DEP0054857DA - Process for the production of butadiene - Google Patents
Process for the production of butadieneInfo
- Publication number
- DEP0054857DA DEP0054857DA DEP0054857DA DE P0054857D A DEP0054857D A DE P0054857DA DE P0054857D A DEP0054857D A DE P0054857DA
- Authority
- DE
- Germany
- Prior art keywords
- butadiene
- production
- der
- voa
- acetylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001203952 Feia Species 0.000 description 1
- 101150094640 Siae gene Proteins 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
gar Μ®τ-®%®ΧΧνιη&. -von .Ieven Μ®τ-®% ®ΧΧνιη &. -of .I
is wur&fc gefimden., de« β sicii iäutadiea du.rcb ä voa $ e t Ij anal ©«if Aeet yXen toeiwe were found., de «β sicii iäutadiea du.rcb ä voa $ et Ij anal ©« if Aeet yXen toei
evfieeh&n 158° umi 600° unmittelbar in eines Arbei'fee-gesg herstellen Igest.. Di« ü erfolgt z*®%akta.'$MB:ig in der Vy ei se, 4ase ein Chmisoh. von fletÄaaoM.aiapf uaä Ä©etyl©n na.oh entepreeiiend«!' Ä durch- ein mit Füll.kc5z'periievfieeh & n 158 ° umi 600 ° directly in an Arbei'fee-Gesg Igest .. Tue is done z * ®% akta. '$ MB: ig in the Vy ei se, 4ase a Chmisoh. by fletÄaaoM.aiapf uaä Ä © etyl © n na.oh entepreeiiend «! ' Ä through- one with filling.kc5z'perii
,Die.für die iJ»©eta'uüs ^eeigs.et@n, The.for the iJ »© eta'uüs ^eeigs.et@n
etwa I.5O0 und 600°, Yorzugeweia« bei 'Ju-C bis 4-00β. üie wie 9teh weiter g#s#igt to,»t> in Abixwigigteeit von der B last wag des l^stsMs®· Bei boliM Stl&steß.gen k&trn die β I.5O about 0 and 600 °, Yorzugeweia 'at' Ju-C to 4-00. üie like 9th further g # s # igt to, »t> in Abixwigigteeit from the B last wag des l ^ stsMs® · At boliM Stl & steß.gen k & trn
ti© $0 bis 1(J0* höfeer li#gsn. als beiti © $ 0 to 1 (J0 * höfeer li # gsn. than at
ilettoaaaol k8.rin®ii iii glelehwe-rtigen Mengen oderilettoaaaol k8.rin®ii iii equivalent amounts or
im iJebersohaas einest 'Bestaüi.fceiles bei sormal^JB oder ge«*im iJebersohaas a 'bestaüi.fceiles at sormal ^ JB or ge «*
elftes üeb«r6c.hUBße.e το» Sfetiianol gmt© I werden. Anstelle- See A^etjleiis kUriata aucli aoft-yl«&Jialeleventh over «r6c.hUBße.e το» Sfetiianol gmt © I become. Instead- See A ^ etjleiis kUriata aucli aoft-yl «& Jial
tig® 0-ase, wie a.»B# ttii dujpefe S5erö«teu»g voa liethaai its MoMfeogen eriialtea® ö&.s.gsaisohs verwenägttig® 0-ase, like a. »B # ttii dujpefe S5erö« teu »g voa liethaai its MoMfeogen eriialtea® ö & .s.gsaisoh s used
eriialt@ö© Bmt&clitJä wirä in. bt^annter Weise, ä.B. durch ileßrfl&lung, .Αde-orptloji o4er äuswsssekang -®it Lö. abgeechieden*eriialt @ ö © Bmt & clitJä wirä in. bt ^ annter way, Ä.B. by ileßrfl & lung, .Αde-orptloji o4er äuswsssekang -®it Lö. departed *
der 3>urohe«'t* weyfea ämrefa eriatfelißli geeteigwt. Als Äweeleft.S83ig.e eiöii die Elemeaije baw» dl© Oxyäe i®r Bl®ia@nt@ der 2», 5« tmd 4»^3mf^e d*· jJtrioaiseheft Systeme Si® köimea allein ou@r la Hieehttag mit«ia;«di4er»·der 3> urohe "'t * weyfea ämrefa eriatfelißli geeteigwt. As Äweeleft.S83ig.e eiöii die Elemeaije baw »dl © Oxyäe i®r Bl®ia @ nt @ der 2», 5 «tmd 4» ^ 3mf ^ e d * · jJtrioaiseheft Systems Si® köimea alone ou @ r la Hieehttag with «ia;« di4er »·
