DE758512C - Fusion of an iron or nickel alloy with glass - Google Patents

Fusion of an iron or nickel alloy with glass

Info

Publication number
DE758512C
DE758512C DEA88059D DEA0088059D DE758512C DE 758512 C DE758512 C DE 758512C DE A88059 D DEA88059 D DE A88059D DE A0088059 D DEA0088059 D DE A0088059D DE 758512 C DE758512 C DE 758512C
Authority
DE
Germany
Prior art keywords
glass
iron
nickel alloy
expansion coefficient
fusion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEA88059D
Other languages
German (de)
Inventor
Louis Navias
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AEG AG
Original Assignee
AEG AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AEG AG filed Critical AEG AG
Application granted granted Critical
Publication of DE758512C publication Critical patent/DE758512C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/02Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing by fusing glass directly to metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Glass Compositions (AREA)

Description

Verschmelzung einer Eisen- oder Nickellegierung mit Glas Die Herstellung einer Verschmelzung einer Eisen-Nickel-Legierung, die etwa 58% Eisen enthält, mit Glas von gleichem Ausdehnungskoeffizienten unter Verwendung einer Glaszwischenschicht, deren Ausdehnungskoeffizient mit dem der zu verbindenden Körper nicht übereinstimmt, bietet Schwierigkeiten. Diese Schwierigkeiten werden erfindungsgemäß dadurch behoben, daß die Eisen-Nickel-Legierung mit einem Glas aus 3q.0/0 Si02, 281/o B203, 7019 A12031 :291/o Pb 0 und 2% Nag O unter Verwendung eines Zwischenglases aus 62 % S i 02, 29% B2 03, 3 % A1203 und 6 % Na20 verschmolzen wird. Das zuletzt genannte Glas weicht in seinem Ausdehnungskoeffizienten von dem zuerst genannten und von dem der Eisen-Nickel-Legierung merklich ab. Es hat jedoch die Eigenschaft, an der Eisen-Nickel-Legierung sehr gut zu haften. Es entsteht daher überraschenderweise trotz der Verschiedenheit der Ausdehnungskoeffizienten eine zuverlässige Verbindung zwischen dem Bleiglas und der Eisen-Nickel-Legierung unter Vermittlung des bleifreien Zwischenglases.Fusing an iron or nickel alloy with glass The preparation of a fusing of an iron-nickel alloy, which contains about 58% iron, with glass of the same expansion coefficient using an intermediate glass layer, the expansion coefficient of which does not match that of the bodies to be joined, presents difficulties. According to the invention, these difficulties are eliminated by using the iron-nickel alloy with a glass made of 3q.0 / 0 Si02, 281 / o B203, 7019 A12031: 291 / o Pb 0 and 2% Nag O using an intermediate glass made of 62% S i 02, 29% B2 03, 3% A1203 and 6% Na20 is fused. The last-mentioned glass differs markedly in its coefficient of expansion from the first-mentioned one and from that of the iron-nickel alloy. However, it has the property of adhering very well to the iron-nickel alloy. Therefore, surprisingly, despite the difference in the expansion coefficients, a reliable connection is created between the lead glass and the iron-nickel alloy with the intermediary of the lead-free intermediate glass.

Glas und Metall unter Vermittlung von Zwischengläsern miteinander zu verschmelzen, ist an sich bekannt. Die erfindungsgemäße Verschmelzung unterscheidet sich von den bekannten Verschmelzungen dadurch, daß zwischen das mit der Eisen-Nickel-Legierung hinsichtlich des Ausdehnungskoeffizienten übereinstimmenden Bleiglases, das an dieser Legierung keine genügende Haftfähigkeit besitzt, eine Zwischenschicht vorgesehen ist, die aus bleifreiem Glas besteht, das infolge seines Abweichens im Ausdehnungskoeffizienten von der Legierung bisher als ungeeignet zu einer derartigen Verschmelzung angesehen wurde, das aber die Eigenschaft hat, an der Legierung hervorragend zu haften, so daß sich trotz der Verschiedenheit im Ausdehnungskoeffizienten eine zuverlässige Verbindung zwischen dem Bleiglas und der Eisen-N ickel-Legierung herstellen läßt.Glass and metal with the intermediary of intermediate glasses to merge is known per se. The inventive merger differs from the known amalgamations in that between the with of the iron-nickel alloy with regard to the expansion coefficient Lead glass, which does not have sufficient adhesion to this alloy, is a Interlayer is provided, which consists of lead-free glass, as a result of its Deviations in the expansion coefficient from the alloy have so far been considered unsuitable such a merger was considered, but which has the property to adhere to the alloy excellently, so that despite the difference in the expansion coefficient a reliable connection between the lead glass and the iron-nickel alloy can be produced.

