DE967298C - Joint glue made from hardenable resins - Google Patents

Joint glue made from hardenable resins

Info

Publication number
DE967298C
DE967298C DEB32448A DEB0032448A DE967298C DE 967298 C DE967298 C DE 967298C DE B32448 A DEB32448 A DE B32448A DE B0032448 A DEB0032448 A DE B0032448A DE 967298 C DE967298 C DE 967298C
Authority
DE
Germany
Prior art keywords
glue
hardenable resins
parts
joint glue
glue made
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB32448A
Other languages
German (de)
Inventor
Dr Otto Burian
Dr Hans Scheuermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB32448A priority Critical patent/DE967298C/en
Application granted granted Critical
Publication of DE967298C publication Critical patent/DE967298C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09J161/22Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C09J161/24Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28Non-macromolecular organic substances
    • C08L2666/34Oxygen-containing compounds, including ammonium and metal salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Veneer Processing And Manufacture Of Plywood (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Description

Fugenleim aus härtbaren Harzen Fugenleime aus härtbaren Harzen werden in der holzverarbeitenden Industrie zum Verleimen von Furnieren verwendet. Hierbei trägt man den Leim, meistens ein Harnstofformaldehydharz, auf die zu verklebenden Flächen auf und verleimt anschließend die Furniere miteinander in Fugenverleimungsmaschinen unter Anwendung von Druck und Wärme.Grout glue made from hardenable resins Grout glue made from hardenable resins can be used Used in the woodworking industry for gluing veneers. Here the glue, usually a urea-formaldehyde resin, is applied to the parts to be bonded Surfaces and then glued the veneers together in joint gluing machines using pressure and heat.

Es läßt sich nun nicht vermeiden, daß beim Pressen der Furniere aus den Fugen etwas Leim austritt, der die Gleitschienen und Raupenbänder der Fugenverleimungsmaschine verschmutzt. Die Maschinen müssen daher häufiger abgestellt und gereinigt werden. Erhält der Leim einen Zusatz der üblichen Gleitmittel, etwa von Salzen höhermolekularer Fettsäuren, z. B. des Zinks, Aluminiums oder Magnesiums, so verschmutzt die Maschine noch schneller, weil durch doppelte Umsetzung mit den Härtungsmitteln entstehende Salze, z. B. Zinkchlorid, das Haften des Leims an den Maschinenteilen begünstigen.It can now not be avoided that when pressing the veneers from A little glue escapes the joints, which the slide rails and caterpillar belts of the joint gluing machine dirty. The machines therefore have to be shut down and cleaned more frequently. If the glue contains the usual lubricants, such as salts of higher molecular weight Fatty acids, e.g. B. of zinc, aluminum or magnesium, so the machine is dirty even faster because of the double reaction with the hardening agents Salts, e.g. B. zinc chloride, favor the adhesion of the glue to the machine parts.

Es wurde nun gefunden, daß man diese Nachteile vermeiden kann, wenn man dem Fugenleim freie Carbonsäuren mit mehr als 16 Kohlenstoffatomen, vorzugsweise in Mengen von a bis 811/o, bezogen auf den Fugenleim, zusetzt. Besonders geeignet sind solche Fettsäuren, die sich bei den in den Fugenverleimungsmasch,inen auftretemden Temperaturen zersetzen. Der Leim haftet zwar zunächst auch an -den Maschinenteilen, doch lösen sich die entstehenden Leimkrusten von selbst ab. Besonders geeignete Säuren sind z. B. Palmitinsäure, Stearinsäure oder Gemische derselben oder Säuren der Paraffinoxydation.It has now been found that these disadvantages can be avoided if one of the joint glue free carboxylic acids with more than 16 carbon atoms, preferably in amounts of a to 811 / o, based on the joint glue. Particularly suitable are those fatty acids that are found in the joint gluing machines Temperatures decompose. The glue initially sticks to the machine parts, but it loosens the resulting glue crusts off by themselves. Particularly suitable acids are z. B. palmitic acid, stearic acid or mixtures thereof or acids of paraffin oxidation.

Während Leime, die die üblichen Gleitmittel, z. B. Salze höhermolekularer Fettsäuren, enthalten, die Verschmutzung der Metallteile von Preßformen beim maschinellen Verleimen vors Furnierhölzern eher fördern als verringern, wird dieser Nachteil durch Zugabe der freien Säuren vollkommen vermieden. Es ist ferner auch bekannt, die Maschinenteile zur Verhinderung des- Haftens der Leime mit Wachs zu bestreichen. Hierbei müssen die Metalloberflächen sorgfältig gereinigt und getrocknet werden, bevor man sie mit den Wachsen bestreicht. Die Metallteite dürfen niemals mit Wasser gewaschen werden, wenn die beabsichtigte Wirkung des Wachsens eintreten soll. Nach dem neuen Verfahren dagegen werden wäßrige Leimlösungen verwendet, ohne daß die günstige Wirkung der Carbonsäuren mit mehr als 16 Kohlenstoffatomen beeinträchtigt wird.While glues containing the usual lubricants, e.g. B. Salts of higher molecular weight Fatty acids, contain, which contaminate the metal parts of press molds in the machine This disadvantage will promote rather than reduce gluing in front of veneers completely avoided by adding the free acids. It is also known To coat the machine parts with wax to prevent the glue from sticking. The metal surfaces must be carefully cleaned and dried, before you brush them with the wax. The metal side must never be filled with water washed when the intended effect of waxing is to occur. To the new method, however, aqueous glue solutions are used without the beneficial effect of carboxylic acids with more than 16 carbon atoms impaired will.

Schließlich ist es bekannt, Butylstearat Sperrholzleimen aus Phenolformaldehydharzen zuzusetzen. Das Butylstearat wirkt hierbei als Plastifizierungsmittel.Finally, it is known to use butyl stearate plywood glues made from phenol-formaldehyde resins to add. The butyl stearate acts as a plasticizer.

Die in dem Beispiel genannten Teile sind Gewichtsteile.The parts mentioned in the example are parts by weight.

Beispiel 8o Teile eines pulverförmigen Harnstofformaldehydharzleimes werden mit io Teilen Stärke, 5 Teilen Stearinsäure und 5 Teilen eines Härtungsmittels für das Harnstoffharz vermischt. Man. stellt aus i Teil des Leimpulvers und o,5 Teilen Wasser eine Paste her, die man auf Furnierhölzer aufträgt. Beim Verleimen. der Furniere in einer Fugenverleimungsmaschine bei etwa i8o bis i85° treten keine Störungen auf.Example 8o parts of a powdered urea-formaldehyde resin glue are with 10 parts starch, 5 parts stearic acid and 5 parts of a hardening agent for the urea resin mixed. Man. represents from i part of the glue powder and o, 5 Water make a paste that is applied to wood veneers. When gluing. of the veneers in a joint gluing machine at around i8o to i85 ° do not occur Disturbances on.

Claims (1)

PATENTANSPRUCH: Fugenleim aus härtbaren Harzen, dadurch gekennzeichnet, daß er freie Carbonsäuren mit mehr als 16 Kohlenstoffatomen enthält. In Betracht gezogene Druckschriften: Schweizerische Patentschrift Nr. 179 455; deutsche Patentschrift Nr. 86o 2io; Plath, »Die Holzverleimung«, 1951, S. 187. PATENT CLAIM: Joint glue made from hardenable resins, characterized in that it contains free carboxylic acids with more than 16 carbon atoms. Documents considered: Swiss Patent No. 179 455; German Patent No. 86o 2io; Plath, "Die Holzverleimung", 1951, p. 187.
DEB32448A 1954-09-02 1954-09-02 Joint glue made from hardenable resins Expired DE967298C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB32448A DE967298C (en) 1954-09-02 1954-09-02 Joint glue made from hardenable resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB32448A DE967298C (en) 1954-09-02 1954-09-02 Joint glue made from hardenable resins

Publications (1)

Publication Number Publication Date
DE967298C true DE967298C (en) 1957-10-31

Family

ID=6963757

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB32448A Expired DE967298C (en) 1954-09-02 1954-09-02 Joint glue made from hardenable resins

Country Status (1)

Country Link
DE (1) DE967298C (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH179455A (en) * 1933-04-19 1935-09-15 Whitehead Hutton Horatio Process for the preparation of liquid dispersions of synthetic resins.

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH179455A (en) * 1933-04-19 1935-09-15 Whitehead Hutton Horatio Process for the preparation of liquid dispersions of synthetic resins.

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