DE966648C - Process for joining two layers and suitable dispersions for this - Google Patents

Process for joining two layers and suitable dispersions for this

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Publication number
DE966648C
DE966648C DEP6590A DEP0006590A DE966648C DE 966648 C DE966648 C DE 966648C DE P6590 A DEP6590 A DE P6590A DE P0006590 A DEP0006590 A DE P0006590A DE 966648 C DE966648 C DE 966648C
Authority
DE
Germany
Prior art keywords
concrete
old
polyvinyl
layers
polyvinyl acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP6590A
Other languages
German (de)
Inventor
Karl Strehle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
POLYCHEMIE CHEMIE INGENIEUR GE
Original Assignee
POLYCHEMIE CHEMIE INGENIEUR GE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by POLYCHEMIE CHEMIE INGENIEUR GE filed Critical POLYCHEMIE CHEMIE INGENIEUR GE
Priority to DEP6590A priority Critical patent/DE966648C/en
Application granted granted Critical
Publication of DE966648C publication Critical patent/DE966648C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4857Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/63Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Description

Verfahren zur Verbindung zweier Schichten und hierfür geeignete Dispersionen Die Erfindung betrifft ein Verfahren zur homogenen Verbindung von altem mit frischem Beton, und sie besteht darin, daß zwischen üblichem Alt-und Frischbeton eine selbständige Zwischenschicht gebildet wird, die aus Füllstoffen und einer wäßrigen Dispersion aus Polyvinylacetat oder aus Mischpolymerisaten, wie Polyvinylacetat und Polyvinylchlorid oder Polyvinylacetat und Polyvinylacrylsäureester, besteht. Dieses Verfahren wird mit dem Vorteil in der Weise durchgeführt, daß ein oder mehrere Anstriche oder/und Spachtelungsaufträge mit der Kunstharzdispersion auf den gut gereinigten Altbeton aufgebracht werden.Process for joining two layers and dispersions suitable therefor The invention relates to a method for the homogeneous connection of old with fresh Concrete, and it consists in the fact that between the usual old and fresh concrete an independent Intermediate layer is formed, which consists of fillers and an aqueous dispersion from polyvinyl acetate or from copolymers such as polyvinyl acetate and polyvinyl chloride or polyvinyl acetate and polyvinyl acrylic acid ester. This procedure will with the advantage carried out in such a way that one or more coats and / or Filling applications with the synthetic resin dispersion on the well-cleaned old concrete be applied.

Die anorganischen Füllstoffe der Anstrich- oder Spachtelungsmasse bestehen vorteilhafterweise aus Quarzsanden in Korngrößen o bis a oder o bis 3 mm oder auch aus anderen Gruben- und Flußsanden. Es ist bekannt, daß frische Beton- bzw. Zementmörtelschichten mit altem, ausgetrocknetem Beton keine Bindung eingehen. Man behalf sich bisher so, daß die Oberfläche des alten Betons aufgerauht, intensiv genäßt . und mit Zementmilch eingeschlämmt wurde, ehe der frische Beton aufgebracht wurde. Diese Maßnahmen ergeben zwar eine gewisse Verankerung der beiden Betonschichten, die aber mit zunehmender Austrocknung der frischen Betonschicht wieder weitgehend aufgehoben wird, so daß diese hohl liegt und bei mechanischer Beanspruchung zerstört wird. Bei vertikalen Arbeitsfugen zwischen altem und neuem Beton entstehen Schwindrisse.The inorganic fillers of the paint or leveling compound consist advantageously of quartz sands with grain sizes o to a or o to 3 mm or from other pit and river sands. It is known that fresh concrete or cement mortar layers do not bond with old, dried-out concrete. So far, people have managed to roughen the surface of the old concrete, intensely wet. and slurried with cement milk before the fresh concrete was applied became. Although these measures result in a certain anchoring of the two concrete layers, but that again largely as the fresh concrete layer dries out is canceled, so that this is hollow and destroyed by mechanical stress will. Shrinkage cracks occur in vertical construction joints between old and new concrete.

Es ist bekannt, durch Zusatz von gewissen Kunststoffen physikalischen Eigenschaften, wie Biegsamkeit, Zugfestigkeit und Druckfestigkeit, von Zement zu ändern und stabile Mischungen von Zement mit Hochpolymeren, wie z. B. Polyvinylacetat, herzustellen sowie durch Zugabe dieses Kunstharzes zu Beton und Mörtel zähe, festhaftende Schichten zu bilden, die auch als Mörtel für Mauersteine u. dgl. verwendbar sind.It is known to be physical due to the addition of certain plastics Properties such as flexibility, tensile strength and compressive strength, of cement too change and stable mixtures of cement with high polymers, such as B. polyvinyl acetate, to manufacture as well as tough, firmly adhering layers by adding this synthetic resin to concrete and mortar to form, which can also be used as mortar for bricks and the like.

Erfindungsgemäß wurde erkannt, daß es zur Verbindung von altem und frischem Beton nicht notwendig ist, dem frischen Beton oder dem frischen und alten Beton Vinylharze zuzusetzen, um die erforderliche Verbindung zu erreichen, sondern daß es genügt, eine Schicht aus Polyvinylharz, mit Sand gemischt, in besonderen Fällen auch einen dünnen Anstrich allein, herzustellen, um eine innige Verbindung zu erzielen, trotzdem die Zwischenschicht beim Aufbringen, des frischen Betons trocken ist und somit keinerlei klebrige Eigenschaften aufweist. Hierin liegt ein wesentlicher technischer Fortschritt, .denn es ist ungleich billiger, eine Zwischenschicht herzustellen, statt dem meistens dicken Aufbeton eine zur Erzielung genügender Haftung am Altbeton notwendige Menge von Vinylharzen zuzusetzen.According to the invention it was recognized that it is used to connect old and fresh concrete is not necessary, the fresh concrete or the fresh and old Add vinyl resins to concrete to achieve the required bond, rather that it is enough to put a layer of polyvinyl resin, mixed with sand, in special Cases also apply a thin coat of paint alone, to establish an intimate bond to achieve, despite the fact that the intermediate layer is dry when the fresh concrete is applied and therefore does not have any sticky properties. Herein lies an essential one technical progress, because it is much cheaper to produce an intermediate layer, instead of the mostly thick topping-up concrete, to achieve sufficient adhesion to the old concrete to add the necessary amount of vinyl resins.

Der Gedanke, auf altem Beton zunächst eine selbständige Schicht aufzubringen, die aus Polyvinylacetat und anorganischen Füllstoffen besteht, und dann einen kunststofffreien Beton aufzutragen, ist bisher nicht bekanntgeworden. Erfindungsgemäß wird zuerst eine selbständige Schicht auf den alten Beton aufgetragen, die aus Füllstoffen und einer wäßrigen Dispersion aus Polyvinylacetat oder aus Mischpolymerisaten besteht, die so weit erhärten muß, daß sie der mechanischen Beanspruchung beim Aufbringen des kunstharzfreien Frischbetons widersteht. Beim Aufbringen des Frischbetons tritt ein Anquellen dieser auf den Altbeton aufgetragenen Grenzschicht ein, in der sich Frischbeton und Zwischenschicht zu einem Mischmaterial vereinigen.The thought of first applying a separate layer to old concrete, which consists of polyvinyl acetate and inorganic fillers, and then a plastic-free one Applying concrete has not yet become known. According to the invention is first a separate layer is applied to the old concrete, made up of fillers and an aqueous dispersion of polyvinyl acetate or of copolymers, which has to harden so far that it can withstand the mechanical stress during application of the synthetic resin-free fresh concrete. When applying the fresh concrete occurs a swelling of this boundary layer applied to the old concrete, in which Combine fresh concrete and intermediate layer to form a mixed material.

Die erfindungsgemäßen Zwischenschichten haften auf altem Beton hervorragend. Wird nach teilweisem oder völligem Abtrocknen dieser Zwischenschichten der frische Beton aufgebracht, so tritt eine starke Ouellung dieser Schichten durch die Zementmilch des Betons ein, wodurch diese weit in das Innere der aufgebrachten Zwischenschicht gelangt. Beim Abtrocknen der frischen Betonschicht bildet sich ein Zement- bzw. Betongerüst, das fest in der Zwischenschicht verankert ist, die wiederum auf dem alten Beton ausgezeichnet haftet. Dadurch ist eine innige und plastische Verbindung der alten und frischen Betonschicht gesichert.The intermediate layers according to the invention adhere extremely well to old concrete. When these intermediate layers have dried partially or completely, the new one becomes fresh When concrete is applied, these layers are strongly oozed by the cement milk of the concrete, making it deep into the interior of the applied intermediate layer got. When the fresh concrete layer dries, a cement or Concrete framework that is firmly anchored in the intermediate layer, which in turn is on the old concrete adheres excellently. This creates an intimate and plastic connection the old and fresh concrete layer secured.

