DE69629891T2 - Vielschichtige biozide filmzusammensetzungen - Google Patents
Vielschichtige biozide filmzusammensetzungen Download PDFInfo
- Publication number
- DE69629891T2 DE69629891T2 DE69629891T DE69629891T DE69629891T2 DE 69629891 T2 DE69629891 T2 DE 69629891T2 DE 69629891 T DE69629891 T DE 69629891T DE 69629891 T DE69629891 T DE 69629891T DE 69629891 T2 DE69629891 T2 DE 69629891T2
- Authority
- DE
- Germany
- Prior art keywords
- layer
- chlorine dioxide
- hydrophobic
- composite material
- hydrophilic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- BWMISRWJRUSYEX-SZKNIZGXSA-N terbinafine hydrochloride Chemical compound Cl.C1=CC=C2C(CN(C\C=C\C#CC(C)(C)C)C)=CC=CC2=C1 BWMISRWJRUSYEX-SZKNIZGXSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/704—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/788—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/14—Coating with a protective layer; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/16—Preserving with chemicals
- A23B9/24—Preserving with chemicals in the form of liquids or solids
- A23B9/30—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Materials For Medical Uses (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US461304 | 1995-06-05 | ||
| US08/461,304 US5705092A (en) | 1995-06-05 | 1995-06-05 | Multilayered biocidal film compositions |
| PCT/US1996/009199 WO1996039028A1 (en) | 1995-06-05 | 1996-06-04 | Multilayered biocidal film compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69629891D1 DE69629891D1 (de) | 2003-10-16 |
| DE69629891T2 true DE69629891T2 (de) | 2004-07-15 |
Family
ID=23832035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69629891T Expired - Fee Related DE69629891T2 (de) | 1995-06-05 | 1996-06-04 | Vielschichtige biozide filmzusammensetzungen |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5705092A (OSRAM) |
| EP (1) | EP0774897B1 (OSRAM) |
| JP (1) | JP3987108B2 (OSRAM) |
| KR (1) | KR100428229B1 (OSRAM) |
| AR (1) | AR003684A1 (OSRAM) |
| AU (1) | AU700406B2 (OSRAM) |
| BR (1) | BR9606419A (OSRAM) |
| CA (1) | CA2196781C (OSRAM) |
| DE (1) | DE69629891T2 (OSRAM) |
| MX (1) | MX9700956A (OSRAM) |
| MY (1) | MY115463A (OSRAM) |
| NZ (1) | NZ311875A (OSRAM) |
| TW (1) | TW371257B (OSRAM) |
| WO (1) | WO1996039028A1 (OSRAM) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2529927A2 (en) | 2007-07-20 | 2012-12-05 | Bayer Innovation Gmbh | Polymer composite material with biocide functionality |
| US8372417B2 (en) | 2007-07-20 | 2013-02-12 | Bayer Innovation Gmbh | Polymer composite film with barrier functionality |
| US8383549B2 (en) | 2007-07-20 | 2013-02-26 | Bayer Cropscience Lp | Methods of increasing crop yield and controlling the growth of weeds using a polymer composite film |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6585843B2 (en) * | 1992-01-10 | 2003-07-01 | Super Sack Mfg. Corp. | Anti-static, anti-corrosion, and/or anti-microbial films, fabrics, and articles |
| US6046243A (en) * | 1993-02-12 | 2000-04-04 | Bernard Technologies, Inc. | Compositions for sustained release of a gas |
| BR9606515A (pt) * | 1995-06-12 | 1998-12-15 | Bernard Technologies Inc | Composições biocidas transparentes de liberação contida |
| DE69732913T2 (de) * | 1996-09-18 | 2006-05-04 | Bernard Technologies, Inc., Chicago | Puder für die kontrollierte freisetzung eines gases |
| US6174508B1 (en) | 1997-02-11 | 2001-01-16 | Fred Klatte | Method of producing chlorine dioxide using sodium chlorite and a water-retaining substance impregnated in zeolite or in aqueous solution |
| AU1120399A (en) | 1997-11-07 | 1999-05-31 | Engelhard Corporation | Method and device for the production of an aqueous solution containing chlorine dioxide |
| US6605304B1 (en) | 1998-02-09 | 2003-08-12 | Bernard Technologies, Inc. | Silicate-containing powders providing controlled, sustained gas release |
| US6277408B1 (en) | 1998-02-09 | 2001-08-21 | Southwest Research Institute | Silicate-containing powders providing controlled, sustained gas release |
| AU6435399A (en) * | 1998-10-09 | 2000-05-01 | Dennis Charles Clemes | Chlorine dioxide generators |
| WO2000032052A1 (en) * | 1998-11-25 | 2000-06-08 | Raytec Corporation | Methods and systems for reducing microbial populations |
| US6039979A (en) * | 1999-01-13 | 2000-03-21 | Laboratoires Prographarm | Multiparticulate pharmaceutical form with programmed and pulsed release and process for its preparation |
| WO2000069775A1 (en) * | 1999-05-18 | 2000-11-23 | Southwest Research Institute | Energy-activated compositions for controlled sustained release of a gas |
| US7273567B1 (en) | 1999-11-24 | 2007-09-25 | Microactive Corp. | Energy-activated compositions for controlled sustained release of a gas |
| US6767509B1 (en) | 1999-06-16 | 2004-07-27 | Kimberly-Clark Worldwide, Inc. | Self-sterilizing packaging |
| BR0108486A (pt) * | 2000-02-18 | 2003-04-22 | Selective Micro Technologies L | Aparelho e método para liberação controlada de um gás |
| US6607696B1 (en) * | 2000-02-18 | 2003-08-19 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US7922984B2 (en) * | 2000-02-18 | 2011-04-12 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6764661B1 (en) | 2000-06-27 | 2004-07-20 | Avantec Technologies, Inc. | Device for producing an aqueous chlorine dioxide solution |
| WO2002058748A1 (en) * | 2001-01-26 | 2002-08-01 | Camelot Technologies Limited | Absorbent pad for rendering hazardous liquids non-hazardous |
| US6589591B1 (en) | 2001-07-10 | 2003-07-08 | Baylor College Of Medicine | Method for treating medical devices using glycerol and an antimicrobial agent |
| US7195744B2 (en) * | 2001-08-28 | 2007-03-27 | Ecolab, Inc. | Device for holding a container for a composition that produces an antimicrobially active gas |
| US6620380B2 (en) | 2001-09-14 | 2003-09-16 | Ecolab, Inc. | Method, device and composition for the sustained release of an antimicrobial gas |
| AU2002357279A1 (en) * | 2001-12-17 | 2003-06-30 | Selective Micro Technologies, Llc | Apparatus and methods for delivery of a gas |
| ATE525095T1 (de) * | 2002-01-08 | 2011-10-15 | Bernard Technologies Inc | Antimikrobielle körperbedeckungsartikel |
| US7150854B2 (en) * | 2002-03-19 | 2006-12-19 | Engelhard Corporation | Device for generating aqueous chlorine dioxide solutions |
| US20030190273A1 (en) * | 2002-04-09 | 2003-10-09 | Bernard Technologies, Inc. | Container liner for inhibiting decay of perishable items |
| JP2005523867A (ja) * | 2002-04-29 | 2005-08-11 | エスケー アクアテック カンパニー リミテッド | 二酸化塩素ガスの簡易発生装置 |
| US6619051B1 (en) | 2002-07-12 | 2003-09-16 | Ecolab Inc. | Integrated cleaning and sanitizing system and method for ice machines |
| US20040137039A1 (en) * | 2002-07-22 | 2004-07-15 | Trustees Of Stevens Institute Of Technology | Methods for controlled release of molecules from layered polymer films |
| US7922992B2 (en) * | 2002-09-13 | 2011-04-12 | Ica Trinova, Llc | Composition and method for producing carbon dioxide |
| GB0228870D0 (en) * | 2002-12-10 | 2003-01-15 | Ace Three Uk Ltd | Sulphur dioxide release coastings |
| US7285255B2 (en) * | 2002-12-10 | 2007-10-23 | Ecolab Inc. | Deodorizing and sanitizing employing a wicking device |
| US20040170671A1 (en) * | 2003-03-05 | 2004-09-02 | Jian Tao | Thin wall gloves that release chlorine dioxide |
| US20040256561A1 (en) * | 2003-06-17 | 2004-12-23 | Allyson Beuhler | Wide band light sensing pixel array |
| US7243788B2 (en) * | 2003-10-22 | 2007-07-17 | Kimberly-Clark Worldwide, Inc. | Package for segregating and mixing substances |
| US20060216496A2 (en) * | 2003-11-13 | 2006-09-28 | Bernard Technologies, Inc. | Gas Generating Polymers |
| US7238363B2 (en) * | 2004-04-02 | 2007-07-03 | Baylor College Of Medicine | Modification of medical prostheses |
| US9364579B2 (en) * | 2004-08-30 | 2016-06-14 | Southwest Research Institute | Biocidal fibrous and film materials utilizing silver ion |
| WO2006132653A2 (en) * | 2004-08-30 | 2006-12-14 | Southwest Research Institute | Biocidal fibrous and film materials comprising silver and chlorite ions |
| US20060178445A1 (en) * | 2004-12-16 | 2006-08-10 | Mcintyre Patrick F | Composition for controlled sustained release of a gas |
| JP4659827B2 (ja) | 2005-05-30 | 2011-03-30 | 株式会社カネカ | グラファイトフィルムの製造方法 |
| US8673297B2 (en) | 2006-02-28 | 2014-03-18 | Basf Corporation | Chlorine dioxide based cleaner/sanitizer |
| US20080131395A1 (en) * | 2006-11-27 | 2008-06-05 | Microactive Corp. | Controlled gas release from a melt processable compatible polymer blend |
| US8129327B2 (en) | 2006-12-01 | 2012-03-06 | The Procter & Gamble Company | Packaging for high moisture bar soap |
| US8741325B2 (en) * | 2008-12-18 | 2014-06-03 | The Hong Kong University Of Science And Technology | Material for forming a multi-level antimicrobial surface coating and its preparation |
| US20100183785A1 (en) * | 2009-01-21 | 2010-07-22 | Manuel Ii Zuniga | Method for doing business to retard bacterial, fungal, and viral contamination and mold growth in fruits |
| US9382116B2 (en) | 2013-01-10 | 2016-07-05 | Ica Trinova, Llc | Mixtures for producing chlorine dioxide gas in enclosures and methods of making the same |
| US9517934B2 (en) | 2013-03-14 | 2016-12-13 | The United States Of America As Represented By The Secretary Of The Army | Process for the generation of chlorine dioxide |
| WO2015130992A1 (en) * | 2014-02-28 | 2015-09-03 | Biovation Ii, Llc | Biocidal sachet for food safety |
| MX2018001846A (es) * | 2015-08-18 | 2018-09-18 | Wisconsin Alumni Res Found | Liberacion de gas de dioxido de cloro (c1o2) de la pelicula de empaque de dispositivos medicos. |
| US10988724B2 (en) | 2016-05-05 | 2021-04-27 | Southwest Research Institute | Three-dimensional bioreactor for cell expansion and related applications |
| US11149244B2 (en) | 2018-04-04 | 2021-10-19 | Southwest Research Institute | Three-dimensional bioreactor for T-cell activation and expansion for immunotherapy |
| CN108690625B (zh) * | 2018-04-28 | 2020-12-15 | 上海市环境科学研究院 | 一种用于处理土壤中持久性卤代烃的缓释复合修复药剂及其制备方法 |
| SG11202102986XA (en) | 2018-09-24 | 2021-04-29 | Southwest Res Inst | Three-dimensional bioreactors |
| US11492580B2 (en) | 2020-05-12 | 2022-11-08 | Southwest Research Institute | Method using a three-dimensional bioprocessor |
| WO2022093970A1 (en) | 2020-10-27 | 2022-05-05 | Selective Micro Technologies, Llc | Gas generation apparatus and method utilizing hydrophobic membrane pouch reactor |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2071625A (en) * | 1931-06-03 | 1937-02-23 | W E Long Co | Preservation of packaged food products |
| US2546568A (en) * | 1945-01-11 | 1951-03-27 | Olin Mathieson | Process for the preservation of comestible materials |
| US2482891A (en) * | 1945-03-16 | 1949-09-27 | Olin Mathieson | Solid, stable chlorine dioxide generating compositions |
| US2558942A (en) * | 1947-02-03 | 1951-07-03 | Eagleson Craig | Sanitizing composition |
| US3183057A (en) * | 1958-11-03 | 1965-05-11 | Wallace & Tiernan Inc | Products and procedures for effecting treatiment with chlorinous gas |
| US3591515A (en) * | 1968-04-16 | 1971-07-06 | Int Dioxide Inc | Pulverulent chlorine dioxide compositions |
| US3585147A (en) * | 1969-10-01 | 1971-06-15 | Int Dioxcide Inc | Stabilized chlorine dioxide solutions containing a chloride and processes of making and using same |
| US3767787A (en) * | 1971-10-07 | 1973-10-23 | H Segal | Retarded vaporization compositions and method for making |
| GB1579431A (en) * | 1976-03-23 | 1980-11-19 | Minnesota Mining & Mfg | Disinfecting and/or sterilising |
| US4330531A (en) * | 1976-03-26 | 1982-05-18 | Howard Alliger | Germ-killing materials |
| US4499077A (en) * | 1981-02-03 | 1985-02-12 | Stockel Richard F | Anti-microbial compositions and associated methods for preparing the same and for the disinfecting of various objects |
| JPS57198775A (en) * | 1981-06-01 | 1982-12-06 | Nasa:Kk | Molding material having deodorizing function, etc. |
| US4728498A (en) * | 1981-11-02 | 1988-03-01 | Alza Corporation | Process for disinfecting article with device dispensing chlorine donor and chlorine acceptor |
| US4681739A (en) * | 1982-10-19 | 1987-07-21 | The Scopas Technology Co., Inc. | Use of chlorine dioxide gas as a chemosterilizing agent |
| US4504442A (en) * | 1982-10-19 | 1985-03-12 | Scopas Technology Corporation | Use of chlorine dioxide gas as a chemosterilizing agent |
| JPS6092759A (ja) * | 1983-10-26 | 1985-05-24 | 土倉 満 | 合成樹脂素材の成型に係る物品に消臭浄化剤の含浸装置 |
| US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
| US4547381A (en) * | 1983-11-10 | 1985-10-15 | Rio Linda Chemical Co., Inc. | Dry compositions for the production of chlorine dioxide |
| US4533691A (en) * | 1983-12-12 | 1985-08-06 | Polysar Limited | Chlorine dioxide antimicrobial agent for latex |
| IN160430B (OSRAM) * | 1984-03-18 | 1987-07-11 | Alcide Corp | |
| US4986990A (en) * | 1984-03-21 | 1991-01-22 | Alcide Corporation | Disinfection method and composition therefor |
| US4585482A (en) * | 1984-05-25 | 1986-04-29 | Southern Research Institute | Long-acting biocidal compositions and method therefor |
| US4889654A (en) * | 1984-07-31 | 1989-12-26 | Rio Linda Chemical Company, Inc. | Aqueous foam disinfectant containing chlorine dixoide and preparation and use thereof |
| US4748904A (en) * | 1986-07-01 | 1988-06-07 | Razeto Andres V R | Chlorine generator for preservation of fruits and vegetables |
| US4891216A (en) * | 1987-04-14 | 1990-01-02 | Alcide Corporation | Disinfecting compositions and methods therefor |
| US4829129A (en) * | 1987-05-29 | 1989-05-09 | International Dioxcide, Inc. | Reaction product of polymer with chlorine dioxide |
| US4975109A (en) * | 1988-05-02 | 1990-12-04 | Lester Technologies Corp. | Microbiocidal combinations of materials and their use |
| US4956184A (en) * | 1988-05-06 | 1990-09-11 | Alcide Corporation | Topical treatment of genital herpes lesions |
| US4880638A (en) * | 1988-08-23 | 1989-11-14 | Bioxy International, Ltd. | Biocidal composition and method for disinfecting articles |
| US4925645A (en) * | 1988-10-05 | 1990-05-15 | Mason James A | Method of preparing a mixture of chlorine containing substances including chlorine dioxide |
| CN1023205C (zh) * | 1989-06-23 | 1993-12-22 | 栾和林 | 二氧化氯的制备方法及控制盒 |
| US5078908A (en) * | 1989-10-02 | 1992-01-07 | Allergan, Inc. | Methods for generating chlorine dioxide and compositions for disinfecting |
| US5126070A (en) * | 1989-10-20 | 1992-06-30 | The Drackett Company | Chlorine dioxide generator |
| US5387350A (en) * | 1989-11-20 | 1995-02-07 | George L. Williamson | Method and apparatus for treating and disinfecting infectious wastes |
| US5104660A (en) * | 1989-11-21 | 1992-04-14 | Bruce A. Barber | Method of preparing an antimicrobial wound dressing |
| JPH04164005A (ja) * | 1990-10-26 | 1992-06-09 | Takasugi Seiyaku Kk | 環境浄化組成物 |
| AU640053B2 (en) * | 1991-06-17 | 1993-08-12 | Rio Linda Chemical Co., Inc. | Generation of chlorine dioxide in a non-aqueous medium |
| US5252343A (en) * | 1992-03-20 | 1993-10-12 | Alcide Corporation | Method and composition for prevention and treatment of bacterial infections |
| IL102627A (en) * | 1992-07-23 | 1996-05-14 | Abic Ltd | Solid composition releasing chlorine dioxide |
| JPH06107971A (ja) * | 1992-09-25 | 1994-04-19 | Honny Chem Ind Co Ltd | 被覆用組成物 |
| ATE185681T1 (de) * | 1993-02-12 | 1999-11-15 | Southwest Res Inst | Polymere biozide zusammensetzung und verfahren zu ihrer herstellung |
| US5360609A (en) * | 1993-02-12 | 1994-11-01 | Southwest Research Institute | Chlorine dioxide generating polymer packaging films |
| US5631300A (en) * | 1993-02-12 | 1997-05-20 | Southwest Research Institute | Method of making a sustained release biocidal composition |
| EP0744895B1 (en) * | 1994-12-14 | 1999-08-04 | Alcide Corporation | Adherent disinfecting compositions and methods relating thereto |
-
1995
- 1995-06-05 US US08/461,304 patent/US5705092A/en not_active Expired - Lifetime
-
1996
- 1996-06-03 MY MYPI96002145A patent/MY115463A/en unknown
- 1996-06-04 BR BR9606419A patent/BR9606419A/pt unknown
- 1996-06-04 DE DE69629891T patent/DE69629891T2/de not_active Expired - Fee Related
- 1996-06-04 EP EP96922397A patent/EP0774897B1/en not_active Expired - Lifetime
- 1996-06-04 KR KR1019970700792A patent/KR100428229B1/ko not_active Expired - Fee Related
- 1996-06-04 CA CA002196781A patent/CA2196781C/en not_active Expired - Fee Related
- 1996-06-04 MX MX9700956A patent/MX9700956A/es unknown
- 1996-06-04 JP JP50157897A patent/JP3987108B2/ja not_active Expired - Lifetime
- 1996-06-04 AU AU63280/96A patent/AU700406B2/en not_active Ceased
- 1996-06-04 NZ NZ311875A patent/NZ311875A/en unknown
- 1996-06-04 WO PCT/US1996/009199 patent/WO1996039028A1/en not_active Ceased
- 1996-06-05 AR ARP960102937A patent/AR003684A1/es unknown
- 1996-07-23 TW TW085108997A patent/TW371257B/zh not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2529927A2 (en) | 2007-07-20 | 2012-12-05 | Bayer Innovation Gmbh | Polymer composite material with biocide functionality |
| US8372418B2 (en) | 2007-07-20 | 2013-02-12 | Bayer Innovation Gmbh | Polymer composite film with biocide functionality |
| US8372417B2 (en) | 2007-07-20 | 2013-02-12 | Bayer Innovation Gmbh | Polymer composite film with barrier functionality |
| US8383549B2 (en) | 2007-07-20 | 2013-02-26 | Bayer Cropscience Lp | Methods of increasing crop yield and controlling the growth of weeds using a polymer composite film |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0774897A1 (en) | 1997-05-28 |
| MY115463A (en) | 2003-06-30 |
| AR003684A1 (es) | 1998-09-09 |
| TW371257B (en) | 1999-10-01 |
| WO1996039028A1 (en) | 1996-12-12 |
| KR970704338A (ko) | 1997-09-06 |
| BR9606419A (pt) | 1997-09-30 |
| MX9700956A (es) | 1998-01-31 |
| EP0774897B1 (en) | 2003-09-10 |
| HK1013212A1 (en) | 1999-08-20 |
| KR100428229B1 (ko) | 2004-06-16 |
| AU6328096A (en) | 1996-12-24 |
| CA2196781C (en) | 2005-11-29 |
| EP0774897A4 (en) | 2000-08-09 |
| DE69629891D1 (de) | 2003-10-16 |
| JP3987108B2 (ja) | 2007-10-03 |
| AU700406B2 (en) | 1999-01-07 |
| CA2196781A1 (en) | 1996-12-12 |
| US5705092A (en) | 1998-01-06 |
| JPH11501938A (ja) | 1999-02-16 |
| NZ311875A (en) | 1998-11-25 |
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