EP0022805B1 - Liquid spraying head - Google Patents

Liquid spraying head Download PDF

Info

Publication number
EP0022805B1
EP0022805B1 EP80900118A EP80900118A EP0022805B1 EP 0022805 B1 EP0022805 B1 EP 0022805B1 EP 80900118 A EP80900118 A EP 80900118A EP 80900118 A EP80900118 A EP 80900118A EP 0022805 B1 EP0022805 B1 EP 0022805B1
Authority
EP
European Patent Office
Prior art keywords
valve
container
outlet
inlet
fact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP80900118A
Other languages
German (de)
French (fr)
Other versions
EP0022805A1 (en
Inventor
Paul Comment
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Technospray Te Vaduz Liechtenstein Ets
Original Assignee
COMMENT Paul
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AT80900118T priority Critical patent/ATE3526T1/en
Application filed by COMMENT Paul filed Critical COMMENT Paul
Publication of EP0022805A1 publication Critical patent/EP0022805A1/en
Application granted granted Critical
Publication of EP0022805B1 publication Critical patent/EP0022805B1/en
Expired legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/60Contents and propellant separated
    • B65D83/66Contents and propellant separated first separated, but finally mixed, e.g. in a dispensing head
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant

Definitions

  • the subject of the present invention is a liquid spray head intended to be connected to a source of compressed gas and to be fixed to an enclosure containing the liquid to be sprayed, comprising a distributor body in which a sliding and integral distribution member is mounted a control button actuated by pressure and provided with a spray nozzle connected to the outlet pipe of the member, said body having an outlet orifice intended to send the propellant gas into the enclosure and an inlet orifice intended to put the enclosure in communication with said outlet duct.
  • the dispensing body is constituted by a cylinder provided with lateral openings in which slides a hollow cylindrical rod also provided with lateral openings cooperating with the holes in the body to form a slide valve.
  • the lower end of the rod acts on the valve of a compressed gas tank screwed to the lower end of the cylinder.
  • the compressed gas tank is placed directly in communication with the liquid to be sprayed. It is therefore difficult to control the pressure in the liquid and impossible to maintain this pressure at a value slightly above atmospheric pressure.
  • the pressure in the enclosure must not exceed a critical value, relatively low, for example 1.1 bar.
  • the present invention aims to provide a spray head for maintaining a controlled low pressure in the enclosure containing the liquid to be sprayed.
  • the spray head according to the invention allows for example to use a compressed gas tank at 10 bars or more and to spray the liquid with a controlled and regulated pressure from 0 to 3 bars or moreover, this low pressure can be adjusted and maintained at a precise value by means of the pressure regulator.
  • the mechanical connection of the valves ensures the correct operation, without loss, of the head and makes it possible to accommodate all of the elements of this head in a cylindrical body of small volume capable of being mounted on an enclosure or bottle of current size.
  • the reservoir can be fixed under the head and introduced therewith into the enclosure when the head is fixed to the opening of the enclosure or fixed around the head outside the enclosure.
  • the body may also have means for plugging into an enclosure also housing a reservoir of compressed gas.
  • the enclosure can be made of both metal and glass.
  • the spray head according to the invention can be used for spraying any liquid.
  • the head comprises a cylindrical body 1 in which are mounted a set of valves 2, a pressure regulator pressure regulator 3 and a safety device 4.
  • the valve assembly is shown in FIG. 12. It consists of two identical valves, superimposed and controlled by a single press button 5. These two valves are of the type used in aerosol cans.
  • the upper valve comprises a valve body 6 provided with two O-ring seals 7 and 8 allowing it to slide in a bore 9 while guaranteeing a sufficient seal in the part of the bore situated below this body 6.
  • a joint press 10 holding a sealing package 11 made of synthetic material crossed by a valve stem 12 minie of a central duct 13 connected in its upper part to a spray nozzle 14 provided in the button 5 and with the inside of the valve body by a lateral hole 15 closed at rest by the package 11.
  • the rod 12 has in its lower part an enlargement 16 by which it abuts, at rest, against the package 11 under the effect of a spring 17 working in compression between the rod 12 and the bottom of the joint press 10.
  • the chamber 18 formed inside the hollow joint press 10 communicates with the inside of the valve body 6 through a hole 19
  • the interior of the body 6 communicates through a hole 20 with a e annular chamber 21 surrounding the body 6 between the 0-ring seals 7 and 8.
  • This annular chamber 21 communicates itself with a conduit 22 opening to the lower part of the body 1 through an inlet orifice 23.
  • the lower valve is identical to the upper valve and comprises, like it, a body 24 provided with two 0-ring seals 25 and 26, a hollow rod 27, a package 28, a press seal 29 and a spring 30. There are also three ports 31, 32 and 33 and an annular chamber 34 which communicates with a conduit 35 connected to a first inlet port 36. The inlet port 23 will be called subsequently the second inlet orifice.
  • a plate 37 provided with a central hole 38 communicating with the conduit 39 of the valve stem 27.
  • the plate 37 also has a radial milling 40 on its face upper forming a conduit communicating the hole 39 with the interior of the bore 9 which is itself connected to a conduit 41.
  • the various elements described can be made either of metal or of synthetic material.
  • the rod 12 is lowered, which, by means of its spring 17 drives the valve body 6 by pushing the valve rod 27 from the lower valve by compressing its spring 30.
  • the spring 30 that is to say work the lower valve, it is therefore necessary to overcome, by means of the spring 17, the frictional force of the body 6 in the bore 9 and the frictional force of the valve stem 27 in its package 28.
  • the springs 17 and 30 are identical, the upper valve opens with a slight advance on the lower valve.
  • the button 5 is released, the same friction causes the upper valve to close with a slight advance on the lower valve.
  • a slight offset has a favorable effect since it prevents untimely escape of the compressed gas.
  • the conduits are formed by drilling along perpendicular axes and plugging the orifices not used by plugs such as 42, 43 and 44.
  • the pressure-regulating pressure regulator comprises a fitted valve body 45 tightened in a bore 46 by means of three 0-ring seals 47, 48 and 49.
  • This valve body 45 itself comprises a bore 50 in which two pistons 51 are mounted and 52 rigidly connected together by a rod 53 and each provided with a segment constituted by an O-ring seal 54, respectively 55. At rest the double piston 51/52 is held in abutment against a screw 56 by a spring 57 s pressing against the bottom of the bore 46.
  • On the periphery of the valve body 45 are machined two annular chambers C3 and 59, the first between the seals 47 and 48 and the second between the seals 48 and 49.
  • the chamber 58 communicates with the space 50 by a nozzle 60 and is connected to the conduit 41 by a conduit 61.
  • the chamber 59 communicates with the part of the bore 50 situated below the pistons by a nozzle 62 and it is further connected to a conduit 63 leading to an outlet orifice 64 and to a conduit 65 leading to the availability safety device represented in FIG. 4.
  • This safety device is a valve made up of a rubber ball 66 held against its seat 67 by a spring 68 whose pressure can be adjusted by means of a screw 69 pierced with a axial hole 70.
  • the device is used for example as shown in FIG. 5. It is integral with a compressed gas tank 71 fixed under the head and communicating with the valves by the first inlet 36.
  • the second inlet 23 is connected to a dip tube in plastic material 72.
  • the head is fixed by means of a ring 73 set on the neck of a metal container 74 with the interposition of a seal 75.
  • the outlet orifice 64 opens freely inside the container.
  • the latter is provided with a removable cap 76.
  • the pressure regulator By means of the pressure regulator it is possible to maintain the pressure inside the container at a constant value, for example 1.1 bar when the pressure regulator is connected to the compressed gas tank, for example air or nitrous oxide, and this in a wide range ranging from at least 5 to 12 bars.
  • the stroke of the piston necessary to connect the chamber 50 and the nozzle 62 has been greatly exaggerated.
  • the double piston 51/52 appears in a state of perfect balance, it is possible to obtain a very slight displacement of this piston making it possible to ensure regulation.
  • the conduit 61 being connected to the compressed gas reservoir, the position of the double piston 51/52 is adjusted by means of the screw 56 so as to obtain the desired pressure in the container. The result obtained is surprising and unexpected.
  • valve body 45 of the pressure regulator could be omitted, the bore 50 then being made directly in the body 1.
  • Figures 6, and 8 illustrate, by way of example, three other possibilities of mounting the head and the reservoir on or in a container.
  • the container 77 is made of glass.
  • the reservoir 78 is of annular shape and surrounds the head 1 to which it is connected from the side. For this purpose, the lateral drilling is used, the plug 44 closing in this case the orifice 36.
  • the reservoir 78 has a projection 79 allowing it to be fixed to the notch in the neck 80 of the container. The whole is hidden by a cap 81 retained to the notch on the tank.
  • the container 82 is made of metal and it contains the compressed gas tank 83 fixed to a cylindrical cup 84 fixed by crimping 85 to the opening of the container.
  • the head 1 comprises, at its base, three nipples 86, 87 and 88 which extend each of the three original orifices and which have the dual function of holding the head on the container while ensuring the tightness necessary for this mounting and allow the head to be recovered on an empty container to be mounted on a new container.
  • the head 1 is provided with an annular compressed gas tank 89 extending below the head 1 by a ribbed central part 90 allowing the tank to be fixed on the neck 91 of a container metal or on the neck 92 of a glass container.
  • the reservoir 89 may be provided with a valve 93 allowing its recharging or the continuous use of the device by connection to a source of compressed gas or other suitable installation. In this case, the head, the tank and the container are recoverable.
  • the head is permanently fixed to a reservoir through which conduits connect the outlet orifice 64 and the inlet orifice 23 to orifices provided on the reservoir and minus of means of connection to an enclosure. In this case the head and the tank are recoverable.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Nozzles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catching Or Destruction (AREA)

Abstract

The spraying head is comprised of a body in which are mounted two similar valves superposed and coupled (16, 17). The rod (12) of the upper valve is integral with a control button (5) provided with a nozzle (14). A pressure reducer-manometer is housed in the body. The body has a hole (36) connecting a pressure gas container to the lower valve, a hole connecting the pressure reducer-manometer to the housing and a hole (23) connecting the housing to the upper valve. The pressure reducer-manometer comprises a slide regulating valve. The spraying head may be fixed removably or not to the pressure air container, as well as to the housing.

Description

La présente invention a pour objet une tête de pulvérisation de liquide destinée à être reliée à une source de gaz comprimé et à être fixée sur une enceinte contenant le liquide à pulvériser, comprenant un corps distributeur dans leqel est monté un organe de distribution coulissant et solidaire d'un bouton de commande actionnable par pression et muni d'une duse de giclage reliée au conduit de sortie de l'organe, ledit corps présentant un orifice de sortie destiné à envoyer le gaz propulseur dans l'enceinte et un orifice d'entrée destinée à mettre en communication l'enceinte avec ledit conduit de sortie.The subject of the present invention is a liquid spray head intended to be connected to a source of compressed gas and to be fixed to an enclosure containing the liquid to be sprayed, comprising a distributor body in which a sliding and integral distribution member is mounted a control button actuated by pressure and provided with a spray nozzle connected to the outlet pipe of the member, said body having an outlet orifice intended to send the propellant gas into the enclosure and an inlet orifice intended to put the enclosure in communication with said outlet duct.

