DE749505C - Process for improving the spinnability of cellulose hydrate fibers - Google Patents

Process for improving the spinnability of cellulose hydrate fibers

Info

Publication number
DE749505C
DE749505C DEP83575D DEP0083575D DE749505C DE 749505 C DE749505 C DE 749505C DE P83575 D DEP83575 D DE P83575D DE P0083575 D DEP0083575 D DE P0083575D DE 749505 C DE749505 C DE 749505C
Authority
DE
Germany
Prior art keywords
tall oil
spinnability
improving
cellulose hydrate
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP83575D
Other languages
German (de)
Inventor
Dr Hans Hoefelmann
Dr Erich Torke
Albert Wicklein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KURMAERKISCHE ZELLWOLLE und ZE
RHEINISCHE KUNSTSEIDE AG
RHEINISCHE ZELLWOLLE AG
SCHLESISCHE ZELLWOLLE AG
ZELLWOLLE und ZELLULOSE AG KUE
Original Assignee
KURMAERKISCHE ZELLWOLLE und ZE
RHEINISCHE KUNSTSEIDE AG
RHEINISCHE ZELLWOLLE AG
SCHLESISCHE ZELLWOLLE AG
ZELLWOLLE und ZELLULOSE AG KUE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KURMAERKISCHE ZELLWOLLE und ZE, RHEINISCHE KUNSTSEIDE AG, RHEINISCHE ZELLWOLLE AG, SCHLESISCHE ZELLWOLLE AG, ZELLWOLLE und ZELLULOSE AG KUE filed Critical KURMAERKISCHE ZELLWOLLE und ZE
Priority to DEP83575D priority Critical patent/DE749505C/en
Application granted granted Critical
Publication of DE749505C publication Critical patent/DE749505C/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Description

Verfahren zur Verbesserung der Spinnbarkeit von Cellulosehydratfasern Es wurde gefunden, daß brauchbare A\-ivagen für die Verbesserung der Spinnbarkeit von Cellulosehydratfasern, insbesondere Zellu#olle, erhalten werden können, wenn rohes oder gereinigtes Tallöl oder Tallölseifen oder aus dem Tallöl fraktionierte Fettsäuren mit einem über i °`o liegenden Harzgehalt, gegebenenfalls zusammen mit anderen bekannten Avivagemitteln in Emulsion auf die Faser gebracht werden. Im. Bedarfsfalle kann man den Harzsäuregehalt des Fettsäureanteils des Tallöls dadurch bis über i % herabsetzen, daß man die aus dem Tallöl isolierten Fettsäuren durch fraktionierte Destillation und Kristallisation reinigt. Mit gleichem Erfolg wie die freien Säuren können auch die Ester mit über i % Harz als Avivagemittel benutzt werden.Process for improving the spinnability of hydrate cellulose fibers It has been found that useful additives for improving spinnability from cellulose hydrate fibers, in particular cellulose, can be obtained if crude or purified tall oil or tall oil soaps or fractionated from tall oil Fatty acids with a resin content above i ° `o, possibly together with other known softeners can be applied to the fiber in emulsion. In the. If necessary, the resin acid content of the fatty acid content of the tall oil can thereby be adjusted Reduce to over i% that the fatty acids isolated from the tall oil by fractional distillation and crystallization purifies. With the same success as the free acids can also be used as a softener, the esters with more than 1% resin will.

Beispielsweise konnten brauchbare Avivagen auch noch erzielt werden, wenn Tallölseifen mit einem Harzsäuregehalt von 5oo;o verwendet wurden. Bei Verwendung solcher Avivagen traten wesentliche Schwierigkeiten bei Verspinnung und Weiterverarbeitung des präparierten Textilgutes nicht auf. Auch Avivagen mit einem noch höheren Harzsäureanteil ergaben eine brauchbare Präparation der Zellwolleflocke. Es stellte sich dabei heraus, daß der Harzsäureanteil fast Ibis So o/o betragen kann. Avivagen mit einem so hohen Gehalt an Harzsäure erwiesen sich insbesondere als noch.; gut brauchbar für die Avivage von Zelljute: -Beispiel 1 Zur Ansetzung eines Avivagebades wird Tallöl unter Zusatz von Türkischrotöl in Wasser eingerührt, und zwar in einer Menge, Iafi das fertige Avivagebad o,5 bis i g/1 Tallöl 1117i1 o,i bis o,2 g/1 Türkischrotöl enthält. In drn3 3vivagebad werden Viscosefasern vom Wolltyp getränkt. Die avivierte Faser besitzt einen guten öffnungsgrad und läßt sich auf den Spinnmaschinen anstandslos verarbeiten.For example, usable finishing agents could also be achieved, if tall oil soaps with a resin acid content of 500; o were used. Using Such finishing agents encountered significant difficulties during spinning and further processing of the prepared textile material does not appear. Also finishing agents with an even higher resin acid content resulted in a usable preparation of the rayon flake. It turned out that the resin acid content can be almost Ibis So o / o. Avivages with such a high level salary of resin acid proved to be particularly still .; good for the finishing From cell jute: -Example 1 Tall oil is added with the addition of a finishing bath of Turkish red oil stirred into water, in an amount equal to the finished product Avivage bath contains 0.5 to 0.2 g / 1 tall oil 1117i1 0.1 to 0.2 g / 1 Turkish red oil. In drn3 3vivagebad is soaked in viscose fibers of the wool type. The enriched fiber possesses a good degree of opening and can be processed on the spinning machine without any problems.

An Stelle von Türkischrotöl können auch andere bekannte Ernulgatoren, wie Fettalkoholsulfonate,verwendet werden. Durch Zusatz geringer Mengen von organischen Lösungsmitteln kann die Beständigkeit der Avivageemulsion erhöht werden. Beispiel 2 Zur Herstellung eines Avivagebades werden Tallölseife und ylineralöl in Wasser emulgiert. Es wird so viel Tallölseife zugesetzt, daß das fertige Bad i bis 2,5 g/1 enthält. Der Mineralölgehalt des Bades soll o,5 bis i g/1 betragen. Zur besseren Emulgierung werden noch pro Liter o,o5 g Fettalköholsulfonat zugesetzt.Instead of Turkish red oil, other known emulsifiers, such as fatty alcohol sulfonates, can also be used. The resistance of the finishing emulsion can be increased by adding small amounts of organic solvents. Example 2 To produce a finishing bath, tall oil soap and ylineral oil are emulsified in water. So much tall oil soap is added that the finished bath contains 1 to 2.5 g / l. The mineral oil content of the bath should be 0.5 to ig / 1. To improve emulsification, 0.05 g of fatty alcohol sulfonate are added per liter.

Beispiel 3 Rohes Tallöl, wie es in der Zellstoffabrik anfällt, wird in einer Menge von 5 bis i o g/1 in Wasser gelöst. Mit der Lösung «-erden Zelljutefasei-n getränkt und das überschüssige Avivagebad abgescbleudert. Die getrockneten Fasern zeigen einen feuchten Griff, lassen sich aber ausgezeichnet verspinnen.Example 3 Crude tall oil as produced in the pulp mill is used dissolved in water in an amount of 5 to 10 g / l. With the solution «- ground cell jute fibers soaked and the excess avivage bath was thrown off. The dried fibers show a damp handle, but can be spun very well.

Eine etwas bessere Avivierung wird erzielt, wenn an Stelle des Rohöls die gleiche Menge #l-ereiillgt.es Tallöl benutzt wird und dieses für die Herstellung der Avivage oder durch Zu-, C- ,a be von Ammoniak ganz oder teilweise verseift wird.A slightly better finish is achieved if instead of the crude oil the same amount # l-ereiillgt.es tall oil is used and this one for the production the avivage or by adding, C-, a be of ammonia is completely or partially saponified.

Claims (3)

PATENTANSPRÜCHE: i. Verfahren zur Verbesserung der Spinnbarkeit von Cellulosehydratfasern, dadurch gekennzeichnet, daß Tallölfettsäuren bzw. ihre Ester, deren beider Harzgehalt über i 0,o liegt, unter Benutzung eines geeigneten Emulgators in Emulsion auf die Faser aufgebracht werden. PATENT CLAIMS: i. Process to improve the spinnability of Cellulose hydrate fibers, characterized in that tall oil fatty acids or their esters, both of which have resin contents above i 0, o, using a suitable emulsifier can be applied to the fiber in emulsion. 2. Verfahren nach Anspruch i, dadurch gekennzeichnet, daß Tallöl selbst oder Tallöiseifen verwendet werden. 2. The method according to claim i, characterized characterized in that tall oil itself or tall oil soaps are used. 3. Verfahren nach Anspruch i oder 2, dadurch gekennzeichnet, daß die Tallölproduk.te zusammen mit anderen bekannten Avivagemitteln verwendet werden. Zur Abgrenzung des Anmeldungsgegenstandes vom Stand der Technik sind im Erteilungsverfahren keine Druckschriften in Betracht gezogen worden.3. Procedure according to claim i or 2, characterized in that the tall oil products together can be used with other known softeners. To delimit the subject of the registration No publications from the state of the art are considered in the granting procedure been drawn.
DEP83575D 1941-08-20 1942-01-01 Process for improving the spinnability of cellulose hydrate fibers Expired DE749505C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEP83575D DE749505C (en) 1941-08-20 1942-01-01 Process for improving the spinnability of cellulose hydrate fibers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE233161X 1941-08-20
DEP83575D DE749505C (en) 1941-08-20 1942-01-01 Process for improving the spinnability of cellulose hydrate fibers

Publications (1)

Publication Number Publication Date
DE749505C true DE749505C (en) 1944-11-24

Family

ID=5884651

Family Applications (3)

Application Number Title Priority Date Filing Date
DEP82923D Expired DE742523C (en) 1941-08-20 1941-08-21 Process for improving the spinnability of cellulose hydrate fibers
DEP83575D Expired DE749505C (en) 1941-08-20 1942-01-01 Process for improving the spinnability of cellulose hydrate fibers
DEP84866D Expired DE747490C (en) 1941-08-20 1942-01-13 Process for improving the spinnability of cellulose hydrate fibers

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DEP82923D Expired DE742523C (en) 1941-08-20 1941-08-21 Process for improving the spinnability of cellulose hydrate fibers

Family Applications After (1)

Application Number Title Priority Date Filing Date
DEP84866D Expired DE747490C (en) 1941-08-20 1942-01-13 Process for improving the spinnability of cellulose hydrate fibers

Country Status (5)

Country Link
BE (2) BE448956A (en)
CH (1) CH233161A (en)
DE (3) DE742523C (en)
FR (2) FR884961A (en)
NL (1) NL59670C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE840137C (en) * 1948-10-02 1952-05-29 Glanzstoff Ag Process for impregnating artificial silk with agents to increase rubber adhesion
DE975156C (en) * 1954-03-27 1961-10-05 Zschimmer & Schwarz Resin-containing mineral oil spinning melts

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE611780C (en) * 1929-07-09 1935-04-06 I G Farbenindustrie Akt Ges Softeners

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE840137C (en) * 1948-10-02 1952-05-29 Glanzstoff Ag Process for impregnating artificial silk with agents to increase rubber adhesion
DE975156C (en) * 1954-03-27 1961-10-05 Zschimmer & Schwarz Resin-containing mineral oil spinning melts

Also Published As

Publication number Publication date
BE448956A (en)
BE446800A (en)
DE742523C (en) 1943-12-06
FR884961A (en) 1943-09-01
NL59670C (en)
DE747490C (en) 1944-09-27
FR52714E (en) 1945-05-17
CH233161A (en) 1944-07-15

Similar Documents

Publication Publication Date Title
DE749505C (en) Process for improving the spinnability of cellulose hydrate fibers
DE1278987C2 (en) Process for the electrostatic flocking of carrier materials with synthetic fibers
DE680835C (en) Softener for textile treatment
DE715255C (en) Process for refining fibrous material, feathers or tobacco products
DE546213C (en) Sizing agents
DE646289C (en) Process for the impregnation of materials
DE1013832B (en) Process for achieving a smooth draft when spinning fibers from regenerated cellulose by finishing
DE502234C (en) Process for oiling textile fibers
DE592817C (en) Matting agent for textiles
DE720555C (en) Process for increasing the sliding properties of textiles
AT154568B (en) Process for waterproofing all types of textiles.
AT119026B (en) Process for the production of artificial textile structures with a matt, silk-like to completely reduced gloss.
DE896843C (en) Process for the production of artificial, hollow cellulose threads
DE683206C (en) Process for the production of anhydrous and electrolyte-free sulphonation products
DE566944C (en) Process for reducing the electrical charge on textile fibers
DE686170C (en) Method for sizing rayon
DE702628C (en) Process for impregnating textiles
DE438969C (en) Method for reinforcing tricot fabrics
DE572613C (en) Process for the finishing of cleaned textile fabrics
AT160080B (en) Dry spinning process for the production of synthetic threads from cellulose acetate.
AT127380B (en) Preparations for treating textiles.
DE743397C (en) Process for the production of threads and bristles
DE649027C (en) Process for finishing textiles of all kinds
DE940727C (en) Detergents for textiles
AT210380B (en) Fat- and oil-free lubricants for the wool industry