Es ist weiterhin vorteilhaft, den erfindungsgemäßen Zwischenschichten etwas Zement zuzusetzen. Durch den Zementzusatz wird die O_uellbarkeit dieser Schichten zwar etwas herabgesetzt, so daß bei lang anhaltender Einwirkung der Feuchtigkeit aus dem frischen Beton und bei hoher Gewichtsbelastung, also bei dicken Neubetonschichten, keine zu weitgehende Auflösung der Zwischenschichten sich einstellt. Es wurde gefunden, daß die Verankerung des frischen Betons in der Zwischenschicht durch den Zementzusatz noch verbessert wird, während die auf die Klebeeigenschaften der verwendeten Kunststoffe zurückzuführende Haftung am alten Beton nicht beeinträchtigt wird.It is also advantageous to use the intermediate layers according to the invention to add some cement. The addition of cement makes these layers swellable although somewhat reduced, so that with prolonged exposure to moisture from the fresh concrete and with a high weight load, i.e. with thick new concrete layers, the intermediate layers do not dissolve too far. It was found, that the anchoring of the fresh concrete in the intermediate layer by the cement additive is still being improved, while on the adhesive properties of the plastics used traceable adhesion to the old concrete is not impaired.

Das Verfahren nach der Erfindung ist auch bei der Ausbesserung von Verschleißspuren, flachen Abplattungen und Löchern in alten Betonschichten mit -besonderem Vorteil anwendbar. Es wurde gefunden, daß ein Trennen der frischen von der alten Betonschicht, auch bei sehr dünnen frischen Betonschichten, nicht mehr eintritt. Es hat sich ferner gezeigt, daß neben der Erzielung besonders guter Verbindung zwischen altem und frischem Beton gleichzeitig das Brüchigwerden dünner Frischbeton- bzw. Zementmörtelschichten bis herunter zu einigen mm Stärke aufgehoben . wird, wenn dem Anmachwasser des frischen Betons in an sich bekannter Weise Polyvinylacetatdispersion in Mengen von io bis 3°/a Festharz, auf die Betonfeststofe gerechnet, zugesetzt wird.The method of the invention is also useful in repairing Traces of wear, flat flattened areas and holes in old concrete layers with special features Advantage applicable. It has been found that separating the fresh from the old Concrete layer, even with very thin fresh concrete layers, no longer occurs. It has also been shown that in addition to achieving particularly good connection between old and fresh concrete, thin fresh concrete or Cement mortar layers down to a few mm thick. will when the mixing water of the fresh concrete in a known manner polyvinyl acetate dispersion in amounts of 10 to 3% solid resin, calculated on the concrete solid, added will.

Claims (2)

PATENTANSPRÜCHE: I. Verfahren zur homogenen Verbindung von altem mit frischem Beton, dadurch gekennzeichnet, daß zwischen üblichem Alt- und Frischbeton eine selbständige Zwischenschicht gebildet wird, die aus Füllstoffen und einer wäßrigen Dispersion aus Polyvinylacetat oder aus Mischpolymerisaten, wie Polyvinylacetat und Polyvinylchlorid oder Polyvinylacetat und Polyvinylarylsäureester, besteht. PATENT CLAIMS: I. Process for the homogeneous connection of old with fresh concrete, characterized in that between the usual old and fresh concrete an independent intermediate layer is formed, which consists of fillers and an aqueous Dispersion of polyvinyl acetate or of copolymers such as polyvinyl acetate and polyvinyl chloride or polyvinyl acetate and polyvinyl aryl acid ester. 2. Verfahren nach Anspruch I, dadurch gekennzeichnet, daß ein oder mehrere Anstriche oder/und Spachtelungsaufträge mit der Kunstharzdispersion als Zwischenschicht auf den gut gereinigten Altbeton aufgebracht werden. In Betracht gezogene Druckschriften: Deutsche Patentschriften Nr. 824 61o, 825 520, 827 917, 851 127; französische Patentschriften Nr. 962 687, 982 740; Zeitschrift »Plastics«, 1950, 15; Zeitschrift »Soc. Chem. Ind.«, London, 1947, S. 578 bis 58o; Holländische Zeitschrift »Zement-Beton«, 1950, S. 303; Broschüre »Le Betocel«, 195o, S. 5; Franz Keiner: »Polyvinylalkohole«, 1949, s.-,132. The method according to claim I, characterized in that one or more paints and / or filler applications with the synthetic resin dispersion as an intermediate layer are applied to the well-cleaned old concrete. Considered publications: German Patent Nos. 824 61o, 825 520, 827 917, 851 127; French Patent Nos. 962 687, 982 740; Magazine »Plastics«, 1950, 15; Magazine »Soc. Chem. Ind. ", London, 1947, pp. 578 to 58o; Dutch magazine "Zement-Beton", 1950, p. 303; Brochure "Le Betocel", 195o, p. 5; Franz Keiner: "Polyvinyl alcohols", 1949, s .-, 13
DEP6590A 1951-11-16 1951-11-16 Process for joining two layers and suitable dispersions for this Expired DE966648C (en)

