EA201400856A1 - Способ разделения газов для получения водорода посредством автотермического реформинга природного газа с извлечением углекислого газа - Google Patents

Способ разделения газов для получения водорода посредством автотермического реформинга природного газа с извлечением углекислого газа

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Publication number
EA201400856A1
EA201400856A1 EA201400856A EA201400856A EA201400856A1 EA 201400856 A1 EA201400856 A1 EA 201400856A1 EA 201400856 A EA201400856 A EA 201400856A EA 201400856 A EA201400856 A EA 201400856A EA 201400856 A1 EA201400856 A1 EA 201400856A1
Authority
EA
Eurasian Patent Office
Prior art keywords
gas
separation
carbon
gases
extracting
Prior art date
Application number
EA201400856A
Other languages
English (en)
Other versions
EA028109B1 (ru
Inventor
Николас Пи. Уинн
Дуглас Готтшлих
Хайкинг Лин
Original Assignee
Мембрэйн Текнолоджи Энд Рисёч, Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Мембрэйн Текнолоджи Энд Рисёч, Инк. filed Critical Мембрэйн Текнолоджи Энд Рисёч, Инк.
Publication of EA201400856A1 publication Critical patent/EA201400856A1/ru
Publication of EA028109B1 publication Critical patent/EA028109B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

В заявке описан способ разделения газа для получения водорода путем автотермического реформинга природного газа с одновременным извлечением диоксида углерода с использованием избирательного мембранного отделения диоксида углерода. Остаточный газ после получения водорода и извлечения диоксида углерода возвращают в повторный цикл в установку автотермического реформинга.
EA201400856A 2012-02-10 2013-02-01 Способ разделения газов для получения водорода посредством автотермического риформинга природного газа с извлечением углекислого газа EA028109B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/370,942 US8771637B2 (en) 2012-02-10 2012-02-10 Gas separation process for production of hydrogen by autothermal reforming of natural gas, with carbon dioxide recovery
US13/370,942 2012-02-10
PCT/US2013/024359 WO2013119465A1 (en) 2012-02-10 2013-02-01 Gas separation process for production of hydrogen by autothermal reforming of natural gas, with carbon dioxide recovery

Publications (2)

Publication Number Publication Date
EA201400856A1 true EA201400856A1 (ru) 2015-01-30
EA028109B1 EA028109B1 (ru) 2017-10-31

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA201400856A EA028109B1 (ru) 2012-02-10 2013-02-01 Способ разделения газов для получения водорода посредством автотермического риформинга природного газа с извлечением углекислого газа

Country Status (5)

Country Link
US (1) US8771637B2 (ru)
CN (1) CN104203811B (ru)
EA (1) EA028109B1 (ru)
MY (1) MY169751A (ru)
WO (1) WO2013119465A1 (ru)

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CN110921616B (zh) * 2019-10-28 2023-08-01 中科液态阳光(苏州)氢能科技发展有限公司 二氧化碳混合余气重整方法
CN110862067B (zh) * 2019-10-28 2023-08-18 中科院大连化学物理研究所张家港产业技术研究院有限公司 甲醇水加氢站低压制氢系统及其工作方法
US11535514B2 (en) * 2020-02-26 2022-12-27 Gas Technology Institute System and method for recycling pressure swing absorber off-gas
US11718522B2 (en) 2021-01-04 2023-08-08 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via bi-reforming
US11814289B2 (en) 2021-01-04 2023-11-14 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via steam reforming
US11820658B2 (en) 2021-01-04 2023-11-21 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via autothermal reforming
US11724943B2 (en) 2021-01-04 2023-08-15 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via dry reforming
MX2023007845A (es) * 2021-01-08 2023-07-07 Lummus Technology Inc Recuperacion mejorada de hidrogeno utilizando membranas para la separacion del gas, integradas con una unidad de adsorcion por cambio de presion y/o un sistema de separacion criogenica.
EP4294756A1 (en) * 2021-02-22 2023-12-27 Fluor Technologies Corporation Improved gas reformer for producing hydrogen
US20230082135A1 (en) * 2021-09-08 2023-03-16 Uop Llc Apparatuses and processes for the recovery of carbon dioxide streams
EP4433414A1 (en) 2021-11-18 2024-09-25 8 Rivers Capital, LLC Apparatus for hydrogen production
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WO2023173279A1 (en) * 2022-03-15 2023-09-21 Uop, Llc Process for producing hydrogen from hydrogen-containing gas

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Also Published As

Publication number Publication date
CN104203811A (zh) 2014-12-10
EA028109B1 (ru) 2017-10-31
US8771637B2 (en) 2014-07-08
WO2013119465A1 (en) 2013-08-15
CN104203811B (zh) 2017-02-22
US20120141367A1 (en) 2012-06-07
MY169751A (en) 2019-05-15

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Designated state(s): AM AZ BY KZ KG TJ TM RU