DK2528985T3 - Nanofibrillær cellulose til oliefeltsapplikationer - Google Patents
Nanofibrillær cellulose til oliefeltsapplikationer Download PDFInfo
- Publication number
- DK2528985T3 DK2528985T3 DK11734416.8T DK11734416T DK2528985T3 DK 2528985 T3 DK2528985 T3 DK 2528985T3 DK 11734416 T DK11734416 T DK 11734416T DK 2528985 T3 DK2528985 T3 DK 2528985T3
- Authority
- DK
- Denmark
- Prior art keywords
- cellulose
- nfc
- fluid
- water
- fluids
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/588—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
- C08L1/04—Oxycellulose; Hydrocellulose, e.g. microcrystalline cellulose
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/06—Clay-free compositions
- C09K8/08—Clay-free compositions containing natural organic compounds, e.g. polysaccharides, or derivatives thereof
- C09K8/10—Cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/40—Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/514—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/516—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/70—Compositions for forming crevices or fractures characterised by their form or by the form of their components, e.g. foams
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/12—Methods or apparatus for controlling the flow of the obtained fluid to or in wells
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/08—Fiber-containing well treatment fluids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/10—Nanoparticle-containing well treatment fluids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Claims (3)
1. Anvendelse af et middel der er en nanofibrillær cellulose (NFC-L), som er i stand til at blive dispergeret i vand, som et viskositetsmodificerende middel til oliefeltsapplikationer, hvilken nanofibrillær cellulose er ikke-parenkymal cellulose, som er fibriller fra sekundære cellevægge af fibrøst råmateriale, der er afledt af træ, hvilken cellulose er kemisk præmodificeret ved oxidation, fibrillerne har en krystallinitetsgrad på mindst 55 % og har en diameter under 50 nm.
2. Fremgangsmåde i et oliefelt, hvorved en sammensætning der omfatter vand som bærer og et middel, der er blandet med vandet, pumpes til en underjordisk olieholdig formation, kendetegnet ved, at midlet er nanofibrillær cellulose (NFC-L), der er i stand til at blive dispergeret i vand, og den nanofibrillære cellulose er ikke-parenkymal cellulose, som er fibriller fra sekundære cellevægge af fibrøst råmateriale, der er afledt af træ, hvor cellulosen er blevet kemisk præmodificeret ved oxidation, hvilke fibriller har en krystallinitetsgrad på mindst 55 % og har en diameter under 50 nm.
3. Fremgangsmåden ifølge krav 2, kendetegnet ved, at sammensætningen anvendes som - hydraulisk fraktureringsvæske, - bærevæske til gruspakning, - separationsvæske, - forskydningsvæske, dvs. "oversvømmelsesvæske" til forbedret olieudvinding, - borevæske, - væske der indeholder et tætningsmiddel, eller - arbejdsvæske.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20100022A FI20100022A (fi) | 2010-01-25 | 2010-01-25 | Aine ja koostumus öljykenttäsovelluksiin |
PCT/FI2011/050058 WO2011089323A1 (en) | 2010-01-25 | 2011-01-25 | Agent and composition for oilfield applications |
Publications (1)
Publication Number | Publication Date |
---|---|
DK2528985T3 true DK2528985T3 (da) | 2018-08-20 |
Family
ID=41620831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK11734416.8T DK2528985T3 (da) | 2010-01-25 | 2011-01-25 | Nanofibrillær cellulose til oliefeltsapplikationer |
Country Status (11)
Country | Link |
---|---|
US (1) | US9200193B2 (da) |
EP (1) | EP2528985B1 (da) |
CN (1) | CN102803431B (da) |
AU (1) | AU2011208609C1 (da) |
BR (1) | BR112012017281A2 (da) |
CA (1) | CA2786831C (da) |
DK (1) | DK2528985T3 (da) |
EA (1) | EA023815B1 (da) |
FI (1) | FI20100022A (da) |
MX (1) | MX349129B (da) |
WO (1) | WO2011089323A1 (da) |
Families Citing this family (36)
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EP2734819A4 (en) | 2011-09-20 | 2015-02-25 | Halliburton Energy Serv Inc | SYSTEMS AND TOOLS FOR THE DETECTION OF PROHIBITED OR DANGEROUS SUBSTANCES |
