DE830023C - Lime-bound stone and process for its manufacture - Google Patents

Lime-bound stone and process for its manufacture

Info

Publication number
DE830023C
DE830023C DEA398A DEA0000398A DE830023C DE 830023 C DE830023 C DE 830023C DE A398 A DEA398 A DE A398A DE A0000398 A DEA0000398 A DE A0000398A DE 830023 C DE830023 C DE 830023C
Authority
DE
Germany
Prior art keywords
ash
lime
lignite
lignite ash
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEA398A
Other languages
German (de)
Inventor
Rudolf Gunzelmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlas Werke AG
Original Assignee
Atlas Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Werke AG filed Critical Atlas Werke AG
Priority to DEA398A priority Critical patent/DE830023C/en
Application granted granted Critical
Publication of DE830023C publication Critical patent/DE830023C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

Kalkgebundener Stein und Verfahren zu seiner Herstellung Es ist schon vorgeschlagen worden, kalkhaltige Braunkohlenasche an Stelle von Kalk als Bindemittel für Baustoffe zu verwenden. Die bisherige Entwicklung zur praktischen Durchführung derartiger Verfahren hat jedoch zu keinem befriedigenden Ergebnis geführt; vielmehr blieb die Verwendung von Braunkohlenasche als Bindemittel auf gelegentliche, versuchsweise Herstellung von minderwertigen Baustoffen geringer Festigkeit beschränkt.Lime-bonded stone and method of making it It is beautiful It has been proposed to use calcareous lignite ash in place of lime as a binder to use for building materials. The previous development for practical implementation However, such a method has not led to a satisfactory result; much more The use of lignite ash as a binder remained on the occasional, experimental basis Production of low-quality, low-strength building materials is limited.

Der vorliegenden Erfindung liegt die Erkenntnis zugrunde, daß die mangelhafte Festigkeit der mit Braunkohlenasche als Bindemittel hergestellten Steine und Baustoffe darauf zurückzuführen ist, daß der in der Braunkohlenasche enthaltene Kalk in der Braunkohlenfeuerung einer erheblich höheren Temperatur unterworfen war als bei der normalen Kalkbrennung angewandt zu werden pflegt. Es ist zwar an sich bekannt, daß bei einer so hohen Temperatur gebrannter Kalk bei Löschung unter atmosphärischem Druck und atmosphärischer Temperatur nur unvollkommen gelöscht wird. Man hat jedoch diesen Umstand bei der Verwendung von Braunkohlenasche als Bindemittel bisher nicht beachtet, sondern die mangelhaften Ergebnisse der mit Braunkohlenasche als Bindemittel hergestellten Baustoffe und Steine auf andere Einflüsse, insbesondere solche der schwankenden Zusammensetzung der Braunkohlenasche zurückgeführt.The present invention is based on the knowledge that the Insufficient strength of the stones made with lignite ash as a binding agent and building materials is due to the fact that the contained in the lignite ash Lime in the lignite furnace was subjected to a considerably higher temperature than is usually used in normal lime burning. It is true in itself known that at such a high temperature quicklime when slaked under atmospheric conditions Pressure and atmospheric temperature is only imperfectly deleted. However, one has this fact has not yet occurred when using lignite ash as a binder but the poor results of using lignite ash as a binder manufactured building materials and stones on other influences, especially those of the fluctuating composition of the lignite ash.