Selon une exécution antérieure d'une telle tête de pulvérisation (US-A-2 973 885) le corps de distribution est constitué par un cylindre muni d'orifices latéraux dans lequel coulisse une tige cylindrique creuse munie également d'orifices latéraux coopérant avec les orifices du corpes pour constituer une vanne à tiroir. L'extrémité inférieure de la tige agit sur la valve d'un réservoir de gaz comprimé vissé à l'extrémité inférieur du cylindre. Le réservoir de gaz comprimé est mis directement en communication avec le liquide à pulvériser. Il est donc difficile de contrôler la pression dans le liquide et impossible de maintenir cette pression à une valeur légèrement au-dessus de la pression atmosphérique. Or, pour certaines applications, en particulier pour les parfums dont les caractéristiques sont détruites lorsqu'ils sont mélangés avec un gaz comprimé, la pression dans l'enceinte ne doit pas dépasser une valeur critique, relativement basse, par exemple 1,1 bar.According to a previous embodiment of such a spray head (US-A-2 973 885) the dispensing body is constituted by a cylinder provided with lateral openings in which slides a hollow cylindrical rod also provided with lateral openings cooperating with the holes in the body to form a slide valve. The lower end of the rod acts on the valve of a compressed gas tank screwed to the lower end of the cylinder. The compressed gas tank is placed directly in communication with the liquid to be sprayed. It is therefore difficult to control the pressure in the liquid and impossible to maintain this pressure at a value slightly above atmospheric pressure. However, for certain applications, in particular for perfumes whose characteristics are destroyed when they are mixed with a compressed gas, the pressure in the enclosure must not exceed a critical value, relatively low, for example 1.1 bar.

La présente invention a pour but de réaliser une tête de pulvérisation permettant de maintenir une basse pression contrôlée dans l'enceinte contenant le liquide à pulvériser.The present invention aims to provide a spray head for maintaining a controlled low pressure in the enclosure containing the liquid to be sprayed.

La tête de pulvérisation selon l'invention, telle que définie par la revendication 1, permet par exemple d'utiliser un réservoir de gaz comprimé à 10 bars ou davantage et de pulvériser le liquide avec une pression contrôlée et régulée de 0 à 3 bars ou davantage, cette basse pression pouvant être réglée et maintenue à une valeur précise au moyen du manodétendeur régulateur de pression. La liaison mécanique des valves assure le bon fonctionnement, sans perte, de la tête et permet de loger l'ensemble des élément de cette tête dans un corps cylindrique de faible volume susceptible d'être monté sur une enceinte ou bouteille de dimension courante. Le réservoir peut être fixé sous la tête et introduit avec celle-ci dans l'enceinte lors de la fixation de la tête sur l'ouverture de l'enceinte ou fixé autour de la tête à l'extérieur de l'enceinte. Le corps peut en outre présenter des moyens d'enfichage sur une enceinte abritant également un réservoir de gaz comprimé. L'enceinte peut être réalisée aussi bien en métal qu'en verre.The spray head according to the invention, as defined by claim 1, allows for example to use a compressed gas tank at 10 bars or more and to spray the liquid with a controlled and regulated pressure from 0 to 3 bars or moreover, this low pressure can be adjusted and maintained at a precise value by means of the pressure regulator. The mechanical connection of the valves ensures the correct operation, without loss, of the head and makes it possible to accommodate all of the elements of this head in a cylindrical body of small volume capable of being mounted on an enclosure or bottle of current size. The reservoir can be fixed under the head and introduced therewith into the enclosure when the head is fixed to the opening of the enclosure or fixed around the head outside the enclosure. The body may also have means for plugging into an enclosure also housing a reservoir of compressed gas. The enclosure can be made of both metal and glass.

La tête de pulvérisation selon l'invention peut être utilisée pour la pulvérisation de tout liquide.The spray head according to the invention can be used for spraying any liquid.

Le dessin annexé représente, à titre d'exemple, une forme d'exécution de l'invention.

  • La figure 1 en représente une vue en plan de dessus.
  • La figure 2 en représente une vue en coupe selon II-II de la figure 1.
  • La figure 3 en représente une vue en coupe selon III-III de la figure 1.
  • La figure 4 en représente une vue partielle en coupe selon IV-IV de la figure 1.
  • La figure 5 illustre un premier mode de montage de la tête.
  • La figure 6 illustre un deuxième mode de montage de la tête.
  • La figure 7 illustre un troisième mode de montage de la tête.
  • La figure 8 illustre un quatrième mode de montage de la tête.
The accompanying drawing shows, by way of example, an embodiment of the invention.
  • Figure 1 shows a plan view from above.
  • FIG. 2 represents a sectional view along II-II of FIG. 1.
  • FIG. 3 represents a sectional view along III-III of FIG. 1.
  • FIG. 4 represents a partial view in section along IV-IV of FIG. 1.
  • FIG. 5 illustrates a first method of mounting the head.
  • FIG. 6 illustrates a second method of mounting the head.
  • FIG. 7 illustrates a third method of mounting the head.
  • FIG. 8 illustrates a fourth method of mounting the head.

La tête comprend un corps cylindrique 1 dans lequel sont montés un ensemble de valves 2, un manodétendeur régulateur de pression 3 et un dispositif de sécurité 4.The head comprises a cylindrical body 1 in which are mounted a set of valves 2, a pressure regulator pressure regulator 3 and a safety device 4.

