DE902246C - Process for the treatment of natural or artificial protein-containing fibers - Google Patents
Process for the treatment of natural or artificial protein-containing fibersInfo
- Publication number
- DE902246C DE902246C DEZ701D DEZ0000701D DE902246C DE 902246 C DE902246 C DE 902246C DE Z701 D DEZ701 D DE Z701D DE Z0000701 D DEZ0000701 D DE Z0000701D DE 902246 C DE902246 C DE 902246C
- Authority
- DE
- Germany
- Prior art keywords
- natural
- treatment
- containing fibers
- artificial protein
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims description 13
- 102000004169 proteins and genes Human genes 0.000 title claims description 11
- 108090000623 proteins and genes Proteins 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000000969 carrier Substances 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- 235000018102 proteins Nutrition 0.000 description 9
- 210000002268 wool Anatomy 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- -1 amino, imino Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000002925 chemical effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012084 conversion product Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zur Behandlung von natürlichen oder künstlichen eiweißhaltigen Fasern Der Erfindung liegt der Gedanke zugrunde, die Stabilität von natürlichen oder künstlichen eiweißhaltigen Fasern, wie Wolle, Seide, Kaseinfasern od. dgl., gegenüber mechanischen oder chemischen Einwirkungen dadurch zu erhöhen, daB die Eiweißbausteine in sich oder miteinander an ihren reaktionsfähigen Stellen durch chemische Umsetzung mit brückenartigen Verbindungen vernetzt werden.Method for the treatment of natural or artificial protein-containing Fibers The invention is based on the idea of the stability of natural or artificial protein-containing fibers such as wool, silk, casein fibers or the like, to increase compared to mechanical or chemical effects by the fact that the Protein building blocks in themselves or with each other at their reactive points chemical conversion are crosslinked with bridge-like compounds.
Unter brückenartigen Verbindungen sind im vorliegenden Falle solche Verbindungen zu verstehen, die mindestens zwei reaktionsfähige Gruppen besitzen, die mit den reaktionsfähigen Stellen der Eiweißbausteine, insbesondere mit den Carboxylgruppen, den Amino-, Imino- bzw. schwefelhaltigen Gruppen, in Reaktion zu treten vermögen.In the present case, bridge-like connections are those To understand compounds that have at least two reactive groups, those with the reactive sites of the protein building blocks, especially with the carboxyl groups, the amino, imino or sulfur-containing groups are able to react.
Als brückenartige Verbindungen kommen z. B. die quarternären Umsetzungsprodukte zwischen tertiären Basen und solchen Reaktionsträgern in Betracht, die ein tertiäres Stickstoffatom und ein an Kohlenstoff gebundenes Halogenatom besitzen, welches mit wäB-riger Silbernitratlösung leicht reagiert.As bridge-like connections z. B. the quaternary conversion products between tertiary bases and those reaction carriers that have a tertiary Have nitrogen atom and a halogen atom bonded to carbon, which with aqueous silver nitrate solution reacts easily.
Den zuletzt genannten Reaktionsträgern sei die allgemeine Formel XY;Z zugeschrieben. In dieser Formel steht X für ein Radikal, das ein tertiäres Stickstoffatom enthält, z. B. für das Radikal in denen R, und R2 Wasserstoff oder beliebige Kohlenwasserstoffreste bedeuten und in denen der Brückensauerstoff durch ein äquivalentes Atom oder eine äquivalente Atomgruppierung, z. B. durch Schwefel oder durch die Iminogruppe, die gegebenenfalls auch substituiert ist, ersetzt sein kann; Z steht für Halogen, z. B. für Chlor oder Brom.The general formula XY; Z is ascribed to the last-mentioned reaction carriers. In this formula, X stands for a radical containing a tertiary nitrogen atom, e.g. B. for the radical in which R, and R2 are hydrogen or any hydrocarbon radicals and in which the bridging oxygen is represented by an equivalent atom or an equivalent atom grouping, e.g. B. can be replaced by sulfur or by the imino group, which is optionally also substituted; Z is halogen, e.g. B. for chlorine or bromine.
