DE69626133D1 - Hydroumwandlungsverfahren mit phosphor enthaltendem katalysator mit spezifischer porengrössenverteilung - Google Patents

Hydroumwandlungsverfahren mit phosphor enthaltendem katalysator mit spezifischer porengrössenverteilung

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Publication number
DE69626133D1
DE69626133D1 DE69626133T DE69626133T DE69626133D1 DE 69626133 D1 DE69626133 D1 DE 69626133D1 DE 69626133 T DE69626133 T DE 69626133T DE 69626133 T DE69626133 T DE 69626133T DE 69626133 D1 DE69626133 D1 DE 69626133D1
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DE
Germany
Prior art keywords
angstrom
volume
present
catalyst
micropores
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69626133T
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English (en)
Inventor
Edward Sherwood
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Texaco Development Corp
Original Assignee
Texaco Development Corp
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Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Application granted granted Critical
Publication of DE69626133D1 publication Critical patent/DE69626133D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/185Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/65150-500 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/69Pore distribution bimodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE69626133T 1995-08-24 1996-08-22 Hydroumwandlungsverfahren mit phosphor enthaltendem katalysator mit spezifischer porengrössenverteilung Expired - Lifetime DE69626133D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/518,773 US5968348A (en) 1994-05-16 1995-08-24 Hydroconversion process employing a phosphorus loaded NiMo catalyst with specified pore size distribution
PCT/IB1996/000828 WO1997008273A1 (en) 1995-08-24 1996-08-22 HYDROCONVERSION PROCESS EMPLOYING A PHOSPHORUS LOADED NiMoP CATALYST WITH A SPECIFIED PORE SIZE DISTRIBUTION

Publications (1)

Publication Number Publication Date
DE69626133D1 true DE69626133D1 (de) 2003-03-13

Family

ID=24065442

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69626133T Expired - Lifetime DE69626133D1 (de) 1995-08-24 1996-08-22 Hydroumwandlungsverfahren mit phosphor enthaltendem katalysator mit spezifischer porengrössenverteilung

Country Status (8)

Country Link
US (1) US5968348A (de)
EP (1) EP0876442B1 (de)
JP (1) JPH11515038A (de)
AT (1) ATE232231T1 (de)
CA (1) CA2228800C (de)
DE (1) DE69626133D1 (de)
PL (1) PL182661B1 (de)
WO (1) WO1997008273A1 (de)

Families Citing this family (22)

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Publication number Priority date Publication date Assignee Title
ES2227852T3 (es) 1997-06-24 2005-04-01 Process Dynamics, Inc. Hidroprocesado en dos fases.
US7569136B2 (en) 1997-06-24 2009-08-04 Ackerson Michael D Control system method and apparatus for two phase hydroprocessing
US7291257B2 (en) * 1997-06-24 2007-11-06 Process Dynamics, Inc. Two phase hydroprocessing
ATE296679T1 (de) * 1998-12-08 2005-06-15 Japan Energy Corp Katalysator zur hydrodesulforierung und verfahren zu seiner herstellung
FR2819430B1 (fr) * 2001-01-15 2003-02-28 Inst Francais Du Petrole Catalyseur comportant une silice-alumine et son utilisation en hydrocraquage de charges hydrocarbonees
US7074740B2 (en) * 2002-07-02 2006-07-11 Chevron U.S.A. Inc. Catalyst for conversion processes
JP4798685B2 (ja) * 2002-09-24 2011-10-19 Jx日鉱日石エネルギー株式会社 石油系重質油の脱金属方法
FR2846574B1 (fr) * 2002-10-30 2006-05-26 Inst Francais Du Petrole Catalyseur et procede d'hydrocraquage de charges hydrocarbonees
US8372268B2 (en) 2009-03-24 2013-02-12 Shell Oil Company High surface area composition for use in the catalytic hydroconversion of a heavy hydrocarbon feedstock, a method making such composition and its use
HRP20240945T1 (hr) 2010-12-30 2024-10-25 Chevron U.S.A. Inc. Katalizatori za hidropreradu i postupci njihove priprave
US9096804B2 (en) 2011-01-19 2015-08-04 P.D. Technology Development, Llc Process for hydroprocessing of non-petroleum feedstocks
WO2013032628A1 (en) * 2011-09-01 2013-03-07 Advanced Refining Technologies Llc Catalyst support and catalysts prepared therefrom
EP3074486B1 (de) * 2013-11-25 2018-06-27 Shell International Research Maatschappij B.V. Verfahren zur katalytischen umwandlung von mikrokohlenstoffresten von schweren kohlenwasserstoffeinsätzen und katalysatorzusammensetzung mit niedrigem oberflächenbereich zur verwendung darin
FR3022159B1 (fr) 2014-06-13 2018-04-27 IFP Energies Nouvelles Catalyseur mesoporeux et macroporeux d'hydroconversion de residus et methode de preparation
FR3022157B1 (fr) 2014-06-13 2017-09-01 Ifp Energies Now Catalyseur bimodal a phase active comalaxee, son procede de preparation et son utilisation en hydrotraitement de residus
FR3022156B1 (fr) 2014-06-13 2018-02-23 Ifp Energies Now Catalyseur mesoporeux et macroporeux a phase active comalaxee, son procede de preparation et son utilisation en hydrotraitement de residus
FR3022158B1 (fr) 2014-06-13 2018-02-23 IFP Energies Nouvelles Catalyseur mesoporeux d'hydroconversion de residus et methode de preparation
CN107511178B (zh) * 2016-06-15 2020-08-18 中国石油化工股份有限公司 一种改性氧化铝载体及制备方法和一种加氢催化剂及制备方法和应用
US9956553B2 (en) * 2016-06-28 2018-05-01 Chevron U.S.A. Inc. Regeneration of an ionic liquid catalyst by hydrogenation using a macroporous noble metal catalyst
CN116440918B (zh) * 2022-01-06 2024-10-15 中国石油化工股份有限公司 加氢催化剂级配方法及其应用
WO2023137350A1 (en) 2022-01-13 2023-07-20 Chevron U.S.A. Inc. Improved ebullated bed reactor and process
WO2023154077A1 (en) 2022-02-14 2023-08-17 Chevron U.S.A. Inc. Metals recovery from spent supported catalyst

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GB1550684A (en) * 1975-08-28 1979-08-15 Mobil Oil Corp Demetalation-desulphurisation catalyst and the preparation and use thereof
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US4357263A (en) * 1979-10-22 1982-11-02 Mobil Oil Corporation Catalyst for the upgrading of aromatic liquids
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Also Published As

Publication number Publication date
MX9802265A (es) 1998-08-30
PL182661B1 (pl) 2002-02-28
US5968348A (en) 1999-10-19
CA2228800C (en) 2002-12-24
CA2228800A1 (en) 1997-03-06
EP0876442A1 (de) 1998-11-11
WO1997008273A1 (en) 1997-03-06
JPH11515038A (ja) 1999-12-21
EP0876442B1 (de) 2003-02-05
PL325159A1 (en) 1998-07-06
ATE232231T1 (de) 2003-02-15

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