DE69423353T2 - Wasserfrei selbstemulgierbare biologisch abbaubare chemische weichmachende zusammensetzung anwendbar in faserigen zellulosematerialien - Google Patents
Wasserfrei selbstemulgierbare biologisch abbaubare chemische weichmachende zusammensetzung anwendbar in faserigen zellulosematerialienInfo
- Publication number
- DE69423353T2 DE69423353T2 DE69423353T DE69423353T DE69423353T2 DE 69423353 T2 DE69423353 T2 DE 69423353T2 DE 69423353 T DE69423353 T DE 69423353T DE 69423353 T DE69423353 T DE 69423353T DE 69423353 T2 DE69423353 T2 DE 69423353T2
- Authority
- DE
- Germany
- Prior art keywords
- ester
- quaternary ammonium
- compound
- functional quaternary
- diester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 143
- 239000000126 substance Substances 0.000 title claims abstract description 96
- 239000000463 material Substances 0.000 title abstract description 32
- 229920002678 cellulose Polymers 0.000 title description 4
- 239000001913 cellulose Substances 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 68
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 53
- 239000003760 tallow Substances 0.000 claims abstract description 46
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 39
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims abstract description 35
- 150000005690 diesters Chemical class 0.000 claims abstract description 34
- -1 polyoxyethylene Polymers 0.000 claims abstract description 28
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims abstract description 16
- 150000002334 glycols Chemical class 0.000 claims abstract description 9
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 61
- 230000008569 process Effects 0.000 claims description 29
- 235000011187 glycerol Nutrition 0.000 claims description 17
- 150000002148 esters Chemical class 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 125000001424 substituent group Chemical group 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- 239000008240 homogeneous mixture Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 6
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- PGZPBNJYTNQMAX-UHFFFAOYSA-N dimethylazanium;methyl sulfate Chemical compound C[NH2+]C.COS([O-])(=O)=O PGZPBNJYTNQMAX-UHFFFAOYSA-N 0.000 claims description 5
- 239000004973 liquid crystal related substance Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 33
- 239000006185 dispersion Substances 0.000 abstract description 30
- 239000012530 fluid Substances 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 4
- 229920000223 polyglycerol Polymers 0.000 abstract description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 126
- 239000000835 fiber Substances 0.000 description 63
- 229920005989 resin Polymers 0.000 description 45
- 239000011347 resin Substances 0.000 description 45
- 239000000047 product Substances 0.000 description 30
- 239000002002 slurry Substances 0.000 description 24
- 239000002245 particle Substances 0.000 description 22
- 241000219927 Eucalyptus Species 0.000 description 15
- 230000002745 absorbent Effects 0.000 description 15
- 239000002250 absorbent Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000001179 sorption measurement Methods 0.000 description 13
- 238000001035 drying Methods 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 238000003825 pressing Methods 0.000 description 9
- 238000009736 wetting Methods 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 229920001131 Pulp (paper) Polymers 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000004049 embossing Methods 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000001143 conditioned effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 230000000717 retained effect Effects 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 238000011020 pilot scale process Methods 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 229930182470 glycoside Natural products 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000003113 dilution method Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- NARVIWMVBMUEOG-UHFFFAOYSA-N 2-Hydroxy-propylene Natural products CC(O)=C NARVIWMVBMUEOG-UHFFFAOYSA-N 0.000 description 1
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- RSRUVVHEPPGEOF-UHFFFAOYSA-N 2-chloro-4,4-dimethoxy-n-methylbutanamide Chemical compound CNC(=O)C(Cl)CC(OC)OC RSRUVVHEPPGEOF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JNQYNXFGVRUFNP-JGVFFNPUSA-N 4-amino-1-[(2r,5s)-5-(hydroxymethyl)oxolan-2-yl]-5-methylpyrimidin-2-one Chemical compound O=C1N=C(N)C(C)=CN1[C@@H]1O[C@H](CO)CC1 JNQYNXFGVRUFNP-JGVFFNPUSA-N 0.000 description 1
- MQOKYEROIFEEBH-UHFFFAOYSA-N 5-methyl-6-phenylphenanthridin-5-ium-3,8-diamine;bromide Chemical compound [Br-].C12=CC(N)=CC=C2C2=CC=C(N)C=C2[N+](C)=C1C1=CC=CC=C1 MQOKYEROIFEEBH-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Chemical group 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- IIDJRNMFWXDHID-UHFFFAOYSA-N Risedronic acid Chemical compound OP(=O)(O)C(P(O)(O)=O)(O)CC1=CC=CN=C1 IIDJRNMFWXDHID-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003868 ammonium compounds Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- HONIICLYMWZJFZ-UHFFFAOYSA-N azetidine Chemical group C1CNC1 HONIICLYMWZJFZ-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- AKDNDOBRFDICST-UHFFFAOYSA-N methylazanium;methyl sulfate Chemical compound [NH3+]C.COS([O-])(=O)=O AKDNDOBRFDICST-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- HVLUSYMLLVVXGI-USGGBSEESA-M trimethyl-[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C HVLUSYMLLVVXGI-USGGBSEESA-M 0.000 description 1
- 239000002676 xenobiotic agent Substances 0.000 description 1
- 230000002034 xenobiotic effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
Landscapes
- Paper (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7229793A | 1993-06-03 | 1993-06-03 | |
| PCT/US1994/005778 WO1994029521A1 (en) | 1993-06-03 | 1994-05-23 | Waterless self-emulsifiable biodegradable chemical softening composition useful in fibrous cellulosic materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69423353D1 DE69423353D1 (de) | 2000-04-13 |
| DE69423353T2 true DE69423353T2 (de) | 2000-10-12 |
Family
ID=22106731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69423353T Expired - Lifetime DE69423353T2 (de) | 1993-06-03 | 1994-05-23 | Wasserfrei selbstemulgierbare biologisch abbaubare chemische weichmachende zusammensetzung anwendbar in faserigen zellulosematerialien |
Country Status (25)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5538595A (en) * | 1995-05-17 | 1996-07-23 | The Proctor & Gamble Company | Chemically softened tissue paper products containing a ploysiloxane and an ester-functional ammonium compound |
| DE19711452A1 (de) | 1997-03-19 | 1998-09-24 | Sca Hygiene Paper Gmbh | Feuchtigkeitsregulatoren enthaltende Zusammensetzung für Tissueprodukte, Verfahren zur Herstellung dieser Produkte, Verwendung der Zusammensetzung für die Behandlung von Tissueprodukten sowie Tissueprodukte in Form von wetlaid einschließlich TAD oder Airlaid (non-woven) auf Basis überwiegend Cellulosefasern enthaltender flächiger Trägermaterialien |
| CA2346658C (en) * | 1998-10-15 | 2005-12-06 | The Procter & Gamble Company | Process for making soft tissue paper |
| US6607637B1 (en) * | 1998-10-15 | 2003-08-19 | The Procter & Gamble Company | Soft tissue paper having a softening composition containing bilayer disrupter deposited thereon |
| CA3067388C (en) | 2019-01-11 | 2022-09-06 | The Procter & Gamble Company | Quaternary ammonium compound compositions and methods for making and using same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5217576A (en) * | 1991-11-01 | 1993-06-08 | Dean Van Phan | Soft absorbent tissue paper with high temporary wet strength |