Ausgehend von der Erkenntnis, daß die mangelhafte Löschung des in der Braunkohlenasche enthaltenen, bei sehr hoher Temperatur gebrannten Kalkes der Grund für die bisherigen schlechten Ergebnisse gewesen ist, wird gemäß der Erfindung der Löschprozeß bei Dampfdrücken über Atmosphärendruck durchgeführt. Wie Versuche gezeigt haben, läßt sich auf diese Weise eine vorzügliche Bindung auch bei Verwendung von Braunkohlenasche an Stelle von Kalk herbeiführen, so daß die hergestellten Steine im wesentlichen gleiche Festigkeit aufweisen, wie die mit normalem Kalkzusatz hergestellten Steine, wenn in den zu vergleichenden :Mischungen ein Ca0-Gehalt gleichen Prozentsatzes vorliegt. Dies bedeutet eine sehr erhebliche wirtschaftliche Verbesserung, da der bisher zur Kalkbindung fast ausschließlich verwendete, aus Kalksteinen hergestellte gebrannte Kalk einen erheblichen Prozentsatz, etwa 30 bis 35% der Herstellungskosten ausmacht, während die Braunkohlenasche in großen Mengen als bisher unverwendbarer Abfallstoff anfällt.Based on the knowledge that the inadequate deletion of the in the lignite ash contained in the lime burnt at a very high temperature The reason for the poor results so far has been is according to the invention the extinguishing process is carried out at vapor pressures above atmospheric pressure. Like attempts have shown, an excellent bond can be achieved in this way even when used of lignite ash instead of lime, so that the produced stones have essentially the same strength as those with normal Stones made with added lime if the mixtures to be compared have a Ca0 content the same percentage is present. This means a very substantial economic Improvement, as the one used almost exclusively to bind lime up to now Quick lime is made from limestones in a significant percentage, around 30 to 35% of the manufacturing cost, while the lignite ash in large quantities than previously unusable waste material.

Vorteilhaft verwendet man die Braunkohlenasche als Bindemittel in Verbindung mit Steinkohlenasche als Grundstoff zur Herstellung von Aschesteinen. Bei Mischung von 8 Raumteilen Steinkohlenasche mit 2 Raumteilen Braunkohlenasche bei 9,8% Ca 0-Gehalt der Mischung ergab sich beispielsweise für den gepreßten Stein bei einer Härtedauer von 3 Stunden und einem Härtedruck von 16 atü eine Festigkeit von i29 kg/cm2, bei einem Raumgewicht von 424 kg/1. Man kann aber auch andere kieselsäurehaltige Grundstoffe verwenden.The lignite ash is advantageously used as a binder in Combination with coal ash as a raw material for the production of ash stones. Mixing 8 parts of coal ash with 2 parts of lignite ash a 9.8% Ca 0 content of the mixture resulted, for example, for the pressed stone with a hardening time of 3 hours and a hardening pressure of 16 atmospheres a strength of i29 kg / cm2, with a density of 424 kg / l. But you can also use other silicic acid Use raw materials.

In der Anlage zur Herstellung der Steine nach dem neuen Verfahren sind für den Löschprozeß unter erhöhter Temperatur besondere Dampffässer vorzusehen.In the plant for the production of the stones according to the new process special steam barrels must be provided for the extinguishing process at elevated temperatures.

Bei der Herstellung hochwertiger kalkgebundener Steine hat man zwar früher zur Beschleunigung des Verfahrens die Kalklöschung auch schon bei Dampfdrücken über Atmosphärendruck durchgeführt; die schlechtenVersuehsergebnisse mit Braunkohlenasche als Bindemittel bei Löschung unter atmosphärischem Druck hatten jedoch zu dem Vorurteil geführt, daß sich der Einsatz von Braunkohlenasche in Herstellungsverfahren für hochwertige Baustoffe erst recht nicht lohne.In the production of high-quality lime-bound stones you have earlier, to speed up the process, the lime slaking even at steam pressures carried out above atmospheric pressure; the bad test results with lignite ash as a binder when extinguishing under atmospheric pressure, however, had to the prejudice led to the use of lignite ash in manufacturing processes for high-quality building materials are certainly not worth it.

Claims (5)

PATENTANSPRÜCHE: I. Verfahren zur Herstellung kalkgebundener Steine, insbesondere mit Dampfhärtung, dadurch gekennzeichnet, daß bei Verwendung von kalkhaltiger Braunkohlenasche als Bindemittel der Löschprozeß bei Dampfdrücken über Atmosphärendruck durchgeführt wird. PATENT CLAIMS: I. Process for the production of lime-bound stones, in particular with steam hardening, characterized in that when using calcareous Lignite ash as a binding agent in the extinguishing process at vapor pressures above atmospheric pressure is carried out. 2. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß zur Herstellung eineMischung von Steinkohlenasche und Braunkohlenasche verwendet wird. 2. The method according to claim i, characterized in that for Producing a mixture of hard coal ash and lignite ash is used. 3. Nach dem Verfahren gemäß Anspruch I und 2 hergestellter kalkgebundener Stein, dadurch gekennzeichnet, daß er aus einem kieselsäurehaltigen Grundstoff besteht, der durch kalkhaltige Braunkohlenasche unter Dampfhärtung gebunden ist. 3. Lime-bonded stone produced by the method according to claim I and 2, characterized in that it consists of a base material containing silica, which is bound by calcareous lignite ash under steam hardening. 4. Stein nach Anspruch 3, dadurch gekennzeichnet, daß er aus Sand als Grundstoff und Braunkohlenasche al-s Bindemittel hergestellt ist. 4th stone according to claim 3, characterized in that it consists of sand as the base material and lignite ash as a binder is made. 5. Stein nach Anspruch 3, dadurch gekennzeichnet, daß er aus Steinkohlenasche als Grundstoff und Braunkoblenasche als Bindemittel hergestellt ist. Angezogene Druckschriften: Stoffhütte, Taschenbuch der Stoffkunde, Berlin 1937, S. 48o.5. Stone according to claim 3, characterized in that it is made of coal ash as the base material and lignite ash as the binder. Printed publications: Stoffhütte, Taschenbuch der Stoffkunde, Berlin 1937, p. 48o.
DEA398A 1949-12-09 1949-12-09 Lime-bound stone and process for its manufacture Expired DE830023C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEA398A DE830023C (en) 1949-12-09 1949-12-09 Lime-bound stone and process for its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEA398A DE830023C (en) 1949-12-09 1949-12-09 Lime-bound stone and process for its manufacture

Publications (1)

Publication Number Publication Date
DE830023C true DE830023C (en) 1952-01-31

Family

ID=6919198

Family Applications (1)

Application Number Title Priority Date Filing Date
DEA398A Expired DE830023C (en) 1949-12-09 1949-12-09 Lime-bound stone and process for its manufacture

Country Status (1)

Country Link
DE (1) DE830023C (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Similar Documents

Publication Publication Date Title
DE830023C (en) Lime-bound stone and process for its manufacture
CH621319A5 (en) Process for producing mineral wool products
DE376085C (en) Process for the production of cores for iron and metal foundries
CH98789A (en) Process for the preparation of sulphurous acid and hydraulic binders from gypsum.
DE654369C (en) Process for the production of porous, refractory moldings
DE3330124A1 (en) Process for producing mineral-bonded wood materials, using a latent hydraulic binder
DE411584C (en) Process for the production of a hydraulic binder from oil shale or oil slate slag
DE698857C (en) Process for the production of solid, meltable briquettes from iron and steel chips
AT275392B (en) Process for increasing the storage stability of refractory bricks
DE663453C (en) Process for the production of high-pore ceramic products
DE802925C (en) Process for the production of calcined quartz artificial stones
DE922154C (en) Process for the production of sand-lime bricks
DE867072C (en) Process for the production of refractory bricks and steam masses from sintered dolomite
DE946333C (en) Process for the production of unfired components and ramming compounds
AT200801B (en) Process for the production of moldings from fine-grained materials, in particular fine ores, fine coals and slag and / or other fine-grained materials which are used for stone manufacture
DE836467C (en) Process for the production of building materials
DE3325775A1 (en) Process for producing a coarse granular aggregate for concrete
DE898573C (en) Manufacture of building materials from fly ash
DE825522C (en) Process for the manufacture of silica stones
DE904876C (en) Process for the production of solid materials consisting of solid particles joined together
DE606495C (en) Process for the production of refractory porous insulating bricks
DE951342C (en) Process for the production of fired components
DE510090C (en) Production of grainy active coal
DE1010903B (en) Process for the production of sand-lime bricks
DE858377C (en) Process for making refractory bricks