US9133384B2 (en) | 2012-01-31 | 2015-09-15 | Halliburton Energy Services, Inc. | Cellulose nanowhiskers in well services |
FI126819B (en) | 2012-02-13 | 2017-06-15 | Upm Kymmene Corp | Procedure for concentrating fibrillar cellulose and fibrillar cellulose product |
US20150072902A1 (en) * | 2012-04-13 | 2015-03-12 | Schlumberger Technology Corporation | Fluids and Methods Including Nanocellulose |
US20130274149A1 (en) * | 2012-04-13 | 2013-10-17 | Schlumberger Technology Corporation | Fluids and methods including nanocellulose |
FI20125943A (fi) * | 2012-09-11 | 2014-03-12 | Upm Kymmene Corp | Menetelmä ja seos keraamien valmistamiseksi |
US20140155301A1 (en) * | 2012-11-30 | 2014-06-05 | Api Intellectual Property Holdings, Llc | Processes and apparatus for producing nanocellulose, and compositions and products produced therefrom |
NO343138B1 (no) * | 2013-03-20 | 2018-11-19 | Elkem Materials | Viskositetsøkende middel for borefluider |
WO2014154348A1 (en) | 2013-03-25 | 2014-10-02 | Borregaard As | Composition comprising water-soluble polymer and microfibrillated cellulose, product and method for oilfield applications |
CA2921219C (en) * | 2013-08-30 | 2021-09-07 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Additive for drilling mud comprising i-type crystal structure cellulose fibers with specified number average fiber diameters and aspect ratios |
RU2016105773A (ru) * | 2013-08-30 | 2017-10-05 | Дай-Ити Когио Сейяку Ко., Лтд. | Добавка для извлечения сырой нефти |
GB2535889A (en) | 2013-11-05 | 2016-08-31 | Halliburton Energy Services Inc | Wellbore fluid additives of fibrillated fibers |
FI126042B (en) | 2014-03-31 | 2016-06-15 | Upm Kymmene Corp | Method for producing nanofibril cellulose and nanofibril cellulose product |
US10550305B2 (en) | 2014-06-30 | 2020-02-04 | Oji Holdings Corporation | Subterranean formation processing composition comprising ultrafine cellulose fibers |
JP6477702B2 (ja) | 2014-06-30 | 2019-03-06 | 王子ホールディングス株式会社 | 微細セルロース繊維を含有する組成物 |
CA2964727A1 (en) * | 2014-10-15 | 2016-04-21 | Oji Holdings Corporation | Composition comprising ultrafine cellulose fibers |
US10294403B2 (en) | 2014-12-19 | 2019-05-21 | Halliburton Energy Services, Inc. | Additive of chemically-modified cellulose nanofibrils or cellulose nanocrystals |
CA2961569C (en) * | 2014-12-19 | 2019-07-02 | Halliburton Energy Services, Inc. | Additive of cellulose nanofibrils or nanocrystals and a second polymer |
US9822285B2 (en) | 2015-01-28 | 2017-11-21 | Gpcp Ip Holdings Llc | Glue-bonded multi-ply absorbent sheet |
WO2016152491A1 (ja) * | 2015-03-26 | 2016-09-29 | 花王株式会社 | 粘性水系組成物 |
WO2016187361A1 (en) | 2015-05-20 | 2016-11-24 | Schlumberger Technology Corporation | Water control agent for oilfield application |
NO343499B1 (en) * | 2015-05-29 | 2019-03-25 | Elkem Materials | A fluid containing nanofibrillated cellulose as a viscosifier |
NO343188B1 (en) * | 2015-05-29 | 2018-11-26 | Elkem Materials | A fluid for use in enhanced oil recovery, containing nanofibrillated cellulose as viscosity modifier |
CN105062454A (zh) * | 2015-08-21 | 2015-11-18 | 西南石油大学 | 纳米纤维素在作为或制备驱油剂中的应用 |
US10689564B2 (en) | 2015-11-23 | 2020-06-23 | Schlumberger Technology Corporation | Fluids containing cellulose fibers and cellulose nanoparticles for oilfield applications |
US10954634B2 (en) * | 2016-01-19 | 2021-03-23 | Gpcp Ip Holdings Llc | Nanofibrillated cellulose ply bonding agent or adhesive and multi-ply absorbent sheet made therewith |
US10662366B2 (en) | 2016-08-09 | 2020-05-26 | Schlumberger Technology Corporation | Compositions and methods for servicing subterranean wells |
JP2018070851A (ja) * | 2016-11-04 | 2018-05-10 | 株式会社服部商店 | 非水系粘度調整剤 |
CA3056918A1 (en) * | 2017-05-11 | 2018-11-15 | Halliburton Energy Services, Inc. | Nanocelluloses and biogums for viscosity modification |
CN107955586B (zh) * | 2017-11-08 | 2021-03-02 | 中石化石油工程技术服务有限公司 | 纤维素纳米纤维作为钻井液用流型调节剂的应用 |
CN107955589B (zh) * | 2017-11-08 | 2022-12-23 | 中国石油化工集团有限公司 | 一种纤维素纳米纤维及含有该组分的无粘土相水基钻井液 |
CN107843522B (zh) * | 2017-12-08 | 2023-11-17 | 中国石油化工股份有限公司 | 聚合物溶液在多孔介质中拉伸特性测试系统与测试方法 |
GB2580819B (en) * | 2017-12-20 | 2022-07-20 | Halliburton Energy Services Inc | Rheology control of Nanocellulose treatment fluids |
CN110157393B (zh) * | 2019-05-06 | 2021-11-16 | 滨州学院 | 钻井液用纳米纤维-黄原胶复合物提粘提切剂及制备方法 |
WO2021167691A1 (en) * | 2020-02-19 | 2021-08-26 | Halliburton Energy Services, Inc. | Rheology modifiers comprising nanocellulose materials for high fluid-loss squeeze applications |
WO2022011449A1 (en) * | 2020-07-16 | 2022-01-20 | Performance Biofilaments Inc. | Fibrillated cellulose consolidation of mineralized particulates |
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US3882029A (en) | 1972-09-29 | 1975-05-06 | Union Oil Co | Well completion and workover fluid |
US4629575A (en) | 1982-09-03 | 1986-12-16 | Sbp, Inc. | Well drilling and production fluids employing parenchymal cell cellulose |
US5207826A (en) | 1990-04-20 | 1993-05-04 | Weyerhaeuser Company | Bacterial cellulose binding agent |
CA2223731A1 (en) * | 1995-06-07 | 1996-12-19 | The Nutrasweet Company | Stable suspension of hydrocolloids |
EP0912634B1 (fr) * | 1996-07-15 | 2002-11-06 | Rhodia Chimie | Additivation de nanofibrilles de cellulose essentiellement amorphes avec de la cellulose carboxylee a haut degre de substitution |
DE69708294T2 (de) * | 1996-07-15 | 2002-07-25 | Rhone Poulenc Chimie | Cellulosenanofibrillen enthaltende flüssigkeit und seine verwendung zur betreibung von erdölfeldern |
SK3599A3 (en) * | 1996-07-15 | 2000-04-10 | Rhodia Chimie Sa | Composition containing cellulose nanofibrils, the preparation method thereof, an aqueous suspension containing cellulose nanofibrils and the use of this composition and suspension |
US7351680B2 (en) | 2001-09-19 | 2008-04-01 | Hayes James R | High performance water-based mud system |
US20080146701A1 (en) | 2003-10-22 | 2008-06-19 | Sain Mohini M | Manufacturing process of cellulose nanofibers from renewable feed stocks |
US8276664B2 (en) | 2007-08-13 | 2012-10-02 | Baker Hughes Incorporated | Well treatment operations using spherical cellulosic particulates |
AU2008344471B2 (en) | 2007-12-28 | 2012-12-20 | Nippon Paper Industries Co., Ltd. | Processes for producing cellulose nanofibers, cellulose oxidation catalysts and methods for oxidizing cellulose |
US20090197779A1 (en) | 2008-01-31 | 2009-08-06 | Scott Christopher Jackson | Method for enhanced recovery of oil from oil reservoirs |
JP6148178B2 (ja) * | 2011-02-10 | 2017-06-14 | ウーペーエム−キュンメネ コーポレイションUPM−Kymmene Corporation | 繊維状生成物および複合材料の製造方法 |
FI127301B (fi) * | 2011-02-10 | 2018-03-15 | Upm Kymmene Corp | Menetelmä nanoselluloosan käsittelemiseksi ja menetelmällä saatu tuote |
-
2010
- 2010-01-25 FI FI20100022A patent/FI20100022A/fi not_active Application Discontinuation
-
2011
- 2011-01-25 CN CN201180007072.3A patent/CN102803431B/zh active Active
- 2011-01-25 DK DK11734416.8T patent/DK2528985T3/da active
- 2011-01-25 EA EA201290693A patent/EA023815B1/ru not_active IP Right Cessation
- 2011-01-25 MX MX2012008357A patent/MX349129B/es active IP Right Grant
- 2011-01-25 US US13/575,135 patent/US9200193B2/en not_active Expired - Fee Related
- 2011-01-25 CA CA2786831A patent/CA2786831C/en active Active
- 2011-01-25 BR BR112012017281A patent/BR112012017281A2/pt not_active Application Discontinuation
- 2011-01-25 AU AU2011208609A patent/AU2011208609C1/en active Active
- 2011-01-25 WO PCT/FI2011/050058 patent/WO2011089323A1/en active Application Filing
- 2011-01-25 EP EP11734416.8A patent/EP2528985B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
CA2786831C (en) | 2019-07-30 |
WO2011089323A1 (en) | 2011-07-28 |
AU2011208609C1 (en) | 2015-04-23 |
EP2528985B1 (en) | 2018-05-16 |
US9200193B2 (en) | 2015-12-01 |
EP2528985A1 (en) | 2012-12-05 |
MX349129B (es) | 2017-07-13 |
FI20100022A0 (fi) | 2010-01-25 |
BR112012017281A2 (pt) | 2016-04-19 |
CA2786831A1 (en) | 2011-07-28 |
AU2011208609B2 (en) | 2014-11-13 |
CN102803431A (zh) | 2012-11-28 |
AU2011208609A1 (en) | 2012-08-09 |
US20130035263A1 (en) | 2013-02-07 |
MX2012008357A (es) | 2012-08-08 |
EP2528985A4 (en) | 2013-08-14 |
FI20100022A (fi) | 2011-07-26 |
EA023815B1 (ru) | 2016-07-29 |
CN102803431B (zh) | 2015-06-17 |
EA201290693A1 (ru) | 2012-12-28 |
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