DE734851C - Cutting fluid for the metal-cutting deformation of aluminum and its alloys - Google Patents

Cutting fluid for the metal-cutting deformation of aluminum and its alloys

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Publication number
DE734851C
DE734851C DEM141081D DEM0141081D DE734851C DE 734851 C DE734851 C DE 734851C DE M141081 D DEM141081 D DE M141081D DE M0141081 D DEM0141081 D DE M0141081D DE 734851 C DE734851 C DE 734851C
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Germany
Prior art keywords
cutting
aluminum
alloys
metal
deformation
Prior art date
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Expired
Application number
DEM141081D
Other languages
German (de)
Inventor
Friedrich Karl Frhr Goeler Dr
Dr-Ing Heinrich Faber
Dr-Ing Gerhard Rosesner
Dr-Ing Ludwig Schuster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
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Metallgesellschaft AG
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Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Priority to DEM141081D priority Critical patent/DE734851C/en
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Publication of DE734851C publication Critical patent/DE734851C/en
Expired legal-status Critical Current

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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F4/00Processes for removing metallic material from surfaces, not provided for in group C23F1/00 or C23F3/00
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/061Carbides; Hydrides; Nitrides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/063Peroxides
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/081Inorganic acids or salts thereof containing halogen
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/084Inorganic acids or salts thereof containing sulfur, selenium or tellurium
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/086Chromium oxides, acids or salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16Carbon dioxide
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18Ammonia
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2080/00Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)

Description

Schneidesüssigkeit für die spanabhebende Verformung von Aluminium und dessen Legierungen Gegenstand der Erfindung ist eigie Schneidflüssigkeit für Verfahren zur spanabhebenden Verformung von Aluminium und dessen Le= gierungen. Es hat sich nämlich gezeigt, daß man durch geeignete Wahl der Schneidflüssigkeit beim spanabhebenden Bearbeiten, wie Drehen und Bohren, von Aluminium oder dessen Legierungen überraschende Verbesserungen erzielen kann.Cutting fluid for the metal-cutting deformation of aluminum and its alloys. The subject of the invention is cutting fluid for Process for the metal-cutting deformation of aluminum and its alloys. It has been shown that by a suitable choice of the cutting fluid when machining, such as turning and drilling, of aluminum or its Alloys can achieve surprising improvements.

Versuche haben ergeben, daß als Schneidflüssigkeiten wäßrige alkalische Chromatlösungen, wie sie für die chemische Oberflächenbehandlung von '.Metallen verwendet werden, besonders gute Ergebnisse zeitigen. Diese Lösungen können, als solche oder in Gemischen mit Ölen angewandt werden.Tests have shown that aqueous alkaline cutting fluids are used Chromate solutions such as those used for the chemical surface treatment of metals used, produce particularly good results. These solutions can, as such or in mixtures with oils.

Die Vorteile, die mit solchen Schneidflüssigkeiten zu erzielen sind, sind mehrfacher Art.-Bei dem Verfahren gemäß Erfindung ist die Haltbarkeit des Werkzeuges verlängert, die Verbesserung der Schneidhaltigkeit hat eine bessere Maßhaltigkeit des Werkstückes zur Folge. Ein Nachschleifen des Stahles ist viel seltener nötig bei gleicher Güte des abgedrehten Werkstückes.The advantages that can be achieved with such cutting fluids are multiple art. In the method according to the invention, the durability of the tool extended, the improvement in edge retention has better dimensional accuracy of the workpiece. A regrinding of the steel is required much less often with the same quality of the machined workpiece.

Außerdem ist eine höhere Schnittgeschwindigkeit ohne Überbeanspruchung des Stahles möglich bzw. größerer Vorschub oder größere Spantiefe.In addition, a higher cutting speed is without overuse of the steel possible or greater feed rate or greater depth of cut.

Folgende Beispiele mögen die durch die Erfindung erzielten Vorteile dartun. Bearbeitet wurde ein Block aus einer Aluminium-Silicium-Legierung mit 13 % Silicium und o,3 0!o Magnesium, wobei als Drehstahl ein solcher aus gehärtetem Kohlenstoffstahl benutzt--wurde. Die Versuche wurden bei. Drehgeschwindigkeiten, die infolge- der Durchmesserabnahme zwischen 140 und 128m je Minute schwankten; durchgeführt. Der Vorschub betrug., o,25 nim je Umdrehung, die Spanti@fe 2 min. Die nachstehend angegebenen Drehlängen be-, zeichnen die Gesamtverschiebung des Sup- -ports während eines Versuches, also nicht die Spanlängen.The following examples like the advantages achieved by the invention to show. A block made of an aluminum-silicon alloy with 13 was machined % Silicon and o, 3 0! O magnesium, the turning steel being a hardened one Carbon steel used - was. The trials were at. Rotation speeds, which fluctuated between 140 and 128 m per minute as a result of the decrease in diameter; carried out. The advance was .0.25 nim per revolution, the Spanti @ fe 2 min. The turning lengths given below denote the total displacement of the Sup- -ports during an attempt, so not the chip lengths.

Zum Vergleich mit dem Verfahren der Erfindung wurden zwei Versuche mit dem üblichen Bohröl ausgeführt. Das erstemal versagte der Stahl nach 125 mm D,rehläng,e dadurch, daß sich ein Span an diefäshe4e angesetzt hatte; der Span wurde entfernt. Nach 5 mm versagte der Span schon wieder aus dem gleichen Grunde. Bei einem zweiten Versuch mußten bei 115, 18o, 235 und 265 mm Späne entfernt werden. Der Stahl lief jedoch jedesmal noch notdürftig. Im praktischen Betrieb hätte man ihn allerdings schon das erstemal geschliffen. Bei etwa 30o mm Drehlänge versagte er endgültig.For comparison with the method of the invention, two tests were carried out with the usual drilling oil. The first time the steel failed after a diameter of 125 mm, lengthwise, because a chip had attached itself to the barrel; the chip has been removed. After 5 mm, the chip failed again for the same reason. In a second attempt, chips had to be removed at 115, 18o, 235 and 265 mm. However, the steel still ran poorly every time. In practical operation, however, it would have been sharpened for the first time. At about 30o mm turning length it finally failed.

Diesen Beispielen gegenüber zeigt das folgende die gemäß Erfindung erzielten Vorteile Als Schneidflüssigkeit wurde eine wäßrige Lösung von 5 % calcinierter Soda und i, 5 0lo Natriumchromat in Wasser angewandt. Der Stahl lief ohne Schwierigkeiten i ioo mm lang. Die Späne liefen gut ab. Die bearbeitete Oberfläche war bei diesem Schmiermittel am glattesten. Dann wurde die Schneide allmählich stumpf. Bei - etwa i3oo mm zog die Maschine nicht mehr richtig durch, so daß man den Stahl hätte nachschleifen müssen. Immerhin wäre ein Weiterdrehen noch möglich gewesen.In contrast to these examples, the following shows those according to the invention Achieved advantages An aqueous solution of 5% calcined was used as the cutting fluid Soda and 1.5 0lo sodium chromate applied in water. The steel ran without difficulty ioo mm long. The chips ran off well. The machined surface was on this one Lubricants the smoothest. Then the edge gradually became blunt. At - about The machine no longer pulled through 300 mm so that the steel would have to be regrinded have to. At least it would have been possible to continue turning.

Während bei Bohröl die Schneide unregelmäßig abgenutzt war und die Schneidhaltigkeit anscheinend auch durch angeschweißte Aluminiumstückchen beeinträchtigt wurde, war bei dem Beispiel gemäß Erfindung zum _; Schluß des Versuches die Schneide ganz gleichmäßig abgenutzt, so daß sie gegen Ende 4es 'Versuches um einige Zehntelmillimeter tiefer und etwas vom Stück weg versetzt war. Sie war aber immer noch verhältnismäßig scharf und blank.While with drilling oil the cutting edge was worn irregularly and the Edge retention apparently also impaired by welded-on pieces of aluminum was, was in the example according to the invention to _; End of the attempt the cutting edge worn quite evenly, so that towards the end of the 4th attempt it was a few tenths of a millimeter was deeper and slightly offset from the piece. But it was still proportionate sharp and shiny.

Es können auch andere wäßrige alkalische Chromatlösungen verwendet werden, beispielsweise solche mit 15 g Natriumchromat und 5 g Ätznatron im Liter oder mit 15g Natriumchromat und 40 g Kaliumcarbonat im Liter.Other aqueous alkaline chromate solutions can also be used be, for example those with 15 g sodium chromate and 5 g caustic soda per liter or with 15g sodium chromate and 40 g potassium carbonate per liter.

Es ist schon vorgeschlagen worden, bei der Metallbearbeitung zur Kühlung und Schmierung wäßrige/ Sodalösu:ngen zu verwenden, und zwar ist dieses Mittel in erster Linie für die Bearbeitung von Eisen und Stahl vorgeschlagen. Diesem Bekannten gegenüber bringt die gemeinsame Venvendttng von Soda und Chromat eine überraschende Steigerung der Wirkung hinsichtlich der Schneiderleichterung.It has already been proposed in metalworking for cooling and lubrication aqueous / soda solutions to use, namely this agent is in suggested primarily for working iron and steel. This friend on the other hand, the joint use of soda and chromate is surprising Increasing the effect in terms of making it easier to cut.

Claims (2)

PATEVTADISPRLCHR: i. Verwendung von wäßrigen alkalischen Chromatlösungen, wie sie für chemische Oberflächenbehandlung von Al:etallen bekanntgeworden sind, gegebenenfalls in Mischung mit ölen, als Schneidflüssigkeit bei der spanabhebenden Verformung c-on Aluminium und dessen Legierungen. PATEVTADISPRLCHR: i. Use of aqueous alkaline chromate solutions, as they have become known for chemical surface treatment of Al: metals, possibly in a mixture with oils, as cutting fluid for machining Deformation of c-on aluminum and its alloys. 2. Verwendung einer Lösung nach Anspruch i zu dem in Anspruch i genannten Zweck, gekennzeichnet durch folgende Zusammensetzung: 50'() calcinierte Soda, i,5 % Natritunchromat in wäßriger Lösung.2. Use a solution after Claim i for the purpose stated in claim i, characterized by the following composition: 50 '() calcined soda, 1.5% sodium chromate in aqueous solution.
DEM141081D 1938-03-04 1938-03-19 Cutting fluid for the metal-cutting deformation of aluminum and its alloys Expired DE734851C (en)

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DEM141081D DE734851C (en) 1938-03-04 1938-03-19 Cutting fluid for the metal-cutting deformation of aluminum and its alloys

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DE525655X 1938-03-04
DEM141081D DE734851C (en) 1938-03-04 1938-03-19 Cutting fluid for the metal-cutting deformation of aluminum and its alloys

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1257335B (en) * 1960-11-23 1967-12-28 United States Steel Corp Aqueous lubricating oil emulsion for cold rolling of sheet metal

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1257335B (en) * 1960-11-23 1967-12-28 United States Steel Corp Aqueous lubricating oil emulsion for cold rolling of sheet metal

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