DE736400C - Wetting agents, foaming agents and dispersants - Google Patents
Wetting agents, foaming agents and dispersantsInfo
- Publication number
- DE736400C DE736400C DEB144608D DEB0144608D DE736400C DE 736400 C DE736400 C DE 736400C DE B144608 D DEB144608 D DE B144608D DE B0144608 D DEB0144608 D DE B0144608D DE 736400 C DE736400 C DE 736400C
- Authority
- DE
- Germany
- Prior art keywords
- agents
- wetting
- dispersants
- foaming
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002270 dispersing agent Substances 0.000 title claims description 3
- 239000004088 foaming agent Substances 0.000 title claims description 3
- 239000000080 wetting agent Substances 0.000 title claims description 3
- 238000006277 sulfonation reaction Methods 0.000 claims description 7
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- PYUYQYBDJFMFTH-WMMMYUQOSA-N naphthol red Chemical compound CCOC1=CC=CC=C1NC(=O)C(C1=O)=CC2=CC=CC=C2\C1=N\NC1=CC=C(C(N)=O)C=C1 PYUYQYBDJFMFTH-WMMMYUQOSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000007903 penetration ability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 238000004048 vat dyeing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/04—Sulfonates or sulfuric acid ester salts derived from polyhydric alcohols or amino alcohols or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/52—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
- D06M13/522—Fulling
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Coloring (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
Netz-, Schaum- und Dispergierungsnuttel Es wurde gefunden, daß die Sulfanierungsprodukte der höhermolekularen aliphatischen mehrwertigen Alkohole vorteilhaft als Netz-, Schaum- und Dispergierungsmitt-el verwendet werden können. Die Sulfonierungsprodukte mehrwertiger Alkohole zeigen gegenüber den Sulfonierungsprodukten einwertiger Alkohole den Vorteil, daß sie bzw. ihre Alkali-, Kaik-und Magnesiumsalze noch leichter löslich sind, was darauf zurückzuführen ist, daß die mehrwertigen Alkohole mehr Schwefelsäurereste aufzunehmen vermögen.Netz-, Schaum- und Disperspergierungsnuttel It has been found that the Sulphanation products of the higher molecular weight aliphatic polyhydric alcohols are advantageous can be used as wetting agents, foaming agents and dispersing agents. The sulfonation products Polyhydric alcohols show the sulfonation products of monohydric alcohols the advantage that they or their alkali, calcium and magnesium salts are even more readily soluble are, which is due to the fact that the polyhydric alcohols have more sulfuric acid residues able to absorb.
Als Ausgangsstoffe für die Herstellung der Sulfonierungsprodukte können z. B. die Alkohole dienen, die man aus den Estern höhermolekularer Oxysäuren durch Reduktion erhält. Man kommt auf diese Weise zu einem zweiwertigen Alkohol.As starting materials for the production of the sulfonation products can z. B. serve the alcohols obtained from the esters of higher molecular weight oxyacids Reduction received. This is how you get a dihydric alcohol.
Beispiel n 286 kg Octadecandiol-i, 12, das in bekannter Weise durch Reduktion von i 2-Oxystearinsäure dargestellt werden kann, werden mit .232 kg Chlorsulfonsäure bei 3o' sulfoniert. Das rohe Sulfonierungsprodukt neutralisiert man unmittelbar mit Natronlauge und trennt die anorganischen Bestandteile (Natriumsulfat, Natriumchlorid) ab. Durch Eindampfen kann das Produkt im wasserfreien Zustande gewonnen werden. Die vorliegenden Sulfonierungsprodukte zeigen neben ihren Beständigkeits,eigenschaften, die darauf beruhen, daß keine freie oder veresterte Carboxylgruppe vorhanden ist, hohes Netz-, Schaum-, Emulgierungs- und Reinigungsvermögen sowie die Eigenschaft, Textilfasern und verwandten Stoffen einen weichen, glatten und nicht klebenden Griff zu erteilen. Sie sind deswegen für eine mannigfaltige Verwendung in der Textil- und Lederindustrie, aber auch in anderen Industriezweigen geeignet.Example n 286 kg octadecanediol-i, 12, which in a known manner by Reduction of i 2-oxystearic acid can be represented with .232 kg of chlorosulfonic acid sulfonated at 3o '. The crude sulfonation product is neutralized immediately with sodium hydroxide solution and separates the inorganic components (sodium sulfate, sodium chloride) away. The product can be obtained in an anhydrous state by evaporation. The present sulfonation products show in addition to their resistance, properties, which are based on the fact that no free or esterified carboxyl group is present, high wetting, foaming, emulsifying and cleaning power as well as the property Textile fibers and related fabrics have a soft, smooth and non-sticky feel granted. They are therefore suitable for a wide range of uses in textile and leather industry, but also suitable in other branches of industry.