L'ensemble de valves est représenté à la figure 12. Il est constitué de deux valves identiques, superposées et commandées par un unique bouton à pression 5. Ces deux valves sont du type utilisé dans les boîtes à aérosol. La valve supérieure comprend un corps de valve 6 muni de deux joints O-ring 7 et 8 lui permettant de coulisser dans un alésage 9 tout en garantissant une étanchéité suffisante dans la partie de l'alésage située au-dessous de ce corps 6. Dans ce corps 6 est vissé un presse-joint 10 maintenant un paquetage d'étanchéité 11 en matière synthétique traversé par une tige des valve 12 minie d'un conduit central 13 relié dans sa partie supérieure à une duse d'aspersion 14 prévue dans le bouton 5 et avec l'intérieur du corps de valve par un trou latéral 15 obturé au repos par le paquetage 11. La tige 12 présente en sa partie inférieure un élargissement 16 par lequel elle vient buter, au repos, contre le paquetage 11 sous l'effet d'un ressort 17 travaillant en compression entre la tige 12 et le fond du presse-joint 10. La chambre 18 formée à l'intérieur du presse-joint 10 évidé communique avec l'intérieur du corps de valve 6 par un trou 19. L'intérieur du corps 6 communique par un trou 20 avec une chambre annulaire 21 entourant le corps 6 entre les joints 0-ring 7 et 8. Cette chambre annulaire 21 communique elle-même avec un conduit 22 débouchant à la partie inférieure du corps 1 par un orifice d'entrée 23.The valve assembly is shown in FIG. 12. It consists of two identical valves, superimposed and controlled by a single press button 5. These two valves are of the type used in aerosol cans. The upper valve comprises a valve body 6 provided with two O-ring seals 7 and 8 allowing it to slide in a bore 9 while guaranteeing a sufficient seal in the part of the bore situated below this body 6. In this body 6 is screwed a joint press 10 holding a sealing package 11 made of synthetic material crossed by a valve stem 12 minie of a central duct 13 connected in its upper part to a spray nozzle 14 provided in the button 5 and with the inside of the valve body by a lateral hole 15 closed at rest by the package 11. The rod 12 has in its lower part an enlargement 16 by which it abuts, at rest, against the package 11 under the effect of a spring 17 working in compression between the rod 12 and the bottom of the joint press 10. The chamber 18 formed inside the hollow joint press 10 communicates with the inside of the valve body 6 through a hole 19 The interior of the body 6 communicates through a hole 20 with a e annular chamber 21 surrounding the body 6 between the 0-ring seals 7 and 8. This annular chamber 21 communicates itself with a conduit 22 opening to the lower part of the body 1 through an inlet orifice 23.

La valve inférieure est indentique à la valve supérieure et comprend comme elle un corps 24 muni de deux joints 0-ring 25 et 26, une tige creuse 27, un paquetage 28, un presse-joint 29 et un ressort 30. On retrouve également trois orifices 31, 32 et 33 et une chambre annulaire 34 qui communique avec un conduit 35 relié à un premier orifice d'entrée 36. L'orifice d'entrée 23 sera appelé par la suite second orifice d'entrée. A la face inférieure du presse-joint 1.0 de la première valve est fixée une plaque 37 munie d'un trou central 38 communiquant avec le conduit 39 de la tige de valve 27. La plaque 37 présente en outre un fraisage radial 40 sur sa face supérieure formant un conduit faisant communiquer le trou 39 avec l'intérieur de l'alésage 9 qui est relié lui-même à un conduit 41.The lower valve is identical to the upper valve and comprises, like it, a body 24 provided with two 0-ring seals 25 and 26, a hollow rod 27, a package 28, a press seal 29 and a spring 30. There are also three ports 31, 32 and 33 and an annular chamber 34 which communicates with a conduit 35 connected to a first inlet port 36. The inlet port 23 will be called subsequently the second inlet orifice. To the underside of the seal 1.0 of the first valve is fixed a plate 37 provided with a central hole 38 communicating with the conduit 39 of the valve stem 27. The plate 37 also has a radial milling 40 on its face upper forming a conduit communicating the hole 39 with the interior of the bore 9 which is itself connected to a conduit 41.

Les différents éléments décrites peuvent être exécutés soit en métal soit en matière synthétique. Dans l'exécution décrite on a utilisé partiellement du métal et des matières synthétiques connues. Il ressort de la figure 2 que lorsqu'on exerce une pression selon F1 sur le bouton 5 on fait descendre la tige 12, laquelle, par l'intermédiaire de son ressort 17 entraîne le corps de valve 6 en repoussant la tige de valve 27 de la valve inférieure en comprimant son ressort 30. Pour comprimer le ressort 30, c'est-à-dire ouvrier la valve inférieure, il est dès lors nécessaire de vaincre, par l'intermédiaire du ressort 17, la force de frottement du corps 6 dans l'alésage 9 et la force de frottement de la tige de valve 27 dans son paquetage 28. Etant donné que les ressorts 17 et 30 sont indentiques, la valve supérieure s'ouvre avec une légère avance sur la valve inférieure. Lorsqu'on relâche le bouton 5, les mêmes frottements ont pour effet que la valve supérieure se ferme avec une légère avance sur la valve inférieure. Comme on pourra s'en rendre compte dans la suite de la description, de léger décalage a un effet favorable puisqu'il empêche un échappement intempestif du gaz comprimé.The various elements described can be made either of metal or of synthetic material. In the described embodiment partially used metal and known plastics. It appears from FIG. 2 that when a pressure is exerted on button 5 according to F1, the rod 12 is lowered, which, by means of its spring 17 drives the valve body 6 by pushing the valve rod 27 from the lower valve by compressing its spring 30. To compress the spring 30, that is to say work the lower valve, it is therefore necessary to overcome, by means of the spring 17, the frictional force of the body 6 in the bore 9 and the frictional force of the valve stem 27 in its package 28. Since the springs 17 and 30 are identical, the upper valve opens with a slight advance on the lower valve. When the button 5 is released, the same friction causes the upper valve to close with a slight advance on the lower valve. As will be seen in the following description, a slight offset has a favorable effect since it prevents untimely escape of the compressed gas.

