DE69718878D1 - Ruthenium-optisch-aktiver Phosphin-Komplex, Verfahren zur Herstellung und Verfahren zur Herstellung von optisch-aktiven 4-Methyl-2-Oxetanon unter Verwendung derselben - Google Patents
Ruthenium-optisch-aktiver Phosphin-Komplex, Verfahren zur Herstellung und Verfahren zur Herstellung von optisch-aktiven 4-Methyl-2-Oxetanon unter Verwendung derselbenInfo
- Publication number
- DE69718878D1 DE69718878D1 DE69718878T DE69718878T DE69718878D1 DE 69718878 D1 DE69718878 D1 DE 69718878D1 DE 69718878 T DE69718878 T DE 69718878T DE 69718878 T DE69718878 T DE 69718878T DE 69718878 D1 DE69718878 D1 DE 69718878D1
- Authority
- DE
- Germany
- Prior art keywords
- optically active
- producing
- oxetanone
- ruthenium
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title 1
- GSCLMSFRWBPUSK-UHFFFAOYSA-N beta-Butyrolactone Chemical compound CC1CC(=O)O1 GSCLMSFRWBPUSK-UHFFFAOYSA-N 0.000 title 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31121196A JP3919268B2 (ja) | 1996-11-08 | 1996-11-08 | ルテニウム−光学活性ホスフィン錯体、その製法およびこれを用いた光学活性4−メチル−2−オキセタノンの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69718878D1 true DE69718878D1 (de) | 2003-03-13 |
DE69718878T2 DE69718878T2 (de) | 2003-06-18 |
Family
ID=18014447
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69718878T Expired - Fee Related DE69718878T2 (de) | 1996-11-08 | 1997-11-05 | Ruthenium-optisch-aktiver Phosphin-Komplex, Verfahren zur Herstellung und Verfahren zur Herstellung von optisch-aktiven 4-Methyl-2-Oxetanon unter Verwendung derselben |
Country Status (4)
Country | Link |
---|---|
US (2) | US5981782A (de) |
EP (1) | EP0841343B1 (de) |
JP (1) | JP3919268B2 (de) |
DE (1) | DE69718878T2 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080214787A1 (en) * | 1992-03-11 | 2008-09-04 | Jan Zavada | MN Gene and Protein |
DE69933904T2 (de) * | 1998-05-08 | 2007-09-06 | Takasago International Corp. | Ruthenium-iodo optisch aktiver Phosphinkomplex |
US7348290B2 (en) * | 2002-03-11 | 2008-03-25 | Japan Science And Technology Agency | Arene-ruthenium complexes immobilized on polymers, catalysts consisting of the complexes, and processes for organic syntheses with the same |
US7728153B2 (en) * | 2002-04-17 | 2010-06-01 | The Burnham Institute For Medical Research | Method for the asymmetric synthesis of beta-lactone compounds |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5202474A (en) * | 1989-06-22 | 1993-04-13 | Monsanto Company | Asymmetric catalytic hydrogenation of α-arylpropenoic acids |
US5412109A (en) * | 1992-07-16 | 1995-05-02 | Takasago International Corporation | Process for preparing optically active 4-methyl-2-oxetanone |
JP3310056B2 (ja) * | 1992-07-16 | 2002-07-29 | 高砂香料工業株式会社 | 光学活性4−メチル−2−オキセタノンの製造方法 |
JP3437623B2 (ja) * | 1994-01-12 | 2003-08-18 | 高砂香料工業株式会社 | ルテニウム−ヨード−光学活性ホスフィン錯体の製法、およびこの錯体を用いた光学活性4−メチル−2−オキセタノンの製法 |
-
1996
- 1996-11-08 JP JP31121196A patent/JP3919268B2/ja not_active Expired - Fee Related
-
1997
- 1997-11-04 US US08/963,619 patent/US5981782A/en not_active Expired - Lifetime
- 1997-11-05 DE DE69718878T patent/DE69718878T2/de not_active Expired - Fee Related
- 1997-11-05 EP EP97308913A patent/EP0841343B1/de not_active Expired - Lifetime
-
1998
- 1998-06-22 US US09/100,755 patent/US5981771A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5981782A (en) | 1999-11-09 |
DE69718878T2 (de) | 2003-06-18 |
JP3919268B2 (ja) | 2007-05-23 |
EP0841343B1 (de) | 2003-02-05 |
JPH10139791A (ja) | 1998-05-26 |
US5981771A (en) | 1999-11-09 |
EP0841343A2 (de) | 1998-05-13 |
EP0841343A3 (de) | 1998-11-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |