AT275392B - Process for increasing the storage stability of refractory bricks - Google Patents
Process for increasing the storage stability of refractory bricksInfo
- Publication number
- AT275392B AT275392B AT893065A AT893065A AT275392B AT 275392 B AT275392 B AT 275392B AT 893065 A AT893065 A AT 893065A AT 893065 A AT893065 A AT 893065A AT 275392 B AT275392 B AT 275392B
- Authority
- AT
- Austria
- Prior art keywords
- tar
- storage stability
- dolomite
- finely dispersed
- stones
- Prior art date
Links
- 238000003860 storage Methods 0.000 title claims description 13
- 239000011449 brick Substances 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 11
- 239000010459 dolomite Substances 0.000 claims description 22
- 229910000514 dolomite Inorganic materials 0.000 claims description 22
- 239000004575 stone Substances 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 15
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000292 calcium oxide Substances 0.000 claims description 8
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 6
- 239000001095 magnesium carbonate Substances 0.000 claims description 4
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 2
- 239000011269 tar Substances 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 235000012255 calcium oxide Nutrition 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- -1 bitumina Substances 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/013—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics containing carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/03—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/47—Oils, fats or waxes natural resins
- C04B41/478—Bitumen, asphalt, e.g. paraffin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/46—Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
- C04B2103/465—Water-sorbing agents, hygroscopic or hydrophilic agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/20—Tar bonded
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Oxide Ceramics (AREA)
Description
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Verfahren zur Erhöhung der Lagerungsbeständigkeit von feuerfesten Steinen
Die Erfindung betrifft ein Verfahren zur Erhöhung der Lagerungsbeständigkeit von feuerfesten Steinen auf der Basis Calciumoxyd und bzw. oder Sinterdolomit oder Magnesit durch Tauchen in ein Teerbad.
Zur Herstellung eines stabilisierten Sinters ist es bekannt, den vorgebrannten Dolomit mit gelöster oder hochdisperser Kieselsäure durch Bespritzen, Besprühen od. dgl. zu behandeln und diesen so behan- delten, vorgebrannten Dolomit anschliessend zu sintern. Beim Brennen von Kalk oder Dolomit zusam- men mit Kieselsäure bilden sich Calciumsilikate, die im Gegensatz zuCalciumoxyd hydratationsbeständig sind. Aus dem stabilisierten Sinter und einem organischen Bindemittel können auch unter Zusatz hochdisperser Kieselsäure, Steine oder Massen hergestellt werden, wobei die Kieselsäure mit dem Dolomit chemisch reagiert.
Weiters ist ein Verfahren zur Herstellung feuerfester Gegenstände aus gesintertem Dolomit unter Zusatz von Kaolin bzw. Feldspat und Ölen bekannt, bei dem die aus diesen Stoffen erhältliche Masse geformt und gebrannt wird.
Ferner sind die sogenannten Temperprozesse für Teerdolomitmassen bekannt ; die Ausgangsstoffe, also Sinterdolomit undTeer oder teerartige Stoffe, werden gemischt, gepresst und nach einer bestimmten Temperaturzeitkurve getempert. Um den Kohlenstoffgehalt im fertigen Stein zu erhöhen, werden dem Teer Koks, Graphit oder Russ zugesetzt. Den gleichen Zweck sollen teilweise Oxyde der Metalle Eisen, Mangan usw. erfüllen, welche als Katalysatoren bei der Teerverkrackung wirken.
Die Lagerungsbeständigkeit hochfeuerfester Steine aus Sinterdolomit ist bekanntlich begrenzt, da die Kalkkomponente des Materials bestrebt ist, Feuchtigkeit aufzunehmen und damit das Gefüge dieser hochfeuerfesten Erzeugnisse zerstört. Um die Lagerungsbeständigkeit zu erhöhen, werden die Steine daher üblicherweise nach dem Tunnelofenbrand in einem Teerbad getränkt.
In der Praxis ist man jedoch bestrebt, die Lagerungsbeständigkeit noch weiter zu verbessern. Dies ist im Hinblick auf die Lagerhaltung und den Transport von hochfeuerfesten Dolomitsteinen von grösster wirtschaftlicher Bedeutung.
Überraschenderweise wurde nun gefunden, dass man die Lagerungsbeständigkeit hochfeuerfester Steine auf der Basis Calciumoxyd und bzw. oder Sinterdolomit oder Magnesit beträchtlich steigern kann, wenn das Teerbad feindisperse Stoffe enthält, die keine schädlichen Reaktionen mit der feuerfesten Grundsubstanz des Steines, also beispielsweise mit dem Sinterdolomit oder seinen chemischen Bestandteilen, eingehen, die Feuerfestigkeit der Steine nicht oder nicht wesentlich herabsetzen, die physikalisch und bzw. oder chemisch Wasser zu binden vermögen und deren mittlere Teilchendurchmesser geringer sind als die mittleren Porendurchmesser des Steines.
Dieses Verfahren lässt sich in vorteilhafter Weise nicht nur auf hochfeuerfeste, durch Brennen oberhalb 15000C gesinterte Steine, sondern auch auf bei niedrigen Temperaturen (200 bis 400 C) getemperte Steine aus Teer-Dolomit-Mischung anwenden.
Als feindisperse Stoffe gemäss der Erfindung eignen sich solche, die die Fähigkeit besitzen, Wasser
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physikalische und bzw. oder chemisch unter Volumenvergrösserung zu binden, beispielsweise gebrannter Kalk oder weichgebrannter Sinterdolomit, in entsprechenden Feinheiten. Durch sie wird-eventuell durch dieTeerschicht diffundierende-Feuchtigkeit gebunden und von dem Steinmaterial ferngehalten.
Ausserdem bewirkt die Bindung von Feuchtigkeit durch die in den Poren befindlichen feindispersen Stoffe durch die Volumenzunahme einen wirksamen Verschluss der Poren.
Es hat sich gezeigt, dass durch den Zusatz dieser feindispersen Stoffe die Poren der Steine besser ausgefülltwerden und dass darüber hinaus die oberflächliche Schutzschicht auf den Steinengleichmässiger und dichter wird. Durch die Ausfüllung der Poren mittels der feindispersen Stoffe im Gemisch mit Teer wird die Diffusion von Feuchtigkeit in den Stein sehr erschwert, so dass mit dem erfindungsgemässen Verfahren beträchtliche - wie sich aus den Beispielen ergibt bis zu 45% erhöhte-Lagerungsbeständig- keiten erzielt werden können.
Selbstverständlich ist es möglich, die erfindungsgemäss verwendbaren feindispersen Stoffe der verschiedensten Art miteinander zu kombinieren.
Erfindungsgemäss werden die feindispersen Stoffe in Mengen von etwa 1 bis 20 Gew.-%, vorzugsweise 5 bis 10 Gew.-%-bezogen auf den Tauchteer - zugesetzt.
Um eine bessere Durchtränkung der Steine zu erreichen, hat es sich als zweckmässig erwiesen, die Tauchung unter Vakuum oder auch unter Vakuum und anschliessend unter Druck vorzunehmen.
Das Verfahren eignet sich besonders, gut für hochfeuerfeste Steine, die aus Calciumoxyd bestehen oder nennenswerte Mengen davon enthalten. Für die Praxis eignet sich das erfindungsgemässe Verfahren besonders gut für die Herstellung von Steinen aus Sinterdolomit, jedoch ist es selbstverständlich auch für solche Steine zu empfehlen, die einen erhöhten Magnesiumoxydgehalt besitzen.
Es ist auch möglich, das der Erfindung zugrunde liegende Verfahren einzusetzen, wenn die Formkörper mit einer organischen Schutzschicht, z. B. aus Teeren, Pechen, Bitumina, Asphalten, Wachsen usw., überzogen werden.
Die folgenden Beispiele zeigen das Ausmass der erzielten Steigerung der Lagerungsbeständigkeit der nach dem vorliegenden Verfahren getauchten Dolomitsteine : Beispiel l : Dolomitsteine wurden in einem Teerbad getaucht, dem 100/0 Rohdolomitstaub zu- gefügt worden waren. Die Steigerung der Lagerungsbeständigkeit dieser Steine betrug 20% gegenüber den in dem Teerbad ohne Zusatz, aber bei gleichen Bedingungen, getauchten Steinen.
Beispiel 2: Bei der Tränkung von Dolomitsteinen in einem Teerbad, das 7% Calciumoxyd enthielt, ergab sich gegenüber den in reinem Teer getauchten Steinen eine Steigerung der Lagerungsbeständigkeit um 45%.
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Process for increasing the storage stability of refractory bricks
The invention relates to a method for increasing the storage stability of refractory bricks based on calcium oxide and / or sintered dolomite or magnesite by immersion in a tar bath.
To produce a stabilized sinter, it is known to treat the prefired dolomite with dissolved or highly dispersed silica by spraying, spraying or the like, and then to sinter this prefired dolomite treated in this way. When lime or dolomite is burned together with silica, calcium silicates are formed which, unlike calcium oxide, are resistant to hydration. The stabilized sinter and an organic binder can also be used to produce stones or masses with the addition of highly dispersed silica, the silica reacting chemically with the dolomite.
Furthermore, a method for producing refractory objects from sintered dolomite with the addition of kaolin or feldspar and oils is known, in which the mass obtainable from these materials is shaped and fired.
The so-called tempering processes for tar dolomite masses are also known; The starting materials, i.e. sintered dolomite and tar or tar-like substances, are mixed, pressed and tempered according to a certain temperature-time curve. In order to increase the carbon content in the finished stone, coke, graphite or soot are added to the tar. Oxides of the metals iron, manganese, etc., which act as catalysts in tar cracking, are supposed to fulfill the same purpose.
The storage stability of highly refractory bricks made of sintered dolomite is known to be limited, since the lime component of the material strives to absorb moisture and thus destroy the structure of these highly refractory products. In order to increase the storage stability, the stones are therefore usually soaked in a tar bath after the tunnel kiln fire.
In practice, however, efforts are made to further improve the storage stability. This is of great economic importance with regard to the storage and transport of highly refractory dolomite bricks.
Surprisingly, it has now been found that the storage stability of highly refractory bricks based on calcium oxide and / or sintered dolomite or magnesite can be increased considerably if the tar bath contains finely dispersed substances that do not react with the refractory substance of the stone, for example with the sintered dolomite or its chemical constituents, do not or not significantly reduce the fire resistance of the stones, which are able to bind physically and / or chemically water and whose mean particle diameter is smaller than the mean pore diameter of the stone.
This method can advantageously be used not only on highly refractory bricks sintered by firing above 15000C, but also on bricks made from a tar-dolomite mixture that are tempered at low temperatures (200 to 400C).
As finely divided substances according to the invention are those which have the ability to water
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to bind physically and / or chemically with an increase in volume, for example burnt lime or soft-burnt sintered dolomite, in appropriate fineness. They bind moisture that may diffuse through the tar layer and keep it away from the stone material.
In addition, the binding of moisture by the finely dispersed substances in the pores causes an effective closure of the pores due to the increase in volume.
It has been shown that by adding these finely dispersed substances, the pores of the stones are better filled and, moreover, that the superficial protective layer on the stones becomes more even and denser. By filling the pores with the finely dispersed substances mixed with tar, the diffusion of moisture into the stone is made very difficult, so that with the method according to the invention considerable - as can be seen from the examples - storage stability can be achieved .
It is of course possible to combine the finely dispersed substances of the most varied of types which can be used according to the invention with one another.
According to the invention, the finely dispersed substances are added in amounts of about 1 to 20% by weight, preferably 5 to 10% by weight, based on the dipped tar.
In order to achieve better impregnation of the stones, it has proven to be expedient to undertake the immersion under vacuum or else under vacuum and then under pressure.
The process is particularly suitable for highly refractory bricks that consist of calcium oxide or contain significant amounts of it. In practice, the method according to the invention is particularly suitable for the production of stones from sintered dolomite, but it is of course also to be recommended for stones which have an increased magnesium oxide content.
It is also possible to use the method on which the invention is based when the shaped bodies are coated with an organic protective layer, e.g. B. from tars, pitch, bitumina, asphalt, wax, etc., are coated.
The following examples show the extent of the increase in storage stability achieved for the dolomite stones immersed in accordance with the present process: Example 1: Dolomite stones were immersed in a tar bath to which 100/0 raw dolomite dust had been added. The increase in the storage stability of these stones was 20% compared to the stones immersed in the tar bath without additives, but under the same conditions.
Example 2: When dolomite stones were soaked in a tar bath which contained 7% calcium oxide, the storage stability was increased by 45% compared to stones dipped in pure tar.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1278920 | 1964-10-02 | ||
| DE1964D0045543 DE1278920C2 (en) | 1964-10-02 | 1964-10-02 | Process to increase the storage stability of highly refractory, burned dolomite stones |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT275392B true AT275392B (en) | 1969-10-27 |
Family
ID=25751589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT893065A AT275392B (en) | 1964-10-02 | 1965-10-01 | Process for increasing the storage stability of refractory bricks |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3330676A (en) |
| AT (1) | AT275392B (en) |
| DE (1) | DE1278920C2 (en) |
| GB (1) | GB1101228A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114477864A (en) * | 2021-12-16 | 2022-05-13 | 深圳市文浩环保再生有限公司 | Permeable pavement brick and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048967C (en) * | 1996-07-25 | 2000-02-02 | 营口青花镁矿总公司 | Burnt oil-immersed conite and its manufacturing process |
| CN104744016A (en) * | 2015-03-16 | 2015-07-01 | 高邑汇德陶瓷有限公司 | Method for producing high-grade interior wall tile by utilizing floor tile industrial waste |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3141790A (en) * | 1964-07-21 | Burned basic refractory shapes | ||
| CH156978A (en) * | 1930-09-13 | 1932-09-15 | Stevenson Garnett Cecil | Process for making refractory articles. |
| DE1027121B (en) * | 1956-06-07 | 1958-03-27 | Mannesmann Ag | Process for the production of refractory bricks or converter floors |
| US3106475A (en) * | 1961-05-29 | 1963-10-08 | Harbison Walker Refractories | Burned refractory product |
| US3148238A (en) * | 1961-08-21 | 1964-09-08 | Harbison Walker Refractories | Oxygen converter linings |
-
1964
- 1964-10-02 DE DE1964D0045543 patent/DE1278920C2/en not_active Expired
-
1965
- 1965-10-01 US US492325A patent/US3330676A/en not_active Expired - Lifetime
- 1965-10-01 AT AT893065A patent/AT275392B/en active
- 1965-10-04 GB GB42008/65A patent/GB1101228A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114477864A (en) * | 2021-12-16 | 2022-05-13 | 深圳市文浩环保再生有限公司 | Permeable pavement brick and preparation method thereof |
| CN114477864B (en) * | 2021-12-16 | 2023-02-24 | 深圳市文浩环保再生有限公司 | Permeable pavement brick and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1101228A (en) | 1968-01-31 |
| DE1278920C2 (en) | 1973-11-15 |
| DE1278920B (en) | 1968-09-26 |
| US3330676A (en) | 1967-07-11 |
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