DK2751188T3 - Vulkaniserbare sammensætninger på basis af epoxygruppe-holdige ethylen-vinylacetat-copolymerisater - Google Patents
Vulkaniserbare sammensætninger på basis af epoxygruppe-holdige ethylen-vinylacetat-copolymerisater Download PDFInfo
- Publication number
- DK2751188T3 DK2751188T3 DK12753978.1T DK12753978T DK2751188T3 DK 2751188 T3 DK2751188 T3 DK 2751188T3 DK 12753978 T DK12753978 T DK 12753978T DK 2751188 T3 DK2751188 T3 DK 2751188T3
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- DK
- Denmark
- Prior art keywords
- ether
- weight
- epoxyheptyl
- vinyl acetate
- glycidyl
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0884—Epoxide containing esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Claims (12)
1. Vulkaniserbar sammensætning indeholdende (a) i det mindste et epoxygruppe-holdigt ethylen-vinylacetat-copolymerisat med et vinylacetatindhold på i det mindste 20 vægt-%, fortrinsvis i det mindste 30 vægt-%, særligt foretrukket i det mindste 40 vægt-%, baseret på det epoxygruppe-holdige ethylen-vinylacetat-copolymerisat og (b) i det mindste en carboxyleret nitrilkautsjuk, idet forholdet mellem (a) og (b) udgør fra 1 : 3 til 3 : 1, fortrinsvis 1:1.
2. Vulkaniserbar sammensætning ifølge krav 1, kendetegnet ved, at det epoxidgruppe-holdige ethylen-vinylacetat-copolymerisat (a) har gentagelsesenheder fra en epoxygruppe-holdig monomer med den almene formel (I)
(i) hvor m er 0 eller 1, og X står for O, O(CR2)p, (CR2)pO, C(=O)O, C (=0) O (CR2) p, C(=O)NR, (CR2)p, N(R), N(R) (CR2)p, P(R), P(R)(CR2)p, P(=0)(R), P (=0) (R) (CR2)p, S, S(CR2)p, S(=0), S(=O)(CR2)p, S(=O)2(CR2)p eller S(=0)2, idet R i disse grupper kan have de samme betegnelser som R2-R6, Y står for gentagelsesenheder fra en eller flere, en eller flere gange umættede monomerer omfattende konjugerede eller ikke-konjugerede diener, alkiner og vinylforbindelser, eller for et strukturelement, som afledes af polymerer omfattende polyether, navnlig polyalkylenglykolethere og polyalkylenoxider, polysiloxaner, polyoler, polycarbonater, polyurethaner, polyisocyanater, polysaccharider, polyestere og polyamider, n og p er ens eller forskellige og hver især ligger i området fra 0 til 10.000,
R, R1, R2, R3, R4, R5 og R6 er ens eller forskellige og står for H, en lineær eller forgrenet, mættet, en eller flere gange umættet alkylgruppe, en mættet, en eller flere gange umættet carbo- eller heterocyclylgruppe, aryl, heteroaryl, arylalkyl, heteroarylalkyl, alkoxy, aryloxy, heteroaryloxy, amino, amido, carbamoyl, alkylthio, arylthio, sulfanyl, thiocarboxy, sulfinyl, sulfono, sulfino, sulfeno, sulfonsyrer, sulfamoyl, hydroxyimino, alkoxycarbonyl, F, Cl, Br, I, hydroxy, phosphonato, phosphinato, silyl, silyloxy, nitril, borater, selenater, carbonyl, carboxy, oxycarbonyl, oxysulfonyl, oxo, thioxo, epoxy, cyanater, thiocyanater, isocyanater, thioisocyanater eller isocyanider.
3. Vulkaniserbar sammensætning ifølge krav 2, kendetegnet ved, at det epoxidgruppe-holdige ethylen-vinylacetat-copolymerisat (a) indeholder gentagelsesenheder fra en epoxygruppe-holdig monomer udvalgt af gruppen 2-ethylglycidylacrylat, 2-ethylglycidylmethacrylat, 2- (n-propyl)glycidylacrylat, 2-(n-propyl)glycidylmethacrylat, 2-(n-butyl)glycidylacrylat, 2- (n-butyl)glycidylmethacrylat, glycidylmethacrylat, glycidylmethylacrylat, glycidylmethyl-methacrylat, glycidylacrylat, (3',4'-epoxyheptyl)-2-ethylacrylat, (3 ' , 4'-epoxyheptyl)-2-ethyl-meth-acrylat, (6' , 7'-epoxyheptyl)acrylat, (6',7'-epoxyheptyl)methacrylat, allylglycidylether, allyl-3,4-epoxyheptyl-ether, 6,7-epoxyheptylallylether, vinylglycidylether, vinyl-3,4-epoxyheptylether, 3,4-epoxyheptylvinylether, 6,7-epoxyheptylvinylether, o-vinyl-benzylglycidylether, m-vinyl-benzylglycidylether, p-vinylbenzylglycidylether og 3-vinylcyclohexenoxid.
4. Vulkaniserbar sammensætning ifølge krav 3, kendetegnet ved, at den har en andel af epoxy-monomerer på mindre end 20 vægt-%, fortrinsvis mindre end 15 vægt-%, særligt foretrukket mindre end 10 vægt-%, baseret på ethylen-vinylacetat-copolymerisatet.
5. Vulkaniserbar sammensætning ifølge krav 4, kendetegnet ved, at den carboxylerede nitrilkautsjuk i gentagelsesenhederne er afledt af i det mindste en konjugeret dien, i det mindste en a, β-umættet nitril og en eller flere carboxylgruppe-holdige monomerer.
6. Vulkaniserbar sammensætning ifølge krav 5, kendetegnet ved, at den carboxylerede nitrilkautsjuk har gentagelsesenheder fra en carboxylgruppe-holdig monomer med den almene formel (II)
(Π) hvor R1, R2, R3 er ens eller forskellige og står for H, en lineær eller forgrenet, mættet, en eller flere gange umættet alkylgruppe, en mættet, en eller flere gange umættet carbo-eller heterocyclylgruppe, aryl, heteroaryl, arylalkyl, heteroarylalkyl, alkoxy, aryloxy, heteroaryloxy, amino, amido, carbamoyl, alkylthio, arylthio, sulfanyl, thiocarboxy, sulfinyl, sulfono, sulfino, sulfeno, sulfonsyrer, sulfamoyl, hydroxyimino, alkoxycarbonyl, F, Cl, Br, I, hydroxy, phosphonato, phosphinato, silyl, silyloxy, nitril, borater, selenater, carbonyl, carboxy, oxycarbonyl, oxysulfonyl, oxo, thioxo, epoxy, cyanater, thiocyanater, isocyanater, thioisocyanater, isocyanider eller carboxylgrupper, n er 0 eller 1, og X står for 0, O(CR2)P, (CR2)PO, C(=0)0, C (=0) 0 (CR2) P, C(=0)NR, (CR2)p, N(R), N(R) (CR2)p, P (R) , P(R)(CR2)P, P (=0) (R) , P (=0) (R) (CR2)p, S, S(CR2)p, S(=0), S(=O)(CR2)p, S(=O)2(CR2)p eller S(=0)2, idet R i disse grupper kan have de samme betegnelser som R3-R3, og P kan antage værdier mellem 1 og 1.000, m er 0 eller 1, og Y er ens eller forskellig og står for en lineær eller forgrenet, mættet, en eller flere gange umættet alkylgruppe, en mættet, en eller flere gange umættet carbo- eller
heterocyclylgruppe, aryl, heteroaryl, arylalkyl, heteroarylalkyl eller alkoxyarylgruppe.
7. Vulkaniserbar sammensætning ifølge krav 6, kendetegnet ved, at mængden af caboxylgruppe-holdige monomerer udgør 1 -20 vægtandele, fortrinsvis 2-10 vægtandele, baseret på 100 vægtandele af nitrilskautsjukken, som kan afledes af acrylnitril og de konjugerede dien-monomerer.
8. Vulkaniserbar sammensætning ifølge krav 7, kendetegnet ved, at den carboxylerede nitrilkautsjuk er helt eller delvist hydreret.
