DE851485C - Process for foam swimming pool preparation - Google Patents
Process for foam swimming pool preparationInfo
- Publication number
- DE851485C DE851485C DEL3591D DEL0003591D DE851485C DE 851485 C DE851485 C DE 851485C DE L3591 D DEL3591 D DE L3591D DE L0003591 D DEL0003591 D DE L0003591D DE 851485 C DE851485 C DE 851485C
- Authority
- DE
- Germany
- Prior art keywords
- swimming pool
- terpene
- carbinols
- foam
- pool preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- 230000009182 swimming Effects 0.000 title description 3
- 235000007586 terpenes Nutrition 0.000 claims description 9
- 150000003505 terpenes Chemical class 0.000 claims description 7
- 238000005187 foaming Methods 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 6
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- -1 terpene alcohols Chemical class 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- 229930006739 camphene Natural products 0.000 description 2
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000010665 pine oil Substances 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 235000005039 Brassica rapa var. dichotoma Nutrition 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 244000130745 brown sarson Species 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000010675 spruce oil Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/04—Frothers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Detergent Compositions (AREA)
Description
Verfahren zur Schaumschwimmaufbereitung Es ist bekannt, als Schäumer-Reagentien in der Schaumschwimmaufbereitung aliphatische und aromatische Verbindungen mit hydrophil-hydrophobem Molekelbau und oberflächenaktiven Eigenschaften zu verwenden, die hydrophile Gruppen, Alkohol-, Phenol-, Keto-, Aldehyd-, Carbonsäure- oder Amidogrupp,n enthalten. Von der großen Zahl dieser Verbindungen hat sich jedoch nur eine sehr geringe Anzahl für die Praxis als brauchbar erwiesen, die den besonderen Verhältnissen bei der Schwimmaufbereitung gerecht w.-rden (Beschränkung der Wirkung auf die Grenzfläche Wasser - Luft, Erzielung tragfähiger Schäume, Wirksamkeit schon bei Zusatz möglichst kleiner Mengen). Verwendet werden deshalb z. Z. nur leichtere und mittlere Teeröle, Fichten- und Kiefernöle, Terpenalkohole, wie Pineoil oder ihr ähnliche künstliche Erzeugnisse, und Hydroxylderivate des Benzols, wie Kresol u. a.Foam flotation method It is known as frother reagents Aliphatic and aromatic compounds with hydrophilic-hydrophobic compounds in foam swimming pool treatment Molecular structure and surface-active properties to use the hydrophilic groups, Alcohol, phenol, keto, aldehyde, carboxylic acid or amido group, n contain. from However, the large number of these compounds has only been a very small number Proven to be useful in practice, the special conditions in the Swimming treatment is fair (limitation of the effect on the interface Water - air, achieving stable foams, effectiveness when added as much as possible small quantities). Are therefore used z. Currently only lighter and medium tar oils, Spruce and pine oils, terpene alcohols such as pineoil or similar artificial ones Products and hydroxyl derivatives of benzene such as cresol and others.
Es wurde nun gefunden, daß sich Terpencarbinole sehr gut für die Schwimmaufbereitung
von Erzen und Nichterzen eignen, da sie alle Bedingungen erfüllen, die an die hochwertigsten
Schäumer der Praxis gestellt werden. Ihre Wirkung übertrifft sogar noch die der
z. Z. als die besten deutschen Schäumer geltenden Terpenalkoholgemische. Die Terpencarbinole
entstehen in bekannter Weise durch Anlagerung von Kohlenoxyd und Wasserstoff unter
Druck und bei erhöhter Temperatur in Gegenwart von Kontakten an ungesättigte Terpenkohlenwasserstoffe,
wie beispielsweise Pinen, Camphen, Limonen, Dipenten, Fenchen usw. Die hierbei primär
entstehenden Aldehyde werden in üblicher Weise zu den Terpencarbinolen hydriert.
Ihr
Bildungsmechanismus läßt sich etwa folgendermaßen skizzieren:
Die Terp3ncarbinole sind wasserhelle, ölige Flüssigkeiten von angenehmem Geruch.
Es sieden z. B. bei i mm Restdruck die Carbinole aus
Auch die Anwendung der Terpencarbinole zusammen mit bisher üblichen Schäumern ist gegebenenfalls von Vorteil. Es hat sich in der Praxis als überraschende Tatsache weiterhin herausgestellt, daß durch die Anwendung dieser hervorragenden Schäumer neben der üblichen Ölsäure bei gleich guter Schäumerwirkung eine Verringerung der Olsäurezusatzmenge ermöglicht wird, was wegen der dadurch ermöglichten Einsparung dieses Sammlers bedeutsam ist.Also the use of terpene carbinols together with the usual ones Foaming may be beneficial. It has proven to be surprising in practice Fact further revealed that through the application of this excellent Foamer a reduction in addition to the usual oleic acid with the same good foaming effect the amount of added oleic acid is made possible, which is because of the savings made possible thereby of this collector is significant.
Beispiele
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEL3591D DE851485C (en) | 1945-01-11 | 1945-01-11 | Process for foam swimming pool preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEL3591D DE851485C (en) | 1945-01-11 | 1945-01-11 | Process for foam swimming pool preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE851485C true DE851485C (en) | 1952-10-06 |
Family
ID=7256251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEL3591D Expired DE851485C (en) | 1945-01-11 | 1945-01-11 | Process for foam swimming pool preparation |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE851485C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993007110A1 (en) * | 1991-10-09 | 1993-04-15 | Henkel Kommanditgesellschaft Auf Aktien | Method of concentrating and or cleaning coal and minerals by flotation using hydroxyimone ethers |
-
1945
- 1945-01-11 DE DEL3591D patent/DE851485C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993007110A1 (en) * | 1991-10-09 | 1993-04-15 | Henkel Kommanditgesellschaft Auf Aktien | Method of concentrating and or cleaning coal and minerals by flotation using hydroxyimone ethers |
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