparatus as also described hereinafter.
  • the web is also creped, calendered and reeled after being impregnated and dried to further increase its stretch, bulk and softness, and to control its caliper.
  • web 20 and the preferred process for making it in accordance with the present invention are described hereinafter as paper sheet 20 and papermaking processes, respectively, although it is not intended to thereby limit the present invention.
  • FIG 3 is a fragmentary sectional view drawing of a paper sheet 20 made in accordance with the present invention which view is taken along line 3-3 of Figure 2, and which sectional view drawing generally corresponds to the photographic sectional view of Figure 1. That is, paper sheet 20 is shown in Figure 3 to comprise arcuate-shape low density span portions 24 which are alternately spaced by relatively long and short high density zones 22 and 23 respectively, which dense zones are generally planar and are impregnated with binder material 25. As may be seen in Figure 2, a multiplicity of dense zones 22 and 23 are disposed in a predetermined pattern or array on a generally low density field of which portions 24, Figure 3, are representative.
  • FIG 4 is a fragmentary sectional view drawing of a pattern densified paper sheet 20a which generally corresponds with paper sheet 20, Figure 3, except paper sheet 20a is not impregnated with binder material. That is, paper sheet 20a is a pattern densified web which has not had its high density zones impregnated with binder material in accordance with the present invention. Also, the relative fibre density of zones 22a and 23a of unimpregnated sheet 20a is shown to be somewhat less than the fibre density of zones 22 and 23 of sheet 20 because zones 22a and 23a have not been subjected to the mechanical compaction experienced by zones 22 and 23 through the practice of the present invention as hereinbefore described.
  • FIG. 5 is a fragmentary, somewhat schematic side elevational view of an exemplary papermaking machine 30 through the use of which paper sheet embodiments of the present invention can be made and the process of the present invention can be practised.
  • Papermaking machine 30 is a fixed roof former type papermaking machine wherein a fibrous slurry is delivered from a headbox 32 onto a Fourdrinier wire 33 passing over a vacuum type breast roll 34. The Fourdrinier wire then passes over a forming board 35 and suction box 36 and is further looped about turning rolls 41 through 46. The slurry is partially dewatered by the vacuum and table roll action of the breast roll.
  • dewatering is precipitated by forming board 35 and suction box 36 so that an embryonic fibrous web 20e is formed and forwarded on the Fourdrinier wire to a first transfer station generally designated 50 where it is transferred from Fourdrinier wire 33 to an endless intermediate carrier fabric 51 which partially wraps roll 42, passes over suction boxes 52 and 53, then over vacuum transfer box 54, and then is looped about rolls 55, 56, 57 and 58.
  • Dewatering is furthered as the embryonic web 20e is forwarded in sandwiched relation between Fourdrinier wire 33 and fabric 51 past suction boxes 52 and 53, and then over a portion of vacuum transfer box 54 after which the embryonic web 20e is disposed and forwarded on fabric 51 to an endless imprinting carrier fabric 59 at a second transfer station designated 60.
  • embryonic web 20e is transferred by the action of vacuum transfer box 61 from the intermediate carrier fabric 51 to the imprinting carrier fabric 59 which is looped past/about suction box 62, turning roll 63, below through predryer 64, impregnating means 65, turning roll 66, pressure roll 67, turning roll 68, showers 69, suction box 70, and turning rolls 71 and 72.
  • formation of the web continues due to the differential fluid pressure applied to the web to effect the second transfer and fibre mobility enabled by a sufficiently high water content (preferably a fibre consistency of 30 percent or less), the embryonic web becomes pattern densified with dense zones of fibres juxtaposed the knuckles of the imprinting carrier fabric 59.
  • the embryonic web After being transferred to the imprinting carrier fabric 59, the embryonic web is further dewatered by suction box 62 and blow through predryer 64; then partially impregnated with binder material 25 by pressure biased impregnating means 65; and then transferred to Yankee dryer 75 by the action of pressure roll 67 which is biased towards the Yankee dryer by biasing means 76. Transfer of the web to the Yankee dryer and adherence thereto is enabled by creping adhesive applied through applicator 77. Finally, upon being fully dried on the Yankee dryer, the transformation of embryonic web 20e to paper sheet 20 is completed as the final drying thereof is effected and, preferably, it is creped from the Yankee dryer by the action of doctor blade 78.
  • the paper sheet 20 is then calendered and reeled to control its caliper and enable its subsequent conversion from reels into paper products such as paper towels, toilet and facial tissue paper.
  • the binder material requires curing, such curing may be effected at least in part after the paper sheet has been removed from the papermaking machine.
  • FIG. 6 is a plan view of the top, outwardly facing surface of an exemplary imprinting carrier fabric 59 which may be used on a papermaking machine such as papermaking machine 30, Figure 5, to practise the present invention.
