DK169717B1 - Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf - Google Patents
Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf Download PDFInfo
- Publication number
- DK169717B1 DK169717B1 DK666689A DK666689A DK169717B1 DK 169717 B1 DK169717 B1 DK 169717B1 DK 666689 A DK666689 A DK 666689A DK 666689 A DK666689 A DK 666689A DK 169717 B1 DK169717 B1 DK 169717B1
- Authority
- DK
- Denmark
- Prior art keywords
- sio2
- sio
- crystalline aluminosilicate
- reaction mixture
- catalyst
- Prior art date
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims abstract description 42
- 229910052976 metal sulfide Inorganic materials 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 136
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 68
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 68
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 68
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 68
- 239000000203 mixture Substances 0.000 claims abstract description 57
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 56
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 50
- -1 sulfide compound Chemical class 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 150000001768 cations Chemical class 0.000 claims abstract description 11
- 150000002739 metals Chemical class 0.000 claims abstract description 6
- 150000002897 organic nitrogen compounds Chemical group 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 74
- 239000011701 zinc Substances 0.000 claims description 64
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 49
- 239000011541 reaction mixture Substances 0.000 claims description 38
- 239000011734 sodium Substances 0.000 claims description 38
- 239000010949 copper Substances 0.000 claims description 30
- 239000000243 solution Substances 0.000 claims description 29
- 229910052708 sodium Inorganic materials 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 17
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims description 17
- 229910052725 zinc Inorganic materials 0.000 claims description 17
- 229910001868 water Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 238000005342 ion exchange Methods 0.000 claims description 8
- 229910018404 Al2 O3 Inorganic materials 0.000 claims description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical group [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011591 potassium Chemical group 0.000 claims 2
- 235000005039 Brassica rapa var. dichotoma Nutrition 0.000 claims 1
- 108010021119 Trichosanthin Proteins 0.000 claims 1
- 244000130745 brown sarson Species 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000007669 thermal treatment Methods 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 12
- 229910052733 gallium Inorganic materials 0.000 abstract description 8
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052796 boron Inorganic materials 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 51
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 38
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 31
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 27
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 238000005899 aromatization reaction Methods 0.000 description 24
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 20
- 239000010457 zeolite Substances 0.000 description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 18
- 239000004115 Sodium Silicate Substances 0.000 description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 16
- 229910052911 sodium silicate Inorganic materials 0.000 description 16
- 239000007787 solid Substances 0.000 description 16
- 229910021536 Zeolite Inorganic materials 0.000 description 15
- 238000001914 filtration Methods 0.000 description 15
- 238000003756 stirring Methods 0.000 description 14
- 239000001294 propane Substances 0.000 description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
- 238000009826 distribution Methods 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 9
- 235000013844 butane Nutrition 0.000 description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 9
- 238000000634 powder X-ray diffraction Methods 0.000 description 9
- 239000011780 sodium chloride Substances 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 9
- 239000008096 xylene Substances 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 235000013305 food Nutrition 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 150000003738 xylenes Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000012452 mother liquor Substances 0.000 description 6
