DE69812417D1 - Barium-ausgetauschte ets-4 und ihre verwendung zur trennung einer mischung enthaltend stickstoff und methan - Google Patents

Barium-ausgetauschte ets-4 und ihre verwendung zur trennung einer mischung enthaltend stickstoff und methan

Info

Publication number
DE69812417D1
DE69812417D1 DE69812417T DE69812417T DE69812417D1 DE 69812417 D1 DE69812417 D1 DE 69812417D1 DE 69812417 T DE69812417 T DE 69812417T DE 69812417 T DE69812417 T DE 69812417T DE 69812417 D1 DE69812417 D1 DE 69812417D1
Authority
DE
Germany
Prior art keywords
methane
barium
separating
mixture containing
containing nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69812417T
Other languages
English (en)
Other versions
DE69812417T2 (de
Inventor
M Kuznicki
A Behl
Ivan Petrovic
W Blosser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Catalysts LLC
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engelhard Corp filed Critical Engelhard Corp
Application granted granted Critical
Publication of DE69812417D1 publication Critical patent/DE69812417D1/de
Publication of DE69812417T2 publication Critical patent/DE69812417T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28047—Gels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Catalysts (AREA)
DE69812417T 1997-12-22 1998-12-08 Barium-ausgetauschte ets-4 und ihre verwendung zur trennung einer mischung enthaltend stickstoff und methan Expired - Fee Related DE69812417T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/996,298 US5989316A (en) 1997-12-22 1997-12-22 Separation of nitrogen from mixtures thereof with methane utilizing barium exchanged ETS-4
PCT/US1998/025995 WO1999032222A1 (en) 1997-12-22 1998-12-08 Barium exchanged ets-4 and its use in a process for the separation of nitrogen from mixtures thereof with methane

Publications (2)

Publication Number Publication Date
DE69812417D1 true DE69812417D1 (de) 2003-04-24
DE69812417T2 DE69812417T2 (de) 2003-12-24

Family

ID=25542741

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69812417T Expired - Fee Related DE69812417T2 (de) 1997-12-22 1998-12-08 Barium-ausgetauschte ets-4 und ihre verwendung zur trennung einer mischung enthaltend stickstoff und methan

Country Status (8)

Country Link
US (1) US5989316A (de)
EP (1) EP1042065B1 (de)
JP (1) JP2001526109A (de)
AT (1) ATE234677T1 (de)
AU (1) AU1808099A (de)
DE (1) DE69812417T2 (de)
DK (1) DK1042065T3 (de)
WO (1) WO1999032222A1 (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2781693B1 (fr) * 1998-07-31 2000-09-08 Inst Francais Du Petrole Procede et installation de traitement d'un gaz naturel a fortes teneurs en co2 et n2 avec recyclage
US6197092B1 (en) * 1999-03-22 2001-03-06 Engelhard Corporation Selective removal of nitrogen from natural gas by pressure swing adsorption
US6464957B1 (en) * 2000-08-16 2002-10-15 Engelhard Corporation Polymorph-enriched ETS-4
US6486086B1 (en) 2000-09-15 2002-11-26 Engelhard Corporation Simplified methods of manufacturing titanium silicate membranes
US6340433B1 (en) 2000-09-15 2002-01-22 Engelhard Corporation Water purification using titanium silicate membranes
US6395067B1 (en) 2000-09-15 2002-05-28 Engelhard Corporation Geometric separation processes involving modified CTS membranes
US6444012B1 (en) 2000-10-30 2002-09-03 Engelhard Corporation Selective removal of nitrogen from natural gas by pressure swing adsorption
US6497750B2 (en) 2001-02-26 2002-12-24 Engelhard Corporation Pressure swing adsorption process
US6517611B1 (en) 2001-07-23 2003-02-11 Engelhard Corporation Olefin separations employing CTS molecular sieves
US6610124B1 (en) 2002-03-12 2003-08-26 Engelhard Corporation Heavy hydrocarbon recovery from pressure swing adsorption unit tail gas
US6631626B1 (en) 2002-08-12 2003-10-14 Conocophillips Company Natural gas liquefaction with improved nitrogen removal
WO2005032693A2 (en) * 2003-08-29 2005-04-14 Velocys Inc. Process for separating nitrogen from methane using microchannel process technology
US20060191410A1 (en) * 2005-02-28 2006-08-31 Dolan William B NGL trap-method for recovery of heavy hydrocarbon from natural gas
WO2006094190A2 (en) * 2005-03-02 2006-09-08 Velocys Inc. Separation process using microchannel technology
US20070068386A1 (en) * 2005-09-23 2007-03-29 Mitariten Michael J Landfill gas upgrading process
US20070243129A1 (en) * 2006-03-16 2007-10-18 Bell Valerie A Exchange cation selection in ETS-4 to control adsorption strength and effective pore diameter
US20100269694A1 (en) * 2006-06-28 2010-10-28 The Governors Of The University Of Alberta Silicate Materials, Method For Their Manufacture, And Method For Using Such Silicate Materials For Adsorptive Fluid Separations
CA2618267C (en) * 2008-01-21 2016-04-05 The Governors Of The University Of Alberta Modified ets-10 zeolites for olefin separation
CA2657127C (en) 2009-03-05 2016-07-05 The Governors Of The University Of Alberta Removal of carbon dioxide from paraffins
US8221524B2 (en) * 2009-10-23 2012-07-17 Guild Associates, Inc. Oxygen removal from contaminated gases
KR101728809B1 (ko) 2014-09-25 2017-04-21 한국화학연구원 질소 선택적 흡착능을 갖는 유무기 하이브리드 나노세공체 및 이를 이용한 질소 함유 혼합기체의 분리 방법
CN107206330B (zh) 2015-01-30 2021-04-16 日本碍子株式会社 分离膜结构体及降低氮浓度的方法
JP6670764B2 (ja) 2015-01-30 2020-03-25 日本碍子株式会社 分離膜構造体
WO2016121887A1 (ja) * 2015-01-30 2016-08-04 日本碍子株式会社 分離膜構造体
WO2018026516A1 (en) 2016-08-04 2018-02-08 Exxonmobil Research And Engineering Company High purity nitrogen/hydrogen production from an exhaust stream
WO2018026518A1 (en) 2016-08-04 2018-02-08 Exxonmobil Research And Engineering Company High temperature pressure swing adsorption for advanced sorption enhanced water gas shift
WO2019191436A1 (en) 2018-03-29 2019-10-03 Praxair Technology, Inc. Characteristics of tunable adsorbents for rate selective separation of nitrogen from methane
MX2020013556A (es) 2018-06-14 2021-05-27 Sysadvance Sist De Engenharia S A Proceso de psa de varias etapas para eliminar gases contaminantes de corrientes de metano sin procesar.
CN110773120B (zh) * 2019-11-08 2021-05-07 四川大学 金属盐改性分子筛及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4938939A (en) * 1987-09-08 1990-07-03 Engelhard Corporation Preparation of small-pored crystalline titanium molecular sieve zeolites
US4853202A (en) * 1987-09-08 1989-08-01 Engelhard Corporation Large-pored crystalline titanium molecular sieve zeolites
US4964889A (en) * 1989-12-04 1990-10-23 Uop Selective adsorption on magnesium-containing clinoptilolites
KR930701219A (ko) * 1991-06-21 1993-06-11 스티븐 아이. 밀러 순환식 건조법에 있어서 하전된 8면체 부위를 함유하는 결정성 분자체의 용도
US5346535A (en) * 1991-08-23 1994-09-13 Engelhard Corporation Use of crystalline molecular sieves containing charged octahedral sites in removing volatile organic compounds from a mixture of the same
US5453263A (en) * 1994-05-24 1995-09-26 Engelhard Corporation Halide-free process for the synthesis of ETS-10
US5616170A (en) * 1995-08-11 1997-04-01 The Boc Group, Inc. Adsorptive separation of nitrogen from other gases
US5669958A (en) * 1996-02-29 1997-09-23 Membrane Technology And Research, Inc. Methane/nitrogen separation process

Also Published As

Publication number Publication date
DK1042065T3 (da) 2003-07-07
DE69812417T2 (de) 2003-12-24
JP2001526109A (ja) 2001-12-18
AU1808099A (en) 1999-07-12
WO1999032222A1 (en) 1999-07-01
EP1042065B1 (de) 2003-03-19
ATE234677T1 (de) 2003-04-15
EP1042065A1 (de) 2000-10-11
US5989316A (en) 1999-11-23

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee