EA201490227A1 - Металлоцен-катализированный полиэтилен - Google Patents

Металлоцен-катализированный полиэтилен

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Publication number
EA201490227A1
EA201490227A1 EA201490227A EA201490227A EA201490227A1 EA 201490227 A1 EA201490227 A1 EA 201490227A1 EA 201490227 A EA201490227 A EA 201490227A EA 201490227 A EA201490227 A EA 201490227A EA 201490227 A1 EA201490227 A1 EA 201490227A1
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EA
Eurasian Patent Office
Prior art keywords
polyethylene resin
metallocene
iso
measured
polyethylene
Prior art date
Application number
EA201490227A
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English (en)
Other versions
EA027509B1 (ru
Inventor
Аурелиен Вантомме
Пьер Бернард
Якус Мишель
Кристофер Виллок
Армелле Сигвальд
Original Assignee
Тотал Ресерч & Технолоджи Фелай
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=46508038&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EA201490227(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Тотал Ресерч & Технолоджи Фелай filed Critical Тотал Ресерч & Технолоджи Фелай
Publication of EA201490227A1 publication Critical patent/EA201490227A1/ru
Publication of EA027509B1 publication Critical patent/EA027509B1/ru

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08Surfaces simulating grass ; Grass-grown sports grounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Investigating Or Analyzing Materials Using Thermal Means (AREA)

Abstract

Смола металлоцен-катализированного полиэтилена с мультимодальным молекулярно-массовым и композиционным распределением, включающая от 45 до 75 мас.% фракции низкой плотности, ниже или равной 918 г/см, измеряемой методом стандартного испытания по ISO 1183 при температуре 23°С, имеющая плотность полиэтиленовой смолы от 0,920 до 0,945 г/см, характеризующаяся отношением M/Mполиэтилена от 2,8 до 6, имеющая индекс расплава MI2 полиэтиленовой смолы от 0,1 до 5 г/10 мин, измеряемый по условию D ISO 1133 при 190°С под нагрузкой 2,16 кг; и характеризующаяся показателем ширины распределения по составу (ПШРС/CDBI) полиэтиленовой смолы менее 70%, полученным посредством анализа ФЭВТ/TREF (фракционированием элюцией при возрастающей температуре) в закалочном режиме.
EA201490227A 2011-07-08 2012-07-06 Металлоцен-катализированный полиэтилен EA027509B1 (ru)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP11173375 2011-07-08
EP11173376 2011-07-08
EP11184554 2011-10-10
EP11184553 2011-10-10
EP12171379 2012-06-08
PCT/EP2012/063217 WO2013007619A1 (en) 2011-07-08 2012-07-06 Metallocene-catalyzed polyethylene

Publications (2)

Publication Number Publication Date
EA201490227A1 true EA201490227A1 (ru) 2014-04-30
EA027509B1 EA027509B1 (ru) 2017-08-31

Family

ID=46508038

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201490227A EA027509B1 (ru) 2011-07-08 2012-07-06 Металлоцен-катализированный полиэтилен

Country Status (13)

Country Link
US (1) US10053522B2 (ru)
EP (1) EP2729525B1 (ru)
CN (1) CN103781838B (ru)
BR (1) BR112014000435B1 (ru)
CA (1) CA2839965C (ru)
DK (1) DK2729525T3 (ru)
EA (1) EA027509B1 (ru)
ES (1) ES2764413T3 (ru)
HU (1) HUE046972T2 (ru)
PL (1) PL2729525T3 (ru)
PT (1) PT2729525T (ru)
TW (1) TWI460221B (ru)
WO (1) WO2013007619A1 (ru)

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Also Published As

Publication number Publication date
CA2839965A1 (en) 2013-01-17
PL2729525T3 (pl) 2020-04-30
WO2013007619A1 (en) 2013-01-17
EP2729525B1 (en) 2019-10-09
BR112014000435B1 (pt) 2020-03-31
TWI460221B (zh) 2014-11-11
CN103781838A (zh) 2014-05-07
PT2729525T (pt) 2020-01-16
EA027509B1 (ru) 2017-08-31
TW201311799A (zh) 2013-03-16
HUE046972T2 (hu) 2020-04-28
US20140127427A1 (en) 2014-05-08
BR112014000435A2 (pt) 2017-02-14
WO2013007619A9 (en) 2013-03-07
US10053522B2 (en) 2018-08-21
CA2839965C (en) 2020-02-25
DK2729525T3 (da) 2020-01-02
CN103781838B (zh) 2016-04-06
ES2764413T3 (es) 2020-06-03
EP2729525A1 (en) 2014-05-14

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