  • Fabric 59 is a five-shed satin weave of polyester monofilaments which were woven using a 1, 4, 2, 5, 3 warp pick sequence and wherein the filaments 90-1 through 90-5 which extend in the machine direction, MD, alternatively pass over four and under one of the filaments 91-1 through 91-5 which extend in the cross machine direction, CD, and wherein the CD filaments alternately pass over one and under four MD filaments.
  • Fabric 59 has been stressed, heat set, and sanded to provide coplanar sets of long MD imprinting knuckles 92, and relatively short 1-over CD imprinting knuckles 93.
  • the outwardly facing surfaces of coplanar sets of knuckles 92 and 93 corporately define a top-surface-plane of fabric 59.
  • Fabric 59 also has adjacent pairs of sub-top-surface filament crossovers designated 94 which, by virtue of the weave, stressing, and heat setting are recessed below the top-surface-plane of the fabric.
  • Such a fabric is described more fully in Trokhan US Patent No. 4,329,065 issued December 16, 1980.
  • such a fabric is particularly useful for making soft and absorbent imprinted paper having uncompressed portions circumscribed by picket-like lineaments of alternately spaced areas of compacted fibres and non-compacted fibres which compacted fibre areas or zones are precipitated by imprinting the top-surface-plane knuckles of the fabric into a relatively uncompacted, low density, high bulk paper sheet.
  • This is more fully described in the commonly assigned Trokhan US Patent 4,191,609 issued March 4, 1980. While the 5-speed fabric 59, Figure 5, has been described above as exemplary with respect to the present invention it is not intended to thereby limit the present invention to any particular fabric weave, or knuckle geometry or disposition.
  • Impregnating means 65 comprises rotagravure cylinder 81, backing roll 82, biasing means 83, and reservoir 85 which is adapted by means not shown to maintain a relatively constant predetermined level of liquid impregnating material 25 therein. This level insures that a downwardly facing arcuate portion of rotagravure cylinder 81 is immersed in the impregnating material. Doctor means, not shown, are provided for removing the excess impregnating material from the rotagravure cylinder as it rotates upwardly towards the travelling embryonic web.
  • Synchronous drive means may also be provided as needed to obviate deleterious drag on the embryonic web as it passes through the nip between rotagravure cylinder 81 and backing roll 82.
  • impregnating means 65 of papermaking machine 30 is a gravure type applicator, it is not intended to thereby limit the present invention to gravure applicators or impregnators. Rather, it is believed that other contacting type applicators such as, for instance, foam applicators may be used to practise the present invention.
  • FIG 7 is an enlarged scale, radially inwardly looking view of a fragmentary portion of an exemplary rotagravure cylinder 81 which has its cylindrical surface covered by a partially peeled back, opaque mask 96 which is apertured in the top-surface-plane knuckle pattern of imprinting carrier fabric 59, Figure 6. That is, apertures 92a and 93a in mask 96 are sized and disposed in the image of the top-surface-plane knuckle pattern of fabric 59, Figure 6.
  • the entire gravure surface of rotagravure cylinder 81 is defined by a full field pattern of truncated pyramidal cavities or reservoirs 100.
  • the area of the web which becomes impregnated may in fact be substantially larger than the sanded areas of knuckles 92 and 93 because the filaments of the woven fabric 59 gradually slope away from the sanded areas of the knuckles and thus cause web portions contiguous thereto to be impregnated along with the web portions immediately juxtaposed the sanded areas of the knuckles.
  • the absence of biasing of the unsupported span portions of the embryonic web substantially obviates transfer of binding material thereto from rotagravure cylinder 81.
  • displacement of the unsupported span portions into the interfilamentary spaces of the imprinting fabric may be effected to virtually totally obviate their being impregnated by rotagravure cylinder 81.
  • Figures 8 through 12 are similar to Figure 7 except the alternate embodiment rotagravure cylinders 81 a through 81e of Figures 8 through 12, respectively, are provided with less-than-full-field checkerboard type patterns of reservoirs 100 which reservoirs cover 75, 50, 50, 50 and 25 percent, respectively, of the working surfaces of cylinders 81a, 81b, 81c, 81d and 81e.
  • less-than-full-field patterned rotagravure cylinders will coat with a patterned imprinting fabric to apply impregnating material to only the surface portions of an embryonic web which are in registered relation with top-surface-plane knuckles and adjacent reservoir portions of the rotagravure cylinder pattern.
  • Such patterned cylinders are useful with respect to providing various degrees of web strength through binder impregnation while preserving various complementary degrees of binder-free surface areas. Thus, strength may be increased by impregnating larger percentages of web surface area.
  • less-than-full-field, rotagravure cylinders 81 a through 81 have relatively small checkerboard-type patterns with respect to the knuckle pattern of fabric 59
  • Figure 6 less-than-full-field patterns (not shown) having larger open (non-printing/non-impregnating) areas may be used to assure not impregnating a substantial proportion of the dense zones as well as concurrently assuring that a substantial proportion of the dense zones will be impregnated.
  • creping adhesive e.g. polyvinyl alcohol applied by spray applicators 77, Figure 5
  • the proportion of binder impregnated zones is maintained great enough to provide adequate web strength while the proportion of non-binder-impregnated zones is made great -enough to enable the creping adhesive to securely affix those zones to the Yankee dryer (creping cylinder) to control the web and the creping thereof in substantially the manner disclosed in the hereinbefore referenced Sanford-Sisson patent.
  • Figure 13 is a somewhat schematic side elevational view of a handsheet impregnating apparatus 106 which comprises rotatably mounted, rubber covered rolls 107 and 108, a slanted feed plate 109, a horizontal feed plate 110, and a receiving plate 111. Means not shown are provided to pressure bias rolls 107 and 108 together, and to synchronously rotate rolls 107 and 108 in the directions indicated by the arrows drawn thereon.
  • Figure 14 is a fragmentary enlarged scale view of the nip portion of apparatus 106, Figure 13, which view shows fragmentary sections of rolls 107 and 108, a gravure plate 115, and a paper handsheet 116 disposed on the under side of an imprinting carrier fabric 117.
  • Figure 15 is substantially identical to Figure 14 except the handsheet 116 in Figure 15 is self-supported, i.e. not disposed on an imprinting carrier fabric.
  • a gravure plate 115 is placed on plate 110 with its pattern side up and with its cells filled with binder material. Then, a handsheet 116 is placed on plate 109. Handsheet 116 may be associated with an imprinting carrier fabric 117 as indicated in Figure 14, or not so associated as indicated by the absence of such a fabric 117 from Figure 15. Then, rolls 107 and 108 are biased together with a predetermined force and rotated synchronously while the handsheet 116 and the gravure plate 115 are simultaneously moved so that their leading edges enter the nip between the rolls. Thus, as the handsheet and gravure plate pass through the nip, the handsheet becomes impregnated.
  • the pattern of web impregnation is the knuckle pattern of the fabric when a full field gravure plate is used. Therefore, when the handsheet has been pattern densified by formation on an imprinting carrier fabric so that the dense zones of the handsheet are juxtaposed the knuckles of the imprinting carrier fabric, only the dense zones of the handsheet become impregnated by a full field gravure plate through the use of handsheet impregnating apparatus 106.
  • an embryonic web 20e is preferably formed and forwarded without subjecting it to substantial mechanical compaction until it reaches the impregnating means 65.
  • a principal web-strength fibre constituent in the furnish which constituent consists of fibres having a predetermined average length relation with respect to the knuckle pattern of the imprinting carrier fabric 59, and by controlling dewatering a pattern densified embryonic web may be formed in which web relatively high fibre density zones are juxtaposed the outwardly facing knuckles of imprinting carrier fabric 59, and in which web the remaining portions which are unsupported and span the spaces between the knuckles have relatively low fibre density.
  • the unsupported spans are also acted on by sufficient differential fluid pressure while the web is at a sufficiently low fibre consistency to sufficiently displace the unsupported spans into the interfilamentary spaces between the knuckles of the imprinting carrier fabric to obviate their being impregnated by impregnating means 65 although it is not intended to thereby limit the present invention.
  • the embryonic web is preferably predried to from about 30 to about 95 percent fibre consistency and more preferably to from about 60 to about 90 percent fibre consistency prior to being impregnated. Also, preferably the drying is sufficiently asymmetrical to dry the unsupported portions of the web substantially more than the dense portions.
  • This may be effected, for instance, by blow through predrying of the web while it is disposed on the imprinting carrier fabric of papermaking machine 30.
  • This enhances the Z-direction penetration of the binder material through the thickness of the web and lessens the propensity of the binder material to migrate laterally in the X-Y directions into the low density portions of the web.
  • Such X-Y migration into the low density portions of the web from the high density zones is further inhibited due to their relative capillary structures: i.e. normally capillary flow is greater from low density to high density zones than from high density to low density zones.
  • the biasing In addition to the impregnation of the high density zones which is effected as the web is carried on the imprinting carrier fabric 59 through the pressure biased impregnating means 65, Figure 5, the biasing also precipitates some compaction of and bonding within the high density zones of the web. Subsequently; as the high density zones of the web are again subjected to knuckle pressure between pressure roll 67 and Yankee dryer 75, the penetration of the binder is enhanced, and the degree of compaction and bonding within the high density zones is increased.
  • handsheet examples evidence the benefits of impregnating only dense zones of a pattern densified paper sheet in accordance with the present invention
  • papermaking machine examples evidence the benefit of subjecting impregnated high density zones to further mechanical pressure after the impregnating, and the benefits which may be derived from the present invention through the use of different impregnating materials.
  • a pattern densified, one foot square (30 cm square) handsheet having a basis weight of 16.5 pounds per 3000 square feet (27 grams per square metre) was formed from a fibrous furnish on a foraminous polyester fabric of the 5-shed satin weave shown in Figure 6 and having a 36-MD/32-CD filaments per inch (14-MD by 12.6-CD filaments per centimetre) mesh count.
  • the furnish comprised 60 percent by fibre weight of Tongacel (registered trademark of Louisiana Pacific Corporation) K 324N, a relatively low bond, long fibre, post bleach cold caustic extracted dissolving grade Northern Softwood Sulfite which is available from Louisiana Pacific Corporation, and 40 percent by fibre weight of relatively long softwood fibres which were obtained from the Buckeye Cellulose Corporation under the designation Grand Prairie Prime, a Northern Softwood Kraft.
  • the handsheet was further dewatered by pulling the fabric with the handsheet disposed thereon over a vacuum slot having 10 inches (25.4 centimetres) of mercury vacuum applied thereto. The handsheet was then dried on a can type dryer while still disposed on the fabric and in its original relation thereto.
  • the dried handsheet was then impregnated in its zones juxtaposed the top-surface-plane knuckles of the fabric by passing the fabric/sheet combination and a full-field gravure plate through the handsheet impregnating apparatus 106 as indicated in the enlarged scale Figure 14 and as hereinbefore described.
  • the latex binder comprised a 25 percent solids, self-crosslinking acrylic latex emulsion which was obtained from Rohm and Haas Company, Philadelphia, Pennsylvania, and which was designated TR-520.
  • the latex binder further comprised ammonium nitrate (NH,N03), a latent acid catalyst, in the amount of 0.5 percent by weight of latex solids; Pluronic L-92 of 1.0 percent by weight of latex solids, which is a nonionic surfactant sold by BASF Wyandotte Corporation, Parsippany, New Jersey, and which was added to serve as a finished product wetting agent; ammonium hydroxide (NH 4 0H) in sufficient amount to raise the pH of the binder solution to 5.0; Lithium Acetate (CH 3 CO 2 Li) in the amount of 200 ppm Lithium based on the weight of latex solids to serve as a tracer to facilitate analysis of samples to ascertain their latex content; and an anionic water soluble dye was added to allow visual inspection of the impregnation pattern.
  • the gravure plate was etched to provide a full field of reservoirs which numbered 22,500 reservoirs per square inch (3500 reservoirs per square centimetre) and the corporate volume of the reservoir
  • Handsheet Example 2 was a replicate of Handsheet Example 1 insofar as variables in the making thereof permitted.
  • Handsheet Example 3 was prepared like Handsheet Examples 1 and 2 except for Number 3 the etched, full field gravure pattern comprised 40,000 reservoirs per square inch (6200 reservoirs per square centimetre), and the corporate volume of the reservoirs was 2.2 microlitres per square centimetre.
  • Handsheet Example 4 was prepared like Handsheet Example 1 except that after it was dried on its forming fabric it was removed therefrom, rotated 90 degrees with respect thereto, and reassociated therewith with adhesive tape.
  • the pattern of the zone densified handsheet was placed out of registration with the knuckle pattern of the fabric prior to impregnation so that comparative data could be obtained with respect to out-of-registration impregnation (Handsheet Example 4) versus in-registration impregnation (Handsheet Examples 1, 2 and 3) of pattern densified fibrous webs.
  • Handsheet Example 5 was prepared like Handsheet Example 4 except, prior to impregnation, the densified structure of the handsheet was placed out of registration with the knuckle pattern of the fabric by removing the handsheet from the fabric and turning the handsheet over prior to reassociating it with the fabric with adhesive tape.
  • This handsheet provided further out-of-registration-impregnation data which is tabulated along with the corresponding data from Handsheet Examples 1 through 4 in Table I.
  • Handsheet Examples 1 through 5 were pattern densified during their formation on relatively coarse 36x32 mesh fabrics of the 5-shed satin weave shown in Figure 6, Handsheet Example 6 was formed with relatively uniform density on a relatively fine mesh fabric having 110x95, MDxCD filaments per inch (43x37, MDxCD filaments per centimetre), and woven with a 4-shed satin weave using a 1, 2, 3, 4 warp pick sequence. But for the difference forming fabrics, Handsheet Example 6 was made and dried in the same manner and of the same furnish as Handsheet Example 1.
  • the relatively fine mesh 4-shed satin weave fabric described above is much smoother than the relatively coarse 5-shed fabric shown in Figure 6, and because the fibres of the furnish were very long with respect to the knuckle-to-knuckle span of the 110x95, 4-shed as compared to the coarser 36x32, 5-shed fabric, the handsheet formed on the 4-shed was relatively uniformly dense as compared to the pattern densified Handsheet Examples 1 througho, inclusive. But, it is not intended to thereby imply that pattern densified sheets cannot be formed on fine mesh fabrics such as the 4-shed satin weave described above.
  • Handsheet Example 6 was removed from the 110x95 forming fabric and taped onto a 36x32 mesh, 5-shed fabric identical to those used for Handsheet Examples 1 through 5 prior to being impregnated by passing it through handsheet impregnating apparatus 106 in the manner indicated in Figure 14.
  • the gravure plate and the latex binder composition were also the same for Handsheet Example 6 as for Handsheet Examples 1, 2, 4 and 5.
  • Handsheet Example 6 was a pattern impregnated sheet of relatively uniform density which yielded data which is also tabulated in Table I for conveniently comparing the pattern densified/pattern impregnated Handsheet Examples 1 through 3 made in accordance with the present invention with the uniform density/pattern impregnated Handsheet Example 6.
  • the Handsheet Examples 1 through 3 made in accordance with the present invention clearly have superior (lower) bending modulus (i.e. greater flexibility) as compared to the out-of-registration impregnated/pattern densified Handsheet Examples 4 and 5, and as compared to the pattern impregnated/uniform density Handsheet Example 6.
  • This handsheet was of relatively uniform density and was formed, dewatered and dried substantially identically to Handsheet Example 6 using the same furnish as for Handsheet Examples 1 through 8.
  • Handsheet Example 6 was impregnated by a full-field gravure plate while backed by a 36x32 5-shed fabric in the manner shown in Figure 14
  • Handsheet Example 9 was impregnated in the manner shown in Figure 15; that is, not backed by a fabric.
  • the gravure plate 115 was prepared with a pattern identical in size and geometry to the top-surface-plane knuckles of a 36x32 5-shed fabric, Figure 6.
  • the gravure pattern comprised 22,500 reservoirs per square inch of reservoirs (3500 reservoirs per square centimetre of reservoirs) and was derived from a 150x 150 lines per inch (59x59 lines per centimetre) screen which was superimposed on a knuckle-pattern print made from the 36x32 5-shed fabric 59, Figure 6, to make a negative which was then used in producing an acid etched gravure plate. Therefore, the uniform density Handsheet Example 9 was pattern impregnated in the same pattern as Handsheet Examples 7 and 8.
  • Handsheet Example 9 was of uniform density, i.e. having no dense zones.
  • a papermaking machine of the general configuration as papermaking machine 30, Figure 5 was run to produce two families of samples during which run: the percent of latex solids in the binder emulsion in reservoir 85 was incremented from 10 to 25 and then to 40 percent; the after predryer (APD) fibre consistency was varied from about 68 percent to about 91 percent; and samples were taken from adjacent the doctor blade 78 which samples had about zero crepe, and from intermediate roll 66 and pressure roll 67.
  • the former samples are designated Pressed Samples, and the latter samples are designated Unpressed Samples; and pairs of samples are designated by pair numbers which pairs each comprise a Pressed Sample and an Unpressed Sample.
  • Example 10 The samples of Example 10 were made on a papermaking machine of the general geometry of machine 30, Figure 5, using the 60 percent Tongacel/40 percent Grand Prairie Prime (low bond/kraft softwood fibres, respectively), long fibre furnish as used to make Handsheet Examples 1 through 9 described above. This furnish was chosen to produce, if not impregnated in accordance with the present invention, a weak web with less than 59 grams per cm total tensile strength (the sum of the machine direction tensile strength plus the cross machine direction strength). A 0.12 percent fibre consistency pulp slurry of this furnish was distributed on a Fourdrinier wire 33 of a 4-shed satin weave having a 78x60, MDxCD filament mesh count per inch (31 by 24 filaments per centimetre).
  • Dewatering was progressively effected while the web was being forwarded on the 78x60 Fourdrinier wire, and then on intermediate carrier wire 51 of the same mesh, weave, and material as the Fourdrinier wire to increase the fibre consistency of the web to about 22 percent prior to being transferred to the imprinting carrier fabric 59 which was a 5-shed satin weave of the type shown in Figure 6 and having 31 x25, MDxCD filaments per inch (12x10 filaments per centimetre). Further dewatering was precipitated by vacuum transfer box 61 and the triple vacuum box 62 to provide a fibre consistency of about 32 percent.
  • the binder material used to impregnate the samples of Example 10 was the same latex emulsion as for the hereinbefore described handsheets except: the percent solids was incremented from 10 to 25 and then to 40 percent; and very low levels of commercial defoamers (Foammaster 160L and Colloid 694) were added to suppress foaming of the latex emulsion 25 in reservoir 85 as cylinder 81 rotated therethrough and the excess latex was doctored therefrom.
  • Foammaster 160L was obtained from Diamond Shamrock Corporation, Cleveland, Ohio, and Colloid 694 was obtained from Colloids Inc, Newark, New Jersey.
  • backing roll 82 was an 80 Shore A Durometer rubber covered roll; and pressure roll 67 was an 85 Shore A Durometer rubber covered roll.
  • Roll 82 was biased towards cylinder 81 with a force of about 20 pounds per lineal inch (3.5 kilograms per lineal centimetre); and pressure roll 67 was biased towards Yankee cylinder 75 at 440 pounds per lineal inch (78 kilograms per lineal centimetre).
  • the creping adhesive which was applied to Yankee dryer 75 via spray applicators 77 to enable creping was Gelvatol 20-90; a polyvinyl alcohol/acetate manufacture by Monsanto Co, St Louis, Missouri.
  • Example 10 After being creped from the Yankee dryer 75 by doctor blade 78, the paper web from which the pressed samples were taken was reeled at the same speed as the Yankee; thus the samples exhibited virtually zero residual crepe so that residual crepe would not be a substantial difference between the pressed samples and the unpressed samples which were obtained as follows.
  • the unpressed samples of Example 10 were obtained by pressing a sheet width, adhesive coated, rotatably mounted spool against the web on fabric 59 running from roll 66 towards pressure roll 67 to accumulate sufficient web on the spool to run samples thereof which were not adulterated by the adhesive on the spool.
  • the samples were tested to obtain the Tables Illa and IlIb data after being cured for 5 minutes at 300°F (150°C).
  • post-impregnation pressing as described hereinbefore precipitates improved wet tensile strength; and greater wet tensile strength for a 25 percent level of solids in a latex binder emulsion than for either a 10 percent or 40 percent level of solids.
  • post-impregnation pressing also generally improves the ratio of total wet strength to total dry strength of the paper which is generally regarded as a performance parameter for paper towels and the like
  • Examples 11 and 12 were made using low bond Tongacel, described hereinbefore, in the furnishes to provide low bond webs, and the process conditions were so controlled that the webs were pattern densified when fully formed, and then impregnated with binder material in their dense zones to enhance both their wet and dry strengths: a latex emulsion binder for Example 11 and a polymeric solution type binder for Example 12.
  • Example 11 was made from the same 60% Tongacel/40% Northern Softwood Kraft and in the same manner as Example 10 except for a relatively constant APD fibre consistency of 78 percent; and except for the latex binder having 40 percent solids and containing no lithium tracer or dye. After the paper web was creped and doctored from the Yankee dryer, Example 11 was calendered by a rubber/steel calender roll pair at 58 pounds per square inch (400 kPa) and reeled at a speed of 75 percent of the Yankee to provide a relatively high degree of residual crepe.
  • Example 12 was also made on a papermaking machine of the same general geometry as machine 30, Figure 5, except, a three chamber divided headbox (not shown) was used to deliver two types of fibre slurries onto the Fourdrinier wiere 33 in superposed relation.
  • the first-down slurry juxtaposed the Fourdrinier wire was identical to the low bonding pulp slurry of Tongacel/Northern Softwood Kraft which was used to make Examples 10 and 11, and was issued from the bottom chamber of the headbox at a fibre consistency of 0.20 percent.
  • Northern Softwood Kraft slurries were simultaneously issued from both the centre and top headbox chambers at a fibre consistency of 0.12 percent.
  • the Fourdrinier wire 33, and intermediate carrier fabric 51 were the same 78x60 mesh and weave, respectively, as used for Examples 10 and 11.
  • the imprinting carrier fabric 59 was the same 36x32, 5-shed mesh and weave as used for Handsheet Example 1. Fibre consistency was 13 percent prior to transfer to fabric 59; 29 percent before predryer (BPD); and 96
  • the binder used for Example 12 was a 10 percent solution of Parez 631 NC, a papermaking wet strength resin sold by American Cyanamid Company, Wayne, New Jersey. This is believed to be a reaction product of glyoxal with a copolymer of dialkyl dimethyl ammonium chloride and acrylamide.
  • Example 12 The rotagravure cylinder used for Example 12 was the same as for Examples 10 and 11; and the web was finished, creped, calendered, reeled, converted to 2-ply paper towels, and tested to the same degree and in the same manner as Example 11 except both plies were oriented to place their low bond layers on the outside of the structure.
  • Table IV The resulting data are tabulated in Table IV.
  • Example 13 was formed as a 3-layer structure using the 3-compartment headbox described above and in the same general manner in the same papermaking machine as Example 12.
  • the three layers consisted of Champion Eucalyptus on the top and bottom and Grand Prairie Prime Northern Softwood Kraft in the middle.
  • the Champion Eucalyptus was obtained from Champion International Corporation, Stamford, Connecticut. All pulps were at 0.13 percent consistency when distributed at three equal basis weights to produce a web on the machine of 17.7 pounds per 3000 square feet (28.9 grams per square metre) basis weight.
  • the kraft layer was made from low bonding pulp furnish which had Quaker 2003 (a stearyl imidazoline made by Quaker Chemical Company, Conshohocken, Pennsylvania) added at a level of about 0.25 weight percent of the kraft.
  • the web was initially formed on the same 78x60 Fourdrinier wire used for Examples 10, 11 and 12, and subsequently transferred and dewatered as generally described with respect to those Examples.
  • the imprinting carrier fabric was a 3-shed semi-twill having a mesh count of 31 x25, MDxCD filaments/inch (12x10, MDxCD filaments/cm) and was treated to provide imprinting knuckles as described in US Patent No. 3,905,863 which issued September 16, 1975 to P. G. Ayers.
  • the latex binder used was Airflex 402 which was obtained from Air Products and Chemicals Inc, Allentown, Pennsylvania; a dry strength vinyl-acetate ethylene emulsion. This was adjusted to have a 5% level of solids, and applied by the same rotagravure cylinder of Example 10.
  • the impregnated web, still disposed on and in register with the 31 x25 imprinting carrier fabric, was then pressed at 440 p.l.i. (78 kilograms per lineal centimetre) against the Yankee dryer, using a rubber covered pressure roll with a Shore A Durometer hardness of 85 loaded against the dryer to imprint the knuckle pattern of the fabric into the web and thereby compact the dense zones thereof.
  • Gelvatol 20-90 polyvinyl alcohol/acetate manufactured by Monsanto was applied to the Yankee dryer upstream from the pressure roll to adhere the web to the Yankee and allow creping at the doctor blade after the web was dried.
  • the web was then run through a rubber roll/steel roll papermaking calendering nip at a light load and wound up on a reel at 82% of the Yankee speed.
  • the reels of paper thus obtained were rewound and slit into standard toilet tissue rolls and tested.
  • the test data was tabulated in Table IV.

Claims (10)

1. Procédé de fabrication d'une nappe fibreuse partiellement imprégnée densifiée selon un motif, ce procédé comprenant la formation à l'état humide sans compression mécanique substantielle d'une nappe embryonnaire (20e) ayant une intégrité structurelle insuffisante pour être autoporteuse, l'égouttage de la dite nappe embryonnaire, le soutien de la dite nappe embryonnaire (20e) sur un réseau de supports espacés (92, 93, 94) sur un tissu d'impression (59) de telle sorte que chacun des sous-réseaux prédéterminés de zones discrètes (22, 23) de la nappe (20e) et chacun des sous-réseaux prédéterminés (92, 93) des dits supports soient juxtaposés et l'impression du motif du tissu sur la nappe (20e), pour donner une nappe densifiée selon un dessin (20) formée d'un réseau de zones discrètes (22, 23) de haute densité fibreuse, et l'achèvement du séchage de la dite nappe, caractérisé en ce que le procédé comprend le fléchissement des portées de la dite nappe embryonnaire disposées entre les dits supports espacés dans les espaces disposés entre les dits supports pour former une multiplicité de portées cintrées (24), l'inclinaison du sous-réseau prédéterminé (92, 93) des dits supports vers un dispositif d'imprégnation du type à contact (81 ), le dit sous-réseau des dites zones (22, 23) étant disposé entre le dit sous-réseau des dits supports (92, 93) et le dit dispositif d'imprégnation (81) et l'imprégnation au moins partielle d'au moins une proportion substantielle de sous-réseau prédéterminé des dites zones (22, 23) avec un matériau liant (25), les dites portées cintrées (24) de la dite nappe étant fléchies suffisamment pour éviter essentiellement une imprégnation des dites portées avec le dit matériau de liant.
2. Procédé selon la revendication 1, dans lequel les dits supports (92, 93, 94) comprennent des protubérances tournées vers l'extérieur d'une boucle d'un tissu support d'impression (59), le dit tissu ayant des mailles dans la gamme de 4-SM/4-ST à 24-SM/24-ST filaments par centimètre, de préférence de 8-SM/8-ST à 20-SM/20-ST filaments par centimère.