Claims (1)

PATENTANSPPUCII: Verschmelzung einer Eisen-Nickel-Legierung, die etwa 58% Eisen enthält, mit Glas gleichen Ausdehnungskoeffizienten unter Verwendung .einer Glaszwischenschicht, deren Ausdehnungskoeffizient nicht mit dem Ausdehnungskoeffizient der zu verbindenden Körper übereinstimmt, dadurch gekennzeichnet, daß die Eisen-Nickel-Legierung mit einem Glas aus 3q.0/0 S'02, 28% BZ 03, 7»/o A120,31 29% Pb0 und 2% Na20 unter Verwendung eines Zwischenglases aus 62% Si 02, 290/0 B20,3, 3% Ale 03 und 6% Na" 0 verschmolzen ist. Zur Abgrenzung des Erfindungsgegenstands vom Stand der Technik sind im Erteilungsverfahren folgende Druckschriften in Betracht gezogen worden: Deutsche Patentschriften Nr. III 954, z 13 588, 228 840, 309 343. 634 236; britische Patentschrift Nr. 456 662; S t u c k e r t, »Die Emailfabrikation«, 1929, S, 117 ff.PATENTANSPPUCII: Fusion of an iron-nickel alloy, which contains about 58% iron, with glass with the same expansion coefficient using a glass intermediate layer, the expansion coefficient of which does not match the expansion coefficient of the body to be connected, characterized in that the iron-nickel alloy with a glass of 3q.0 / 0 S'02, 28% BZ 03, 7 »/ o A120.31 29% Pb0 and 2% Na20 using an intermediate glass made of 62% Si 02, 290/0 B20.3, 3% Ale 03 and 6% Na " 0 is fused. To distinguish the subject matter of the invention from the state of the art, the following publications have been taken into account in the grant procedure: German Patent Specifications No. III 954, z 13 588, 228 840, 3 0 9 343, 634 236 ; British patent specification No. 456 662; S tuckert, "Die Emailfabrikation", 1 929, pp. 117 ff.
DEA88059D 1938-05-21 1938-09-13 Fusion of an iron or nickel alloy with glass Expired DE758512C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US758512XA 1938-05-21 1938-05-21

Publications (1)

Publication Number Publication Date
DE758512C true DE758512C (en) 1953-05-04

Family

ID=22128385

Family Applications (1)

Application Number Title Priority Date Filing Date
DEA88059D Expired DE758512C (en) 1938-05-21 1938-09-13 Fusion of an iron or nickel alloy with glass

Country Status (1)

Country Link
DE (1) DE758512C (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE113588C (en) *
DE228840C (en) *
DE309343C (en) * 1917-12-04 1918-11-14
DE634236C (en) * 1929-07-27 1936-08-21 Johannes Nienhold Gas-tight sealing of metal electrodes in vacuum tubes made of glass
GB456662A (en) * 1934-05-08 1936-11-09 Porzellanfabrik Kahla Improvements in and relating to lead-in arrangements for electric conductors

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE113588C (en) *
DE228840C (en) *
DE309343C (en) * 1917-12-04 1918-11-14
DE634236C (en) * 1929-07-27 1936-08-21 Johannes Nienhold Gas-tight sealing of metal electrodes in vacuum tubes made of glass
GB456662A (en) * 1934-05-08 1936-11-09 Porzellanfabrik Kahla Improvements in and relating to lead-in arrangements for electric conductors

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