DE943076C - Detergents and cleaning agents - Google Patents

Detergents and cleaning agents

Info

Publication number
DE943076C
DE943076C DEH2868D DEH0002868D DE943076C DE 943076 C DE943076 C DE 943076C DE H2868 D DEH2868 D DE H2868D DE H0002868 D DEH0002868 D DE H0002868D DE 943076 C DE943076 C DE 943076C
Authority
DE
Germany
Prior art keywords
detergents
cleaning agents
soap
cleaning
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEH2868D
Other languages
German (de)
Inventor
Dr Otto Lind
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to DEH2868D priority Critical patent/DE943076C/en
Application granted granted Critical
Publication of DE943076C publication Critical patent/DE943076C/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/42Per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • C11D9/14Phosphates; Polyphosphates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Wasch- und Reinigungsmittel Es wurde gefunden., daß Gemische aus Seife, Alkalimetaphosohaten und Sauerstoff abgebenden Verbindungen ausgezeichnete Wascrh- und Reinigungsmittel darstellen. Die Gemische können daneben aucjh andere bekannte Wasch- und Reiniguings;mittel, wie alkalisch reagierende Salze, Soda, Phosphate, Silikate, Borate, sowie Hilfsstoffe, wie Lösungsmittel, Überfettungsmitbel u. dgl. m., enthalten.Detergents and cleaning agents It has been found that mixtures of soap, Alkali metaphosohates and oxygen-releasing compounds have excellent washing and represent detergents. The mixtures can also contain other known ones Detergents and cleaning agents, such as alkaline salts, soda, phosphates, Silicates, borates, and auxiliaries such as solvents, superfatting agents and the like. m., included.

Als »Alkalinnetap@h;osp'hate« kommen besonders die Natriummet!aphos:phate zur Anwendung. Unter »Sauerstoff abgebenden Verbindungen« sind die sogeuannten Perverbindungen, wie Alkaliperborate, -perkarbonate, -perphosphate, -perpyrophosphate u. dgl., verstanden. Die genannten Perverbindungen können als solche oder mit einem Gehalt an Stabilis,ierun@gsmitteln, wie Wasserglas, Pyrophosphaten, Magnesiumverbnnd ragen u. dgl., verwendet werden.Sodium met! Aphos: phate are particularly useful as "Alkalinnetap @ h; osp'hate" to use. Under "oxygen-releasing compounds" are the so-called per compounds, such as alkali perborates, percarbonates, perphosphates, perpyrophosphates and the like. The per-compounds mentioned can be used as such or with a content of stabilizers, ierun @ gsmittel, such as water glass, pyrophosphates, magnesium compounds and the like can be used.

Die neuen erfindungsgemäßen Wasch- und Reinigungsmittel übertreffen .die bisher bekannten in vieler Beziehung vorteilhaft. Bei der Verwendung der bisher bekannten Mittel, die z. B. Trinatriumphosphat enthalten konnten, hat sich gezeigt, daß sich bei unsachgemäßer -Anwendung Meta:14:niederschläge, wie Metallflecke, in den behandelten MateriaIien, wie Wäsche u, dgl. Textilien, :bilden. können. Diese FZüeken können dabei aus Metallverbindungen bestehen, die entweder in dem belhandelten Material oder in dem verwendeten Wasser oder Waschmittel enthalten sind oder durch die Einwirkung der Soda auf die Ge£äßhazstoffe entstehen. Eine solche unerwünschte und schädliche Fleckenbildung wird bei Verwendung: des neuen Wa2s-ch-und Reinigungsmittels vermieden. Gleichzeitig ergibt sich bei :der Verwendung des neuen Wasch-und Reinigungsmittels bei Textilien der weitere Vorteil, daß oftmals damit gewaschene Gewebe nur einem geringen Aschegdhalt und damit verbunden einen sehr weichem Grig aufweisen. Ferner wird die Sauerstoffabgabe bei der -Verwendung des neuen Waschmittels g4-eichmäßig gestaltet; aus den wäßrigen Lösungen entwickeln sich die Gasbläschen sehrgleichmäßigundin!besonders wirlsamer,feiner Form. Dadurch untersicheiden sich die Metaphosp'hate von dem. Pyrophosphaten, die man ails Stabilisierumgszusat!z .zu B1eidhlbädern vorgeschlagen hat, Die Pyrophosphatebesitzen aber, wie in diesem Vorschlag ausgeführt wird, eine so starke Stahilisserungswirkung, daaß nach Beendigung des Waschvorganges noch große Meergen an aktivem Sauerstoff gebunden vorliegen, d. h. nicht -zur Wirkung gekommen sind. Dies isst bei Verwendung von Metaphosphaten nicht der Fall. Legt mann jedboh auf eine so: starke Stäbi!lisi:erwng Wert, so kann man Metaphosphatezusammen mit Pyrophosph aten.oder anderen StalbiEsierungsmiitteln verwenden. Damit hat man die Möglichkeit, die Eigenschaften der erfindungsgemäßen Wasch- und Reinigungsmittel allen Erfordernissen der Praxis nach Beäeben anzupassen. .The new detergents and cleaning agents according to the invention outperform .the previously known ones are advantageous in many respects. When using the previously known means that z. B. could contain trisodium phosphate, has has shown that if used improperly, Meta: 14: deposits, such as metal stains, in the treated materiaIien, such as laundry and the like. Textiles,: form. can. These FZüeken can consist of metal compounds that are either in the belhandelten Material or contained in the water or detergent used or by the action of the soda on the gas substances arise. Such an undesirable and harmful staining occurs when using: the new Wa2s-ch and cleaning agent avoided. At the same time, this results in: the use of the new detergent and cleaning agent In the case of textiles, the further advantage that fabrics washed with them are often only used for one have a low ash content and therefore a very soft grig. Further the oxygen release when using the new detergent is g4-calibrated designed; The gas bubbles develop very evenly and especially from the aqueous solutions wholesome, fine form. In this way the metaphosphates differ from that. Pyrophosphates, which have been proposed as a stabilizer additive for baths that contain pyrophosphates but, as pointed out in this proposal, such a strong steel dissolution effect, that after the washing process has ended, there are still large oceans of active oxygen are bound, d. H. did not have any effect. This eats when in use of metaphosphates is not the case. Anyway, if you lay on such a: strong staff! Lisi: erwng Value, metaphosphates can be used together with pyrophosphates or other stabilizers use. This gives you the opportunity to use the properties of the invention Adapt detergents and cleaning agents to all practical requirements. .

Zur Herstellung :der neuen Wasch- und R:einigwrrg !mittel eignen sich a1:le in der Seifenindustrie be'kan'nten: Verfahren. Man kann beispielsweise die Ausgangskomponenten in geeignetem Mischvorrichtungen - miteinander mischen. So kann man das Alkalnmetaphosphat mit einem Seifenleim vermischen., die erstarrte Seifenmasse mahlen und mit den gewünschten Mengen von Natriumperborat misrhen. Den Gemisdhen kann man jede gewünschte Form geben; beispielsweise kamen. man diese Gemische in Fomm von Fhocl<en, Nudeln, Lösungen, Pasten, Stücken oder Pulvern in den Verkehr bringen.For the production of: the new detergents and detergents are suitable a1: le known in the soap industry: process. For example, you can use the Starting components in suitable mixing devices - mix together. So can you mix the alkali metaphosphate with a soap glue., the solidified soap mass grind and mix with the desired amounts of sodium perborate. The Gemisdhen you can give it any shape you want; for example came. one these mixtures in Fomm of foxes, noodles, solutions, pastes, pieces or powders on the market bring.

Der Gehalt der einzelnen Komponenten in dem erfirndungsgennäß verwendeten Gemisch kann in weiten Grenzen sohwanken. Man erhält besonders vorteilhafte Mischungen, wenn die Menge an Perverbindumgen sogroß ist,da1derGehalt an aktivem Sauerstoff etwa 10/9 des Gesumtgemenges ausmacht und der Gehalt an Seifen 30 bis 5ofl/o der Gesamtkomposition .beträgt.The content of the individual components in the mixture used according to the invention can vary within wide limits. Particularly advantageous mixtures are obtained when the amount of per-compound is so large that the active oxygen content is about 10/9 of the total mixture and the content of soaps is 30 to 50% of the total composition.

Die neuem, Wasch- und Reinigungsmittel können sowohl im Haushalt als auch, in gewerb'ikchen Betrieben, wie Wäschereien, Waschanstalten, Krankehäusern, Hotels u. dgl. m., zum Waschen und Reinigen von Kleidungsstiidl,.en, Wäsche und anderen Textilien und anderen Gegenständen des häuslichen un!d gewerblichen Lebens verwendet werden. Beispiel 15 Gewichtsbeile Metaphosphat werden mit 5o Gewichbsteilen Seife, 8 Gewidhtsteiilen Soda und Io Gewi!chtstei@len Natniwmperborat güt gemischt. Man erhält ein, ausgezeichnetes Wasch- und Reinigungsmittel, dessen wäßrige Lösungen mit Vorteil im Haushalt und im Gewerbe zum Waschen und Re!inigen verwendet werden können.The new detergents and cleaning agents can be used both in the household also, in commercial establishments such as laundries, laundries, hospitals, Hotels and the like, for washing and cleaning clothes items, laundry and the like other textiles and other items of domestic and commercial life be used. Example 15 parts by weight of metaphosphate are mixed with 50 parts by weight Soap, 8 parts by weight of soda and 8 parts by weight of sodium perborate mixed well. An excellent detergent and cleaning agent and its aqueous solutions are obtained can be used with advantage in the household and in trade for washing and cleaning can.

Claims (1)

PATENTANSPRUCH: Wasch- und Reinigungsmittel, bestehend aus einem Gemisch von Seife, A,l:kalirnetaphosphaten und Perverbindungen, gegebenenfalls im weiteren Gemisch mit anderen an sich bekannten Wasch- und Reinigungsmitteln sowie Hi!lfsstoffen. Angezogene Druckschriften: Deutsche Patentschriften Nr. 279 3o6, 5o6 338, 58o 233, 571 738e britische Patentschriften Nr. 273 414, 277 6:283-289 156; Seifensieder-Zeitung, 1933, S- 758, 850.PATENT CLAIM: Detergents and cleaning agents, consisting of a mixture of soap, A, 1: potassium naphosphates and per compounds, optionally in a further mixture with other detergents and cleaning agents known per se as well as auxiliaries. Energized publications: German Patent No. 279 3o6, 5o6 338, 58o 233 57 1 738e British Patent No. 273 414, 277 6: 283-289156;.. Seifensieder-Zeitung, 1933, S- 758, 850.
DEH2868D 1933-12-09 1933-12-09 Detergents and cleaning agents Expired DE943076C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEH2868D DE943076C (en) 1933-12-09 1933-12-09 Detergents and cleaning agents

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH2868D DE943076C (en) 1933-12-09 1933-12-09 Detergents and cleaning agents

Publications (1)

Publication Number Publication Date
DE943076C true DE943076C (en) 1956-05-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
DEH2868D Expired DE943076C (en) 1933-12-09 1933-12-09 Detergents and cleaning agents

Country Status (1)

Country Link
DE (1) DE943076C (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE506338C (en) * 1925-06-13
DE279306C (en) *
GB273414A (en) * 1926-04-07 1927-07-07 Theodor Benckiser A process for maintaining the effectiveness of washing and bleaching powders containing soap and oxygen-evolving compounds
GB289156A (en) * 1926-01-14 1928-04-23 Theodor Benckiser Improved process for stabilising bleaching liquors
GB277628A (en) * 1926-09-16 1928-10-11 Oesterr Chem Werke Improved process for the manufacture of stable solutions of peroxides, persalts and peracids
DE571738C (en) * 1932-02-03 1933-03-04 Chem Fab Joh A Benckiser G M B Process for producing a soft soap-like soda soap
DE580233C (en) * 1932-05-27 1933-07-07 Chem Fab Joh A Benckiser G M B Cleaning agents for household and commercial appliances

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE279306C (en) *
DE506338C (en) * 1925-06-13
GB289156A (en) * 1926-01-14 1928-04-23 Theodor Benckiser Improved process for stabilising bleaching liquors
GB273414A (en) * 1926-04-07 1927-07-07 Theodor Benckiser A process for maintaining the effectiveness of washing and bleaching powders containing soap and oxygen-evolving compounds
GB277628A (en) * 1926-09-16 1928-10-11 Oesterr Chem Werke Improved process for the manufacture of stable solutions of peroxides, persalts and peracids
DE571738C (en) * 1932-02-03 1933-03-04 Chem Fab Joh A Benckiser G M B Process for producing a soft soap-like soda soap
DE580233C (en) * 1932-05-27 1933-07-07 Chem Fab Joh A Benckiser G M B Cleaning agents for household and commercial appliances

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