EA035710B1 - Способ удаления соединений серы из технологических потоков - Google Patents
Способ удаления соединений серы из технологических потоков Download PDFInfo
- Publication number
- EA035710B1 EA035710B1 EA201890938A EA201890938A EA035710B1 EA 035710 B1 EA035710 B1 EA 035710B1 EA 201890938 A EA201890938 A EA 201890938A EA 201890938 A EA201890938 A EA 201890938A EA 035710 B1 EA035710 B1 EA 035710B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- aqueous solution
- solids content
- organic solids
- glyoxal
- glycolaldehyde
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 23
- WGCNASOHLSPBMP-UHFFFAOYSA-N Glycolaldehyde Chemical compound OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000007864 aqueous solution Substances 0.000 claims abstract description 48
- 150000003464 sulfur compounds Chemical class 0.000 claims abstract description 9
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 60
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 48
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 33
- 229940015043 glyoxal Drugs 0.000 claims description 32
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical group CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 claims description 28
- 239000007787 solid Substances 0.000 claims description 22
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- 239000011593 sulfur Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 claims description 13
- 229940120731 pyruvaldehyde Drugs 0.000 claims description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 239000003915 liquefied petroleum gas Substances 0.000 claims description 6
- 239000010779 crude oil Substances 0.000 claims description 5
- 239000003345 natural gas Substances 0.000 claims description 5
- 239000002283 diesel fuel Substances 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 4
- 239000003350 kerosene Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- -1 syngas Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 29
- 239000000203 mixture Substances 0.000 description 20
- 239000002516 radical scavenger Substances 0.000 description 17
- 238000013467 fragmentation Methods 0.000 description 14
- 238000006062 fragmentation reaction Methods 0.000 description 14
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 9
- 235000000346 sugar Nutrition 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000001172 regenerating effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 235000014633 carbohydrates Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 238000001149 thermolysis Methods 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 231100000722 genetic damage Toxicity 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229940048181 sodium sulfide nonahydrate Drugs 0.000 description 1
- WMDLZMCDBSJMTM-UHFFFAOYSA-M sodium;sulfanide;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[SH-] WMDLZMCDBSJMTM-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0005—Degasification of liquids with one or more auxiliary substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
- C10G29/24—Aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/101—Sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA201500633 | 2015-10-14 | ||
| PCT/EP2016/074745 WO2017064267A1 (en) | 2015-10-14 | 2016-10-14 | A process for removing sulphur compounds from process streams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201890938A1 EA201890938A1 (ru) | 2018-11-30 |
| EA035710B1 true EA035710B1 (ru) | 2020-07-29 |
Family
ID=57136899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201890938A EA035710B1 (ru) | 2015-10-14 | 2016-10-14 | Способ удаления соединений серы из технологических потоков |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10875789B2 (enExample) |
| EP (1) | EP3362535B1 (enExample) |
| CN (1) | CN108026454B (enExample) |
| BR (1) | BR112018004879B8 (enExample) |
| CA (1) | CA3001767C (enExample) |
| EA (1) | EA035710B1 (enExample) |
| MX (1) | MX383761B (enExample) |
| PL (1) | PL3362535T3 (enExample) |
| SA (1) | SA518391338B1 (enExample) |
| WO (1) | WO2017064267A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2839510T3 (es) | 2016-06-16 | 2021-07-05 | Haldor Topsoe As | Fragmentación termolítica de azúcares |
