DE70793C - Process for printing tar paints on aniline black ground - Google Patents
Process for printing tar paints on aniline black groundInfo
- Publication number
- DE70793C DE70793C DENDAT70793D DE70793DA DE70793C DE 70793 C DE70793 C DE 70793C DE NDAT70793 D DENDAT70793 D DE NDAT70793D DE 70793D A DE70793D A DE 70793DA DE 70793 C DE70793 C DE 70793C
- Authority
- DE
- Germany
- Prior art keywords
- aniline black
- printing
- tar
- black ground
- aniline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000767 polyaniline Polymers 0.000 title claims description 11
- 238000000034 method Methods 0.000 title description 3
- 239000003973 paint Substances 0.000 title 1
- 239000004744 fabric Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 4
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 claims description 3
- 229920001864 tannin Polymers 0.000 claims description 3
- 235000018553 tannin Nutrition 0.000 claims description 3
- 239000001648 tannin Substances 0.000 claims description 3
- WBTCZEPSIIFINA-UHFFFAOYSA-J Antimony potassium tartrate Chemical compound O.O.O.[K+].[K+].O1C(=O)C2O[Sb-]1(OC1=O)OC1C(C(=O)O1)O[Sb-]31OC(=O)C2O3 WBTCZEPSIIFINA-UHFFFAOYSA-J 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 238000005755 formation reaction Methods 0.000 claims 1
- 239000000976 ink Substances 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- CXKWCBBOMKCUKX-UHFFFAOYSA-M Methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 2
- 229940042115 Methylene blue Drugs 0.000 description 2
- BDKZHNJTLHOSDW-UHFFFAOYSA-N [Na].CC(O)=O Chemical compound [Na].CC(O)=O BDKZHNJTLHOSDW-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- MMCPOSDMTGQNKG-UHFFFAOYSA-N Anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 240000007119 Malus pumila Species 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 240000003152 Rhus chinensis Species 0.000 description 1
- 235000014220 Rhus chinensis Nutrition 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- OCPOWIWGGAATRP-UHFFFAOYSA-N potassium hexacyanoferrate(4-) Chemical compound [K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N OCPOWIWGGAATRP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
. Gemäfs vorliegender Erfindung wird das Tuch oder sonstige Gewebe zuerst mit einer Lösung von Tannin oder Abkochungen von Sumach, Galläpfeln oder dergleichen geklotzt und sodann mit Brechweinstein oder anderen, Antimon oder Zinn enthaltenden Salzen nach dem schon bekannten Beizverfahren behandelt. Zunächst wird das Tuch gewaschen, getrocknet und mit einer Mischung von Änilinöl oder Anilinsalz mit anderen zweckentsprechenden Stoffen, welche sich zur Herstellung von Anilinschwarz eignen, geklotzt. . According to the present invention, the cloth or other fabric is first with a Solution of tannin or decoctions of sumac, gall apples or the like padded and then with tartar or other salts containing antimony or tin treated with the well-known pickling process. First the cloth is washed and dried and with a mixture of aniline oil or aniline salt with other suitable ones Fabrics that are suitable for the production of aniline black are padded.
Ehe man nun das Anilinschwarz durch Dämpfen oder längeres Aufhängen entwickelt, erfolgt ein Musterdruck durch Aufdrucken einer mit essigsaurem Natrium oder anderen geeigneten Stoffen verdickten Färbereserve, welche die Entwickelung des Anilinschwarz auf den gedruckten Stellen verhindert.Before developing the aniline black by steaming or hanging it up for a long time, a pattern printing is carried out by printing one with sodium acetic acid or other suitable one Substances thickened dye reserve, which the development of the aniline black on the printed areas prevented.
"Wird nun das Anilinschwarz auf den nicht gedruckten Stellen durch Dämpfen oder Aufhängen entwickelt, so werden auch gleichzeitig die gefärbten Theile durch die Beize fixirt."Now the aniline black on the unprinted areas by steaming or hanging developed, the colored parts are also fixed by the stain at the same time.
Die oben beschriebenen Verfahren sind im Einzelnen nicht neu, aber durch ihre Combination in obiger Weise werden die allerfeinsten Musterungen, welche sonst nur schwierig erzielt werden können, möglich.The procedures described above are in Individuals are not new, but through their combination in the above manner the very finest become Patterns that are otherwise difficult to achieve are possible.
Um' z. B. auf einem mit Anilinschwarz grundirten Tuch eine blaue Musterung zu entwickeln, wird das Tuch nach der neuen Erfindung in folgender Weise behandelt. Zuerst wird das Tuch durch eine Lösung, bei welcher auf 4 1 Wasser ca. 30 g Tannin kommen, hindurchgezogen, sodann getrocknet und darauf in eine andere Lösung von ca. 30 g Brechweinstein auf je 4 1 Wasser · gebracht, ausgewaschen und abermals getrocknet. Darauf wird das Tuch mit einer Lösung, welche im Folgenden angegeben ist, geklotzt.To 'z. B. to develop a blue pattern on a cloth primed with aniline black, the cloth is treated according to the new invention in the following way. First, the cloth is through a solution in which add approx. 30 g of tannin to 4 liters of water, pulled through, then dried and on top placed in another solution of approx. 30 g of tartar emetic to 4 liters of water, washed out and dried again. The cloth is then padded with a solution, which is specified below.
3 kg chlorsaures Kali werden in 24 1 heifsem Wasser und 7,5 kg Ferrocyankalium in der gleichen Menge heifsen Wassers gelöst. Nachdem die zwei Lösungen abgekühlt sind, werden sie zusammengemischt und man setzt noch 6 1 Änilinöl und 6 1 Salzsäure (von 3 2 ° Twaddle = 19,8 Baume = spec. Gew. 1,160), welche schon gemischt, und gekühlt sind, zu. Dies bildet die Normalmischung. Vor dem Gebrauch wird für jede 4 1 dieser Mischung ein Zusatz von 60 g Salzsäure gemacht.3 kg of potassium chlorate are in 24 liters of hot water and 7.5 kg of potassium ferrocyanide in the dissolved in the same amount of hot water. After the two solutions have cooled, be mix them together and add 6 liters of aniline oil and 6 liters of hydrochloric acid (from 3 2 ° Twaddle = 19.8 trees = spec. Weight 1,160), which already mixed, and chilled, too. This forms the normal mix. Before use an addition of 60 g of hydrochloric acid is made for every 4 liters of this mixture.
Das mit dieser Mischung geklotzte Tuch wird sodann getrocknet und mit einer Reserve bedruckt, - bestehend aus etwa 60 g Methylenblau oder einer anderen geeigneten Farbe, in 0,25 1 Weingeist und 0,25 1 heifsem Wasser gelöst, dazu eine Verdickung aus etwa 140 g essigsaurem Natrium und 80 g Dextrin (britisches Gummi), welche zu je 0,25 1 zugesetzt werden.The cloth padded with this mixture is then dried and with a reserve printed, - consisting of about 60 g of methylene blue or another suitable color, in 0.25 l of alcohol and 0.25 l of hot water dissolved, plus a thickening of about 140 g sodium acetic acid and 80 g of dextrin (British gum), which are added at 0.25 l each.
Zuletzt wird das Tuch in der Dampfkammer aufgehängt, wobei das Anilinschwarz entwickelt und zugleich die methylenblaue Musterung fixirt wird.Lastly, the cloth is in the steam chamber hung up, whereby the aniline black develops and at the same time the methylene blue pattern is fixed.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE70793C true DE70793C (en) |
Family
ID=344147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT70793D Expired - Lifetime DE70793C (en) | Process for printing tar paints on aniline black ground |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE70793C (en) |
-
0
- DE DENDAT70793D patent/DE70793C/en not_active Expired - Lifetime
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