EP0030060B1 - Procédé et dispositif d'automatisation d'un cycle de dégazage sous vide d'alliages d'aluminium - Google Patents
Procédé et dispositif d'automatisation d'un cycle de dégazage sous vide d'alliages d'aluminium Download PDFInfo
- Publication number
- EP0030060B1 EP0030060B1 EP80201114A EP80201114A EP0030060B1 EP 0030060 B1 EP0030060 B1 EP 0030060B1 EP 80201114 A EP80201114 A EP 80201114A EP 80201114 A EP80201114 A EP 80201114A EP 0030060 B1 EP0030060 B1 EP 0030060B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- partial pressure
- degassing
- degasification
- vacuum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 9
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 8
- 238000009849 vacuum degassing Methods 0.000 title description 6
- 238000007872 degassing Methods 0.000 claims abstract description 33
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 20
- 239000000956 alloy Substances 0.000 claims abstract description 20
- 230000001105 regulatory effect Effects 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 20
- 238000012360 testing method Methods 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims 1
- 238000011835 investigation Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 19
- 239000002184 metal Substances 0.000 abstract description 19
- 230000015654 memory Effects 0.000 abstract description 4
- 238000005266 casting Methods 0.000 abstract 1
- 229910001092 metal group alloy Inorganic materials 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
- 230000001960 triggered effect Effects 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000005587 bubbling Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910000676 Si alloy Inorganic materials 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001508691 Martes zibellina Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002601 radiography Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/068—Obtaining aluminium refining handling in vacuum
Definitions
- the present invention relates to vacuum degassing of aluminum alloys and its regulation.
- the first bubble method is used, which only applies at the start of degassing because then the bubbles are released under an oxide plane and can no longer be observed. This process therefore consists in observing a posteriori that the degassing operation has ended and does not allow this operation to be directed according to its measured evolution.
- the device for implementing the above method comprises a sealed oven, a crucible containing the degassing alloy and a source of vacuum, and is characterized in that it further comprises a pilot regulating an interposed valve between the vacuum source and the sealed oven containing the crucible with the alloy to be degassed, a hydrogen metering electrode immersed in the alloy and connected to a partial hydrogen pressure recorder itself connected to the pilot, pilot comprising an input-output assembly allowing the introduction of the values of the parameters, a computer assembly, and a memory assembly where the values of the corresponding parameters of the optimal curves are stored.
- Figure 1 showing the degassing diagram according to the invention
- Figure 2 illustrating an embodiment of the invention
- Figure 3 illustrating the principle of regulation
- Figure 4 showing a stepped plate.
- This phenomenon would also cause the disappearance of the sodium introduced to ensure the modification of the shape of the silicon of the alloy in the case of silicon alloys.
- the pilot can receive his information from several vacuum furnaces and regulate it like the first from the automated valves 24, 25, etc.
- the enclosure is provided with a glass cover 28 through which the solidification can be followed.
- the plaque is examined by radiography. A satisfactory metal must lead with an AS7606 alloy for example to microporosities: a possible degradation of the modification of the silicon which should only appear in the 20 mm step.
- the mechanical characteristics of the different steps are also compared to the profiles of the curves. The optimal curves to be stored for the different alloys can be determined for example by these tests.
- the furnace can be supplied with metal from the melting furnace by pump, electromagnetic for example. Likewise for the evacuation of the metal after degassing under vacuum, for example to the crucible of a low-pressure machine.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT80201114T ATE28481T1 (de) | 1979-11-28 | 1980-11-19 | Verfahren und vorrichtung zur automatisierung eines vakuumentgasungsverfahrens bei aluminiumlegierungen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7929226A FR2472615A1 (fr) | 1979-11-28 | 1979-11-28 | Procede et dispositif d'automatisation d'un cycle de degazage sous vide d'alliages d'aluminium |
| FR7929226 | 1979-11-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0030060A1 EP0030060A1 (fr) | 1981-06-10 |
| EP0030060B1 true EP0030060B1 (fr) | 1987-07-22 |
Family
ID=9232158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP80201114A Expired EP0030060B1 (fr) | 1979-11-28 | 1980-11-19 | Procédé et dispositif d'automatisation d'un cycle de dégazage sous vide d'alliages d'aluminium |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4427443A (enExample) |
| EP (1) | EP0030060B1 (enExample) |
| JP (1) | JPS56102532A (enExample) |
| AT (1) | ATE28481T1 (enExample) |
| BR (1) | BR8007812A (enExample) |
| CA (1) | CA1182647A (enExample) |
| DE (1) | DE3071995D1 (enExample) |
| ES (1) | ES497192A0 (enExample) |
| FR (1) | FR2472615A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041900C (zh) * | 1994-10-20 | 1999-02-03 | 邱表来 | 一种生产高强抗震铸铝件的真空挤压及热处理的方法 |
| US5917114A (en) * | 1996-11-01 | 1999-06-29 | The Ohio State University | Degassing of liquid aluminum and other metals |
| JP4749816B2 (ja) * | 2005-09-28 | 2011-08-17 | 三菱アルミニウム株式会社 | 高純度アルミニウムスラブの製造方法 |
| CN117655355A (zh) * | 2023-12-05 | 2024-03-08 | 南昌航空大学 | 一种提高选区激光熔化铝合金焊接和修复致密度的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE311051B (enExample) | 1964-02-05 | 1969-05-27 | Asea Ab | |
| US3635696A (en) | 1968-05-21 | 1972-01-18 | Finkl & Sons Co | Treatment of molten metal using arc heat and vacuum |
| US3594155A (en) | 1968-10-30 | 1971-07-20 | Allegheny Ludlum Steel | Method for dynamically controlling decarburization of steel |
| US3700429A (en) | 1970-01-05 | 1972-10-24 | Allegheny Ludlum Steel | Method of controlling vacuum decarburization |
| US3958981A (en) | 1975-04-16 | 1976-05-25 | Southwire Company | Process for degassing aluminum and aluminum alloys |
| FR2312569A1 (fr) | 1975-05-27 | 1976-12-24 | Activite Atom Avance | Perfectionnement aux installations de traitement d'un metal fondu |
-
1979
- 1979-11-28 FR FR7929226A patent/FR2472615A1/fr active Granted
-
1980
- 1980-11-19 AT AT80201114T patent/ATE28481T1/de active
- 1980-11-19 EP EP80201114A patent/EP0030060B1/fr not_active Expired
- 1980-11-19 DE DE8080201114T patent/DE3071995D1/de not_active Expired
- 1980-11-26 US US06/210,622 patent/US4427443A/en not_active Expired - Lifetime
- 1980-11-27 CA CA000365599A patent/CA1182647A/fr not_active Expired
- 1980-11-27 ES ES497192A patent/ES497192A0/es active Granted
- 1980-11-28 JP JP16900780A patent/JPS56102532A/ja active Granted
- 1980-11-28 BR BR8007812A patent/BR8007812A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2472615B1 (enExample) | 1982-01-22 |
| FR2472615A1 (fr) | 1981-07-03 |
| CA1182647A (fr) | 1985-02-19 |
| BR8007812A (pt) | 1981-06-16 |
| ATE28481T1 (de) | 1987-08-15 |
| ES8107325A1 (es) | 1981-10-01 |
| ES497192A0 (es) | 1981-10-01 |
| US4427443A (en) | 1984-01-24 |
| JPS56102532A (en) | 1981-08-17 |
| EP0030060A1 (fr) | 1981-06-10 |
| JPH0224899B2 (enExample) | 1990-05-31 |
| DE3071995D1 (en) | 1987-08-27 |
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