| US10513662B2 (en) * | 2017-02-02 | 2019-12-24 | Baker Hughes, A Ge Company, Llc | Functionalized aldehydes as H2S and mercaptan scavengers |
| CN112424153B (zh) | 2018-07-16 | 2023-11-03 | 托普索公司 | 使用电阻加热对糖进行热裂解 |
| WO2020129446A1 (ja) * | 2018-12-21 | 2020-06-25 | 株式会社クラレ | 炭化水素の製造方法、精製方法及び精製装置 |
| AU2022281113A1 (en) | 2021-05-28 | 2023-10-26 | Topsoe A/S | Process for partial condensation of an oxygenate mixture |
| KR20250036717A (ko) | 2022-07-08 | 2025-03-14 | 토프쉐 에이/에스 | 옥시게네이트 혼합물의 응축 방법 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2426318A (en) * | 1945-11-15 | 1947-08-26 | Stanolind Oil & Gas Co | Inhibiting corrosion |
| US5223175A (en) * | 1989-09-05 | 1993-06-29 | Societe Francaise Hoechst | Water-in-oil emulsions and their use in the elimination of hydrogen sulphide |
| US20020157989A1 (en) * | 2001-04-25 | 2002-10-31 | Clearwater, Inc. | Treatment of hydrocarbons Containing Sulfides |
| US20040022912A1 (en) * | 2000-11-20 | 2004-02-05 | Majerski Piotr A | Production of glycolaldehyde by hydrous thermolysis of sugars |
| WO2014131743A1 (en) * | 2013-02-27 | 2014-09-04 | Haldor Topsøe A/S | Process for removing formaldehyde from a composition comprising glycolaldhedyde |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4680127A (en) | 1985-12-13 | 1987-07-14 | Betz Laboratories, Inc. | Method of scavenging hydrogen sulfide |
| GB8602320D0 (en) | 1986-01-30 | 1986-03-05 | British Petroleum Co | Removing hydrogen sulphide from crude oil |
| US5284635A (en) | 1989-09-05 | 1994-02-08 | Societe Francaise Hoechst | Process for the elimination of hydrogen sulfide by using water-in-oil emulsions |
| US8436120B2 (en) | 2007-11-20 | 2013-05-07 | Jan Piskorz | Method of producing hodge carbonyls and oligomeric lignin |
| US20110147272A1 (en) | 2009-12-23 | 2011-06-23 | General Electric Company | Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers |
| US9068269B2 (en) | 2011-10-05 | 2015-06-30 | Baker Hughes Incorporated | Inhibiting corrosion caused by aqueous aldehyde solutions |
| CN104471144B (zh) * | 2012-06-28 | 2017-03-01 | 国际壳牌研究有限公司 | 使用浆料催化剂的提供集成稳定的水解产物的生物质转化系统及其使用方法 |
-
2016
- 2016-10-14 EP EP16781803.8A patent/EP3362535B1/en active Active
- 2016-10-14 PL PL16781803T patent/PL3362535T3/pl unknown
- 2016-10-14 BR BR112018004879A patent/BR112018004879B8/pt active IP Right Grant
- 2016-10-14 MX MX2018004223A patent/MX383761B/es unknown
- 2016-10-14 US US15/768,302 patent/US10875789B2/en active Active
- 2016-10-14 CA CA3001767A patent/CA3001767C/en active Active
- 2016-10-14 EA EA201890938A patent/EA035710B1/ru not_active IP Right Cessation
- 2016-10-14 CN CN201680055901.8A patent/CN108026454B/zh active Active
- 2016-10-14 WO PCT/EP2016/074745 patent/WO2017064267A1/en not_active Ceased
-
2018
- 2018-04-11 SA SA518391338A patent/SA518391338B1/ar unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2426318A (en) * | 1945-11-15 | 1947-08-26 | Stanolind Oil & Gas Co | Inhibiting corrosion |
| US5223175A (en) * | 1989-09-05 | 1993-06-29 | Societe Francaise Hoechst | Water-in-oil emulsions and their use in the elimination of hydrogen sulphide |
| US20040022912A1 (en) * | 2000-11-20 | 2004-02-05 | Majerski Piotr A | Production of glycolaldehyde by hydrous thermolysis of sugars |
| US20020157989A1 (en) * | 2001-04-25 | 2002-10-31 | Clearwater, Inc. | Treatment of hydrocarbons Containing Sulfides |
| WO2014131743A1 (en) * | 2013-02-27 | 2014-09-04 | Haldor Topsøe A/S | Process for removing formaldehyde from a composition comprising glycolaldhedyde |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2018004223A (es) | 2018-08-01 |
| EP3362535B1 (en) | 2020-05-06 |
| CA3001767C (en) | 2021-04-20 |
| CN108026454A (zh) | 2018-05-11 |
| CN108026454B (zh) | 2020-11-27 |
| EP3362535A1 (en) | 2018-08-22 |
| BR112018004879A2 (enExample) | 2018-10-02 |
| MX383761B (es) | 2025-03-14 |
| US20180312410A1 (en) | 2018-11-01 |
| CA3001767A1 (en) | 2017-04-20 |
| WO2017064267A1 (en) | 2017-04-20 |
| PL3362535T3 (pl) | 2020-11-02 |
| SA518391338B1 (ar) | 2022-02-08 |
| BR112018004879B8 (pt) | 2022-07-26 |
| BR112018004879B1 (pt) | 2022-05-24 |
| EA201890938A1 (ru) | 2018-11-30 |
| US10875789B2 (en) | 2020-12-29 |
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