Les conduits sont formés par perçage selon des axes perpendiculaires et bouchonnage des orifices non utilisés par des bouchons tels que 42, 43 et 44.The conduits are formed by drilling along perpendicular axes and plugging the orifices not used by plugs such as 42, 43 and 44.

Le manodétendeur régulateur de pression comprend un corps de vanne 45 ajusté serré dans un alésage 46 au moyen de trois joints 0-ring 47, 48 et 49. Ce corps de vanne 45 comprend lui-même un alésage 50 dans lequel sont montés deux pistons 51 et 52 reliés rigidement entre eux par une tige 53 et munis chacun d'un segment constitué par un joint O-ring 54, respectivement 55. Au repos le double piston 51/52 est maintenu en butée contre une vis 56 par un ressort 57 s'appuyant contre le fond de l'alésage 46. Sur le pourtour du corps de valve 45 sont usinées deux chambres annulaires C3 et 59, la première entre les joints 47 et 48 et la seconde entre les joints 48 et 49. La chambre 58 communique avec l'espace 50 par un ajutage 60 et est reliée au conduit 41 par un conduit 61. La chambre 59 communique avec la partie de l'alésage 50 située en-dessous des pistons par un ajutage 62 et elle est reliée en outre à un conduit 63 conduisant à un orifice de sortie 64 et à un conduit 65 conduisant au dispositif de sécurité représenté à la figure 4. Ce dispositif de sécurité est une soupape constituée d'une bille en caoutchouc 66 maintenue contre son siège 67 par un ressort 68 dont la pression peut être réglée au moyens d'une vis 69 percée d'un trou axial 70.The pressure-regulating pressure regulator comprises a fitted valve body 45 tightened in a bore 46 by means of three 0-ring seals 47, 48 and 49. This valve body 45 itself comprises a bore 50 in which two pistons 51 are mounted and 52 rigidly connected together by a rod 53 and each provided with a segment constituted by an O-ring seal 54, respectively 55. At rest the double piston 51/52 is held in abutment against a screw 56 by a spring 57 s pressing against the bottom of the bore 46. On the periphery of the valve body 45 are machined two annular chambers C3 and 59, the first between the seals 47 and 48 and the second between the seals 48 and 49. The chamber 58 communicates with the space 50 by a nozzle 60 and is connected to the conduit 41 by a conduit 61. The chamber 59 communicates with the part of the bore 50 situated below the pistons by a nozzle 62 and it is further connected to a conduit 63 leading to an outlet orifice 64 and to a conduit 65 leading to the availability safety device represented in FIG. 4. This safety device is a valve made up of a rubber ball 66 held against its seat 67 by a spring 68 whose pressure can be adjusted by means of a screw 69 pierced with a axial hole 70.

Le dispositif est utilisé par exemple comme représenté à la figure 5. Il est solidaire d'un réservoir de gaz comprimé 71 fixé sous la tête et communiquant avec les valves par la première entrée 36. La seconde entrée 23 est reliée à un tube plongeur en matière plastique 72. La tête est fixée au moyen d'une bague 73 sertie sur le col d'un récipient métallique 74 avec interposition d'une garniture d'étanchéité 75.The device is used for example as shown in FIG. 5. It is integral with a compressed gas tank 71 fixed under the head and communicating with the valves by the first inlet 36. The second inlet 23 is connected to a dip tube in plastic material 72. The head is fixed by means of a ring 73 set on the neck of a metal container 74 with the interposition of a seal 75.

L'orifice de sortie 64 débouche librement à l'intérieur du récipient. Ce dernier est muni d'un capuchon amovible 76.The outlet orifice 64 opens freely inside the container. The latter is provided with a removable cap 76.

Au moyen du manodétendeur régulateur de pression il est possible de maintenir la pression à l'intérieur du récipient à une valeur constante, par exemple 1,1 bar lorsque le manodétendeur est relié au réservoir de gaz comprimé, par exemple de l'air ou du protoxyde d'azote, et ceci dans une large plage allant au moins de 5 à 12 bars. A la figure 3 la course du piston nécessaire pour mettre en communication la chambre 50 et l'ajutage 62 a été fortement exagérée. D'autre part, bien que le double piston 51/52 paraisse en état de parfait équilibre, il est possible d'obtenir un très léger déplacement de ce piston permettant d'assurer la régulation. Le conduit 61 étant relié réservoir de gaz comprimé, on ajuste la position du double piston 51/52 au moyen de la vis 56 de manière à obtenir la pression désirée dans le récipient. Le résultat obtenu est surprenant et inattendu. Tous les prototypes construits étant en métal, donc opaques, il n'a malheuresement pas été possible de déterminer qu'elle est la position du piston 52 au point de régulation. Il est certain que le joint 0-ring 55 de ce piston est déjà à la hauteur de l'ajutage 62, de telle sorte que cet ajutage communique par un passage de très faible section avec la chambre 50. On aurait dès lors une forte réduction de la pression du gaz arrivant par les conduits 41 et 61 dans la chambre 50 à travers ce faible passage. Il faut en effet considérer que le réservoir de gaz comprimé n'est pas relié en permanence avec la chambre 50, mais seulement lorsqu'on ouvre les valves en pressant sur le bouton 5. Il convient néanmoins de souligner qu'aucune des solutions connues n'a permis d'obtenir un fonctionnement satisfaisant du manodétendeur régulateur de pression et que c'est l'adjonction zu piston 51 qui a permis d'atteindre ces résultats.By means of the pressure regulator it is possible to maintain the pressure inside the container at a constant value, for example 1.1 bar when the pressure regulator is connected to the compressed gas tank, for example air or nitrous oxide, and this in a wide range ranging from at least 5 to 12 bars. In FIG. 3, the stroke of the piston necessary to connect the chamber 50 and the nozzle 62 has been greatly exaggerated. On the other hand, although the double piston 51/52 appears in a state of perfect balance, it is possible to obtain a very slight displacement of this piston making it possible to ensure regulation. The conduit 61 being connected to the compressed gas reservoir, the position of the double piston 51/52 is adjusted by means of the screw 56 so as to obtain the desired pressure in the container. The result obtained is surprising and unexpected. All the prototypes built being made of metal, therefore opaque, it was unfortunately not possible to determine that it is the position of the piston 52 at the regulation point. It is certain that the 0-ring seal 55 of this piston is already at the height of the nozzle 62, so that this nozzle communicates by a passage of very small section with the chamber 50. There would therefore be a strong reduction of the pressure of the gas arriving through the conduits 41 and 61 in the chamber 50 through this weak passage. It must indeed be considered that the compressed gas tank is not permanently connected with the chamber 50, but only when the valves are opened by pressing the button 5. It should nevertheless be emphasized that none of the known solutions 'made it possible to obtain satisfactory operation of the pressure regulator pressure regulator and that it was the addition to the piston 51 which made it possible to achieve these results.

Le fonctionnement de la tête de pulvérisation ressort des dessins et de la description ci-dessus. Lorsqu'on appuie sur le bouton 5, on ouvre les deux valves accouplées. Le réservoir de gaz comprimé est mis en communication avec le manodétendeur par le conduit 35, la chambre annulaire 34, les trous 33, 32 et 31, le conduit 39 de la tige 27 et le conduit 41. Le gaz détendu sort du manodétendeur par le conduit 62, la chambre 59, le conduit 63 et l'orifice 64 et s'échappe à l'intérieur du récipient. La légère surpression dans le récipient a pour effet de faire monter le liquide par le tube plongeur 72 dans le conduit 23. Le liquide traverse alors les orifices 20, 19 et 15 pour s'échapper par la duse 14.The operation of the spray head is apparent from the above drawings and description. When button 5 is pressed, the two coupled valves are opened. The compressed gas tank is placed in communication with the pressure regulator through line 35, the annular chamber 34, the holes 33, 32 and 31, the line 39 of the rod 27 and the line 41. The expanded gas leaves the pressure regulator through the conduit 62, the chamber 59, the conduit 63 and the orifice 64 and escapes inside the container. The slight overpressure in the container has the effect of causing the liquid to rise through the dip tube 72 in the duct. 23. The liquid then passes through the orifices 20, 19 and 15 to escape through the nozzle 14.

En variante le corps de valve 45 du manodétendeur pourrait être supprimé, l'alésage 50 étant alors directement pratiqué dans le corps 1.As a variant, the valve body 45 of the pressure regulator could be omitted, the bore 50 then being made directly in the body 1.

Les figures 6, et 8 illustrent, à titre d'exemple, trois autres possibilités de monter la tête et le réservoir sur ou dans un récipient.Figures 6, and 8 illustrate, by way of example, three other possibilities of mounting the head and the reservoir on or in a container.

Dans le montage représenté à la figure 6, le récipient 77 est en verre. Le réservoir 78 est de forme annulaire et entoure la tête 1 à laquelle il est relié de côté. A cet effet on utilise le perçage latéral, le bouchon 44 obturant dans ce cas l'orifice 36. Le réservoir 78 présente une saillie 79 permettant sa fixation à cran dans le col 80 du récipient. Le tout est caché par un capuchon 81 retenu à cran sur le réservoir. Ces dispositions permettent d'obtenir un aspect esthétique satisfaisant. Dans le cas d'un récipient métallique on utilisera de préférence le montage représenté à la figure 5, dans lequel le réservoir de gaz comprimé est situé dans le récipient et occupe dans celui-ci un volume correspondant au volume occupé par le fréon dans les bombes aérosols.In the assembly shown in Figure 6, the container 77 is made of glass. The reservoir 78 is of annular shape and surrounds the head 1 to which it is connected from the side. For this purpose, the lateral drilling is used, the plug 44 closing in this case the orifice 36. The reservoir 78 has a projection 79 allowing it to be fixed to the notch in the neck 80 of the container. The whole is hidden by a cap 81 retained to the notch on the tank. These provisions make it possible to obtain a satisfactory aesthetic appearance. In the case of a metal container, the mounting shown in FIG. 5 is preferably used, in which the compressed gas tank is located in the container and occupies in it a volume corresponding to the volume occupied by the freon in the bombs. aerosols.

Dans le montage représenté à la figure 7, le récipient 82 est en métal et il contient le réservoir de gaz comprimé 83 fixé à une coupelle cylindrique 84 fixée par sertissage 85 à l'ouverture du récipient. La tête 1 comporte, à sa base, trois tétons 86, 87 et 88 qui prolonge chacun des trois orifices d'origine et qui ont pour double fonction de maintenir la tête sur le récipient tout en assurant l'étanchéité nécessaire à ce montage et de permettre à la tête d'être récupérée sur un récipient vide pour être monté sur un nouveau récipient.In the assembly shown in FIG. 7, the container 82 is made of metal and it contains the compressed gas tank 83 fixed to a cylindrical cup 84 fixed by crimping 85 to the opening of the container. The head 1 comprises, at its base, three nipples 86, 87 and 88 which extend each of the three original orifices and which have the dual function of holding the head on the container while ensuring the tightness necessary for this mounting and allow the head to be recovered on an empty container to be mounted on a new container.

Dans le montage représenté à la figure 8 la tête 1 est munie d'un réservoir de gaz comprimé 89 annulaire se prolongeant en-dessous de la tête 1 par une partie centrale nervurée 90 permettant la fixation du réservoir sur le col 91 d'un récipient métallique ou sur le col 92 d'un récipient en verre. Le réservoir 89 peut être muni d'une valve 93 permettant sa recharge ou l'emploi en continue du dispositif par le branchement sur une source de gaz comprimé ou autre installation adéquate. Dans ce cas la tête, le réservoir, ainsi que le récipient sont récupérables.In the assembly shown in FIG. 8, the head 1 is provided with an annular compressed gas tank 89 extending below the head 1 by a ribbed central part 90 allowing the tank to be fixed on the neck 91 of a container metal or on the neck 92 of a glass container. The reservoir 89 may be provided with a valve 93 allowing its recharging or the continuous use of the device by connection to a source of compressed gas or other suitable installation. In this case, the head, the tank and the container are recoverable.

Selon une variante non représentée la tête est fixée à demeure sur un réservoir traversé par des conduits reliant l'orifice de sortie 64 et l'orifice d'entrée 23 à des orifices prévus sur le réservoir et minus de moyens de branchement sur une enceinte. Dans ce cas la tête et le réservoir sont récupérables.According to a variant not shown, the head is permanently fixed to a reservoir through which conduits connect the outlet orifice 64 and the inlet orifice 23 to orifices provided on the reservoir and minus of means of connection to an enclosure. In this case the head and the tank are recoverable.

Dans certains cas il est possible de supprimer le réservoir en branchant directement la tête sur un circuit d'air comprimé en continu.In some cases it is possible to remove the tank by directly connecting the head to a continuous compressed air circuit.

Claims (6)

1. Liquid atomization head adapted to be connected to a source of compressed gas and to be secured to a container (74) containing the liquid to be atomized, comprising a dispensing body (1) in which a sliding dispensing member is mounted and rigid with a control knob (5) actuatable by pressure and provided with a spray nozzle (14) connected to the outlet passage (13) of saidbody, said body (1) having an outlet orifice (64) adapted to deliver the propelling gas into the container and an inlet orifice (23) adapted to connect the container with said outlet passage (13), characterized by the fact that the dispensing member comprises two superposed valves comprising each a movable control system (12, 27) also acting as a valve outlet passage (13, 39) and passing through a packing (11, 28) sealing in the inoperative position a valve passage (14, 31) of the relevant stem, the stem of the upper valve (12) being rigid with the control knob (5) provided with the spray nozzle (14), each valve comprising a spring (17, 30) counteracting the sinking of the corresponding control stem (12, 27), the control stem (27) of the lower valve being actuated by the sliding movement of the upper valve, and by the fact that the body (1) contains a pressure-regulating relief valve (fig. 3) connected through conduits on the one side (60) to the outlet port (39) of the lower valve and on the other side (62) to the outlet orifice (64) leading to the container, and a safety valve (fig. 4) connected to said container, the body (1) comprising a second inlet orifice (36) adapted to connect the source of compressed gas to the inlet (32) of the lower valve and a conduit (41) connecting the outlet (40) of the lower valve to the relief valve, the first inlet orifice (23) connecting the container (74) to the inlet (19) of the upper valve.
2. Atomizing head according to claim 1, characterized by the fact that the pressure-regulating relief valve (fig. 3) comprises a cylindrical bore (58) connected laterally on the one hand to the outlet of the lower valve through an inlet port (60) and on the other hand to said outlet orifice (64) through an outlet port (62), and in which two pistons (51, 52) rigidly coupled to each other and provided with resilient rings (54, 55) are mounted, a spring (57) beeing compression stressed between one of the pistons and the bottom of said bore and an adjustable abutment member (56) for the other piston, the inlet port (60) opening between the pistons and the outlet port (62) opening just beneath the piston engaged by said spring or at the level of the ring of this piston, when the other piston is in abutment.
3. Atomizing head according to claim 1, characterized by the fact that it is secured permanently to a compressed-gas reservoir.
4. Atomizing head according to claim 1, characterized by the fact that it is surrounded by an annular reservoir (fig. 6).
5. Atomizing head according to claim 1, characterized by the fact that the inlet orifices and the outlet orifices are located on the lower face of the head and that they are provided with plug-in means permitting of plugging-in the head on a container containing a liquid and a compressed-gas reserver (fig. 7).
6. Atomization head according to claim 3, characterized by the fact that the outlet orifice and the second inlet orifice are located at the lower end of the reservoir and provided with plug-in means permitting of plugging-in the assembly on a container filled with a liquid to be atomized.
EP80900118A 1979-01-22 1980-07-29 Liquid spraying head Expired EP0022805B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80900118T ATE3526T1 (en) 1979-01-22 1980-01-15 LIQUID SPRAYHEAD.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH606/79 1979-01-22
CH60679A CH618896A5 (en) 1979-01-22 1979-01-22

Publications (2)

Publication Number Publication Date
EP0022805A1 EP0022805A1 (en) 1981-01-28
EP0022805B1 true EP0022805B1 (en) 1983-05-25

Family

ID=4190886

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80900118A Expired EP0022805B1 (en) 1979-01-22 1980-07-29 Liquid spraying head

Country Status (15)

Country Link
US (1) US4519528A (en)
EP (1) EP0022805B1 (en)
JP (2) JPS6335309B2 (en)
AU (1) AU529600B2 (en)
BE (1) BE881235A (en)
CA (1) CA1148512A (en)
CH (1) CH618896A5 (en)
DE (1) DE3063389D1 (en)
ES (1) ES487906A0 (en)
GR (1) GR74070B (en)
IT (1) IT1129556B (en)
MC (1) MC1343A1 (en)
SU (1) SU957756A3 (en)
WO (1) WO1980001482A1 (en)
ZA (1) ZA80364B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH662629A5 (en) * 1984-12-28 1987-10-15 Paul Comment PRESSURE REDUCER-REGULATOR FOR THE DISTRIBUTION OF A GASEOUS, LIQUID, VISCOUS, POWDERY OR PASTY PRODUCT.
JPH0335399Y2 (en) * 1985-11-08 1991-07-26
IN174351B (en) * 1988-03-08 1994-11-12 British Tech Group
DE3832852A1 (en) * 1988-09-28 1990-03-29 Oeco Tech Entwicklung & Vertri AUTOMATIC SPRAY CAN
CA2013636A1 (en) * 1989-04-06 1990-10-06 Sang I. Han Disposable pressure wound irrigation device
US5158215A (en) * 1989-11-08 1992-10-27 Paul Comment Automatic lift valve
GB9107681D0 (en) * 1991-04-11 1991-05-29 Unilever Plc Container
JPH0514866U (en) * 1991-08-01 1993-02-26 オムロン株式会社 Infrared thermometer
NL1008601C2 (en) * 1998-03-16 1999-09-17 Heineken Tech Services Device for dispensing a fluid.
DE10011717A1 (en) * 2000-03-10 2001-09-13 Crown Cork & Seal Tech Corp Valve element for a liquid spray unit comprises an essentially cylindrical body provided with coaxial inlet and outlet valves

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2973885A (en) * 1960-04-11 1961-03-07 Staley Mfg Co A E Pressurizable dispenser
DE2227310C2 (en) * 1962-11-16 1973-09-27 L'oreal, Paris Push-button device for dispensing a mixture of several liquid components
US3315844A (en) * 1965-01-13 1967-04-25 Air Prod & Chem Dispensing apparatus
FR1529193A (en) * 1966-07-16 1968-06-14 Werner & Mertz Gmbh Spray head for aerosol container
GB1317627A (en) * 1970-12-04 1973-05-23 Kovach L J Dental cleaning device

Also Published As

Publication number Publication date
ES8100114A1 (en) 1980-11-01
CA1148512A (en) 1983-06-21
ZA80364B (en) 1981-08-26
JPS63267464A (en) 1988-11-04
IT8019289A0 (en) 1980-01-18
BE881235A (en) 1980-05-16
GR74070B (en) 1984-06-06
ES487906A0 (en) 1980-11-01
MC1343A1 (en) 1981-06-22
AU5482780A (en) 1980-07-31
JPS6335309B2 (en) 1988-07-14
SU957756A3 (en) 1982-09-07
US4519528A (en) 1985-05-28
DE3063389D1 (en) 1983-07-07
EP0022805A1 (en) 1981-01-28
CH618896A5 (en) 1980-08-29
JPS56500164A (en) 1981-02-19
WO1980001482A1 (en) 1980-07-24
JPH0329468B2 (en) 1991-04-24
IT1129556B (en) 1986-06-11
AU529600B2 (en) 1983-06-16

Similar Documents

Publication Publication Date Title
EP0931734B1 (en) Valve for regulating a fluid flow and container equipped with such a valve
CA2172192C (en) Aerosol container with double-outlet valve
EP0022805B1 (en) Liquid spraying head
EP0245172A1 (en) Receptacle for two pressurised containers
EP1035038B9 (en) Unit for storing and dispensing a product under pressure, especially cosmetics
EP0485244B1 (en) Dispensing valve for a container with a fluid under pressure of a gas, and container equipped with such a valve
WO2002020168A1 (en) Multiple-dose device for dispensing a fluid product
EP0656495A1 (en) Liquid distributor with solenoid valves
US6494345B2 (en) Food decorating system
EP2279798A1 (en) Push button for a system for pressurised product distribution
EP0780324A1 (en) Liquid dispenser including a push-button
EP2005273B1 (en) Pneumatic component for the controlled micro-diffusion of gas
CA2407213C (en) Spraying device for application of at least on product on a substrate, namely a keratenized substrate such as skin
EP1202818B1 (en) Device for dispensing a fluid product with closure system
WO2002096776A1 (en) Dosage pump
EP0669167B1 (en) Assembly for the quasi-continuous distribution of liquids comprising a pump and use of such an assembly for spraying a hairspray
EP2295150B1 (en) Push button for a dispensing system with pressurised product
EP2119508A1 (en) Push button for convergent distribution channels
CA1083098A (en) Compressed air assisted manual pump and associated holding tank
FR2569581A1 (en) Aerosol sprayer for variable controlled discharge
EP0450990B1 (en) Self-closing valve especially for an aerosol container
FR2699835A1 (en) Kit for spraying a liquid comprising a precompression pump.
FR2711973A1 (en) Aerosol spraying mechanism
CA1030927A (en) bottle with spray nozzle and air intake valve
CA1104530A (en) Method for reducing flammability of the atomizing stream from a pressurized container

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT DE FR GB LU NL SE

17P Request for examination filed

Effective date: 19810119

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT DE FR GB LU NL SE

REF Corresponds to:

Ref document number: 3526

Country of ref document: AT

Date of ref document: 19830615

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3063389

Country of ref document: DE

Date of ref document: 19830707

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: 732

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

NLS Nl: assignments of ep-patents

Owner name: ETABLISSEMENT TECHNOSPRAY TE VADUZ, LIECHTENSTEIN.

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19940124

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19940126

Year of fee payment: 15

Ref country code: FR

Payment date: 19940126

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19940128

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19940129

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19940131

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 19940331

Year of fee payment: 15

EPTA Lu: last paid annual fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19950115

Ref country code: GB

Effective date: 19950115

Ref country code: AT

Effective date: 19950115

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19950116

EAL Se: european patent in force in sweden

Ref document number: 80900118.3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19950801

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19950115

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19950929

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19950801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19951003

EUG Se: european patent has lapsed

Ref document number: 80900118.3

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST