DE69732606D1 - Herstellung von Äthylen/Buten Copolymeren mit einem einzigen Metallocen-Katalysator und einem einzigen Monomer - Google Patents

Herstellung von Äthylen/Buten Copolymeren mit einem einzigen Metallocen-Katalysator und einem einzigen Monomer

Info

Publication number
DE69732606D1
DE69732606D1 DE69732606T DE69732606T DE69732606D1 DE 69732606 D1 DE69732606 D1 DE 69732606D1 DE 69732606 T DE69732606 T DE 69732606T DE 69732606 T DE69732606 T DE 69732606T DE 69732606 D1 DE69732606 D1 DE 69732606D1
Authority
DE
Germany
Prior art keywords
ethylene
metallocene catalyst
preparation
butene copolymers
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69732606T
Other languages
English (en)
Other versions
DE69732606T2 (de
Inventor
Baireddy Raghava Reddy
Edwar S Shamshoum
Margarito Lopez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Application granted granted Critical
Publication of DE69732606D1 publication Critical patent/DE69732606D1/de
Publication of DE69732606T2 publication Critical patent/DE69732606T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69732606T 1996-12-16 1997-12-16 Herstellung von Äthylen/Buten Copolymeren mit einem einzigen Metallocen-Katalysator und einem einzigen Monomer Expired - Fee Related DE69732606T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/766,075 US5753785A (en) 1996-12-16 1996-12-16 Production of E-B copolymers with a single metallocene catalyst and a single monomer
US766075 1996-12-16

Publications (2)

Publication Number Publication Date
DE69732606D1 true DE69732606D1 (de) 2005-04-07
DE69732606T2 DE69732606T2 (de) 2006-03-16

Family

ID=25075332

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69732606T Expired - Fee Related DE69732606T2 (de) 1996-12-16 1997-12-16 Herstellung von Äthylen/Buten Copolymeren mit einem einzigen Metallocen-Katalysator und einem einzigen Monomer

Country Status (9)

Country Link
US (1) US5753785A (de)
EP (1) EP0848022B1 (de)
JP (1) JPH10182717A (de)
KR (1) KR19980064189A (de)
CN (1) CN1222546C (de)
AT (1) ATE290025T1 (de)
DE (1) DE69732606T2 (de)
ES (1) ES2238710T3 (de)
TW (1) TW363067B (de)

Families Citing this family (34)

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US6153716A (en) * 1994-06-01 2000-11-28 Phillips Petroleum Company Polyethylenes containing a unique distribution of short chain branching
WO1998009995A1 (en) * 1996-09-04 1998-03-12 The Dow Chemical Company Incorporation of free radical inhibitors in polyolefins
US6214761B1 (en) 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6423848B2 (en) 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
US6417305B2 (en) 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
US6432862B1 (en) 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6114483A (en) * 1997-08-27 2000-09-05 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6297338B1 (en) 1998-03-30 2001-10-02 E. I. Du Pont De Nemours And Company Polymerization of olefins
US7906451B2 (en) * 1998-03-30 2011-03-15 E.I. Du Pont De Nemours And Company Mixed polymerization catalyst component for polymerizing olefins
EP0953582A1 (de) * 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
US6329312B1 (en) 1998-06-19 2001-12-11 Phillips Petroleum Company Metallocycle metallocenes and their use
US6221981B1 (en) 1998-09-14 2001-04-24 Phillips Petroleum Company Method for making and using a supported metallcene catalyst system
EP0989141A1 (de) * 1998-09-25 2000-03-29 Fina Research S.A. Herstellung von multimodalem Polyäthylen
US6187880B1 (en) 1999-02-16 2001-02-13 Phillips Petroleum Company Process for producing an olefin polymer using a metallocene
US6620895B1 (en) 1999-03-22 2003-09-16 E. I. Du Pont De Nemours And Company Processing polyethylenes
US6291382B1 (en) 1999-05-24 2001-09-18 Phillips Petroleum Company Metallocenes, polymerization catalyst systems, their preparation, and use
CN1377377A (zh) 1999-09-29 2002-10-30 纳幕尔杜邦公司 聚乙烯的制备
WO2001023445A1 (en) * 1999-09-29 2001-04-05 E.I. Du Pont De Nemours And Company Preparation of curable polymers
US6407188B1 (en) 1999-09-29 2002-06-18 E. I. Du Pont De Nemours And Company Polymerization of olefins
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
KR100786742B1 (ko) * 1999-10-08 2007-12-18 미쓰이 가가쿠 가부시키가이샤 폴리올레핀
US6586541B2 (en) 2000-02-02 2003-07-01 E. I. Du Pont De Nemours And Company Process for production of polyolefins
DE10035091A1 (de) * 2000-07-17 2002-01-31 Bayer Ag Verfahren zur Herstellung von EP(D)M
US6451933B1 (en) 2000-11-16 2002-09-17 Equistar Chemicals, Lp Bimetallic olefin polymerization catalysts
JP5205726B2 (ja) * 2006-08-22 2013-06-05 東ソー株式会社 遷移金属化合物、オレフィン重合用触媒、およびポリオレフィンの製造方法
TW200932762A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
EP2196481A1 (de) * 2008-12-12 2010-06-16 Total Petrochemicals Research Feluy Herstellung von langkettigem, verzweigtem, isotaktischem Polypropylen
JP5749718B2 (ja) 2009-08-17 2015-07-15 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ オレフィン重合法の改善
EP2552973A1 (de) 2010-03-29 2013-02-06 E.I. Du Pont De Nemours And Company Verbessertes olefinpolymerisationsverfahren
EP4276180A3 (de) 2012-01-12 2024-01-10 Endo Global Ventures Clostridium histolyticum enzym
KR101549206B1 (ko) 2012-05-08 2015-09-02 주식회사 엘지화학 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법
US11123280B2 (en) 2017-03-01 2021-09-21 Endo Ventures Limited Method of assessing and treating cellulite
MX2019011574A (es) 2017-03-28 2019-12-19 Endo Ventures Ltd Método mejorado para producir aplicaciones relacionadas con la colagenasa.
KR102292947B1 (ko) 2017-05-10 2021-08-25 유니베이션 테크놀로지즈, 엘엘씨 촉매계 및 이의 사용 방법

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4861846A (en) * 1985-03-22 1989-08-29 Union Carbidae Corporation Process for simultaneously dimerizing ethylene and copolymerizing ethylene with the dimerized product
US5321107A (en) * 1989-01-31 1994-06-14 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
US5137994A (en) * 1991-05-23 1992-08-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the simultaneous trimerization and copolymerization of ethylene
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
DE69224463T2 (de) * 1991-11-28 1998-07-09 Showa Denko Kk Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
US6114480A (en) * 1996-04-19 2000-09-05 Fina Technology, Inc. Process and catalyst for producing polyolefins having low molecular weight

Also Published As

Publication number Publication date
DE69732606T2 (de) 2006-03-16
US5753785A (en) 1998-05-19
CN1222546C (zh) 2005-10-12
EP0848022A1 (de) 1998-06-17
ATE290025T1 (de) 2005-03-15
TW363067B (en) 1999-07-01
EP0848022B1 (de) 2005-03-02
KR19980064189A (ko) 1998-10-07
JPH10182717A (ja) 1998-07-07
ES2238710T3 (es) 2005-09-01
CN1191224A (zh) 1998-08-26

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