9. Vulkaniserbar sammensætning ifølge et eller flere af kravene 1 til 8 indeholdende (a) i det mindste et epoxygruppe-holdigt ethylen-vinylacetat-copolymerisat med et vinylacetatindhold på i det mindste 20 vægt-%, fortrinsvis i det mindste 30 vægt-%, særligt foretrukket i det mindste 40 vægt-%, baseret på det epoxygruppe-holdige ethylen-vinylacetat-copolymerisat, som afleder gentagelsesenheder af i det mindste en ethylen, en vinylester, i det mindste en epoxygruppe-holdig monomer udvalgt af gruppen bestående af 2-ethylglycidylacrylat, 2-ethylglycidylmethacrylat, 2-(n-propyl)glycidylacrylat, 2-(n-propyl)glycidylmethacrylat, 2-(n-butyl)glycidylacrylat, 2-(n-butyl)glycidylmethacrylat, glycidylmethacrylat, glycidylmethylacrylat, glycidylmethyl-methacrylat, glycidylacrylat, (3',4'-epoxyheptyl)-2-ethylacrylat, (3' ,4 '-epoxyheptyl)-2-ethyl-meth-acrylat, (6' , 7'-epoxyheptyl)acrylat, (6', 7'-epoxyheptyl)methacrylat, allylglycidylether, allyl-3,4-epoxyheptylether, 6,7-epoxyheptylallylether, vinylglycidylether, vinyl-3,4-epoxyheptylether, 3,4-epoxyheptylvinylether, 6,7-epoxyheptylvinylether, o-vinyl-benzylglycidylether, m-vinylbenzylglycidylether, p-vinylbenzylglycidylether og 3-vinylcyclohexenoxid og (b) i det mindste en carboxyleret nitrilkautsjuk.
10. Fremgangsmåde til fremstilling af en vulkaniseret sammensætning ifølge et eller flere af kravene 1 til 8 ved hjælp af sammenblanding af i det mindste et epoxygruppe-holdigt ethylen-vinylacetat-copolymerisat (a) med i det mindste en carboxyleret nitrilkautsjuk (b) , idet forholdet mellem (a) og (b) udgør fra 1 : 3 til 3 : 1, fortrinsvis 1 : 1.
11. Fremgangsmåde til fremstilling af vulkanisater på basis af epoxygruppe-holdige ethylen-vinylacetat- copolymerisater, kendetegnet ved, at den vulkaniserbare sammensætning ifølge et eller flere af kravene 1 til 9 tværbindes under forøgelse af temperaturen i området fra 20 til 250°C, fortrinsvis i området fra 50 til 230°C, særligt foretrukket 100°C til 210°C.
12. Vulkanisater, som er opnåelige ved hjælp af fremgangsmåde ifølge krav 11.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11179940A EP2565229A1 (de) | 2011-09-02 | 2011-09-02 | Vulkanisierbare Zusammensetzungen auf Basis von Epoxygruppen-haltigen Ethylenvinylacetat-Copolymerisaten |
| PCT/EP2012/066983 WO2013030352A1 (de) | 2011-09-02 | 2012-08-31 | Vulkanisierbare zusammensetzungen auf basis von epoxygruppen-haltigen ethylen-vinylacetat-copolymerisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2751188T3 true DK2751188T3 (da) | 2018-12-17 |
Family
ID=46796593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12753978.1T DK2751188T3 (da) | 2011-09-02 | 2012-08-31 | Vulkaniserbare sammensætninger på basis af epoxygruppe-holdige ethylen-vinylacetat-copolymerisater |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10100188B2 (da) |
| EP (2) | EP2565229A1 (da) |
| JP (1) | JP5845353B2 (da) |
| CN (1) | CN103814075B (da) |
| DK (1) | DK2751188T3 (da) |
| ES (1) | ES2689404T3 (da) |
| PL (1) | PL2751188T3 (da) |
| WO (1) | WO2013030352A1 (da) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2868676A1 (de) * | 2013-10-30 | 2015-05-06 | LANXESS Deutschland GmbH | Funktionalisierter nitrilgruppenhaltiger Copolymerkautschuk |
| EP3015483A1 (de) * | 2014-10-30 | 2016-05-04 | LANXESS Deutschland GmbH | Epoxygruppenhaltige Ethylen-Vinylacetat-Copolymere |
| CN105802099B (zh) * | 2016-05-17 | 2018-11-06 | 江南大学 | 热塑性组合物及其制备方法 |
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| US3700637A (en) | 1970-05-08 | 1972-10-24 | Shell Oil Co | Diene-nitrile rubbers |
| DE2539132C2 (de) | 1975-09-03 | 1987-04-09 | Bayer Ag, 5090 Leverkusen | Verwendung hydrierter Dien-Copolymere als temperaturbeständige Materialien auf dem Dichtungssektor |
| US4381378A (en) * | 1981-12-28 | 1983-04-26 | E. I. Du Pont De Nemours And Company | Method for vulcanizing ethylene/acrylic or vinyl ester/glycidyl(meth)acrylate copolymer with piperazinium dicarboxylate salt and composition for same |