| US5223096A (en) * | 1991-11-01 | 1993-06-29 | Procter & Gamble Company | Soft absorbent tissue paper with high permanent wet strength |
| US5262007A (en) * | 1992-04-09 | 1993-11-16 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a temporary wet strength resin |
| US5264082A (en) * | 1992-04-09 | 1993-11-23 | Procter & Gamble Company | Soft absorbent tissue paper containing a biodegradable quaternized amine-ester softening compound and a permanent wet strength resin |
| US5240562A (en) | 1992-10-27 | 1993-08-31 | Procter & Gamble Company | Paper products containing a chemical softening composition |
| CZ321395A3 (en) | 1993-06-03 | 1996-07-17 | Procter & Gamble | Substantially anhydrous self-emulsifiable chemical softening agent and water dispersion containing thereof |
-
1994
- 1994-05-23 DK DK94920030T patent/DK0702736T3/da active
- 1994-05-23 JP JP50183695A patent/JP3428650B2/ja not_active Expired - Fee Related
- 1994-05-23 CZ CZ953212A patent/CZ321295A3/cs unknown
- 1994-05-23 DE DE69423353T patent/DE69423353T2/de not_active Expired - Lifetime
- 1994-05-23 BR BR9406786A patent/BR9406786A/pt not_active IP Right Cessation
- 1994-05-23 PT PT94920030T patent/PT702736E/pt unknown
- 1994-05-23 EP EP94920030A patent/EP0702736B1/en not_active Expired - Lifetime
- 1994-05-23 CA CA002162850A patent/CA2162850A1/en not_active Abandoned
- 1994-05-23 AU AU70958/94A patent/AU694739B2/en not_active Ceased
- 1994-05-23 KR KR1019950705461A patent/KR100336445B1/ko not_active Expired - Fee Related
- 1994-05-23 NZ NZ268169A patent/NZ268169A/en unknown
- 1994-05-23 ES ES94920030T patent/ES2142947T3/es not_active Expired - Lifetime
- 1994-05-23 AT AT94920030T patent/ATE190369T1/de not_active IP Right Cessation
- 1994-05-23 WO PCT/US1994/005778 patent/WO1994029521A1/en not_active Application Discontinuation
- 1994-05-23 HU HU9503465A patent/HUT74117A/hu unknown
- 1994-05-23 SG SG1996008286A patent/SG66293A1/en unknown
- 1994-05-27 PH PH48356A patent/PH31546A/en unknown
- 1994-06-01 TR TR00519/94A patent/TR27810A/xx unknown
- 1994-06-02 EG EG32694A patent/EG20526A/xx active
- 1994-06-03 PE PE1994243858A patent/PE53794A1/es not_active Application Discontinuation
- 1994-06-03 MY MYPI94001414A patent/MY111105A/en unknown
- 1994-06-21 TW TW083105619A patent/TW251324B/zh active
-
1995
- 1995-11-30 NO NO954869A patent/NO954869L/no unknown
- 1995-12-01 FI FI955790A patent/FI955790A7/fi unknown
-
2000
- 2000-03-09 GR GR20000400337T patent/GR3032823T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO954869L (no) | 1996-02-02 |
| ATE190369T1 (de) | 2000-03-15 |
| MY111105A (en) | 1999-08-30 |
| DK0702736T3 (da) | 2000-06-05 |
| PE53794A1 (es) | 1995-01-02 |
| TW251324B (enrdf_load_stackoverflow) | 1995-07-11 |
| SG66293A1 (en) | 1999-07-20 |
| ES2142947T3 (es) | 2000-05-01 |
| KR100336445B1 (ko) | 2002-10-04 |
| GR3032823T3 (en) | 2000-06-30 |
| HUT74117A (en) | 1996-11-28 |
| JP3428650B2 (ja) | 2003-07-22 |
| HK1016022A1 (en) | 1999-10-22 |
| JPH08511069A (ja) | 1996-11-19 |
| EP0702736B1 (en) | 2000-03-08 |
| FI955790A7 (fi) | 1996-01-23 |
| PH31546A (en) | 1998-11-03 |
| NZ268169A (en) | 1997-11-24 |
| CZ321295A3 (en) | 1996-07-17 |
| EG20526A (en) | 1999-06-30 |
| NO954869D0 (no) | 1995-11-30 |
| EP0702736A1 (en) | 1996-03-27 |
| DE69423353D1 (de) | 2000-04-13 |
| AU694739B2 (en) | 1998-07-30 |
| KR960702878A (ko) | 1996-05-23 |
| BR9406786A (pt) | 1996-01-30 |
| TR27810A (tr) | 1995-08-29 |
| PT702736E (pt) | 2000-08-31 |
| AU7095894A (en) | 1995-01-03 |
| WO1994029521A1 (en) | 1994-12-22 |
| FI955790A0 (fi) | 1995-12-01 |
| CA2162850A1 (en) | 1994-12-22 |
| HU9503465D0 (en) | 1996-01-29 |
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| 8364 | No opposition during term of opposition |