unter Saeatss sonstiger aütetiTiereaaer BeiÄ«n.gtöi$«Ä, an* s Al» feramehbare zus^tte«, di© btigemeiigi oderunder Saeatss other aütetiTiereaer BeiÄ «n.gtöi $« Ä, an * s Al "feramehbare zu ^ tte", di © btigemeiigi or
aufgebracht sein lcSimfm, seien roter lli f©a Oaloitwa tmi anderen Irdslsmlies, ^ iisehea feia irerte-litis« Kupfer, Oxyd» 4ts Ti&nthan©, O oder- i'ieo.4yaae» s$wi« ^hprivtmoxyd» Wölfraiao^dapplied his lcSimfm, be red lli f © a Oaloitwa tmi other Irdslsmlies, ^ iisehea feia irerte-litis «copper, oxide» 4ts Ti & nthan ©, O or- i'ieo.4yaae »s $ wi« ^ hprivtmoxyd »Wölfraiao ^ d
genannt* Auch die Yejfw^iaimg voa Kaolin, öieberden, K'ieeelgur oder Biets st ^ in als i4auptkoni!.ak;traat®ria.l 'bsw. i'a^waiüttörial iiat βίαίι el©called * Also the Yejfw ^ iaimg voa Kaolin, öieberden, K'ieeelgur or Biets st ^ in as i4auptkoni! .ak; traat®ria.l 'bsw. i'a ^ waiüttörial iiat βίαίι el ©
i)tr Vorteil ies etigegebe,ti©ii Verfahrens liegt 4arin, Acetylen una l^etla&iiol, ^ia bei ä<an bek thm&en nur in me&rtyeaj meist t^ciiniBöii eciiwiei'ig (water Strack asw«) d^rchaitftifaremd.eii Stufen 'UAgeeetat ψ&τ&®η, in eineßi eineig&n Arbeitegeiig· Butsäieni) tr advantage ies etigegebe, ti © ii process lies 4arin, acetylene una l ^ etla & iiol, ^ ia at ä <an bek thm & en only in me & rtyeaj mostly t ^ ciiniBöii eciiwiei'ig (water Strack asw «) d ^ rchaitftifaremd.eii stages 'UAgeeetat ψ & τ & ®η, in einßi some & n Arbeitsegeiig · Butsäien
eia ϊ"ο3?κο1ΐΕϊί3?οίϊϊ' von 1 a L*iage arid 20 mm Alt sinem Rost&kt gefallt i#t» ü®f duych .Mftr&gö&eia ϊ "ο3? κο1ΐΕϊί3? οίϊϊ 'from 1 a L * iage arid 20 mm old sinem rust & kt fallen i # t» ü®f duych .Mftr & gö &
am» 20 @$wie&$3%ellen Zinkoac^a und 80· S '£vLpi$x&t$a, »uf Bimsstein h^rgeg-ttllt ist, wird lit!! eia 3ya®m-«$0;l Ao«tyl#fi» das bei 50c mit 2 Q-ramm-lolon '20 @ $ as & $ 3% ellen Zinkoac ^ a and 80 · S ' £ vLpi $ x & t $ a, 'on pumice stone is rg-tttllt, is lit !! eia 3ya®m - «$ 0 ; l Ao «tyl # fi» that at 50 c with 2 Q-ramm-lol
btBleden ist, bei 55ö6 t^r©fageleitet. Aus ä@m ausge-R@@ktiöB©^.0:!aiscii wiyä äse gebildete Sutadi*» und ■. sieht usgS9©t®tt Methanol durch Ab©orptioa aa Aktivkohle abgeschieden»btBleden is guided at 55ö 6 t ^ r ©. Sutadi * »and ■ formed from ä @ m aus-R @@ ktiöB © ^ .0:! Aiscii wiyä äse. sees usgS9 © t®tt methanol deposited by Ab © orptioa aa activated carbon »
Das Butadien wird mit WataeeMaa^f to eineri Gasometer triebea tund in dasThe butadiene is driven to a gasometer with WataeeMaa ^ f and into the
Bw vnxta* <siae Batadienausb-eate voa IO $ der Theorie, auf das durcägesetste Acetyl «ja, erhalten* 85 $ äes / Bw vnxta * <siae Batadienausb-eate voa IO $ of the theory, to the largest acetyl "yes, get * 85 $ äes /
Claims (1)
Family
ID=
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