Solche Reaktionsträger der allgemeinen Formel XYZ gewinnt man z. B., wenn man ein tertiäres Stickstoffatom enthaltende Alkohole oder Carbonsäuren bzw. deren Derivate, wie Amide, mit Aldehyden und Halogenwasserstoffen in indifferenten Lösungsmitteln zur Reaktion bringt.Such reaction carriers of the general formula XYZ are obtained, for. B., if you have a tertiary nitrogen atom containing alcohols or carboxylic acids or their derivatives, such as amides, with aldehydes and hydrogen halides in indifferent Reacts solvents.
Um die Reaktionsträger der allgemeinen Formel XYZ auf tertiäre Basen einwirken zu lassen, geht man z. B. so vor, daß man die betreffenden Reaktionsträger für sich oder in geeigneten indifferenten Lösungsmitteln gelöst zu einer tertiären Base, wie z. B. zu Pyridinbasen, Triäthylamin, Triäthanolamin, Dirnethylanilin, Dimethylcyclohexylamin, zutropfen läßt und gegebenenfalls das benutzte Lösungsmittel von dem gebildeten quaternären Umsetzungsprodukt anschließend bei vermindertem Druck abdestilliert.To the reaction carriers of the general formula XYZ on tertiary bases to let act, you go z. B. in such a way that one of the reaction carriers concerned by itself or dissolved in suitable inert solvents to form a tertiary one Base, such as B. to pyridine bases, triethylamine, triethanolamine, dirnethylaniline, Dimethylcyclohexylamine, and optionally the solvent used of the quaternary reaction product formed then under reduced pressure distilled off.
Gemäß der Erfindung werden nun derartige quarternäre Umsetzungsprodukte zwischen tertiären Basen und den angeführten Reaktionsträgern in geeigneter Weise den natürlichen oder künstlichen Eiweißfasern einverleibt. Dies kann z. B. in der Weise geschehen, daß man die künstlichen oder natürlichen Eiweißfasern mit wäßrigen Lösungen der quarternären Umsetzungsprodukte tränkt, dann abschleudert und anschließend trocknet.According to the invention, there are now such quaternary reaction products between tertiary bases and the listed reaction carriers in a suitable manner incorporated into natural or artificial protein fibers. This can e.g. B. in the Wise done that you can mix the artificial or natural protein fibers with aqueous Solutions of the quaternary conversion products are soaked, then centrifuged and then dries.
Die so behandelten Eiweißfasern weisen eine erhöhte Festigkeit gegenüber mechanischen Einwirkungen und eine erhöhte Widerstandsfähigkeit gegenüber chemischen Einflüssen auf. Dies zeigt sich z. B: darin, daß die aus den erfindungsgemäß behandelten Fasern hergestellten Gewebe eine erhöhte Strapazierfähigkeit und eine größere Unempfindlichkeit gegenüber den üblichen Färbungen mit sauren Farbstoffen aufweisen. Die in Flockenform vorliegenden eiweißhaltigen Fasern, wie insbesondere die natürliche Wolle, zeigen außerdem überraschenderweise eine verminderte Neigung zur Filzbildung.The protein fibers treated in this way have an increased strength mechanical effects and increased resistance to chemical Influences on. This is shown e.g. B: in that the from the treated according to the invention Fibers made fabrics an increased durability and a greater insensitivity have compared to the usual dyeings with acidic dyes. The ones in flake form present protein-containing fibers, such as, in particular, natural wool also, surprisingly, a reduced tendency to felt formation.
Für die praktische Durchführung des erfindungsgemäßen Verfahrens möge das nachstehende Beispiel als Anleitung dienen Beispiel 1,5 kg a-Chlormethyläther des Triäthanolaminformals in Form des salzsauren Salzes, dargestellt durch Einwirkung von Salzsäuregas auf eine Mischung von 2 Teilen Triäthanolamin und- -1;ä Teilen Paraformaldehyd in io Teilen Trichloräthylen unter Kühlen und Rühren mit anschließender Entfernung des überschüssigen Chlorwasserstoffs im Vakuum, werden allmählich in einer Knetapparatur zu 1,4 kg entwässertem Pyridin zugesetzt. Die Temperatur wird hierbei vorteilhaft zwischen 30 und 50° gehalten.For the practical implementation of the process according to the invention, the following example should serve as a guide Example 1.5 kg of a-chloromethyl ether of triethanolamine formal in the form of the hydrochloric acid salt, represented by the action of hydrochloric acid gas on a mixture of 2 parts of triethanolamine and -1; parts of paraformaldehyde in 10 parts of trichlorethylene with cooling and stirring with subsequent removal of the excess hydrogen chloride in vacuo, are gradually added in a kneading apparatus to 1.4 kg of dehydrated pyridine. The temperature is advantageously kept between 30 and 50 °.
a kg des erhaltenen quaternären Umsetzungsproduktes werden in So 1 Wasser gelöst; mit dieser Lösung werden 2 kg Wollgarn etwa 1/2 Stunde lang behandelt, anschließend abgeschleudert und bei 6o° getrocknet.a kg of the quaternary reaction product obtained are in So 1 Dissolved water; 2 kg of woolen yarn are treated with this solution for about 1/2 hour, then spun off and dried at 60 °.
Mit dem so vorbehandelten Wollgarn wird nun lauwarm in ein Färbebad eingegangen, welches in einer Wanne von Zoo 1 Inhalt mit Zoo g Schwefelsäure und 40 g eines blauen Farbstoffs bestellt ist. Es wird kochend Z1/, Stunden lang gefärbt, anschließend gespült und getrocknet.The wool yarn pretreated in this way is now lukewarm in a dye bath received, which in a tub of Zoo 1 content with Zoo g sulfuric acid and 40 g of a blue dye is ordered. It is colored at the boil Z1 /, for hours, then rinsed and dried.
Das erhaltene Wollgarn, welches sehr offen und weich ist, besitzt gegenüber einem in gleicher Weise gefärbten, aber nicht mit quaternären Umsetzungsprodukten vorbehandelten Wollgarn eine etwa 15 °/" höhere Reißfestigkeit: Es ist bereits bekannt, eiweißhaltige Fasern, wie insbesondere Wolle, durch Einverleibung von kunstharzartigen Stoffen in ihren.Festigkeitseigenschaften gegenüber mechanischen Einwirkungen zu verbessern. Derartigen bekannten Verfahren gegenüber zeichnet sich das vorliegende Verfahren dadurch aus, daß es zu eiweißhaltigen Fasern führt, die nicht nur gegenüber mechanischen Einwirkungen erheblich fester sind, sondern auch darüber hinaus noch andere Vorteile aufweisen, wie insbesondere eine erhöhte Widerstandsfähigkeit gegenüber chemischen Einwirkungen.The wool yarn obtained, which is very open and soft, has compared to one colored in the same way but not with quaternary reaction products pretreated woolen yarn has an approximately 15 ° / "higher tear resistance: It is already known Protein-containing fibers, such as wool in particular, through the incorporation of synthetic resin-like fibers Substances in their strength properties against mechanical influences to enhance. The present invention is characterized by such known methods Method characterized in that it leads to proteinaceous fibers that are not only opposite mechanical effects are considerably stronger, but also beyond that have other advantages, such as in particular an increased resistance to chemical effects.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ701D DE902246C (en) | 1938-12-24 | 1938-12-24 | Process for the treatment of natural or artificial protein-containing fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ701D DE902246C (en) | 1938-12-24 | 1938-12-24 | Process for the treatment of natural or artificial protein-containing fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE902246C true DE902246C (en) | 1954-01-21 |
Family
ID=7617862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEZ701D Expired DE902246C (en) | 1938-12-24 | 1938-12-24 | Process for the treatment of natural or artificial protein-containing fibers |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE902246C (en) |
-
1938
- 1938-12-24 DE DEZ701D patent/DE902246C/en not_active Expired
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