- 229910052950 sphalerite Inorganic materials 0.000 description 6
- 238000001354 calcination Methods 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910003556 H2 SO4 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229910001195 gallium oxide Inorganic materials 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- SBMYBOVJMOVVQW-UHFFFAOYSA-N 2-[3-[[4-(2,2-difluoroethyl)piperazin-1-yl]methyl]-4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound FC(CN1CCN(CC1)CC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CC2=C(CC1)NN=N2)F SBMYBOVJMOVVQW-UHFFFAOYSA-N 0.000 description 1
- VNPMDUDIDCXVCH-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(3-piperazin-1-ylpropyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound O=C(CN1C=C(C(CCCN2CCNCC2)=N1)C1=CN=C(NC2CC3=C(C2)C=CC=C3)N=C1)N1CCC2=C(C1)N=NN2 VNPMDUDIDCXVCH-UHFFFAOYSA-N 0.000 description 1
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- ZXRRHFSTAFVGOC-UHFFFAOYSA-N [AlH3].[K] Chemical compound [AlH3].[K] ZXRRHFSTAFVGOC-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000002259 gallium compounds Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- YZYKBQUWMPUVEN-UHFFFAOYSA-N zafuleptine Chemical compound OC(=O)CCCCCC(C(C)C)NCC1=CC=C(F)C=C1 YZYKBQUWMPUVEN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1009—Compounds containing boron and oxygen having molecular-sieve properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/44—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/181—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by a dry process
- C01B33/185—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by a dry process of crystalline silica-polymorphs having molecular sieve properties, e.g. silicalites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2892—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures containing an element or a compound occluded in the pores of the network, e.g. an oxide already present in the starting reaction mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK666689A DK169717B1 (da) | 1989-12-22 | 1989-12-22 | Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf |
| US07/629,634 US5151259A (en) | 1989-12-22 | 1990-12-18 | Modified crystalline aluminosilicate and method of preparing the same |
| AT90124934T ATE145156T1 (de) | 1989-12-22 | 1990-12-20 | Modifiziert kristalline aluminosilikaten und verfahren für die herstellung derselben |
| DE69029125T DE69029125T2 (de) | 1989-12-22 | 1990-12-20 | Modifiziert kristalline Aluminosilikaten und Verfahren für die Herstellung derselben |
| NO905522A NO304018B1 (no) | 1989-12-22 | 1990-12-20 | Metallsulfidmodifisert krystallinsk aluminiumsilikatzeolittkatalysator og fremgangsmÕte for dens fremstilling |
| ES90124934T ES2096575T3 (es) | 1989-12-22 | 1990-12-20 | Aluminosilicatos cristalinos modificados y metodo para prepararlos. |
| EP90124934A EP0434052B1 (fr) | 1989-12-22 | 1990-12-20 | Aluminosilicates cristallins modifiés et méthode pour les préparer |
| AU68377/90A AU626485B2 (en) | 1989-12-22 | 1990-12-21 | Modified crystalline aluminosilicate and method of preparing the same |
| JP2405044A JPH0676208B2 (ja) | 1989-12-22 | 1990-12-21 | 改質された結晶性アルミノシリケートおよびその製造方法 |
| SU904894020A RU1836143C (ru) | 1989-12-22 | 1990-12-21 | Способ приготовлени катализатора дл получени ароматических углеводородов |
| UA4894020A UA18598A (uk) | 1989-12-22 | 1990-12-21 | Спосіб приготуваhhя каталізатора для одержаhhя ароматичhих вуглеводhів |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK666689 | 1989-12-22 | ||
| DK666689A DK169717B1 (da) | 1989-12-22 | 1989-12-22 | Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DK666689D0 DK666689D0 (da) | 1989-12-22 |
| DK666689A DK666689A (da) | 1991-06-23 |
| DK169717B1 true DK169717B1 (da) | 1995-01-23 |
Family
ID=8148966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK666689A DK169717B1 (da) | 1989-12-22 | 1989-12-22 | Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5151259A (fr) |
| EP (1) | EP0434052B1 (fr) |
| JP (1) | JPH0676208B2 (fr) |
| AT (1) | ATE145156T1 (fr) |
| AU (1) | AU626485B2 (fr) |
| DE (1) | DE69029125T2 (fr) |
| DK (1) | DK169717B1 (fr) |
| ES (1) | ES2096575T3 (fr) |
| NO (1) | NO304018B1 (fr) |
| RU (1) | RU1836143C (fr) |
| UA (1) | UA18598A (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2687163B1 (fr) * | 1992-02-12 | 1994-04-29 | Inst Francais Du Petrole | Utilisation d'un catalyseur comprenant un phosphate de gallium en hydroraffinage de charges petrolieres hydrocarbonees. |
| JPH05310607A (ja) * | 1992-03-11 | 1993-11-22 | Idemitsu Kosan Co Ltd | 芳香族炭化水素の製造方法 |
| DE4424816A1 (de) | 1994-07-14 | 1996-01-18 | Basf Ag | Kristalline Festkörper mit RUB-17 Struktur |
| US6177374B1 (en) * | 1997-01-17 | 2001-01-23 | Council Of Scientific & Industrial Research | Catalyst comprising oxides of silicon, zinc and aluminium used for the preparation of LPG and high octane aromatics and a process for preparing the same |
| US5961818A (en) * | 1997-02-20 | 1999-10-05 | Council Of Scientific And Industrial Research | Process for the production of LPG and high octane aromatic hydrocarbons from non-economically viable petroleum feed stock |
| NO305308B1 (no) * | 1997-07-31 | 1999-05-10 | Sanyo Petrochemical Co Ltd | Zeolitt-basert katalysator med h°yt silisiumoksyd-innhold, samt anvendelse derav ved fremstilling eller omsetning av aromatiske hydrokarboner |
| DE60226681D1 (de) * | 2001-10-10 | 2008-07-03 | Haldor Topsoe As | Verfahren zur Entfernung von höheren Kohlenwasserstoffen aus Erdgas |
| CN101939278A (zh) * | 2007-12-05 | 2011-01-05 | 陶氏环球技术公司 | 用于甲烷的无氧转化的连续方法 |
| WO2010081039A1 (fr) * | 2009-01-08 | 2010-07-15 | Coherex Medical, Inc. | Dispositif médical pour modification de l'appendice auriculaire gauche et systèmes et procédés correspondants |
| GB201418475D0 (en) * | 2014-10-17 | 2014-12-03 | Johnson Matthey Plc | Catalyst and process |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3373109A (en) * | 1963-10-29 | 1968-03-12 | Mobil Oil Corp | Crystalline aluminosilicate catalyst |
| US3322690A (en) * | 1963-12-10 | 1967-05-30 | Exxon Research Engineering Co | Synthetic crystalline zeolite compositions and preparation thereof |
| US3525700A (en) * | 1967-02-13 | 1970-08-25 | Universal Oil Prod Co | Type o crystalline material |
| US3583903A (en) * | 1968-10-18 | 1971-06-08 | Mobil Oil Corp | Hydrocarbon conversion with mole sieve and sulfur selenium or tellurium catalyst |
| US3663424A (en) * | 1969-12-19 | 1972-05-16 | Chevron Res | Hydrotreating catalyst comprising an interstratified crystalline claytype aluminosilicate component and a crystalline zeolitic molecular sieve component,and process using said catalyst |
| US3684691A (en) * | 1969-12-29 | 1972-08-15 | William F Arey Jr | Dewaxing process wherein relatively small pore size crystalline aluminosilicate zeolites are used to chemically convert n-paraffins in hydrocarbon oils |
| US3709814A (en) * | 1970-03-06 | 1973-01-09 | Chevron Res | Hydrofining-hydrocracking process using palladium-containing catalyst |
| US3766056A (en) * | 1970-03-09 | 1973-10-16 | Union Oil Co | Hydrocarbon conversion method |
| US3669873A (en) * | 1970-03-31 | 1972-06-13 | Chevron Res | Hydrofining-hydrocracking process |
| US3949059A (en) * | 1971-05-04 | 1976-04-06 | W. R. Grace & Co. | Process for producing faujasitic-type crystalline zeolites |
| US3789107A (en) * | 1971-05-04 | 1974-01-29 | Grace W R & Co | Process for producing a crystalline zeolite |
| US3853742A (en) * | 1971-10-20 | 1974-12-10 | Union Oil Co | Selective midbarrel hydrocracking |
| US3816341A (en) * | 1972-04-17 | 1974-06-11 | Union Carbide Corp | Crystalline metal aluminosilicates having halide and certain other salts irreversibly occluded therein |
| US4111967A (en) * | 1974-11-09 | 1978-09-05 | Bayer Aktiengesellschaft | Silicon containing catalysts |
| IT1074824B (it) * | 1977-02-01 | 1985-04-20 | Snam Progetti | Metodo di preparazione di "clusters" metallo-carbonilici immobilizzati in zeoliti e loro impiego come catalizzatori eterogenei |
| US4296083A (en) * | 1977-04-22 | 1981-10-20 | Mobil Oil Corporation | Zeolite synthesis |
| US4191663A (en) * | 1978-04-26 | 1980-03-04 | Mobil Oil Corporation | Preparation of shape selective zeolite alpha as catalyst |
| US4299686A (en) * | 1978-04-26 | 1981-11-10 | Mobil Oil Corporation | Shape selective catalyst from zeolite alpha and use thereof |
| FR2440914A1 (fr) * | 1978-11-10 | 1980-06-06 | Mobil Oil Corp | Composition de zeolite cristalline |
| JPS6018451B2 (ja) * | 1981-02-27 | 1985-05-10 | 喜信 武上 | 結晶性アルミノシリケ−トゼオライト触媒への金属および金属酸化物の担持方法 |
| FR2524481B1 (fr) * | 1982-04-05 | 1985-12-13 | Elf France | Hydrotraitement catalytique des coupes petrolieres |
| GB2118534B (en) * | 1982-04-15 | 1985-10-09 | South African Inventions | Electronically conductive tectosilicates |