| CA1203047A (en) | 1982-12-08 | 1986-04-08 | Hormoz Azizian | Polymer hydrogenation process |
| CA1220300A (en) | 1982-12-08 | 1987-04-07 | Polysar Limited | Polymer hydrogenation process |
| DE3329974A1 (de) | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Herstellung von hydrierten nitrilkautschuken |
| JPS6126620A (ja) * | 1984-07-18 | 1986-02-05 | Nippon Zeon Co Ltd | エポキシ基含有エラストマ−加硫性組成物 |
| DE3433392A1 (de) | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | Hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| DE3529252A1 (de) | 1985-08-16 | 1987-02-19 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| USRE34548E (en) | 1985-11-19 | 1994-02-15 | Bayer Aktiengesellschaft | Process for the selective hydrogenation of unsaturated compounds |
| DE3540918A1 (de) | 1985-11-19 | 1987-05-21 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE3541689A1 (de) | 1985-11-26 | 1987-05-27 | Bayer Ag | Verfahren zur selektiven hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| DE3618907A1 (de) | 1986-06-05 | 1987-12-10 | Bayer Ag | Verbundwerkstoffe aus vorbehandeltem fasermaterial und vulkanisaten aus hnbr |
| US4816525A (en) | 1987-07-06 | 1989-03-28 | University Of Waterloo | Polymer hydrogenation process |
| DE58906829D1 (de) | 1988-12-23 | 1994-03-10 | Bayer Ag | Kontinuierliches Verfahren zur Herstellung von Ethylen/Vinylester-Terpolymerisaten. |
| JP2867287B2 (ja) * | 1990-04-11 | 1999-03-08 | 三井・デュポンポリケミカル株式会社 | アイオノマー組成物 |
| DE4025781A1 (de) | 1990-08-15 | 1992-02-20 | Bayer Ag | Hydrierte butadien/isopren/(meth-)acrylnitril- copolymerisate |
| TW307801B (da) * | 1992-03-19 | 1997-06-11 | Minnesota Mining & Mfg | |
| DE19736310A1 (de) | 1997-08-21 | 1999-02-25 | Bayer Ag | Verfahren zur Herstellung von teilhydrierten Acrylnitril-Butadien-Kautschuken (HNBR) unter on-line-Anwendung der Raman-Spektroskopie |
| DE19805612A1 (de) | 1998-02-12 | 1999-08-19 | Bayer Ag | Verfahren zur kontrollierten Herstellung oder Modifizierung von polymeren Produkten mittels IR-ATR-Spektroskopie |
| US6340511B1 (en) | 1999-10-27 | 2002-01-22 | Tokai Rubber Industries, Ltd. | Fuel hose |
| JP2001226527A (ja) * | 2000-02-10 | 2001-08-21 | Jsr Corp | 耐油耐候性ゴム組成物及び耐油耐候性ゴム |
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| CA2350280A1 (en) | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
| US6673881B2 (en) | 2001-06-12 | 2004-01-06 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| DE10213227A1 (de) | 2002-03-25 | 2003-10-16 | Bayer Ag | Zusammensetzung |
| CA2462006A1 (en) * | 2004-02-23 | 2005-08-23 | Bayer Inc. | Curable plasticizer composition |
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-
2011
- 2011-09-02 EP EP11179940A patent/EP2565229A1/de not_active Ceased
-
2012
- 2012-08-31 ES ES12753978.1T patent/ES2689404T3/es active Active
- 2012-08-31 DK DK12753978.1T patent/DK2751188T3/da active
- 2012-08-31 WO PCT/EP2012/066983 patent/WO2013030352A1/de active Application Filing
- 2012-08-31 JP JP2014527678A patent/JP5845353B2/ja active Active
- 2012-08-31 EP EP12753978.1A patent/EP2751188B1/de active Active
- 2012-08-31 US US14/240,781 patent/US10100188B2/en active Active
- 2012-08-31 CN CN201280042867.2A patent/CN103814075B/zh active Active
- 2012-08-31 PL PL12753978T patent/PL2751188T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2689404T3 (es) | 2018-11-13 |
| CN103814075B (zh) | 2016-04-13 |
| EP2751188B1 (de) | 2018-08-22 |
| PL2751188T3 (pl) | 2019-01-31 |
| EP2751188A1 (de) | 2014-07-09 |
| WO2013030352A1 (de) | 2013-03-07 |
| JP5845353B2 (ja) | 2016-01-20 |
| CN103814075A (zh) | 2014-05-21 |
| US10100188B2 (en) | 2018-10-16 |
| US20150203675A1 (en) | 2015-07-23 |
| JP2014527567A (ja) | 2014-10-16 |
| EP2565229A1 (de) | 2013-03-06 |
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