EA201100592A1 - Способ и устройство для производства синтез-газа из газообразных углеводородов - Google Patents

Способ и устройство для производства синтез-газа из газообразных углеводородов

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Publication number
EA201100592A1
EA201100592A1 EA201100592A EA201100592A EA201100592A1 EA 201100592 A1 EA201100592 A1 EA 201100592A1 EA 201100592 A EA201100592 A EA 201100592A EA 201100592 A EA201100592 A EA 201100592A EA 201100592 A1 EA201100592 A1 EA 201100592A1
Authority
EA
Eurasian Patent Office
Prior art keywords
energy
gas
synthesis gas
supplied
hydrocarbons
Prior art date
Application number
EA201100592A
Other languages
English (en)
Other versions
EA019737B1 (ru
Inventor
Карл-Хайнц Тетцлафф
Original Assignee
Карл-Хайнц Тетцлафф
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Карл-Хайнц Тетцлафф filed Critical Карл-Хайнц Тетцлафф
Publication of EA201100592A1 publication Critical patent/EA201100592A1/ru
Publication of EA019737B1 publication Critical patent/EA019737B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00398—Controlling the temperature using electric heating or cooling elements inside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407—Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085—Methods of heating the process for making hydrogen or synthesis gas by electric heating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Представлен и описан способ производства синтез-газа из газообразных углеводородов посредством аллотермического парового риформинга с катализаторами. Для возможности эффективного производства без отработанных газов синтез-газа в компактном устройстве предусмотрено, что энергию, по меньшей мере, частично подают посредством электрической энергии, энергию подают посредством электрически нагреваемых контактных поверхностей, и энергию подают посредством контактных поверхностей внутри засыпки гранул катализатора и/или внутри состоящего, по меньшей мере, частично из частиц катализатора псевдоожиженного слоя.
EA201100592A 2008-10-08 2009-10-08 Способ и устройство для производства синтез-газа из газообразных углеводородов EA019737B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008050817A DE102008050817A1 (de) 2008-10-08 2008-10-08 Abgasfreie allotherme Dampfreformierung
PCT/EP2009/063073 WO2010040795A1 (de) 2008-10-08 2009-10-08 Verfahren und vorrichtung zur herstellung von synthesegas aus gasförmigen kohlenwasserstoffen

Publications (2)

Publication Number Publication Date
EA201100592A1 true EA201100592A1 (ru) 2011-10-31
EA019737B1 EA019737B1 (ru) 2014-05-30

Family

ID=41647087

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201100592A EA019737B1 (ru) 2008-10-08 2009-10-08 Способ и устройство для производства синтез-газа из газообразных углеводородов

Country Status (11)

Country Link
US (1) US9314761B2 (ru)
EP (1) EP2334592B1 (ru)
DE (1) DE102008050817A1 (ru)
DK (1) DK2334592T3 (ru)
EA (1) EA019737B1 (ru)
ES (1) ES2393316T3 (ru)
HK (1) HK1159058A1 (ru)
HR (1) HRP20120911T1 (ru)
PL (1) PL2334592T3 (ru)
TW (1) TWI397504B (ru)
WO (1) WO2010040795A1 (ru)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009032524B3 (de) * 2009-07-10 2011-02-03 Highterm Research Gmbh Reaktor zur Erzeugung eines Produktgases durch allotherme Vergasung von kohlenstoffhaltigen Einsatzstoffen
US9604892B2 (en) * 2011-08-04 2017-03-28 Stephen L. Cunningham Plasma ARC furnace with supercritical CO2 heat recovery
DE102011089656A1 (de) * 2011-12-22 2013-06-27 Friedrich-Alexander-Universität Erlangen-Nürnberg Verfahren zur Einspeicherung von Energie die in Form von elektrischem Strom oder Wärme vorliegt in ein Eduktgasgemisch sowie eine Vorrichtung zur Durchführung dieses Verfahrens
EP3103550A4 (en) * 2014-02-07 2017-10-18 Hitachi Zosen Corporation Catalyst and method for purifying combustion exhaust gas
EP3140601A4 (en) 2014-05-09 2017-11-08 Stephen Lee Cunningham Arc furnace smeltering system & method
DE102014016407A1 (de) * 2014-11-05 2016-05-12 Linde Aktiengesellschaft Verfahren zur Produktion von Synthesegas
WO2019110265A1 (en) 2017-12-08 2019-06-13 Haldor Topsøe A/S A process and system for reforming a hydrocarbon gas
WO2019110268A1 (en) 2017-12-08 2019-06-13 Haldor Topsøe A/S A plant and process for producing synthesis gas
UA127416C2 (uk) 2017-12-08 2023-08-16 Хальдор Топсьое А/С Спосіб і система для виробництва синтез-газу
FR3101075B1 (fr) * 2019-09-19 2022-07-29 Commissariat Energie Atomique : Réacteur à lit fixe catalytique intégrant un élément chauffant électrique, Unité de production d’hydrogène par vaporeformage comprenant un tel réacteur et un générateur de vapeur électrique, procédé de fonctionnement associé.
US11964868B2 (en) 2020-07-28 2024-04-23 Totalenergies Onetech Process to conduct an endothermic steam reforming reaction in a fluidized bed reactor
WO2022049147A1 (en) * 2020-09-02 2022-03-10 Haldor Topsøe A/S Production of syntehsis gas in a plant comprising an electric steam reformer downstream of fired reformer
EP4208409A1 (en) * 2020-09-02 2023-07-12 Topsoe A/S Production of synthesis gas in a plant comprising an electric steam reformer downstream of a heat exchange reformer
KR20230098604A (ko) * 2020-10-30 2023-07-04 가스 테크놀로지 인스티튜트 메탄 및 기타 탄화수소 개질용 전기 가열식 개질 반응기
IT202100026456A1 (it) * 2021-10-15 2023-04-15 Milano Politecnico Reattore con struttura termo-conduttiva riscaldata elettricamente per processi catalitici endotermici
CN115196595A (zh) * 2022-05-16 2022-10-18 西安交通大学 一种天然气制富氢合成气电热蒸汽重整炉

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE258651C (ru) 1912-05-29 1913-04-11
DE1714833U (de) 1955-08-05 1956-01-12 Mueller Schuss K G Kabel- oder seiltrommel, welche in mehreren einheiten uebereinander stapelbar ist.
US3147080A (en) * 1961-07-10 1964-09-01 Exxon Research Engineering Co Process for preparing hydrogen by steam reforming of hydrocarbons
US3499947A (en) * 1966-08-05 1970-03-10 Phillips Petroleum Co Electrothermic fluidized bed process
FR1543423A (fr) * 1967-09-12 1968-10-25 Azote & Prod Chim Procédé de reformage des hydrocarbures lourds
CH645318A5 (de) * 1978-11-21 1984-09-28 Silberring Ludwig Verfahren und vorrichtung zur herstellung von wasserstoff.
DD258651A1 (de) * 1983-08-03 1988-07-27 Jenapharm Veb Elektrisch beheizter rohrbuendelwaermeuebertrager fuer den waermeaustausch zweier medien
US5019356A (en) * 1986-05-23 1991-05-28 Ludwig Silberring Steam reformer with internal heat recovery
US5059404A (en) * 1989-02-14 1991-10-22 Manufacturing And Technology Conversion International, Inc. Indirectly heated thermochemical reactor apparatus and processes
JPH11130405A (ja) * 1997-10-28 1999-05-18 Ngk Insulators Ltd 改質反応装置、触媒装置、それらに用いる発熱・触媒体、及び改質反応装置の運転方法
JP2000007301A (ja) 1998-06-29 2000-01-11 Ngk Insulators Ltd 改質反応装置
US6620386B1 (en) * 1998-07-09 2003-09-16 Stone & Webster, Inc. Radial flow reactor
US6238815B1 (en) * 1998-07-29 2001-05-29 General Motors Corporation Thermally integrated staged methanol reformer and method
JP4648515B2 (ja) * 2000-05-02 2011-03-09 株式会社日本触媒 反応器のスタートアップ方法
US6620368B1 (en) 2000-07-13 2003-09-16 Simax Technologies, Inc. Sol-gel process for production of oxide-based glass and ceramic articles
US6747066B2 (en) * 2002-01-31 2004-06-08 Conocophillips Company Selective removal of oxygen from syngas
CA2396402A1 (en) * 2002-07-29 2004-01-29 Hydrogenics Corporation Electrocatalytic reformer for synthesis gas production
US20040097371A1 (en) * 2002-11-19 2004-05-20 Juzer Jangbarwala Application of conductive adsorbents, activated carbon granules and carbon fibers as substrates in catalysis
US20050229488A1 (en) * 2004-04-19 2005-10-20 Texaco Inc. Method and apparatus for providing a continuous stream of reformate
US7736399B2 (en) * 2006-11-07 2010-06-15 Delphi Technologies, Inc. Electrically-heated metal vaporizer for fuel/air preparation in a hydrocarbon reformer assembly

Also Published As

Publication number Publication date
TW201028365A (en) 2010-08-01
HRP20120911T1 (hr) 2012-12-31
PL2334592T3 (pl) 2013-01-31
EA019737B1 (ru) 2014-05-30
EP2334592A1 (de) 2011-06-22
ES2393316T3 (es) 2012-12-20
TWI397504B (zh) 2013-06-01
US9314761B2 (en) 2016-04-19
DK2334592T3 (da) 2012-11-12
HK1159058A1 (en) 2012-07-27
US20120025140A1 (en) 2012-02-02
WO2010040795A1 (de) 2010-04-15
EP2334592B1 (de) 2012-08-15
DE102008050817A1 (de) 2010-04-15

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU