DE707966C - Process for applying a corrosion-proof metal coating to the inside of a steel pipe - Google Patents

Process for applying a corrosion-proof metal coating to the inside of a steel pipe

Info

Publication number
DE707966C
DE707966C DEB173011D DEB0173011D DE707966C DE 707966 C DE707966 C DE 707966C DE B173011 D DEB173011 D DE B173011D DE B0173011 D DEB0173011 D DE B0173011D DE 707966 C DE707966 C DE 707966C
Authority
DE
Germany
Prior art keywords
steel pipe
corrosion
applying
metal coating
proof metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB173011D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DEB173011D priority Critical patent/DE707966C/en
Application granted granted Critical
Publication of DE707966C publication Critical patent/DE707966C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • C23C24/103Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
    • C23C24/106Coating with metal alloys or metal elements only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Description

Verfahren zum Aufbringen eines korrosionssicheren Metallüberzuges auf die Innenwände eines Stahlrohres Bisher hat man Stahlrohre im Schmelzofen dadurch mit einer dünnen korrosionsbeständigen Metallschicht, z. B. Kupfer, überzogen, daß man als Flußmittel Borax in pulverisierter Farm, allenfalls in Wasser angerührt, verwendete. Die Wirkung dieses Flußmittels in dieser Form hat sich aber für diesen Zweck als unvollkommen herausgestellt. Der geschmolzene Borax ballt sich an den Rohrwandungen in kleinerem oder größerem Maße zusammen, entzieht dadurch an diesen Stellen größere Wärmemengen, so daß der zu schmelzende Kupferüberzug auf seiner Oberfläche rauh und porig wird. Die Folge dieses ungleichmäßigen Überzuges macht sich besonders in der Nachbearbeitung geltend. Wenn das Rohr auf dünneren Durchmesser gezogen wird, reißen die Rohre an diesen Stellen ab, und es entsteht ein unverwertbarer-Ausschuß.Process for applying a corrosion-resistant metal coating on the inner walls of a steel pipe So far, steel pipes have been used in the melting furnace with a thin corrosion-resistant metal layer, e.g. B. Copper, plated that borax is used as a flux in a powdered farm, possibly mixed in water, used. The effect of this flux in this form has proven itself for this one Purpose turned out to be imperfect. The melted borax clumps on the Pipe walls together to a lesser or greater extent, thereby withdrawing from them Provide greater amounts of heat so that the copper coating to be melted is on its Surface becomes rough and porous. The consequence of this uneven coating makes especially in post-processing. When the pipe is on thinner diameter is pulled, the pipes tear off at these points, and there is an unusable scrap.

Die Verwendung von Borsäure, gegebenenfalls unter Zusatz von Kieselsäure, als Flußmittel ist bereits bei der Herstellung eines korrosionssicheren Stahlrohres bekannt. Es ist auch schon für diese Herstellung vorgeschlagen worden, das Überzugsmetall und das feste Flußmittel in .dem zu überziehenden Rohr zu erhitzen, das an einem Ende völlig verschlossen ist, während das andere Ende eine kleine Öffnung behält, und die Gase oder die heiße Luft entweichen zu lassen. _ Erfindungsgemäß wird dieses Flußmittel in flüssigen Zustand gebracht, und diese Flüssigkeit wird in das Stahlrohr eingeträufelt oder eingespritzt oder eingeblasen oder sonstwie hineingebracht. Das Stahlrohr wird sodann an beiden Enden fest verschlossen. Am einfachsten geschieht es durch Zuschlagen der Enden. Wird das so verschlossene Stahlrohr in den Schmelzofen eingebracht, so verdampft oder vergast die flüssige Borsäure im Innern unter der Einwirkung der Schmelzwärme allmählich bis zur vollständigen Gasbildung. Der gasförmige Zustand der Borsäure stellt ihre Auflösung, in die feinsten Teilchen dar und bewirkt eine ganz gleichmäßige Verteilung derselben über die ganze Innenwand des Rohres, so daß zwischen Stahlrohrwand und Schmelzmaterial, unter Zuführung des gasförmigen Flußmittels, eine innige metallische Berührung stattfindet. Unterstützt wird der Vorgang durch den hohen Druck, unter den die Borsäure durch die Vergasung getreten ist. Um diesen Druck hervorzurufen und die Vergasung durchzuführen, ist das Rohr, wie gesagt, an beiden Enden .dicht abgeschlossen worden.The use of boric acid, optionally with the addition of silica, as a flux is already used in the manufacture of a corrosion-proof steel pipe known. It has already been proposed for this production, the coating metal and to heat the solid flux in .the pipe to be coated, which is attached to a End is completely closed, while the other end retains a small opening, and let the gases or hot air escape. _ According to the invention, this Flux is brought into a liquid state, and this liquid is poured into the steel pipe instilled or injected or blown in or otherwise brought into it. That Steel pipe is then tightly closed at both ends. The easiest way to do this it by slamming the ends. The steel pipe thus sealed is put into the melting furnace introduced, so the liquid boric acid evaporates or gasifies inside under the Effect of the heat of fusion gradually until gas is completely formed. The gaseous one The state of boric acid represents and causes its dissolution into the finest particles a very even distribution of the same over the entire inner wall of the pipe, so that between the steel pipe wall and the melting material, with the supply of the gaseous Flux, an intimate metallic contact takes place. The Process due to the high pressure under which the boric acid has entered through the gasification is. In order to create this pressure and to carry out the gasification, the pipe, as I said, sealed at both ends.

In der Zeichnung ist ein Schema des Rohres dargestellt.In the drawing a scheme of the pipe is shown.

d bezeichnet die Stahlrohrwand, b einen Metalldraht oder einen Metallblechstreifen, der in festem Zustand in das Stahlrohr eingeführt ist. In das Innere des Rohres ist Borsäure, mit Kieselsäure vermischt, in flüssigem Zustand eingebracht. An den beiden Ende' und d ist das Stahlrohr durch Zuschlä verschlossen. Der Metalldraht b kann bis: diesen beiden Enden reichen. Ist das Sta " rohr in den Schmelzofen eingeführt, so beginnt das Metall unter dem Einfluß der Hitze zu zerfließen, so daß es die ganze Innenwand des Stahlrohres benetzt. Die Borsäure vergast, wodurch im Rohr ein erheblicher Druck entsteht. Das Flußmittel wird daher durch die Gasform und durch den Einfluß dieses Druckes die Wand des Stahlrohres in hoher Gleichmäßigkea hauchartig überziehen, so daß das Schmelzmetall selbst überall mit der Stahlrohrwand gleichmäßig die Verbindung des Stahlrohres mit dem Schmelzmetall herstellt.d denotes the tubular steel wall, b a metal wire or sheet metal strip, the is inserted into the steel pipe in a solid state. Inside the tube is Boric acid, mixed with silica, introduced in a liquid state. On both of them At the end of 'and d, the steel tube is closed by means of an addition. The metal wire b can until: these two ends are enough. Once the tube has been inserted into the furnace, so the metal begins to flow under the influence of the heat, so that it is the whole The inner wall of the steel pipe is wetted. The boric acid is gasified, causing a considerable amount in the pipe Pressure arises. The flux is therefore by the gaseous form and by the influence this pressure cover the wall of the steel pipe with a high degree of uniformity, so that the molten metal itself is evenly connected to the steel pipe wall everywhere of the steel pipe with the molten metal.

Claims (1)

PATENTANSPRUCH: Verfahren zum Aufbringen eines korrosionssicheren Metallüberzuges auf die Innenwände eines Stahlrohres durch Aufschmelzen in Gegenwart von Flußmitteln, dadurch gekennzeichnet, daß als Flußmittel Borsäure, gegebenenfalls in Mischung mit Kieselsäure, verwendet wird, die in das Rohr in flüssigem Zustand eingeführt wird, während dasÜberzugsmetall in festem Zustand eingebracht wird, und daß das Rohr während des Aufschmelzens fest verschlossen ist.PATENT CLAIM: Method for applying a corrosion-proof Metal coating on the inner walls of a steel pipe by melting in the presence of fluxes, characterized in that boric acid, optionally in mixture with silica, which is used in the tube in liquid state is introduced while the clad metal is being introduced in a solid state, and that the tube is tightly closed during melting.
DEB173011D 1936-02-18 1936-02-18 Process for applying a corrosion-proof metal coating to the inside of a steel pipe Expired DE707966C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB173011D DE707966C (en) 1936-02-18 1936-02-18 Process for applying a corrosion-proof metal coating to the inside of a steel pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB173011D DE707966C (en) 1936-02-18 1936-02-18 Process for applying a corrosion-proof metal coating to the inside of a steel pipe

Publications (1)

Publication Number Publication Date
DE707966C true DE707966C (en) 1941-07-09

Family

ID=7007150

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB173011D Expired DE707966C (en) 1936-02-18 1936-02-18 Process for applying a corrosion-proof metal coating to the inside of a steel pipe

Country Status (1)

Country Link
DE (1) DE707966C (en)

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