| EP0113381A1 (fr) * | 1982-12-31 | 1984-07-18 | Mobil Oil Corporation | Procédé et catalyseur pour la désulfurisation et le déparaffinage simultané d'huiles pétrolières |
| GB8317228D0 (en) * | 1983-06-24 | 1983-07-27 | Exxon Research Engineering Co | Magnetizable adsorbents |
| GB8334626D0 (en) * | 1983-12-30 | 1984-02-08 | Exxon Research Engineering Co | Zeolite coated substrates |
| US4710485A (en) * | 1985-10-02 | 1987-12-01 | Chevron Research Company | Paraffin isomerization catalyst |
| US4902844A (en) * | 1989-04-05 | 1990-02-20 | Chevron Research Company | New zeolite SSZ-23 and xylene isomerization therewith |
| US4835336A (en) * | 1987-12-31 | 1989-05-30 | Mobil Oil Corporation | Method for suppressing hydrogenolysis of noble metal/low acidity zeolites |
| US4880761A (en) * | 1988-12-06 | 1989-11-14 | Uop | Crystalline microporous metal sulfide compositions |
-
1989
- 1989-12-22 DK DK666689A patent/DK169717B1/da not_active IP Right Cessation
-
1990
- 1990-12-18 US US07/629,634 patent/US5151259A/en not_active Expired - Lifetime
- 1990-12-20 EP EP90124934A patent/EP0434052B1/fr not_active Expired - Lifetime
- 1990-12-20 AT AT90124934T patent/ATE145156T1/de not_active IP Right Cessation
- 1990-12-20 ES ES90124934T patent/ES2096575T3/es not_active Expired - Lifetime
- 1990-12-20 DE DE69029125T patent/DE69029125T2/de not_active Expired - Lifetime
- 1990-12-20 NO NO905522A patent/NO304018B1/no not_active IP Right Cessation
- 1990-12-21 JP JP2405044A patent/JPH0676208B2/ja not_active Expired - Fee Related
- 1990-12-21 UA UA4894020A patent/UA18598A/uk unknown
- 1990-12-21 RU SU904894020A patent/RU1836143C/ru active
- 1990-12-21 AU AU68377/90A patent/AU626485B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| RU1836143C (ru) | 1993-08-23 |
| NO304018B1 (no) | 1998-10-12 |
| DE69029125T2 (de) | 1997-03-13 |
| DE69029125D1 (de) | 1996-12-19 |
| US5151259A (en) | 1992-09-29 |
| EP0434052B1 (fr) | 1996-11-13 |
| ATE145156T1 (de) | 1996-11-15 |
| NO905522L (no) | 1991-06-24 |
| JPH04104908A (ja) | 1992-04-07 |
| AU6837790A (en) | 1991-06-27 |
| DK666689A (da) | 1991-06-23 |
| DK666689D0 (da) | 1989-12-22 |
| ES2096575T3 (es) | 1997-03-16 |
| EP0434052A3 (en) | 1991-12-04 |
| JPH0676208B2 (ja) | 1994-09-28 |
| NO905522D0 (no) | 1990-12-20 |
| UA18598A (uk) | 1997-12-25 |
| AU626485B2 (en) | 1992-07-30 |
| EP0434052A2 (fr) | 1991-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4348651B2 (ja) | ゼオライトｉｍ―５、その調製方法およびその触媒的適用 | |
| EP0055529B1 (fr) | Zéolites | |
| EP0106478B1 (fr) | Gallosilicates cristallins, procédé pour leur préparation et leur utilisation comme catalyseurs | |
| US6027707A (en) | NU-88 zeolite, a process for its preparation and catalytic applications thereof | |
| US8629073B2 (en) | Catalyst comprising an izm-2 zeolite and at least one metal, and its use in the transformation of hydrocarbons | |
| EP0057049B1 (fr) | Aluminosilicates cristallins et leur utilisation comme catalyseurs | |
| US7771703B2 (en) | IZM-1 crystalline solid and a process for its preparation | |
| EP0104800B1 (fr) | Procédé pour la préparation d'aluminosilicates cristallins | |
| GB2033358A (en) | Crystalline Zeolite Compositions | |
| DK163576B (da) | Fremgangsmaade til fremstilling af et siliciumoxidholdigt krystallinsk zeolitmateriale, reaktionsblanding til brug ved fremgangsmaaden samt zeolit af typen zsm-22 fremstillet ved fremgangsmaaden | |
| JPH0153205B2 (fr) | ||
| CS266302B2 (en) | Catalyst for hydrocarbons' cracking, hydrocking and isomerization and method of its production | |
| DK169717B1 (da) | Krystallinsk aluminosilikat, som er modificeret med metalsulfid, fremgangsmåde til fremstilling samt anvendelse deraf | |
| CA1232595A (fr) | Production de la zeolite zsm-45 | |
| DK169252B1 (da) | Fremgangsmåde til fremstilling af zeolit ZSM-23 og en katalysator indeholdende denne zeolit samt anvendelse af en sådan katalysator til omdannelse af organiske forbindelser | |
| JPH0576453B2 (fr) | ||
| JP2008543711A (ja) | Ｎ，ｎ−ジメチル−ｎ，ｎ−ジ（３，３−ジメチルブチル）アンモニウムカチオンを含むｅｕｏ構造型ゼオライトとその製造方法 | |
| EP0162719A2 (fr) | Theta-3, un silicate d'aluminium cristallin et sa préparation | |
| AU616722B2 (en) | Zsm-5 catalysts having predominantly framework gallium, methods of their preparation and use | |
| GB2190910A (en) | Synthesis of ZSM-23 | |
| CA1127134A (fr) | Zeolite cristalline | |
| JP2006512273A (ja) | 分子篩ｓｓｚ−６３ | |
| JPH0339007B2 (fr) | ||
| JPH0310571B2 (fr) | ||
| JPS6229370B2 (fr) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B1 | Patent granted (law 1993) | ||
| PBP | Patent lapsed |
Country of ref document: DK |