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Application Number Priority Date Filing Date Title
DEP6590A DE966648C (en) 1951-11-16 1951-11-16 Process for joining two layers and suitable dispersions for this

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DEP6590A DE966648C (en) 1951-11-16 1951-11-16 Process for joining two layers and suitable dispersions for this

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1054900B (en) * 1954-12-09 1959-04-09 Albert Emulsionswerk Ges Mit B Process for firmly bonding fresh and old concrete
DE1173827B (en) * 1958-09-26 1964-07-09 Du Pont Process for increasing the adhesive strength of layers made of hydraulically setting materials on substrates
DE1177060B (en) * 1959-10-29 1964-08-27 Schering Ag Process for the production of multi-layer concrete floors
DE1213779B (en) * 1961-12-19 1966-03-31 Gruenau Gmbh Chem Fab Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent
DE1223291B (en) * 1960-09-29 1966-08-18 Ruberoidwerke A G Process for connecting set and freshly made building materials containing hydraulic binders
DE1266680B (en) * 1960-03-23 1968-04-18 Basf Ag Process for the production of lightweight components

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR962687A (en) * 1950-06-16
FR982740A (en) * 1948-03-09 1951-06-14 Dunlop Sa Compositions containing cement and strongly polymerized substances
DE824610C (en) * 1948-10-02 1951-12-13 Rudolf Haefner Dr Ing Material made from hydraulic and plastic binders
DE825520C (en) * 1949-02-16 1951-12-20 Jakob Bollinger Manufacture of elastic structures from hardenable artificial stone masses
DE827917C (en) * 1938-05-17 1952-01-14 Hellmuth Holz Dr Process for the production of moldings from hydraulically setting material
DE851127C (en) * 1948-04-22 1952-10-02 Dunlop Rubber Co Process for the production of flexible, tubular objects from thermoplastic materials and equipment for carrying out the process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR962687A (en) * 1950-06-16
DE827917C (en) * 1938-05-17 1952-01-14 Hellmuth Holz Dr Process for the production of moldings from hydraulically setting material
FR982740A (en) * 1948-03-09 1951-06-14 Dunlop Sa Compositions containing cement and strongly polymerized substances
DE851127C (en) * 1948-04-22 1952-10-02 Dunlop Rubber Co Process for the production of flexible, tubular objects from thermoplastic materials and equipment for carrying out the process
DE824610C (en) * 1948-10-02 1951-12-13 Rudolf Haefner Dr Ing Material made from hydraulic and plastic binders
DE825520C (en) * 1949-02-16 1951-12-20 Jakob Bollinger Manufacture of elastic structures from hardenable artificial stone masses

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1054900B (en) * 1954-12-09 1959-04-09 Albert Emulsionswerk Ges Mit B Process for firmly bonding fresh and old concrete
DE1173827B (en) * 1958-09-26 1964-07-09 Du Pont Process for increasing the adhesive strength of layers made of hydraulically setting materials on substrates
DE1177060B (en) * 1959-10-29 1964-08-27 Schering Ag Process for the production of multi-layer concrete floors
DE1266680B (en) * 1960-03-23 1968-04-18 Basf Ag Process for the production of lightweight components
DE1223291B (en) * 1960-09-29 1966-08-18 Ruberoidwerke A G Process for connecting set and freshly made building materials containing hydraulic binders
DE1213779B (en) * 1961-12-19 1966-03-31 Gruenau Gmbh Chem Fab Process for the homogeneous connection of old and fresh hydraulically setting building materials with the help of an organic binding agent

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