DE69714830D1 - Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren - Google Patents

Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren

Info

Publication number
DE69714830D1
DE69714830D1 DE69714830T DE69714830T DE69714830D1 DE 69714830 D1 DE69714830 D1 DE 69714830D1 DE 69714830 T DE69714830 T DE 69714830T DE 69714830 T DE69714830 T DE 69714830T DE 69714830 D1 DE69714830 D1 DE 69714830D1
Authority
DE
Germany
Prior art keywords
olefin
polymerization catalysts
making
polymers
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69714830T
Other languages
English (en)
Other versions
DE69714830T2 (de
Inventor
Toshiyuki Kaneko
Akihiro Yano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Publication of DE69714830D1 publication Critical patent/DE69714830D1/de
Application granted granted Critical
Publication of DE69714830T2 publication Critical patent/DE69714830T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69714830T 1996-12-18 1997-12-17 Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren Expired - Lifetime DE69714830T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP33846296 1996-12-18
JP33846396 1996-12-18

Publications (2)

Publication Number Publication Date
DE69714830D1 true DE69714830D1 (de) 2002-09-26
DE69714830T2 DE69714830T2 (de) 2002-12-05

Family

ID=26576094

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69714830T Expired - Lifetime DE69714830T2 (de) 1996-12-18 1997-12-17 Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren

Country Status (3)

Country Link
US (1) US6110858A (de)
EP (1) EP0849292B1 (de)
DE (1) DE69714830T2 (de)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555633B1 (en) * 1999-01-21 2003-04-29 Idemitsu Petrochemical Co., Ltd. Catalysts for α-olefin production and processes for producing α-olefin
EP1136122A4 (de) * 1999-09-16 2002-08-07 Idemitsu Petrochemical Co Uebergangsmetallkatalysator und verfahren zur herstellung von alpha-olefin- und vinyl-polymeren
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) * 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6632911B1 (en) * 1999-11-05 2003-10-14 Japan Polychem Corporation Ethylene/α-olefin copolymer and film made thereof
JP4758589B2 (ja) * 2000-03-06 2011-08-31 出光興産株式会社 ビニル化合物重合用触媒及びビニル重合体の製造方法
EP1399491B1 (de) 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Geträgerte dualübergangsmetallkatalysatorsysteme
US6946420B2 (en) 2001-04-30 2005-09-20 W. R. Grace & Co.-Conn Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
EP1401887A1 (de) 2001-04-30 2004-03-31 W.R. Grace & Co.-Conn. Heterogene chromkatalysatoren und verfahren zur polymerisation von olefinen mit diesen katalysatoren
DE60236653D1 (de) 2001-04-30 2010-07-22 Grace W R & Co Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen
CN1182190C (zh) * 2001-09-27 2004-12-29 中国科学院长春应用化学研究所 原位聚合制备聚烯烃/无机组份纳米复合材料的方法
US6646072B2 (en) * 2002-01-23 2003-11-11 Equistar Chemicals, Lp Process for making polyolefin compositions containing exfoliated clay
US6602966B1 (en) 2002-07-11 2003-08-05 Equistar Chemicals, Lp In-reactor process for making ethylene polymer nanocomposite materials
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
JP5925100B2 (ja) * 2012-10-03 2016-05-25 本田技研工業株式会社 ポリプロピレン組成物の製造方法
US10676547B2 (en) 2015-08-31 2020-06-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins on clays
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
CN107922527A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
ES8604994A1 (es) * 1983-06-06 1986-02-16 Exxon Research Engineering Co Un procedimiento para preparar una mezcla de reactor de un polimero de etileno y al menos una alfa-olefina.
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
CA1338046C (en) * 1986-09-19 1996-02-06 Howard Curtis Welborn Jr. High pressure high temperature polymerization of ethylene
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
MY107639A (en) * 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
JP2807571B2 (ja) * 1990-04-18 1998-10-08 三井化学株式会社 オレフィン重合用固体触媒およびオレフィンの重合方法
JP2901698B2 (ja) * 1990-04-26 1999-06-07 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP2999217B2 (ja) * 1990-04-27 2000-01-17 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
JP3414769B2 (ja) * 1991-05-01 2003-06-09 日本ポリケム株式会社 オレフィン重合用触媒およびこれを用いたオレフィン重合体の製造方法
TW218884B (de) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5198512A (en) * 1991-12-16 1993-03-30 Phillips Petroleum Company Polymerization catalyst and process
JP3033452B2 (ja) * 1993-12-17 2000-04-17 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
DE69412047T2 (de) * 1993-12-17 1999-04-15 Tosoh Corp., Shinnanyo, Yamaguchi Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
JP3376091B2 (ja) * 1994-05-18 2003-02-10 三菱化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
EP0786466B1 (de) * 1996-01-25 2003-04-16 Tosoh Corporation Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators.
EP0791608B1 (de) * 1996-02-23 2000-05-10 Tosoh Corporation Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator
US5906955A (en) * 1996-12-20 1999-05-25 Tosoh Corporation Catalyst for polymerization of an olefin, and method for producing an olefin polymer

Also Published As

Publication number Publication date
EP0849292A1 (de) 1998-06-24
EP0849292B1 (de) 2002-08-21
US6110858A (en) 2000-08-29
DE69714830T2 (de) 2002-12-05

Similar Documents

Publication Publication Date Title
DE69714830D1 (de) Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren
DE69603811D1 (de) Träger für Olefinpolymerisationkatalysator, Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Olefinpolymeren
DE69633569D1 (de) Übergangsmetallkomplex enthaltender polymerisationskatalysator und verfahren zur herstellung von olefinpolymeren
DE69911128D1 (de) Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
DE69432779D1 (de) Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Polypropylen und Propylen-Blockcopolymeren
DE69520400D1 (de) Katalysator zur Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE69418742D1 (de) Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung derselben
DE69412047D1 (de) Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation
DE69426648D1 (de) Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation
DE69600892D1 (de) Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE69407094D1 (de) Katalysator und Verfahren zur Olefinpolymerisation
DE69419893D1 (de) Katalysator und Verfahren zur Olefinpolymerisation
DE69502561D1 (de) Katalysator zur Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE69409690D1 (de) Katalysatorbestandteil für Alpha-olefinpolymerisation und Verfahren zur Herstellung von Alpha-olefinpolymere unter Anwendung derselben
DE69611554D1 (de) Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
DE69500979D1 (de) Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben
DE69413904D1 (de) Olefinpolymerisationskatalysatoren und Methoden zur Olefinpolymerisation
DE69919102D1 (de) Metallocenkatalysatoren für Olefinpolymerisation, Verfahren zur Herstellung von Olefinpolymeren mit Metallocenkatalysatoren
DE69605372D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Katalysator für Olefinpolymerisation, und Verfahren zur Herstellung von Olefinpolymeren
DE69736631D1 (de) Verfahren zur herstellung von olefinpolymeren
DE69509458D1 (de) Olefinpolymerisationskatalysator und Verfahren zur Olefinpolymerisation
DE69502361D1 (de) Katalysatorbestandteil für Alpha-Olefinpolymerisation und Verfahren zur Herstellung von Alpha-Olefinpolymeren unter Anwendung desselben
DE69829423D1 (de) Modifizierte Teilchen, daraus hergestellter Träger, daraus hergestellte Polymerisationskatalysatorkomponente sowie Polymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
DE69225948D1 (de) Katalysator für Olefinpolymerisation und Verfahren zur Herstellung von Olefinpolymeren
DE69403928D1 (de) Katalysator und Verfahren zur Olefin-Polymerisation

Legal Events

Date Code Title Description
8364 No opposition during term of opposition