Sie fördern bei allen Behandlungen der Textilien mit neutralen, sauren oder alkalischen' Behandlungsflüssigkeiten die Wirkung durch die wesentlich erhöhte Ausnutzung und Durchdringung der Bäder und durch überführung von Fetten, Verunreinigungen u. dgl. in wäßrige Dispersion.They promote all treatments of the textiles with neutral, acidic or alkaline 'treatment fluids the effect by the significantly increased Utilization and penetration of the baths and through the transfer of fats and impurities and the like in aqueous dispersion.
In der Küpenfärberei ermöglicht der Zusatz dieser Produkte die Verküpung in Gegenwart von wenig bzw. schwachem Alkali, was beim Färben mit Küpenfarbstoffen auf tierischen Fasern wichtig ist. In der Naphtholrotfärberei können auf diesem Wege auch tierische Fasern gefärbt werden. Auch die Annetzung von pulverförmigen Farbstoffen und sonstigen Pulvern bei der Überführung in wäßrige Flüssigkeiten, bei der Herstellung von Pasten u. dgl. wird durch Zusatz der oben beschriebenen Stolte erleichtert. In der Spinnerei haben sich ihre wäL;rigen Lösungen bzw. ihre mit weiteren Zusätzen hergestellten Dispersionen als wertvolle ßefeuchtungs.mittel erwiesen. Ebenso wird die Wirkung der Behandlungsflüssigkeiten bei der Lederherstellung und Lederveredelung durch Zusatz der vorliegenden Sulfonierungsprodukte beschleunigt, verstärkt und günstig beeinflußt. In der Papierherstellungs- undVerarbeitungsindustrie, der Pigmentfarbenherstellung und der Pelzfärberei sind die Verbindungen überall da verwendbar, wo es auf Netzwirkung, Dispergierung, Durchdringung und Transport wirksamer Bestandteile ankommt. Diese Eigenschaften ermöglichen auch die Verwendung der Produkte in der Pharmazie als Emulgatoren sowie in der pharmazeutischen Technik als Schaum- und Hautschutzmittel sowie als Bestandteil von Salben oder Cremen. Auf die Eigenschaften der starken Netzung und Durchdringung ist auch ihre Eignung als Mittel zur Schädlingsbekämpfung begründet. Auch als ßeizzusätze und Bohröle in der metallverarbeitenden Industrie sind die: Produkte wertvoll. Als Zusatz zu keramischen Massen kommt ihr Durchdrinbungsvermügen, als Staubbindemittel ihre schnell wirksam werdende Netzung zur Geltung.In vat dyeing, the addition of these products enables vatting in the presence of little or weak alkali, which is important when dyeing animal fibers with vat dyes. In naphthol red dyeing, animal fibers can also be dyed in this way. The wetting of pulverulent dyes and other powders when they are converted into aqueous liquids, when making pastes and the like is also facilitated by adding the above-described stolte. In the spinning mill, their aqueous solutions or their dispersions prepared with other additives have proven to be valuable moisturizers. Likewise, the effect of the treatment liquids in leather production and leather finishing is accelerated, intensified and favorably influenced by adding the sulfonation products present. In the paper production and processing industry, pigment dye production and fur dyeing, the compounds can be used wherever the wetting effect, dispersion, penetration and transport of active ingredients are important. These properties also enable the products to be used in pharmacy as emulsifiers and in pharmaceutical technology as foam and skin protection agents and as a component of ointments or creams. Their suitability as a means of pest control is based on the properties of the strong wetting and penetration. The: products are also valuable as acid additives and drilling oils in the metalworking industry. As an additive to ceramic masses, their penetration ability comes into their own;
Claims (1)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL31966D NL31966C (en) | 1929-07-10 | ||
| NL35808D NL35808C (en) | 1929-06-17 | ||
| DEB144608D DE736400C (en) | 1929-07-10 | 1929-07-10 | Wetting agents, foaming agents and dispersants |
| GB15478/30A GB358535A (en) | 1929-07-10 | 1930-05-20 | Improvements in or relating to wetting, penetrating, foaming and dispersing agents |
| FR38628D FR38628E (en) | 1928-09-07 | 1930-06-04 | Preparation of treatment liquids with high wetting and penetrating power |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB144608D DE736400C (en) | 1929-07-10 | 1929-07-10 | Wetting agents, foaming agents and dispersants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE736400C true DE736400C (en) | 1943-06-16 |
Family
ID=7000839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEB144608D Expired DE736400C (en) | 1928-09-07 | 1929-07-10 | Wetting agents, foaming agents and dispersants |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE736400C (en) |
| GB (1) | GB358535A (en) |
| NL (1) | NL31966C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3067053A (en) * | 1958-07-10 | 1962-12-04 | American Cyanamid Co | Pigment compositions |
-
0
- NL NL31966D patent/NL31966C/xx active
-
1929
- 1929-07-10 DE DEB144608D patent/DE736400C/en not_active Expired
-
1930
- 1930-05-20 GB GB15478/30A patent/GB358535A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL31966C (en) | |
| GB358535A (en) | 1931-09-21 |
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