3. Procédé selon l'une quelconque des revendications 1 et 2, dans lequel la dite nappe comprend un constituant principal des fibres fibreux, résistant à l'état humide, de longueur moyenne suffisante par rapport à l'espacement des dits supports constituant le dit sous-réseau prédéterminé des dits supports pour qu'après la formation de la dite nappe une fraction substantielle des dites fibres comporte des portions de ces fibres espacées disposées sur des supports adjacents du dit sous-réseau des dits supports et en relation de recouvrement avec des portions d'autres fibres, les dites fibres constituant un réseau fondamental solide de la dite nappe où les dites portions des dites fibres qui se recouvrent sont soudées les unes aux autres.
4. Procédé selon l'une quelconque des revendications 1-3, dans lequel la pulpe fibreuse aqueuse utilisée pour former la nappe comprend un chargement fibreux de propension au soudage interfibres inhérent suffisamment faible pour que la dite nappe fibreuse embryonnaire ait une intégrité structurelle insuffisante pour être autoporteuse pendant qu'elle est imprégnée avec le dit matériau de liant.
5. Procédé selon l'une quelconque des revendications 1-4, caractérisé en ce qu'il comprend l'étape de séchage de la dite nappe embryonnaire en l'absence d'une compression mécanique substantielle jusqu'à une consistance fibreuse de 30 à 95 pour cent, de préférence de 60 à 90 pour cent, avant la dite imprégnation.
6. Procédé selon la revendication 5, caractérisé en ce que le dit séchage est effectué de telle manière que les portées non supportées (24) de la dite nappe embryonnaire (20e) soient séchées essentiellement plus que les dites zones supportées (22, 23) de la dite nappe embryonnaire (20e).
7. Procédé selon la révendication 6, dans lequel le dit séchage est effectué par soufflage à travers un dispositif de séchage pendant que la dite nappe est supportée sur les dits supports.
8. Procédé selon l'une quelconque des revendications 1-7, dans lequel le fléchissement des portées de la dite nappe embryonnaire est effectué en appliquant une pression de fluide différentielle sur la dite nappe supportée.
9. Procédé selon l'une quelconque des revendications 1-8, caractérisé en ce qu'il comprend l'étape supplémentaire qui consiste à soumettre les dites zones supportées à une compression mécanique substantielle après avoir effectué la dite imprégnation.
10. Procédé selon l'une quelconque des revendications 1-9, caractérisé en ce que le dit sous-réseau prédéterminé des dits supports (92, 93) co-agit avec un motif d'imprégnation (92a, 93a) du dit dispositif d'imprégnation (81) de telle sorte que le dit matériau d'imprégnation (25) soit appliqué seulement aux portions des dites zones disposées entre des surfaces repérées du dit sous-réseau prédéterminé (92, 93) des dits supports et le dit motif d'imprégnation (92a, 93a) pendant la dite imprégnation.
EP81200093A 1980-02-04 1981-01-26 Procédé pour la préparation d'une nappe fibreuse présentant des motifs de creux ayant des zones de haute densité espacées et qui sont imprégnées avec un liant Expired EP0033988B1 (fr)

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AT81200093T ATE20365T1 (de) 1980-02-04 1981-01-26 Verfahren zur herstellung eines durch verdichtung gemustertes faservlies mit getrennten, mit bindemittel getraenkten stellen hoher dichte.

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US11792880A 1980-02-04 1980-02-04
US117928 1980-02-04

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DE (1) DE3174791D1 (fr)
ES (1) ES499051A0 (fr)
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US9915033B2 (en) 2013-08-28 2018-03-13 Kimberly-Clark Worldwide, Inc. Smooth bulky tissue
US10040265B2 (en) 2015-03-31 2018-08-07 Kimberly-Clark Worldwide, Inc. Smooth and bulky rolled tissue products
US10814579B2 (en) 2015-03-31 2020-10-27 Kimberly-Clark Worldwide, Inc. Smooth and bulky rolled tissue products
US11548258B2 (en) 2015-03-31 2023-01-10 Kimberly-Clark Worldwide, Inc. Smooth and bulky rolled tissue products

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CA1155007A (fr) 1983-10-11
IE810209L (en) 1981-08-04
EP0033988A2 (fr) 1981-08-19
ES8205908A1 (es) 1982-07-01
JPS56159400A (en) 1981-12-08
DE3174791D1 (en) 1986-07-17
IE51743B1 (en) 1987-03-18
GR72141B (fr) 1983-09-20
ES499051A0 (es) 1982-07-01
ATE20365T1 (de) 1986-06-15
EP0033988A3 (en) 1981-09-16

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